CN100349839C - 从合成气合成甲醇/二甲醚混合物的方法 - Google Patents
从合成气合成甲醇/二甲醚混合物的方法 Download PDFInfo
- Publication number
- CN100349839C CN100349839C CNB001018833A CN00101883A CN100349839C CN 100349839 C CN100349839 C CN 100349839C CN B001018833 A CNB001018833 A CN B001018833A CN 00101883 A CN00101883 A CN 00101883A CN 100349839 C CN100349839 C CN 100349839C
- Authority
- CN
- China
- Prior art keywords
- methanol
- synthesis gas
- gas stream
- dme
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 222
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 17
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 42
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 39
- 230000008569 process Effects 0.000 claims abstract description 7
- 239000003054 catalyst Substances 0.000 claims description 40
- 238000006297 dehydration reaction Methods 0.000 claims description 21
- 230000018044 dehydration Effects 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 2
- 239000006069 physical mixture Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 description 27
- 239000000047 product Substances 0.000 description 25
- 238000001816 cooling Methods 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 230000000694 effects Effects 0.000 description 8
- 230000002194 synthesizing effect Effects 0.000 description 7
- 230000009466 transformation Effects 0.000 description 5
- 238000010189 synthetic method Methods 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- BVOBEKTUNHUKRO-UHFFFAOYSA-N 1,2-dimethoxyethane;methanol Chemical compound OC.COCCOC BVOBEKTUNHUKRO-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 235000019628 coolness Nutrition 0.000 description 1
- 239000012043 crude product Substances 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA199900132 | 1999-02-02 | ||
| DK199900132A DK173614B1 (da) | 1999-02-02 | 1999-02-02 | Fremgangsmåde til fremstilling af methanol/dimethyletherblanding fra syntesegas |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1270157A CN1270157A (zh) | 2000-10-18 |
| CN100349839C true CN100349839C (zh) | 2007-11-21 |
Family
ID=8090111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB001018833A Expired - Lifetime CN100349839C (zh) | 1999-02-02 | 2000-02-02 | 从合成气合成甲醇/二甲醚混合物的方法 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6191175B1 (enExample) |
| EP (1) | EP1026141B1 (enExample) |
| JP (1) | JP4545855B2 (enExample) |
| KR (1) | KR100392930B1 (enExample) |
| CN (1) | CN100349839C (enExample) |
| AT (1) | ATE243180T1 (enExample) |
| AU (1) | AU766364B2 (enExample) |
| BR (1) | BR0000228A (enExample) |
| CA (1) | CA2297548A1 (enExample) |
| DE (1) | DE60003346T2 (enExample) |
| DK (1) | DK173614B1 (enExample) |
| ES (1) | ES2200734T3 (enExample) |
| NO (1) | NO315155B1 (enExample) |
| ZA (1) | ZA200000433B (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6608114B1 (en) * | 2002-03-13 | 2003-08-19 | Air Products And Chemicals, Inc. | Process to produce DME |
| WO2006033025A1 (en) * | 2004-02-05 | 2006-03-30 | Sasol Technology (Proprietary) Limited | Hydrocarbon synthesis |
| RU2277528C1 (ru) * | 2005-01-25 | 2006-06-10 | Михаил Хаймович Сосна | Способ производства диметилового эфира |
| WO2007014487A1 (en) * | 2005-08-01 | 2007-02-08 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | An integrated process for the co-production of methanol and demethyl ether from syngas containing nitrogen |
| DK2404888T3 (en) | 2006-05-30 | 2017-02-06 | Starchem Tech Inc | METHOD OF PREPARING METHANOL |
| US20080260631A1 (en) * | 2007-04-18 | 2008-10-23 | H2Gen Innovations, Inc. | Hydrogen production process |
| DE102007040707B4 (de) * | 2007-08-29 | 2012-05-16 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung von Methanol |
| EA020700B1 (ru) | 2008-12-17 | 2015-01-30 | Сауди Бейсик Индастриз Корпорейшн | Способ увеличения содержания монооксида углерода в синтез-газе |
| JP5311345B2 (ja) * | 2009-03-12 | 2013-10-09 | Jx日鉱日石エネルギー株式会社 | 含酸素化合物の製造方法 |
| DE102009046790B9 (de) | 2009-11-17 | 2013-05-08 | Chemieanlagenbau Chemnitz Gmbh | Verfahren zur Erzeugung von Kohlenwasserstoffen, insbesondere Benzin, aus Synthesegas |
| EP2450100A1 (en) | 2010-10-22 | 2012-05-09 | Methanol Casale S.A. | Process and plant for the production of methanol with isothermal catalytic beds |
| US9393555B2 (en) | 2012-02-15 | 2016-07-19 | Basf Se | Catalytically active body for the synthesis of dimethyl ether from synthesis gas |
| US9610568B2 (en) | 2012-02-15 | 2017-04-04 | Basf Se | Catalytically active body for the synthesis of dimethyl ether from synthesis gas |
| CN104245126A (zh) | 2012-04-24 | 2014-12-24 | 巴斯夫欧洲公司 | 用于由合成气合成二甲醚的催化活性体 |
| EP2898943B1 (de) * | 2014-01-28 | 2016-11-16 | Linde Aktiengesellschaft | Verfahren und Anlage zur Gewinnung von Dimethylether aus Synthesegas |
| EP2913320A1 (de) * | 2014-02-27 | 2015-09-02 | Linde Aktiengesellschaft | Verfahren und Anlage zur Gewinnung von Oxygenaten mit kontinuierlichem Wärmetausch zwischen Einsatzstrom und Rohproduktstrom |
| WO2018004994A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Fluidized bed membrane reactor |
| WO2018004993A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Reduction of greenhouse gas emission |
| WO2018004992A1 (en) | 2016-07-01 | 2018-01-04 | Res Usa, Llc | Conversion of methane to dimethyl ether |
| EP4110748A4 (en) * | 2020-02-27 | 2024-05-29 | Amol Carbons Private Limited | PROCESS FOR THE SYNTHESIS OF DIMETHYL ETHER |
| US12098122B2 (en) | 2021-03-19 | 2024-09-24 | Saudi Arabian Oil Company | Production of acetic acid through cryogenic separation of syngas |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4590176A (en) * | 1984-06-05 | 1986-05-20 | Shell Oil Company | Catalyst for dimethyl ether synthesis and a process for its preparation |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE291937C (enExample) | ||||
| IT972655B (it) | 1972-12-20 | 1974-05-31 | Snam Progetti | Procedimento per la produzione di dimetil etere |
| US4098809A (en) | 1972-12-20 | 1978-07-04 | Snamprogetti S.P.A. | Process for the production of dimethyl ether |
| IT1065295B (it) | 1976-12-23 | 1985-02-25 | Snam Progetti | Processo per la produzione di dimetil etere e catalizzatore utilizzabile in detto processo |
| NZ199035A (en) | 1981-02-20 | 1984-09-28 | Mobil Oil Corp | Catalyst of co-precipitated cu,zu and a1 components:conversion of syngas into dimethyl ether |
| GB2097383B (en) | 1981-04-28 | 1985-06-12 | Great Lakes Chemical Corp | Perbromination of phenol and diphenyl ether |
| DE3118620A1 (de) | 1981-05-11 | 1982-11-25 | Mobil Oil Corp., 10017 New York, N.Y. | Verfahren zum umwandeln von synthesegas in dimethylaether |
| IT1137176B (it) | 1981-06-02 | 1986-09-03 | Anic Spa | Procedimento per la produzione di dimetiletere |
| US4375424A (en) | 1981-10-21 | 1983-03-01 | Shell Oil Company | Catalyst for the preparation of dimethyl ether |
| US4417000A (en) | 1982-08-04 | 1983-11-22 | Shell Oil Company | Dimethyl ether process |
| DE3540457A1 (de) * | 1985-11-14 | 1987-05-21 | Linde Ag | Verfahren und reaktor zur methanolsynthese |
| US4857667A (en) * | 1987-04-29 | 1989-08-15 | Mobil Oil Corporation | System for conversion of crude oxygenate to gasoline with feedstock extraction |
| ATE83475T1 (de) | 1988-05-04 | 1993-01-15 | Rwe Dea Ag | Verbessertes verfahren zur herstellung von reinem dimethylether. |
| DE3817816A1 (de) * | 1988-05-26 | 1989-11-30 | Union Rheinische Braunkohlen | Verfahren zur herstellung von dimethylether |
| AU5902490A (en) | 1989-07-18 | 1991-08-01 | Air Products And Chemicals Inc. | One-step liquid phase process for dimethyl ether synthesis |
| US5254596A (en) | 1992-09-15 | 1993-10-19 | Eastman Kodak Company | Process for the manufacture of methanol and dimethyl ether |
| DK171707B1 (da) * | 1995-02-03 | 1997-04-01 | Topsoe Haldor As | Fremgangsmåde til fremstilling af dimetylæter i brændstofkvalitet |
-
1999
- 1999-02-02 DK DK199900132A patent/DK173614B1/da not_active IP Right Cessation
- 1999-11-09 JP JP31873999A patent/JP4545855B2/ja not_active Expired - Lifetime
-
2000
- 2000-01-11 AT AT00100167T patent/ATE243180T1/de not_active IP Right Cessation
- 2000-01-11 EP EP00100167A patent/EP1026141B1/en not_active Expired - Lifetime
- 2000-01-11 ES ES00100167T patent/ES2200734T3/es not_active Expired - Lifetime
- 2000-01-11 DE DE60003346T patent/DE60003346T2/de not_active Expired - Lifetime
- 2000-01-25 US US09/491,208 patent/US6191175B1/en not_active Expired - Lifetime
- 2000-01-31 BR BR0000228-3A patent/BR0000228A/pt not_active Application Discontinuation
- 2000-01-31 KR KR10-2000-0004693A patent/KR100392930B1/ko not_active Expired - Fee Related
- 2000-02-01 ZA ZA200000433A patent/ZA200000433B/xx unknown
- 2000-02-01 NO NO20000511A patent/NO315155B1/no not_active IP Right Cessation
- 2000-02-01 CA CA002297548A patent/CA2297548A1/en not_active Abandoned
- 2000-02-01 AU AU14839/00A patent/AU766364B2/en not_active Expired
- 2000-02-02 CN CNB001018833A patent/CN100349839C/zh not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4590176A (en) * | 1984-06-05 | 1986-05-20 | Shell Oil Company | Catalyst for dimethyl ether synthesis and a process for its preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| AU766364B2 (en) | 2003-10-16 |
| ZA200000433B (en) | 2000-09-06 |
| NO20000511L (no) | 2000-08-03 |
| ATE243180T1 (de) | 2003-07-15 |
| EP1026141B1 (en) | 2003-06-18 |
| CN1270157A (zh) | 2000-10-18 |
| DK173614B1 (da) | 2001-04-30 |
| NO20000511D0 (no) | 2000-02-01 |
| DK199900132A (da) | 2000-08-03 |
| KR100392930B1 (ko) | 2003-07-28 |
| NO315155B1 (no) | 2003-07-21 |
| ES2200734T3 (es) | 2004-03-16 |
| AU1483900A (en) | 2000-08-31 |
| KR20000076574A (ko) | 2000-12-26 |
| DE60003346T2 (de) | 2003-12-04 |
| CA2297548A1 (en) | 2000-08-02 |
| EP1026141A1 (en) | 2000-08-09 |
| US6191175B1 (en) | 2001-02-20 |
| JP4545855B2 (ja) | 2010-09-15 |
| BR0000228A (pt) | 2001-08-21 |
| JP2000226348A (ja) | 2000-08-15 |
| DE60003346D1 (de) | 2003-07-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20071121 |
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| CX01 | Expiry of patent term |