CN100338275C - 适合于纺粘非织造织物的聚丙烯纤维 - Google Patents
适合于纺粘非织造织物的聚丙烯纤维 Download PDFInfo
- Publication number
- CN100338275C CN100338275C CNB038229293A CN03822929A CN100338275C CN 100338275 C CN100338275 C CN 100338275C CN B038229293 A CNB038229293 A CN B038229293A CN 03822929 A CN03822929 A CN 03822929A CN 100338275 C CN100338275 C CN 100338275C
- Authority
- CN
- China
- Prior art keywords
- weight
- copolymer
- polymer
- ethene
- mfr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 21
- 239000004745 nonwoven fabric Substances 0.000 title claims abstract description 13
- -1 Polypropylene Polymers 0.000 title description 22
- 239000004743 Polypropylene Substances 0.000 title description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 151
- 239000000203 mixture Substances 0.000 claims abstract description 141
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 75
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 61
- 239000000835 fiber Substances 0.000 claims abstract description 46
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 42
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 39
- 229920005604 random copolymer Polymers 0.000 claims abstract description 26
- 239000002243 precursor Substances 0.000 claims abstract description 25
- 239000005977 Ethylene Substances 0.000 claims abstract description 20
- 238000002144 chemical decomposition reaction Methods 0.000 claims abstract description 19
- 229920001577 copolymer Polymers 0.000 claims description 50
- 239000004711 α-olefin Substances 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229920001519 homopolymer Polymers 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- 229920001384 propylene homopolymer Polymers 0.000 claims description 8
- 238000002425 crystallisation Methods 0.000 claims description 6
- 230000008025 crystallization Effects 0.000 claims description 6
- 230000003252 repetitive effect Effects 0.000 claims description 5
- 238000006731 degradation reaction Methods 0.000 claims description 4
- 230000015556 catabolic process Effects 0.000 claims description 3
- 238000010828 elution Methods 0.000 claims description 3
- 238000005194 fractionation Methods 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 230000000593 degrading effect Effects 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 238000002074 melt spinning Methods 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 46
- 238000002844 melting Methods 0.000 abstract description 4
- 230000008018 melting Effects 0.000 abstract description 4
- 229920005606 polypropylene copolymer Polymers 0.000 abstract description 4
- 239000008096 xylene Substances 0.000 abstract description 4
- 238000009987 spinning Methods 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 15
- 239000007789 gas Substances 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 10
- 229910052749 magnesium Inorganic materials 0.000 description 10
- 239000011777 magnesium Substances 0.000 description 10
- 150000002978 peroxides Chemical class 0.000 description 10
- 239000011949 solid catalyst Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 238000003490 calendering Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000012545 processing Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 229920000297 Rayon Polymers 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 125000000753 cycloalkyl group Chemical group 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 125000003710 aryl alkyl group Chemical group 0.000 description 5
- 230000000379 polymerizing effect Effects 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 4
- 230000004927 fusion Effects 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000002083 X-ray spectrum Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 238000004049 embossing Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- NOSXUFXBUISMPR-UHFFFAOYSA-N 1-tert-butylperoxyhexane Chemical compound CCCCCCOOC(C)(C)C NOSXUFXBUISMPR-UHFFFAOYSA-N 0.000 description 2
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004831 Hot glue Substances 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 238000005243 fluidization Methods 0.000 description 2
- 238000012685 gas phase polymerization Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 150000008301 phosphite esters Chemical class 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000003003 spiro group Chemical group 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical group COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- IJBYVSUZCRXTOD-UHFFFAOYSA-N 1-methoxy-9h-fluorene Chemical class C1C2=CC=CC=C2C2=C1C(OC)=CC=C2 IJBYVSUZCRXTOD-UHFFFAOYSA-N 0.000 description 1
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 1
- 125000006176 2-ethylbutyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(C([H])([H])*)C([H])([H])C([H])([H])[H] 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- WNVMVIYFKFGESM-UHFFFAOYSA-N bis(2-methylpropyl) 2,3-di(propan-2-yl)butanedioate Chemical compound CC(C)COC(=O)C(C(C)C)C(C(C)C)C(=O)OCC(C)C WNVMVIYFKFGESM-UHFFFAOYSA-N 0.000 description 1
- VPCAAUUIFCAFRZ-UHFFFAOYSA-N butylalumane Chemical compound CCCC[AlH2] VPCAAUUIFCAFRZ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
- YCYHZGIPKZHEEL-UHFFFAOYSA-N diethyl 2,3-bis(2,2-dimethylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)(C)C)C(CC(C)(C)C)C(=O)OCC YCYHZGIPKZHEEL-UHFFFAOYSA-N 0.000 description 1
- AVLHXEDOBYYTGV-UHFFFAOYSA-N diethyl 2,3-bis(2-methylpropyl)butanedioate Chemical compound CCOC(=O)C(CC(C)C)C(CC(C)C)C(=O)OCC AVLHXEDOBYYTGV-UHFFFAOYSA-N 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- UIZHEHICSUOPQL-UHFFFAOYSA-N diethyl 2,3-dibenzylbutanedioate Chemical compound C=1C=CC=CC=1CC(C(=O)OCC)C(C(=O)OCC)CC1=CC=CC=C1 UIZHEHICSUOPQL-UHFFFAOYSA-N 0.000 description 1
- CXKANZAMPQTLBJ-UHFFFAOYSA-N diethyl 2,3-dicyclohexylbutanedioate Chemical compound C1CCCCC1C(C(=O)OCC)C(C(=O)OCC)C1CCCCC1 CXKANZAMPQTLBJ-UHFFFAOYSA-N 0.000 description 1
- GRVYPVYGTIWYIC-UHFFFAOYSA-N diethyl 2-(cyclohexylmethyl)butanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)CC1CCCCC1 GRVYPVYGTIWYIC-UHFFFAOYSA-N 0.000 description 1
- YGWFITBRMHORFZ-UHFFFAOYSA-N diethyl 2-cyclopentylbutanedioate Chemical compound CCOC(=O)CC(C(=O)OCC)C1CCCC1 YGWFITBRMHORFZ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229920005674 ethylene-propylene random copolymer Polymers 0.000 description 1
- GATNOFPXSDHULC-UHFFFAOYSA-N ethylphosphonic acid Chemical compound CCP(O)(O)=O GATNOFPXSDHULC-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002596 lactones Chemical class 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical group CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000004291 polyenes Chemical group 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 229920005653 propylene-ethylene copolymer Polymers 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000006340 racemization Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
Landscapes
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Nonwoven Fabrics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02021421 | 2002-09-25 | ||
| EP02021421.9 | 2002-09-25 | ||
| US41699202P | 2002-10-08 | 2002-10-08 | |
| US60/416,992 | 2002-10-08 | ||
| PCT/EP2003/010707 WO2004029342A1 (en) | 2002-09-25 | 2003-09-23 | Polypropylene fibres suitable for spunbonded non-woven fabrics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1685093A CN1685093A (zh) | 2005-10-19 |
| CN100338275C true CN100338275C (zh) | 2007-09-19 |
Family
ID=42777637
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038229293A Expired - Fee Related CN100338275C (zh) | 2002-09-25 | 2003-09-23 | 适合于纺粘非织造织物的聚丙烯纤维 |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP1543185B1 (enExample) |
| JP (1) | JP2006500487A (enExample) |
| CN (1) | CN100338275C (enExample) |
| AR (1) | AR041391A1 (enExample) |
| AT (1) | ATE441745T1 (enExample) |
| AU (1) | AU2003271644A1 (enExample) |
| BR (1) | BR0306556B1 (enExample) |
| CA (1) | CA2499702A1 (enExample) |
| PL (1) | PL374316A1 (enExample) |
| RU (1) | RU2322535C2 (enExample) |
| TW (1) | TW200420767A (enExample) |
| WO (1) | WO2004029342A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104968848A (zh) * | 2012-12-03 | 2015-10-07 | 埃克森美孚化学专利公司 | 聚丙烯纤维和织物 |
| CN105143528A (zh) * | 2012-07-06 | 2015-12-09 | 巴塞尔聚烯烃意大利有限公司 | 聚丙烯纤维 |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8466235B2 (en) | 2002-08-27 | 2013-06-18 | Braskem America, Inc. | Polypropylene blends for non-woven production |
| US7655582B2 (en) | 2004-05-12 | 2010-02-02 | Sunoco Chemicals, Inc. | Polypropylene blends for non-woven fabrics |
| EP2518194B1 (en) * | 2004-11-26 | 2020-01-01 | Mitsui Chemicals, Inc. | Mixed fibre nonwoven fabric and use thereof |
| WO2007071496A1 (en) * | 2005-12-20 | 2007-06-28 | Basell Poliolefine Italia S.R.L. | Soft non-woven fabrics |
| CN101341177B (zh) * | 2005-12-20 | 2012-08-08 | 巴塞尔聚烯烃意大利有限责任公司 | 柔软的无纺布 |
| CN102677393A (zh) * | 2006-02-06 | 2012-09-19 | 三井化学株式会社 | 纺粘非织造布 |
| US8728960B2 (en) * | 2007-01-19 | 2014-05-20 | Exxonmobil Chemical Patents Inc. | Spunbond fibers and fabrics from polyolefin blends |
| EP1964948A1 (en) * | 2007-02-28 | 2008-09-03 | Total Petrochemicals Research Feluy | Polypropylene fibers and spunbond nonwoven with improved properties. |
| US9676920B2 (en) | 2007-11-27 | 2017-06-13 | Basell Poliolefine Italia S.R.L. | Polyolefin nanocomposites materials |
| EP2264099A1 (en) * | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| KR101745975B1 (ko) * | 2009-12-09 | 2017-06-12 | 도레이 카부시키가이샤 | 장섬유 부직포의 제조방법 |
| DK2867295T3 (en) * | 2012-06-27 | 2016-02-01 | Total Res & Technology Feluy Sa | PROPYLENE HOMOPOLYMES FOR FIBER AND NON-WOVEN HIGH TENACITY MATERIALS |
| WO2014046070A1 (ja) * | 2012-09-19 | 2014-03-27 | 三井化学株式会社 | 農業用被覆材及びその製造方法 |
| TWI627321B (zh) * | 2012-09-20 | 2018-06-21 | Asahi Kasei Fibers Corp | Polypropylene non-woven fabric, manufacturing method thereof and sanitary material |
| PT2999722T (pt) * | 2013-05-22 | 2018-11-26 | Borealis Ag | Polipropileno para aplicações de películas |
| KR102001758B1 (ko) * | 2015-06-05 | 2019-10-01 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 프로필렌계 엘라스토머 조성물을 포함하는 스펀본드 패브릭 및 이의 제조 방법 |
| DK3400330T3 (da) * | 2016-01-04 | 2022-01-03 | Borealis Ag | Spunbondede ikke-vævede stoffer fremstillet af phthalatfri pp-homopolymerer |
| US10844529B2 (en) | 2016-05-02 | 2020-11-24 | Exxonmobil Chemicals Patents Inc. | Spunbond fabrics comprising propylene-based elastomer compositions and methods for making the same |
| EP3853399A1 (en) | 2018-09-21 | 2021-07-28 | Borealis AG | Polypropylene composition for melt spun fiber applications |
| JP7282211B2 (ja) * | 2019-05-28 | 2023-05-26 | トーレ・アドバンスド・マテリアルズ・コリア・インコーポレーテッド | 不織布、その製造方法、該不織布を含む物品、及び該不織布を使用した衛生用品 |
| WO2020244912A1 (en) * | 2019-06-07 | 2020-12-10 | Basell Poliolefine Italia S.R.L. | Propylene polymer fibers |
| KR20230118113A (ko) * | 2020-12-08 | 2023-08-10 | 더블유.알. 그레이스 앤드 캄파니-콘. | 고속 방사용 고결정성 올레핀 중합체 |
| CN113337903A (zh) * | 2021-06-01 | 2021-09-03 | 鹤山市东海塑料色母有限公司 | 一种抗病毒聚丙烯无纺布及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6657033B1 (en) * | 1999-04-15 | 2003-12-02 | Basell Poliolefine Italia S.P.A. | Thermal bondable polyolefin fibers comprising a random copolymer of propylene |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW275076B (enExample) * | 1992-12-02 | 1996-05-01 | Hoechst Ag | |
| US5460884A (en) * | 1994-08-25 | 1995-10-24 | Kimberly-Clark Corporation | Soft and strong thermoplastic polymer fibers and nonwoven fabric made therefrom |
| PL194685B1 (pl) * | 1998-08-20 | 2007-06-29 | Montech Usa Inc | Kompozycja krystalicznego kopolimeru propylenu, sposób jej wytwarzania i jej zastosowanie |
| MY132768A (en) * | 2001-10-09 | 2007-10-31 | Basell Poliolefine Italia Spa | Crystalline propylene copolymer compositions having improved sealability and optical properties and reduced solubility. |
-
2003
- 2003-09-23 AT AT03753461T patent/ATE441745T1/de not_active IP Right Cessation
- 2003-09-23 CA CA002499702A patent/CA2499702A1/en not_active Abandoned
- 2003-09-23 TW TW092126183A patent/TW200420767A/zh unknown
- 2003-09-23 JP JP2005509668A patent/JP2006500487A/ja not_active Withdrawn
- 2003-09-23 AU AU2003271644A patent/AU2003271644A1/en not_active Abandoned
- 2003-09-23 BR BRPI0306556-1A patent/BR0306556B1/pt not_active IP Right Cessation
- 2003-09-23 EP EP03753461A patent/EP1543185B1/en not_active Expired - Lifetime
- 2003-09-23 CN CNB038229293A patent/CN100338275C/zh not_active Expired - Fee Related
- 2003-09-23 WO PCT/EP2003/010707 patent/WO2004029342A1/en not_active Ceased
- 2003-09-23 RU RU2005112215/04A patent/RU2322535C2/ru not_active IP Right Cessation
- 2003-09-23 PL PL03374316A patent/PL374316A1/xx unknown
- 2003-09-25 AR ARP030103491A patent/AR041391A1/es not_active Application Discontinuation
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6657033B1 (en) * | 1999-04-15 | 2003-12-02 | Basell Poliolefine Italia S.P.A. | Thermal bondable polyolefin fibers comprising a random copolymer of propylene |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105143528A (zh) * | 2012-07-06 | 2015-12-09 | 巴塞尔聚烯烃意大利有限公司 | 聚丙烯纤维 |
| CN104968848A (zh) * | 2012-12-03 | 2015-10-07 | 埃克森美孚化学专利公司 | 聚丙烯纤维和织物 |
| US10174442B2 (en) | 2012-12-03 | 2019-01-08 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2322535C2 (ru) | 2008-04-20 |
| EP1543185A1 (en) | 2005-06-22 |
| RU2005112215A (ru) | 2005-09-20 |
| AR041391A1 (es) | 2005-05-18 |
| AU2003271644A1 (en) | 2004-04-19 |
| BR0306556A (pt) | 2004-11-30 |
| BR0306556B1 (pt) | 2012-11-27 |
| PL374316A1 (en) | 2005-10-03 |
| EP1543185B1 (en) | 2009-09-02 |
| ATE441745T1 (de) | 2009-09-15 |
| JP2006500487A (ja) | 2006-01-05 |
| CN1685093A (zh) | 2005-10-19 |
| CA2499702A1 (en) | 2004-04-08 |
| TW200420767A (en) | 2004-10-16 |
| WO2004029342A1 (en) | 2004-04-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100338275C (zh) | 适合于纺粘非织造织物的聚丙烯纤维 | |
| CN1132865C (zh) | 抗冲击聚烯烃组合物 | |
| CN1227288C (zh) | 具有改善抗冲击强度和优秀光学特性的丙烯聚合物组合物 | |
| CN1205261C (zh) | 含有低粘度丙烯均聚物的聚烯烃组合物、由其制成的纤维和可伸长无纺布 | |
| EP2535372B1 (en) | In-situ reactor blend of a Ziegler-Natta catalysed, nucleated polypropylene and a metallocene catalysed polypropylene | |
| CN1106409C (zh) | 制备聚丙烯的方法 | |
| CN1097770A (zh) | 具有高熔融流动速率值和窄分子量分布的结晶丙烯聚合物 | |
| CN1171942C (zh) | 塑化聚丙烯热塑性塑料 | |
| CN1282700C (zh) | 抗冲击聚烯烃组合物 | |
| CN101080462A (zh) | 聚合物共混物和由其获得的无纺制品 | |
| CN1128841C (zh) | 聚丙烯组合物和其制备方法及使用的聚合催化剂 | |
| CN1051183A (zh) | 热塑性烯烃聚合物及其制备方法 | |
| CN1079968A (zh) | 在熔融状态下具有改进加工性能的丙烯结晶聚合物及其制备方法 | |
| CN1802392A (zh) | 使用Ziegler－Natta催化剂制备聚丙烯的方法 | |
| CN101065527A (zh) | 聚丙烯无纺布及其用途 | |
| CN1125830C (zh) | 用于制造纤维网的聚烯烃模塑材料 | |
| CN1564847A (zh) | 具有改进的密封性能和光学性能并具有减低的溶解度的晶状丙烯共聚物组合物 | |
| CN1165532A (zh) | 聚烯烃组合物及其模塑制品 | |
| CN1768108A (zh) | 耐冲击的聚烯烃组合物 | |
| CN1423664A (zh) | 用于制备双轴拉伸聚丙烯膜的半结晶丙烯聚合物组合物 | |
| CN1290885C (zh) | 高透明度柔性丙烯共聚物组合物 | |
| CN1798803A (zh) | 聚丙烯树脂组合物 | |
| EP4107196A1 (en) | Propylene-based polymer compositions having a high molecular weight tail | |
| CN1211429C (zh) | 用于烯烃聚合物的添加剂的非挤出分散体和母料 | |
| CN1392190A (zh) | 制备乙烯聚合物组合物的方法,乙烯聚合物组合物的颗粒和由该颗粒制成的膜 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070919 Termination date: 20190923 |