CH617948A5 - Thermoplastic moulding materials based on cellulose esters and ethylene-vinyl ester copolymers - Google Patents
Thermoplastic moulding materials based on cellulose esters and ethylene-vinyl ester copolymers Download PDFInfo
- Publication number
- CH617948A5 CH617948A5 CH678375A CH678375A CH617948A5 CH 617948 A5 CH617948 A5 CH 617948A5 CH 678375 A CH678375 A CH 678375A CH 678375 A CH678375 A CH 678375A CH 617948 A5 CH617948 A5 CH 617948A5
- Authority
- CH
- Switzerland
- Prior art keywords
- weight
- percent
- cellulose
- ethylene
- vinyl ester
- Prior art date
Links
- 229920002678 cellulose Polymers 0.000 title claims description 39
- 229920001567 vinyl ester resin Polymers 0.000 title claims description 26
- 238000009757 thermoplastic moulding Methods 0.000 title claims description 12
- 239000000463 material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 claims description 37
- 238000000465 moulding Methods 0.000 claims description 22
- 239000001913 cellulose Substances 0.000 claims description 19
- 239000004014 plasticizer Substances 0.000 claims description 18
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 17
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 14
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 claims description 12
- 229920002301 cellulose acetate Polymers 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 20
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 229960000583 acetic acid Drugs 0.000 description 7
- 239000010408 film Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920002959 polymer blend Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
- -1 for example Chemical compound 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229940100539 dibutyl adipate Drugs 0.000 description 3
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 235000019260 propionic acid Nutrition 0.000 description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 2
- 229960001826 dimethylphthalate Drugs 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- PZBLUWVMZMXIKZ-UHFFFAOYSA-N 2-o-(2-ethoxy-2-oxoethyl) 1-o-ethyl benzene-1,2-dicarboxylate Chemical compound CCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCC PZBLUWVMZMXIKZ-UHFFFAOYSA-N 0.000 description 1
- YJERZJLSXBRUDQ-UHFFFAOYSA-N 2-o-(3,4-dihydroxybutyl) 1-o-methyl benzene-1,2-dicarboxylate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OCCC(O)CO YJERZJLSXBRUDQ-UHFFFAOYSA-N 0.000 description 1
- GOJCZVPJCKEBQV-UHFFFAOYSA-N Butyl phthalyl butylglycolate Chemical compound CCCCOC(=O)COC(=O)C1=CC=CC=C1C(=O)OCCCC GOJCZVPJCKEBQV-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- YYQRGCZGSFRBAM-UHFFFAOYSA-N Triclofos Chemical compound OP(O)(=O)OCC(Cl)(Cl)Cl YYQRGCZGSFRBAM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- RISLXYINQFKFRL-UHFFFAOYSA-N dibutyl nonanedioate Chemical compound CCCCOC(=O)CCCCCCCC(=O)OCCCC RISLXYINQFKFRL-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- BTOIAAYVFNXNPA-UHFFFAOYSA-N ethenyl 2-chloropropanoate Chemical compound CC(Cl)C(=O)OC=C BTOIAAYVFNXNPA-UHFFFAOYSA-N 0.000 description 1
- WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 1
- AFSIMBWBBOJPJG-UHFFFAOYSA-N ethenyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC=C AFSIMBWBBOJPJG-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- ZQZUENMXBZVXIZ-UHFFFAOYSA-N ethenyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OC=C ZQZUENMXBZVXIZ-UHFFFAOYSA-N 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006352 transparent thermoplastic Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229960001147 triclofos Drugs 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2426178A DE2426178C3 (de) | 1974-05-29 | 1974-05-29 | Thermoplastische Formmassen aus Celluloseestern und Äthylen-Vinylester-Copolymerisaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH617948A5 true CH617948A5 (en) | 1980-06-30 |
Family
ID=5916861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH678375A CH617948A5 (en) | 1974-05-29 | 1975-05-27 | Thermoplastic moulding materials based on cellulose esters and ethylene-vinyl ester copolymers |
Country Status (17)
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2807663A1 (de) * | 1978-02-23 | 1979-08-30 | Bayer Ag | Verwendung von mischungen aus celluloseestern und aethylen-vinylacetat-copolymeren in der kontakt-augenoptik |
| CA1163739A (en) * | 1980-07-12 | 1984-03-13 | Dietrich J. Bahr | Process for producing a polymerized, heat-resistant lacquer |
| JPH0741056B2 (ja) * | 1986-03-14 | 1995-05-10 | 松下電工株式会社 | マツサ−ジ機 |
| JPS6326462A (ja) * | 1986-07-16 | 1988-02-04 | Sumitomo Heavy Ind Ltd | 砥石軸駆動用モ−タプ−リの支持機構 |
| JP5182778B2 (ja) * | 2006-06-12 | 2013-04-17 | 太平化学製品株式会社 | 樹脂組成物および透明シート |
| JP5258233B2 (ja) * | 2006-09-07 | 2013-08-07 | 太平化学製品株式会社 | 樹脂組成物及び成形体 |
| JP6511754B2 (ja) * | 2014-09-26 | 2019-05-15 | 富士ゼロックス株式会社 | 樹脂組成物、及び樹脂成形体 |
| JP6897196B2 (ja) * | 2016-08-31 | 2021-06-30 | 富士フイルムビジネスイノベーション株式会社 | 樹脂組成物、及び、樹脂成形体 |
| JP7208135B2 (ja) * | 2016-11-11 | 2023-01-18 | イーストマン ケミカル カンパニー | 熱安定性セルロースエステル組成物及びこれらの組成物を用いて製造される物品 |
| WO2018089575A1 (en) * | 2016-11-11 | 2018-05-17 | Eastman Chemical Company | Cellulose ester and ethylene vinyl acetate compositions and articles made using these compositions |
| JP6930232B2 (ja) * | 2017-02-17 | 2021-09-01 | Dic株式会社 | セルロースエステル組成物、成形体及びフィルム |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2186454A (en) * | 1937-06-24 | 1940-01-09 | Hercules Powder Co Ltd | Lacquers containing cellulose acetobutyrate and cellulose acetopropionate |
| US3454349A (en) * | 1965-12-28 | 1969-07-08 | Celanese Corp | Cellulose ester shaped articles of improved dyeability |
| DE1745565A1 (de) * | 1967-10-23 | 1971-10-28 | Wacker Chemie Gmbh | Verfahren zur Herstellung von Copolymeren aus AEthylen und Vinylestern |
| JPS50759B1 (enrdf_load_stackoverflow) * | 1969-03-20 | 1975-01-11 | ||
| US3682850A (en) * | 1970-07-30 | 1972-08-08 | Du Pont | Cellulosic esters of two organic acids blended with a copolymer of ethylene and at least one ethylenically unsaturated ester of a saturated fatty acid |
| JPS5343978B2 (enrdf_load_stackoverflow) * | 1973-12-04 | 1978-11-24 |
-
1974
- 1974-05-29 DE DE2426178A patent/DE2426178C3/de not_active Expired
-
1975
- 1975-05-15 NO NO751730A patent/NO143911C/no unknown
- 1975-05-20 GB GB21455/75A patent/GB1501414A/en not_active Expired
- 1975-05-27 JP JP50062610A patent/JPS5845458B2/ja not_active Expired
- 1975-05-27 CA CA227,858A patent/CA1071786A/en not_active Expired
- 1975-05-27 DD DD186280A patent/DD119249A5/xx unknown
- 1975-05-27 CH CH678375A patent/CH617948A5/de not_active IP Right Cessation
- 1975-05-27 IT IT49794/75A patent/IT1035896B/it active
- 1975-05-27 AT AT402175A patent/AT343918B/de not_active IP Right Cessation
- 1975-05-28 ES ES438015A patent/ES438015A1/es not_active Expired
- 1975-05-28 BE BE156781A patent/BE829578A/xx not_active IP Right Cessation
- 1975-05-28 BR BR4324/75D patent/BR7503381A/pt unknown
- 1975-05-28 SE SE7506095A patent/SE411354B/xx not_active IP Right Cessation
- 1975-05-28 DK DK238275A patent/DK238275A/da unknown
- 1975-05-29 NL NLAANVRAGE7506381,A patent/NL183241C/xx not_active IP Right Cessation
- 1975-05-29 FR FR7516869A patent/FR2275514A1/fr active Granted
- 1975-05-29 SU SU752140025A patent/SU828976A3/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| DE2426178A1 (de) | 1975-12-18 |
| AT343918B (de) | 1978-06-26 |
| AU8157375A (en) | 1976-12-02 |
| JPS512756A (en) | 1976-01-10 |
| DD119249A5 (enrdf_load_stackoverflow) | 1976-04-12 |
| DK238275A (da) | 1975-11-30 |
| IT1035896B (it) | 1979-10-20 |
| CA1071786A (en) | 1980-02-12 |
| FR2275514A1 (fr) | 1976-01-16 |
| ES438015A1 (es) | 1977-05-16 |
| NL7506381A (nl) | 1975-12-02 |
| NO143911B (no) | 1981-01-26 |
| BE829578A (fr) | 1975-11-28 |
| NO751730L (enrdf_load_stackoverflow) | 1975-12-02 |
| SU828976A3 (ru) | 1981-05-07 |
| NO143911C (no) | 1981-05-06 |
| DE2426178C3 (de) | 1981-12-03 |
| BR7503381A (pt) | 1976-04-27 |
| JPS5845458B2 (ja) | 1983-10-11 |
| DE2426178B2 (enrdf_load_stackoverflow) | 1980-10-30 |
| GB1501414A (en) | 1978-02-15 |
| SE7506095L (sv) | 1975-12-01 |
| FR2275514B1 (enrdf_load_stackoverflow) | 1979-04-13 |
| SE411354B (sv) | 1979-12-17 |
| ATA402175A (de) | 1977-10-15 |
| NL183241C (nl) | 1988-09-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |