CH511919A - Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlen induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Substrate nicht textiler Art - Google Patents
Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlen induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Substrate nicht textiler ArtInfo
- Publication number
- CH511919A CH511919A CH1408569A CH1408569A CH511919A CH 511919 A CH511919 A CH 511919A CH 1408569 A CH1408569 A CH 1408569A CH 1408569 A CH1408569 A CH 1408569A CH 511919 A CH511919 A CH 511919A
- Authority
- CH
- Switzerland
- Prior art keywords
- substrate
- reaction temperature
- polymerizable compound
- free
- treatment stage
- Prior art date
Links
- 239000000758 substrate Substances 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 238000011282 treatment Methods 0.000 claims abstract description 18
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims description 25
- 238000000034 method Methods 0.000 claims description 15
- 230000009477 glass transition Effects 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 230000005865 ionizing radiation Effects 0.000 claims description 5
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- 238000010559 graft polymerization reaction Methods 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- 239000004753 textile Substances 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 3
- 239000000839 emulsion Substances 0.000 abstract description 7
- 239000000178 monomer Substances 0.000 abstract description 5
- 239000000725 suspension Substances 0.000 abstract description 3
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000007792 gaseous phase Substances 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
- -1 polyethylene Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 230000005855 radiation Effects 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical class C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- ZBFZBSPHMMXVMQ-UHFFFAOYSA-L O.O.O.O.O.O.N.S(=O)(=O)([O-])[O-].[Fe+2] Chemical compound O.O.O.O.O.O.N.S(=O)(=O)([O-])[O-].[Fe+2] ZBFZBSPHMMXVMQ-UHFFFAOYSA-L 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 150000001345 alkine derivatives Chemical class 0.000 description 1
- 229960002684 aminocaproic acid Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000003118 aryl group Chemical class 0.000 description 1
- 125000003609 aryl vinyl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- AFOSIXZFDONLBT-UHFFFAOYSA-N divinyl sulfone Chemical class C=CS(=O)(=O)C=C AFOSIXZFDONLBT-UHFFFAOYSA-N 0.000 description 1
- MQLVWQSVRZVNIP-UHFFFAOYSA-L ferrous ammonium sulfate hexahydrate Chemical compound [NH4+].[NH4+].O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O MQLVWQSVRZVNIP-UHFFFAOYSA-L 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical class 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical class 0.000 description 1
- 125000005350 hydroxycycloalkyl group Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/18—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to irradiated or oxidised macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
- C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/26—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
- D06M14/30—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Toxicology (AREA)
- Textile Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1408569A CH511919A (de) | 1969-06-06 | 1969-06-06 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlen induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Substrate nicht textiler Art |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH863169A CH533200A (de) | 1969-06-06 | 1969-06-06 | Verfahren zum Veredeln von synthetischen Textilfasern durch Pfropfpolymerisation |
| CH1408569A CH511919A (de) | 1969-06-06 | 1969-06-06 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlen induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Substrate nicht textiler Art |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH511919A true CH511919A (de) | 1971-08-31 |
Family
ID=4342851
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH1408569A CH511919A (de) | 1969-06-06 | 1969-06-06 | Verfahren zur Verbesserung der durch energiereiche, ionisierende Strahlen induzierten Pfropfpolymerisation oder Pfropfcopolymerisation einer oder mehrerer radikalisch polymerisierbarer Verbindungen auf aus synthetischen Hochpolymeren bestehende geformte Substrate nicht textiler Art |
| CH863169D CH863169A4 (enrdf_load_stackoverflow) | 1969-06-06 | 1969-06-06 | |
| CH863169A CH533200A (de) | 1969-06-06 | 1969-06-06 | Verfahren zum Veredeln von synthetischen Textilfasern durch Pfropfpolymerisation |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH863169D CH863169A4 (enrdf_load_stackoverflow) | 1969-06-06 | 1969-06-06 | |
| CH863169A CH533200A (de) | 1969-06-06 | 1969-06-06 | Verfahren zum Veredeln von synthetischen Textilfasern durch Pfropfpolymerisation |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE751378A (enrdf_load_stackoverflow) |
| CH (3) | CH511919A (enrdf_load_stackoverflow) |
| DE (1) | DE2027178A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2049741A5 (enrdf_load_stackoverflow) |
| GB (1) | GB1311542A (enrdf_load_stackoverflow) |
| NL (1) | NL7007349A (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2434235A1 (fr) * | 1978-08-21 | 1980-03-21 | Commissariat Energie Atomique | Perfectionnements aux toiles de papeterie et aux procedes et machines de finition de telles toiles |
| US4743267A (en) * | 1982-06-21 | 1988-05-10 | International Yarn Corporation Of Tennessee | Process for improving polymer fiber properties and fibers produced thereby |
| CN116289204B (zh) * | 2023-04-12 | 2023-10-13 | 潮州市丹辉婚纱礼服有限公司 | 一种抗静电透湿涤纶面料的制备方法和应用 |
-
1969
- 1969-06-06 CH CH1408569A patent/CH511919A/de not_active IP Right Cessation
- 1969-06-06 CH CH863169D patent/CH863169A4/xx unknown
- 1969-06-06 CH CH863169A patent/CH533200A/de unknown
-
1970
- 1970-05-21 NL NL7007349A patent/NL7007349A/xx unknown
- 1970-06-01 FR FR7020005A patent/FR2049741A5/fr not_active Expired
- 1970-06-03 BE BE751378D patent/BE751378A/xx unknown
- 1970-06-03 DE DE19702027178 patent/DE2027178A1/de active Pending
- 1970-06-03 GB GB2679370A patent/GB1311542A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| BE751378A (fr) | 1970-12-03 |
| DE2027178A1 (de) | 1970-12-10 |
| CH863169A4 (enrdf_load_stackoverflow) | 1972-09-15 |
| FR2049741A5 (enrdf_load_stackoverflow) | 1971-03-26 |
| CH533200A (de) | 1972-09-15 |
| GB1311542A (en) | 1973-03-28 |
| NL7007349A (enrdf_load_stackoverflow) | 1970-12-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |