CH116287A - Process for the preparation of a vat dye. - Google Patents

Process for the preparation of a vat dye.

Info

Publication number
CH116287A
CH116287A CH116287DA CH116287A CH 116287 A CH116287 A CH 116287A CH 116287D A CH116287D A CH 116287DA CH 116287 A CH116287 A CH 116287A
Authority
CH
Switzerland
Prior art keywords
blue
preparation
vat
dye
vat dye
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellschaft Kalle Co
Original Assignee
Kalle & Co Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kalle & Co Ag filed Critical Kalle & Co Ag
Publication of CH116287A publication Critical patent/CH116287A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
    • C09B5/62—Cyclic imides or amidines of peri-dicarboxylic acids of the anthracene, benzanthrene, or perylene series

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Description

  

      Zusatzpatent    zum Hauptpatent Nr. 113920.    Verfahren zur Darstellung eines     güpenfarbstoffes.       Gegenstand dieses Zusatzpatentes ist ein  Verfahren zur Darstellung eines     Küpenfa,rb-          stoffes    aus dem     Kondensationsprodukt    aus     Mo-          nochlorperylentetrakarbonsäureanhydrid    mit  o     phenylendiamin    und Phenol.  



  Das Verfahren     wird    beispielsweise fol  gendermassen ausgeführt:  10 Teile des violetten Kondensations  produktes aus     Monochlorperylentetrakarbon-          säureanhydrid        (wie    es aus     Perylentetrakar-          bonsäureanhydrid    durch Chlorieren bis zur       Monoahlorstufe,    beispielsweise in     Chlorsulfon,    säure, erhalten werden kann) und     o-Phe-          nylendiamin    werden mit etwa 70 Teilen  Phenol und 7 Teilen     Kaliumkarbonat    acht  bis zehn Stunden unter Rühren zum Sieden  erhitzt.

   Die Aufarbeitung der Schmelze kann  .so erfolgen, dass man nach dem Abkühlen  mit Alkohol verdünnt, absaugt, mit Alkohol  und dann mit Wasser wäscht und trocknet.  



  Der in trockenem, pulverförmigem Zu  stande     schwarzviolette    Farbstoff ist in     Al-          kalien    und Säuren unlöslich. In konzen  trierter Schwefelsäure löst er sich blaugrün,    in organischen Lösungsmitteln violett bis  blau mit braunroter Fluoreszenz. Die     Hydro-          sulfitküpe    ist blau. Auf Baumwolle erhält  man ein echtes, rötliches Blau.



      Additional patent to main patent no. 113920. Process for the preparation of a high quality dye. The subject of this additional patent is a process for the preparation of a vat substance from the condensation product of monochloroperylenetetracarboxylic acid anhydride with phenylenediamine and phenol.



  The process is carried out, for example, as follows: 10 parts of the violet condensation product from monochloroperylenetetracarboxylic acid anhydride (as can be obtained from perylenetetracarboxylic acid anhydride by chlorination up to the monoahlor stage, for example in chlorosulfonic acid) and o-phenylenediamine with about 70 parts of phenol and 7 parts of potassium carbonate heated to the boil for eight to ten hours with stirring.

   The melt can be worked up in such a way that after cooling it is diluted with alcohol, filtered off with suction, washed with alcohol and then with water and dried.



  The black-violet dye when dry, in powder form, is insoluble in alkalis and acids. In concentrated sulfuric acid it dissolves blue-green, in organic solvents purple to blue with brown-red fluorescence. The hydrosulfite vat is blue. On cotton you get a real, reddish blue.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines Küpen- fa.rbstoffes, dadurch gekennzeichnet, dass .man das Kondensationsprodukt aus Mono- chlorperylentetrakarbonsäureanhydrid, wie es aus Tetrakarbonsäureanhydrid durch Chlo rieren bis zur Monochlorstuf e beispielsweise in Chlorsulfonsäure erhalten werden kann, und o-Phenylendiamin mit Phenol umsetzt. PATENT CLAIM: Process for the preparation of a vat dye, characterized in that the condensation product of monochloroperylenetetracarboxylic anhydride, as can be obtained from tetracarboxylic anhydride by chlorination up to the monochloro stage, for example in chlorosulfonic acid, and o-phenylenediamine is reacted with phenol . Der in trockenem, pulverförmigem Zu stande schwarzviolette Farbstoff ist in Al- kalien und Säuren unlöslich. In konzen trierter Schwefelsäure löst er sich blaugrün, in organischen Lösungsmitteln violett bis blau mit braunroter Fluoreszenz. Die Hydro- sulfitküpe ist blau. Auf Baumwolle erhält man ein echtes, rötliches Blau. The black-violet dye when dry, in powder form, is insoluble in alkalis and acids. In concentrated sulfuric acid it dissolves blue-green, in organic solvents purple to blue with brown-red fluorescence. The hydrosulfite vat is blue. On cotton you get a real, reddish blue.
CH116287D 1925-01-26 1925-01-26 Process for the preparation of a vat dye. CH116287A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH116287T 1925-01-26
CH113920T 1925-01-26

Publications (1)

Publication Number Publication Date
CH116287A true CH116287A (en) 1926-08-16

Family

ID=25708250

Family Applications (1)

Application Number Title Priority Date Filing Date
CH116287D CH116287A (en) 1925-01-26 1925-01-26 Process for the preparation of a vat dye.

Country Status (1)

Country Link
CH (1) CH116287A (en)

Similar Documents

Publication Publication Date Title
CH116287A (en) Process for the preparation of a vat dye.
CH116288A (en) Process for the preparation of a vat dye.
CH101757A (en) Process for the preparation of a vat dye.
DE451720C (en) Process for the production of Kuepen dyes
CH116285A (en) Process for the preparation of a vat dye.
CH101758A (en) Process for the preparation of a vat dye.
DE355491C (en) Process for the production of anthraquinonylated saffranines
CH116286A (en) Process for the preparation of a vat dye.
CH205539A (en) Process for the preparation of a water-soluble phthalocyanine series dye.
DE645010C (en) Process for the production of Kuepen dyes
CH116284A (en) Process for the preparation of a vat dye.
DE740489C (en) Process for the production of yellow-tinged green dyes of the dibenzanthrone series
CH105852A (en) Process for the preparation of a vat dye.
CH100706A (en) Process for the preparation of a vat dye.
CH153830A (en) Process for the preparation of a vat dye.
CH101764A (en) Process for the preparation of a vat dye.
CH104012A (en) Process for the preparation of a condensation product of the anthraquinone series which can be used as dye and dye intermediate.
CH154418A (en) Process for the preparation of a new vat dye.
CH138877A (en) Process for the preparation of a vat dye.
CH195859A (en) Process for the production of a vat dye.
CH188226A (en) Process for the production of a vat dye of the anthraquinone series.
CH150185A (en) Process for the preparation of a vat dye of the benzanthrone pyrazole anthrone series.
CH177473A (en) Process for the production of a nitrogen-containing condensation product.
CH140715A (en) Process for the production of a brown vat dye of the benzanthrone series.
CH150190A (en) Process for the preparation of a vat dye of the benzanthrone pyrazole anthrone series.