CA2909715C - In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite - Google Patents
In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite Download PDFInfo
- Publication number
- CA2909715C CA2909715C CA2909715A CA2909715A CA2909715C CA 2909715 C CA2909715 C CA 2909715C CA 2909715 A CA2909715 A CA 2909715A CA 2909715 A CA2909715 A CA 2909715A CA 2909715 C CA2909715 C CA 2909715C
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- graphene
- graphite
- thermoplastic
- peek
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 64
- 239000011160 polymer matrix composite Substances 0.000 title claims abstract description 24
- 229920013657 polymer matrix composite Polymers 0.000 title claims abstract description 23
- 238000004299 exfoliation Methods 0.000 title description 32
- 238000011065 in-situ storage Methods 0.000 title description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 271
- 229920000642 polymer Polymers 0.000 claims abstract description 161
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 134
- 239000010439 graphite Substances 0.000 claims abstract description 134
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 133
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 60
- 239000011859 microparticle Substances 0.000 claims abstract description 13
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 89
- 229920002530 polyetherether ketone Polymers 0.000 claims description 89
- 239000002245 particle Substances 0.000 claims description 54
- -1 polyethylene Polymers 0.000 claims description 43
- 239000010410 layer Substances 0.000 claims description 41
- 239000002105 nanoparticle Substances 0.000 claims description 38
- 239000011159 matrix material Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 31
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 28
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 239000004698 Polyethylene Substances 0.000 claims description 20
- 239000002131 composite material Substances 0.000 claims description 20
- 229920000573 polyethylene Polymers 0.000 claims description 20
- 238000009826 distribution Methods 0.000 claims description 19
- 229920001601 polyetherimide Polymers 0.000 claims description 19
- 229920002492 poly(sulfone) Polymers 0.000 claims description 18
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 18
- 239000002033 PVDF binder Substances 0.000 claims description 17
- 239000004697 Polyetherimide Substances 0.000 claims description 17
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 17
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 17
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 16
- 229920006324 polyoxymethylene Polymers 0.000 claims description 15
- 229940058401 polytetrafluoroethylene Drugs 0.000 claims description 15
- 239000004416 thermosoftening plastic Substances 0.000 claims description 15
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 14
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 14
- 239000004952 Polyamide Substances 0.000 claims description 13
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 13
- 229920002647 polyamide Polymers 0.000 claims description 13
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 12
- 239000004743 Polypropylene Substances 0.000 claims description 11
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 11
- 229920006037 cross link polymer Polymers 0.000 claims description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
- 239000004417 polycarbonate Substances 0.000 claims description 11
- 229920000515 polycarbonate Polymers 0.000 claims description 11
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 11
- 229920000106 Liquid crystal polymer Polymers 0.000 claims description 10
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 claims description 10
- 239000004793 Polystyrene Substances 0.000 claims description 10
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- 239000004800 polyvinyl chloride Substances 0.000 claims description 10
- 229920010741 Ultra High Molecular Weight Polyethylene (UHMWPE) Polymers 0.000 claims description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 9
- 239000011707 mineral Substances 0.000 claims description 9
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 9
- 229920001155 polypropylene Polymers 0.000 claims description 9
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 9
- 239000004642 Polyimide Substances 0.000 claims description 8
- 229920001721 polyimide Polymers 0.000 claims description 8
- 229920001955 polyphenylene ether Polymers 0.000 claims description 8
- 229920006259 thermoplastic polyimide Polymers 0.000 claims description 8
- 229920008285 Poly(ether ketone) PEK Polymers 0.000 claims description 7
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 238000005188 flotation Methods 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 229920006260 polyaryletherketone Polymers 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 2
- 239000011229 interlayer Substances 0.000 claims description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 2
- 125000005650 substituted phenylene group Chemical group 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 5
- 150000003254 radicals Chemical class 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 description 36
- 206010040844 Skin exfoliation Diseases 0.000 description 31
- 239000000523 sample Substances 0.000 description 25
- 239000000463 material Substances 0.000 description 19
- 238000013329 compounding Methods 0.000 description 16
- 238000001125 extrusion Methods 0.000 description 15
- 238000012545 processing Methods 0.000 description 11
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 11
- 230000008569 process Effects 0.000 description 10
- 238000002441 X-ray diffraction Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000004132 cross linking Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000012512 characterization method Methods 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 6
- 125000005647 linker group Chemical group 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 230000003252 repetitive effect Effects 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000005169 Debye-Scherrer Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920001643 poly(ether ketone) Polymers 0.000 description 4
- 230000002787 reinforcement Effects 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000010094 polymer processing Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000007306 functionalization reaction Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000004634 thermosetting polymer Substances 0.000 description 2
- 239000012745 toughening agent Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 208000037062 Polyps Diseases 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 229910021383 artificial graphite Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004918 carbon fiber reinforced polymer Substances 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229940125782 compound 2 Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011978 dissolution method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000001188 haloalkyl group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 125000004474 heteroalkylene group Chemical group 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000002076 thermal analysis method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/28—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/042—Graphene or derivatives, e.g. graphene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/16—Condensation polymers of aldehydes or ketones with phenols only of ketones with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
- C08L79/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/04—Polysulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Carbon And Carbon Compounds (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361813621P | 2013-04-18 | 2013-04-18 | |
| US61/813,621 | 2013-04-18 | ||
| PCT/US2014/034624 WO2014172619A1 (en) | 2013-04-18 | 2014-04-18 | In situ exfoliation method to fabricate a graphene-reninf-orced polymer matrix composite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2909715A1 CA2909715A1 (en) | 2014-10-23 |
| CA2909715C true CA2909715C (en) | 2022-05-24 |
Family
ID=51731868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2909715A Active CA2909715C (en) | 2013-04-18 | 2014-04-18 | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US10253154B2 (enExample) |
| EP (1) | EP2994308B1 (enExample) |
| JP (3) | JP6393743B2 (enExample) |
| KR (1) | KR102292918B1 (enExample) |
| CN (1) | CN105324241B (enExample) |
| BR (1) | BR112015026355B1 (enExample) |
| CA (1) | CA2909715C (enExample) |
| HK (1) | HK1221440A1 (enExample) |
| MX (1) | MX383525B (enExample) |
| SG (1) | SG11201508599PA (enExample) |
| WO (1) | WO2014172619A1 (enExample) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2771395B8 (en) | 2011-10-27 | 2017-10-18 | Garmor Inc. | Method of making high-strength graphene nanocomposites and nanocomposite obtained therefrom. |
| EP2909028B1 (en) | 2012-10-19 | 2019-09-25 | Rutgers, the State University of New Jersey | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
| US11479652B2 (en) | 2012-10-19 | 2022-10-25 | Rutgers, The State University Of New Jersey | Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom |
| US12460064B2 (en) | 2012-10-19 | 2025-11-04 | Rutgers, The State University Of New Jersey | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
| CA2904059C (en) | 2013-03-08 | 2019-06-11 | Garmor Inc. | Graphene entrainment in a host |
| CA2909715C (en) | 2013-04-18 | 2022-05-24 | Rutgers, The State University Of New Jersey | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
| CN116804117A (zh) * | 2014-07-30 | 2023-09-26 | 新泽西鲁特格斯州立大学 | 石墨烯增强的聚合物基质复合材料 |
| US9421739B2 (en) | 2015-01-05 | 2016-08-23 | The Boeing Company | Graphene aerospace composites |
| US10266677B2 (en) | 2015-01-05 | 2019-04-23 | The Boeing Company | Graphene-augmented composite materials |
| US9434826B2 (en) | 2015-01-05 | 2016-09-06 | The Boeing Company | Graphene-augmented carbon fiber for aerospace composites |
| US9518160B2 (en) | 2015-01-05 | 2016-12-13 | The Boeing Company | Graphene-augmented composite materials |
| US10875986B2 (en) | 2015-01-05 | 2020-12-29 | The Boeing Company | Graphene fiber for aerospace composites |
| JP6499450B2 (ja) * | 2015-01-07 | 2019-04-10 | 株式会社日本触媒 | 酸化グラフェン複合組成物 |
| KR101980519B1 (ko) * | 2015-03-13 | 2019-05-22 | 유니버시티 오브 센트럴 플로리다 리서치 파운데이션, 인코포레이티드 | 호스트 중 그래핀 나노입자의 균일한 분산 |
| US10450429B2 (en) * | 2015-04-03 | 2019-10-22 | MICA S.r.l. | Composite materials comprising at least one thermoplastic resin and granular shive from hemp and/or flax |
| US11482348B2 (en) | 2015-06-09 | 2022-10-25 | Asbury Graphite Of North Carolina, Inc. | Graphite oxide and polyacrylonitrile based composite |
| EP3353838B1 (en) | 2015-09-21 | 2023-06-07 | Asbury Graphite of North Carolina, Inc. | Low-cost, high-performance composite bipolar plate |
| US9926427B2 (en) * | 2015-12-10 | 2018-03-27 | Nanotek Instruments, Inc. | Chemical-free production of graphene-reinforced polymer matrix composites |
| US11702518B2 (en) | 2016-07-22 | 2023-07-18 | Rutgers, The State University Of New Jersey | In situ bonding of carbon fibers and nanotubes to polymer matrices |
| EP3513411A4 (en) * | 2016-07-22 | 2020-03-25 | Rutgers, The State University of New Jersey | IN SITU BINDING OF CARBON FIBERS AND NANOTUBES TO A POLYMER |
| CN106496712B (zh) * | 2016-09-30 | 2018-01-23 | 北京化工大学 | 一种原位反应剥离膨胀石墨制备橡胶纳米复合材料的方法 |
| CN106564175B (zh) * | 2016-10-21 | 2018-11-30 | 成都新柯力化工科技有限公司 | 一种石墨烯导电母料及其制备方法 |
| JP6964653B2 (ja) | 2017-03-07 | 2021-11-10 | 株式会社カネカ | スチレン系樹脂押出発泡体及びその製造方法 |
| ES2928754T3 (es) | 2017-03-31 | 2022-11-22 | Arcelormittal | Un procedimiento de fabricación de óxido de grafeno a partir de grafito Kish |
| CN106928448B (zh) | 2017-04-06 | 2017-12-15 | 常州恒利宝纳米新材料科技有限公司 | 一种石墨烯复合材料的连续式生产设备以及制备方法 |
| WO2018189670A1 (en) * | 2017-04-11 | 2018-10-18 | Reliance Industries Limited | Process for preparing polymer-graphene composites |
| CN109082048A (zh) * | 2017-06-13 | 2018-12-25 | 沙冰娟 | 一种基于石墨烯的高导热复合材料的制备方法 |
| US11149129B2 (en) * | 2017-06-26 | 2021-10-19 | Hangzhou Gaoxi Technology Co., Ltd. | Graphene composite material and preparation method thereof |
| CN107501845B (zh) * | 2017-08-25 | 2020-01-31 | 天津大学 | 母粒-球磨-热压法制备石墨烯/abs纳米复合材料 |
| WO2019126196A1 (en) | 2017-12-22 | 2019-06-27 | Lyten, Inc. | Structured composite materials |
| US11479653B2 (en) | 2018-01-16 | 2022-10-25 | Rutgers, The State University Of New Jersey | Use of graphene-polymer composites to improve barrier resistance of polymers to liquid and gas permeants |
| US11352481B2 (en) * | 2018-02-28 | 2022-06-07 | Lyten, Inc. | Composite materials systems |
| US20200002470A1 (en) * | 2018-05-09 | 2020-01-02 | Niagara Bottling, Llc | Poly(ethylene terephthalate)-graphene nanocomposites from improved dispersion |
| CN108659390A (zh) * | 2018-05-14 | 2018-10-16 | 诸城市福日机械有限公司 | 一种汽车后桥壳用塑胶料 |
| US12060473B2 (en) | 2018-07-03 | 2024-08-13 | University Of Notre Dame Du Lac | Polymer/exfoliated nano-composite films with superior mechanical properties |
| US11136480B2 (en) * | 2018-08-01 | 2021-10-05 | The Boeing Company | Thermal spray plastic coating for edge sealing and fillet sealing |
| CN109021454A (zh) * | 2018-08-17 | 2018-12-18 | 于浩淼 | 一种床式电脑桌用高强度面板材料的制备方法 |
| CN109233196A (zh) * | 2018-08-20 | 2019-01-18 | 苏州宏久航空防热材料科技有限公司 | 一种柔性阻燃泡沫材料的制备方法 |
| DE202018106258U1 (de) | 2018-10-15 | 2020-01-20 | Rutgers, The State University Of New Jersey | Nano-Graphitische Schwämme |
| CN109705488A (zh) * | 2018-11-23 | 2019-05-03 | 苏州鼎烯聚材纳米科技有限公司 | 一种石墨烯/pvc浓缩母料的制备方法 |
| CN109486155B (zh) * | 2018-12-06 | 2020-10-23 | 上海长伟锦磁工程塑料有限公司 | 一种石墨烯改性无卤阻燃pc/abs材料及其制备方法 |
| US11807757B2 (en) | 2019-05-07 | 2023-11-07 | Rutgers, The State University Of New Jersey | Economical multi-scale reinforced composites |
| CN110255545B (zh) * | 2019-07-16 | 2022-11-22 | 河北工业大学 | 一种机械驱动聚合物剥离膨胀石墨制备石墨烯的方法 |
| CN110343347B (zh) * | 2019-07-19 | 2021-09-14 | 广州特种承压设备检测研究院 | 聚偏氟乙烯SiO2改性石墨烯复合材料及其制备方法 |
| US11791061B2 (en) | 2019-09-12 | 2023-10-17 | Asbury Graphite North Carolina, Inc. | Conductive high strength extrudable ultra high molecular weight polymer graphene oxide composite |
| TWI786340B (zh) * | 2019-10-08 | 2022-12-11 | 紐澤西州立羅格斯大學 | 石墨烯奈米顆粒與聚合物鏈的共價綴合物、由其所形成的複合材料以及其製造方法 |
| US20230105285A1 (en) * | 2019-12-27 | 2023-04-06 | Tongxiang Small Boss Special Plastic Products Co., Ltd. | Cured product containing single-layer graphene, single-layer graphene, preparation method therefor, and article containing single-layer graphene |
| US12324685B2 (en) | 2020-01-28 | 2025-06-10 | Rutgers, The State University Of New Jersey | Elastomers enhanced with in situ formation of 2D nanoparticles from layered materials for multifunctional sensors |
| CN118772656A (zh) * | 2020-02-06 | 2024-10-15 | 利腾股份有限公司 | 复合材料系统 |
| US11577665B2 (en) | 2020-02-27 | 2023-02-14 | Cpk Interior Products | Urethane and graphene interior trim panel |
| EP3875429A1 (en) * | 2020-03-03 | 2021-09-08 | Avanzare Innovacion Tencologica S.L. | Procedure to produce graphene and graphenic materials |
| CN111393823B (zh) * | 2020-04-22 | 2021-05-18 | 福州大学 | 一种具有优良力学性能的Gn-PET/PC合金及其制备方法 |
| EP3970489A1 (en) | 2020-09-18 | 2022-03-23 | CpK Interior Products Inc. | Graphene-based antiviral polymer |
| US12398247B2 (en) | 2020-10-09 | 2025-08-26 | Rutgers, The State University Of New Jersey | Conductive polymer nanocomposites enhanced with in situ formation of 2D nanoparticles for structural sensors and smart materials |
| CN114763261A (zh) * | 2021-01-14 | 2022-07-19 | 中国科学院大连化学物理研究所 | 一种制备石墨烯材料的方法及其得到的石墨烯材料 |
| CN113121838B (zh) * | 2021-03-31 | 2022-05-06 | 海南大学 | 一种原子层沉积辅助制备mof/碳复合材料的方法及所得产品和应用 |
| CN113546618B (zh) * | 2021-07-27 | 2022-05-27 | 吉林大学 | 一种近红外光热催化剂及其制备方法和应用 |
| CN115490889B (zh) * | 2022-08-26 | 2025-03-21 | 四川大学 | 一种利用高弹态聚合物实现二维填料原位剥离的方法 |
| US11982208B2 (en) * | 2022-10-07 | 2024-05-14 | Hamilton Sundstrand Corporation | Two-piece impeller made of multiple materials |
| CN118501231B (zh) * | 2024-07-16 | 2024-10-18 | 天津大学 | 一种pH传感器、pH传感器的制备方法和pH测量方法 |
| CN119060498B (zh) * | 2024-11-07 | 2025-03-14 | 吉林省聚锋高新材料有限公司 | 一种聚醚醚酮基复合材料及制备方法 |
Family Cites Families (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5298214A (en) | 1990-10-30 | 1994-03-29 | Rutgers, The State University | Method of deriving polystyrene and polyolefin plastics composite from recycled plastics |
| CA2135322C (en) * | 1993-11-10 | 2001-02-06 | Hiroshi Sugahara | Method for producing a fiber-reinforced thermoplastic resin foamed product |
| JP3419093B2 (ja) | 1994-08-11 | 2003-06-23 | 三菱化学株式会社 | 熱可塑性樹脂組成物とその製造方法、およびこの組成物よりなる電磁波シールド成形品 |
| US5789477A (en) | 1996-08-30 | 1998-08-04 | Rutgers, The State University | Composite building materials from recyclable waste |
| US20060047052A1 (en) | 1999-12-07 | 2006-03-02 | Barrera Enrique V | Oriented nanofibers embedded in polymer matrix |
| US6660241B2 (en) | 2000-05-01 | 2003-12-09 | Saint-Gobain Ceramics & Plastics, Inc. | Highly delaminated hexagonal boron nitride powders, process for making, and uses thereof |
| US6962431B1 (en) | 2000-11-08 | 2005-11-08 | Randcastle Extrusion System, Inc. | Extruder mixer |
| JP2002234773A (ja) * | 2001-02-02 | 2002-08-23 | Mitsubishi Gas Chem Co Inc | 多孔質炭素材料の製造方法 |
| JP3958137B2 (ja) | 2001-08-20 | 2007-08-15 | 大塚化学ホールディングス株式会社 | 樹脂組成物 |
| US20050070658A1 (en) * | 2003-09-30 | 2005-03-31 | Soumyadeb Ghosh | Electrically conductive compositions, methods of manufacture thereof and articles derived from such compositions |
| US20050186378A1 (en) | 2004-02-23 | 2005-08-25 | Bhatt Sanjiv M. | Compositions comprising carbon nanotubes and articles formed therefrom |
| JP4245514B2 (ja) | 2004-05-24 | 2009-03-25 | 日信工業株式会社 | 炭素繊維複合材料及びその製造方法、炭素繊維複合金属材料の製造方法、炭素繊維複合非金属材料の製造方法 |
| US8048940B2 (en) | 2004-07-09 | 2011-11-01 | Vanderbilt University | Reactive graphitic carbon nanofiber reinforced polymeric composites showing enhanced flexural strength |
| US20070099792A1 (en) | 2005-04-27 | 2007-05-03 | William Marsh Rice University | Carbon nanotube reinforced thermoplastic polymer composites achieved through benzoyl peroxide initiated interfacial bonding to polymer matrices |
| US20110223405A1 (en) | 2005-11-18 | 2011-09-15 | Northwestern University | Composite polymer film with graphene nanosheets as highly effective barrier property enhancers |
| EP2029265B1 (en) | 2006-06-05 | 2013-08-14 | The University of Akron | Ultrasound assisted continuous process and apparatus for dispersion of nanofibers and nanotubes in polymers |
| AU2006345744A1 (en) | 2006-07-05 | 2008-01-10 | Owens Corning Intellectual Capital, Llc | Polymer foams containing multi-functional layered nano-graphite |
| US7745528B2 (en) | 2006-10-06 | 2010-06-29 | The Trustees Of Princeton University | Functional graphene-rubber nanocomposites |
| JP5207351B2 (ja) | 2007-03-23 | 2013-06-12 | 独立行政法人産業技術総合研究所 | 溶融混練物、樹脂成形物及びその製造方法 |
| US7824651B2 (en) | 2007-05-08 | 2010-11-02 | Nanotek Instruments, Inc. | Method of producing exfoliated graphite, flexible graphite, and nano-scaled graphene platelets |
| US8246856B2 (en) | 2007-08-01 | 2012-08-21 | Dow Global Technologies Llc | Highly efficient process for manufacture of exfoliated graphene |
| WO2009029984A1 (en) | 2007-09-03 | 2009-03-12 | Newsouth Innovations Pty Limited | Graphene |
| DE102007049439A1 (de) | 2007-09-27 | 2009-04-02 | Electrovac Ag | Kunststoff-Composite-Material sowie Verfahren zu dessen Herstellung |
| US7906053B1 (en) * | 2008-02-21 | 2011-03-15 | Northwestern University | Polymer-graphite nanocomposites via solid-state shear pulverization |
| EP2262727A2 (en) | 2008-02-28 | 2010-12-22 | Basf Se | Graphite nanoplatelets and compositions |
| US8497324B2 (en) | 2008-03-18 | 2013-07-30 | Rutgers, The State University Of New Jersey | Methods of increasing toughness of immiscible polymer blends |
| WO2009126592A2 (en) | 2008-04-07 | 2009-10-15 | Vorbeck Materials Corp. | Fuel system components |
| WO2009143405A2 (en) | 2008-05-22 | 2009-11-26 | The University Of North Carolina At Chapel Hill | Synthesis of graphene sheets and nanoparticle composites comprising same |
| JPWO2010007763A1 (ja) | 2008-07-15 | 2012-01-05 | パナソニック株式会社 | 無線受信装置、及び、使用単位バンド外参照信号のメジャメント方法 |
| TW201012749A (en) | 2008-08-19 | 2010-04-01 | Univ Rice William M | Methods for preparation of graphene nanoribbons from carbon nanotubes and compositions, thin films and devices derived therefrom |
| KR101074027B1 (ko) | 2009-03-03 | 2011-10-17 | 한국과학기술연구원 | 그래펜 복합 나노섬유 및 그 제조 방법 |
| KR101935757B1 (ko) | 2009-03-16 | 2019-01-04 | 보르벡크 머터리얼스 코포레이션 | 강화된 중합체 물품 |
| CN102612490B (zh) | 2009-04-03 | 2016-05-18 | 沃尔贝克材料有限公司 | 含有石墨烯片和石墨的聚合物组合物 |
| US20110133134A1 (en) * | 2009-06-09 | 2011-06-09 | Vorbeck Materials Corp. | Crosslinkable and Crosslinked Compositions of Olefin Polymers and Graphene Sheets |
| US8652362B2 (en) | 2009-07-23 | 2014-02-18 | Nanotek Instruments, Inc. | Nano graphene-modified curing agents for thermoset resins |
| KR101090517B1 (ko) | 2009-08-17 | 2011-12-08 | 성균관대학교산학협력단 | 탄소나노물질-고분자 복합체 및 이의 제조방법 |
| US8299159B2 (en) | 2009-08-17 | 2012-10-30 | Laird Technologies, Inc. | Highly thermally-conductive moldable thermoplastic composites and compositions |
| IT1396193B1 (it) | 2009-10-07 | 2012-11-16 | Polimeri Europa Spa | Composizioni polimeriche nanocomposite termoplastiche espansibili con migliorata capacita' di isolamento termico. |
| IT1396918B1 (it) | 2009-11-03 | 2012-12-20 | Polimeri Europa Spa | Procedimento per la preparazione di nanopiastrine grafeniche ad elevata disperdibilita' in matrici polimeriche a bassa polarita' e relative composizioni polimeriche |
| EP2550332B1 (en) | 2010-03-23 | 2018-05-16 | Solvay SA | Polymer compositions comprising semi-aromatic polyamides and graphene materials |
| FR2959231B1 (fr) | 2010-04-22 | 2012-04-20 | Arkema France | Materiau composite thermoplastique et/ou elastomerique a base de nanotubes de carbone et de graphenes |
| CN101817516A (zh) * | 2010-05-21 | 2010-09-01 | 哈尔滨工业大学 | 高效率低成本机械剥离制备石墨烯或氧化石墨烯的方法 |
| KR20120009978A (ko) | 2010-07-23 | 2012-02-02 | 현대자동차주식회사 | 배향 조정된 탄소나노튜브를 이용한 고분자 나노복합 성형물의 제조방법 |
| DE102010032885A1 (de) | 2010-07-30 | 2012-02-02 | Daimler Ag | Befestigungseinrichtung für ein faserverstärktes Kunststoffprofil |
| ES2655730T5 (es) | 2010-08-11 | 2021-07-21 | Imerys Graphite & Carbon Switzerland S A | Aglomerados de grafito expandido molidos, métodos de fabricación y aplicaciones de los mismos |
| CN103756347A (zh) | 2010-09-03 | 2014-04-30 | 积水化学工业株式会社 | 树脂复合材料及树脂复合材料的制造方法 |
| US8420042B2 (en) | 2010-09-21 | 2013-04-16 | High Temperature Physics, Llc | Process for the production of carbon graphenes and other nanomaterials |
| TW201219447A (en) * | 2010-10-12 | 2012-05-16 | Solvay | Polymer compositions comprising poly(arylether ketone)s and graphene materials |
| JP5176001B1 (ja) | 2011-03-30 | 2013-04-03 | 積水化学工業株式会社 | 樹脂複合材料 |
| CN102225759A (zh) * | 2011-04-14 | 2011-10-26 | 温州医学院 | 羟基功能化石墨烯的低温制备方法 |
| US8167190B1 (en) * | 2011-05-06 | 2012-05-01 | Lockheed Martin Corporation | Electrically conductive polymer compositions containing metal particles and a graphene and methods for production and use thereof |
| JP5953014B2 (ja) | 2011-07-08 | 2016-07-13 | 積水化学工業株式会社 | 難燃性樹脂組成物、難燃性樹脂シート及び難燃性多層シート |
| KR101245815B1 (ko) * | 2011-07-14 | 2013-03-21 | 국립대학법인 울산과학기술대학교 산학협력단 | 기계 화학적 방법에 의한 가장자리가 기능화된 그래파이트 및 이의 제조 방법 |
| KR101944140B1 (ko) | 2011-07-21 | 2019-01-30 | 엔테그리스, 아이엔씨. | 나노튜브 및 미세하게 분쇄된 탄소섬유 중합체 복합체 조성물 및 그의 제조 방법 |
| CN103717648A (zh) | 2011-10-18 | 2014-04-09 | 积水化学工业株式会社 | 树脂复合材料的制造方法及树脂复合材料 |
| JP2013233790A (ja) | 2012-04-11 | 2013-11-21 | Sekisui Chem Co Ltd | 樹脂成形体の製造方法及び樹脂成形体 |
| IN2015DN02800A (enExample) | 2012-09-28 | 2015-09-04 | Applied Nanostructured Sols | |
| EP2909028B1 (en) | 2012-10-19 | 2019-09-25 | Rutgers, the State University of New Jersey | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
| US10060019B2 (en) | 2012-11-16 | 2018-08-28 | The Boeing Company | Thermal spray coated reinforced polymer composites |
| GB201304770D0 (en) | 2013-03-15 | 2013-05-01 | Provost Fellows Foundation Scholars And The Other Members Of Board Of | A scalable process for producing exfoliated defect-free, non-oxidised 2-dimens ional materials in large quantities |
| CA2909715C (en) | 2013-04-18 | 2022-05-24 | Rutgers, The State University Of New Jersey | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
| ES2534575B1 (es) | 2013-09-24 | 2016-01-14 | Consejo Superior De Investigaciones Científicas (Csic) | Exfoliación de grafito con disolventes eutécticos profundos |
| CN116804117A (zh) | 2014-07-30 | 2023-09-26 | 新泽西鲁特格斯州立大学 | 石墨烯增强的聚合物基质复合材料 |
| WO2016106312A2 (en) | 2014-12-22 | 2016-06-30 | Reliance Industries Limited | Graphite exfoliation in resin |
| CN104945659A (zh) | 2015-06-29 | 2015-09-30 | 殷明 | 一种新型cnt表面处理方法及其在制备聚合物/cnt纳米复合材料中的应用 |
| US10685763B2 (en) | 2016-01-19 | 2020-06-16 | Xerox Corporation | Conductive polymer composite |
-
2014
- 2014-04-18 CA CA2909715A patent/CA2909715C/en active Active
- 2014-04-18 CN CN201480034794.1A patent/CN105324241B/zh active Active
- 2014-04-18 EP EP14784738.8A patent/EP2994308B1/en active Active
- 2014-04-18 KR KR1020157032961A patent/KR102292918B1/ko active Active
- 2014-04-18 JP JP2016509122A patent/JP6393743B2/ja active Active
- 2014-04-18 SG SG11201508599PA patent/SG11201508599PA/en unknown
- 2014-04-18 MX MX2015014631A patent/MX383525B/es unknown
- 2014-04-18 WO PCT/US2014/034624 patent/WO2014172619A1/en not_active Ceased
- 2014-04-18 US US14/784,974 patent/US10253154B2/en active Active
- 2014-04-18 BR BR112015026355-0A patent/BR112015026355B1/pt active IP Right Grant
- 2014-04-18 HK HK16109585.4A patent/HK1221440A1/zh unknown
-
2018
- 2018-08-27 JP JP2018158453A patent/JP6633703B2/ja active Active
-
2019
- 2019-04-08 US US16/377,962 patent/US11174366B2/en active Active
- 2019-12-12 JP JP2019224864A patent/JP7072259B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2909715A1 (en) | 2014-10-23 |
| JP6633703B2 (ja) | 2020-01-22 |
| BR112015026355A2 (pt) | 2017-09-26 |
| WO2014172619A1 (en) | 2014-10-23 |
| KR20160003719A (ko) | 2016-01-11 |
| MX383525B (es) | 2025-03-14 |
| US20160083552A1 (en) | 2016-03-24 |
| BR112015026355B1 (pt) | 2021-03-30 |
| EP2994308A1 (en) | 2016-03-16 |
| MX2015014631A (es) | 2016-09-29 |
| HK1221440A1 (zh) | 2017-06-02 |
| JP6393743B2 (ja) | 2018-09-19 |
| CN105324241A (zh) | 2016-02-10 |
| JP2019002021A (ja) | 2019-01-10 |
| US11174366B2 (en) | 2021-11-16 |
| SG11201508599PA (en) | 2015-11-27 |
| EP2994308B1 (en) | 2024-04-10 |
| US20190233611A1 (en) | 2019-08-01 |
| CN105324241B (zh) | 2017-06-13 |
| JP2016519191A (ja) | 2016-06-30 |
| US10253154B2 (en) | 2019-04-09 |
| JP2020063447A (ja) | 2020-04-23 |
| JP7072259B2 (ja) | 2022-05-20 |
| EP2994308A4 (en) | 2016-11-23 |
| KR102292918B1 (ko) | 2021-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11174366B2 (en) | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite | |
| US11225558B2 (en) | Graphene-reinforced polymer matrix composites | |
| US11098175B2 (en) | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite | |
| US11479652B2 (en) | Covalent conjugates of graphene nanoparticles and polymer chains and composite materials formed therefrom | |
| US12460064B2 (en) | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite | |
| TWI786340B (zh) | 石墨烯奈米顆粒與聚合物鏈的共價綴合物、由其所形成的複合材料以及其製造方法 | |
| HK1246760B (en) | Graphene-reinforced polymer matrix composites | |
| HK1246760A1 (en) | Graphene-reinforced polymer matrix composites | |
| HK1214209B (en) | In situ exfoliation method to fabricate a graphene-reinforced polymer matrix composite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20190415 |