CA2867714A1 - Laundry care compositions containing dyes - Google Patents
Laundry care compositions containing dyes Download PDFInfo
- Publication number
- CA2867714A1 CA2867714A1 CA2867714A CA2867714A CA2867714A1 CA 2867714 A1 CA2867714 A1 CA 2867714A1 CA 2867714 A CA2867714 A CA 2867714A CA 2867714 A CA2867714 A CA 2867714A CA 2867714 A1 CA2867714 A1 CA 2867714A1
- Authority
- CA
- Canada
- Prior art keywords
- dye
- laundry care
- mixtures
- composition
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 321
- 239000000975 dye Substances 0.000 title claims abstract description 159
- 238000000034 method Methods 0.000 claims abstract description 57
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 17
- 239000004753 textile Substances 0.000 claims abstract description 13
- -1 4-styryl-3-sulfophenyl Chemical group 0.000 claims description 85
- 229920000642 polymer Polymers 0.000 claims description 64
- 239000003795 chemical substances by application Substances 0.000 claims description 49
- 125000000217 alkyl group Chemical group 0.000 claims description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 41
- 229910052739 hydrogen Inorganic materials 0.000 claims description 34
- 239000004094 surface-active agent Substances 0.000 claims description 32
- 239000002304 perfume Substances 0.000 claims description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- 108090001060 Lipase Proteins 0.000 claims description 22
- 239000004367 Lipase Substances 0.000 claims description 22
- 102000004882 Lipase Human genes 0.000 claims description 22
- 235000019421 lipase Nutrition 0.000 claims description 22
- 150000001875 compounds Chemical class 0.000 claims description 19
- 239000000460 chlorine Substances 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 17
- 239000002245 particle Substances 0.000 claims description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- 125000003118 aryl group Chemical group 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 239000000987 azo dye Substances 0.000 claims description 10
- 230000008033 biological extinction Effects 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 150000001408 amides Chemical class 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- VILAVOFMIJHSJA-UHFFFAOYSA-N dicarbon monoxide Chemical compound [C]=C=O VILAVOFMIJHSJA-UHFFFAOYSA-N 0.000 claims description 8
- 125000005647 linker group Chemical group 0.000 claims description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000001768 cations Chemical class 0.000 claims description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 5
- 150000004056 anthraquinones Chemical class 0.000 claims description 5
- 125000000623 heterocyclic group Chemical group 0.000 claims description 5
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- 229930192627 Naphthoquinone Natural products 0.000 claims description 4
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical class C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 claims description 4
- 150000002791 naphthoquinones Chemical class 0.000 claims description 4
- QQBPIHBUCMDKFG-UHFFFAOYSA-N phenazopyridine hydrochloride Chemical group Cl.NC1=NC(N)=CC=C1N=NC1=CC=CC=C1 QQBPIHBUCMDKFG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 4
- 229910001414 potassium ion Inorganic materials 0.000 claims description 4
- 150000003217 pyrazoles Chemical class 0.000 claims description 4
- 229910001415 sodium ion Inorganic materials 0.000 claims description 4
- 150000004961 triphenylmethanes Chemical class 0.000 claims description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000003094 microcapsule Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001204 N-oxides Chemical class 0.000 claims description 2
- 125000002837 carbocyclic group Chemical group 0.000 claims description 2
- 150000002118 epoxides Chemical class 0.000 claims description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims 1
- 239000001000 anthraquinone dye Substances 0.000 claims 1
- PMPJQLCPEQFEJW-HPKCLRQXSA-L disodium;2-[(e)-2-[4-[4-[(e)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical group [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C\C1=CC=C(C=2C=CC(\C=C\C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-HPKCLRQXSA-L 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 50
- 239000007844 bleaching agent Substances 0.000 description 35
- 239000007788 liquid Substances 0.000 description 34
- 239000000047 product Substances 0.000 description 34
- 239000003599 detergent Substances 0.000 description 33
- 239000000463 material Substances 0.000 description 32
- 102000004190 Enzymes Human genes 0.000 description 29
- 108090000790 Enzymes Proteins 0.000 description 29
- 229940088598 enzyme Drugs 0.000 description 28
- 150000003839 salts Chemical class 0.000 description 28
- 239000002253 acid Substances 0.000 description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 24
- 102000035195 Peptidases Human genes 0.000 description 23
- 108091005804 Peptidases Proteins 0.000 description 23
- 230000003750 conditioning effect Effects 0.000 description 23
- 239000004365 Protease Substances 0.000 description 22
- 230000015572 biosynthetic process Effects 0.000 description 22
- 238000003786 synthesis reaction Methods 0.000 description 19
- 125000002091 cationic group Chemical group 0.000 description 18
- 238000005406 washing Methods 0.000 description 18
- 229920002678 cellulose Polymers 0.000 description 17
- 150000004965 peroxy acids Chemical class 0.000 description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 16
- 239000001913 cellulose Substances 0.000 description 16
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 15
- 108010065511 Amylases Proteins 0.000 description 14
- 102000013142 Amylases Human genes 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 14
- 235000019418 amylase Nutrition 0.000 description 14
- 235000010980 cellulose Nutrition 0.000 description 14
- 239000004927 clay Substances 0.000 description 14
- 229920001296 polysiloxane Polymers 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 13
- 229910021653 sulphate ion Inorganic materials 0.000 description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 239000004372 Polyvinyl alcohol Substances 0.000 description 12
- 244000172533 Viola sororia Species 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000000049 pigment Substances 0.000 description 12
- 159000000000 sodium salts Chemical class 0.000 description 12
- 239000002689 soil Substances 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- 239000012190 activator Substances 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- 229920006317 cationic polymer Polymers 0.000 description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 238000007789 sealing Methods 0.000 description 11
- MHOFGBJTSNWTDT-UHFFFAOYSA-M 2-[n-ethyl-4-[(6-methoxy-3-methyl-1,3-benzothiazol-3-ium-2-yl)diazenyl]anilino]ethanol;methyl sulfate Chemical compound COS([O-])(=O)=O.C1=CC(N(CCO)CC)=CC=C1N=NC1=[N+](C)C2=CC=C(OC)C=C2S1 MHOFGBJTSNWTDT-UHFFFAOYSA-M 0.000 description 10
- 239000004382 Amylase Substances 0.000 description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 10
- 229920002125 Sokalan® Polymers 0.000 description 10
- 229910021536 Zeolite Inorganic materials 0.000 description 10
- 239000003945 anionic surfactant Substances 0.000 description 10
- 239000004359 castor oil Substances 0.000 description 10
- 235000019438 castor oil Nutrition 0.000 description 10
- 238000004140 cleaning Methods 0.000 description 10
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 10
- 229920000058 polyacrylate Polymers 0.000 description 10
- 239000010457 zeolite Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 150000001413 amino acids Chemical group 0.000 description 9
- 125000000129 anionic group Chemical group 0.000 description 9
- 239000001768 carboxy methyl cellulose Substances 0.000 description 9
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 9
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 9
- 229940105329 carboxymethylcellulose Drugs 0.000 description 9
- 230000007062 hydrolysis Effects 0.000 description 9
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 101000740449 Bacillus subtilis (strain 168) Biotin/lipoyl attachment protein Proteins 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 8
- 150000004996 alkyl benzenes Chemical class 0.000 description 8
- 125000003710 aryl alkyl group Chemical group 0.000 description 8
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 8
- 239000011162 core material Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
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- VRVDFJOCCWSFLI-UHFFFAOYSA-K trisodium 3-[[4-[(6-anilino-1-hydroxy-3-sulfonatonaphthalen-2-yl)diazenyl]-5-methoxy-2-methylphenyl]diazenyl]naphthalene-1,5-disulfonate Chemical compound [Na+].[Na+].[Na+].COc1cc(N=Nc2cc(c3cccc(c3c2)S([O-])(=O)=O)S([O-])(=O)=O)c(C)cc1N=Nc1c(O)c2ccc(Nc3ccccc3)cc2cc1S([O-])(=O)=O VRVDFJOCCWSFLI-UHFFFAOYSA-K 0.000 description 8
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 7
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 7
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- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 7
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- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 7
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- 125000001246 bromo group Chemical group Br* 0.000 description 6
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
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- 125000001424 substituent group Chemical group 0.000 description 6
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
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- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 4
- KFSNHOUZAIGMAF-UHFFFAOYSA-N 3-n,3-n-diethylbenzene-1,3-diamine Chemical compound CCN(CC)C1=CC=CC(N)=C1 KFSNHOUZAIGMAF-UHFFFAOYSA-N 0.000 description 4
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- 125000001309 chloro group Chemical group Cl* 0.000 description 4
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- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
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- 229940071087 ethylenediamine disuccinate Drugs 0.000 description 4
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- 150000004676 glycans Chemical class 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
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- 238000004519 manufacturing process Methods 0.000 description 4
- 108010020132 microbial serine proteinases Proteins 0.000 description 4
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- 238000003756 stirring Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical compound O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 108010038851 tannase Proteins 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- LKHDXIBHVSGUHN-UHFFFAOYSA-N thiadiazole 1,1-dioxide Chemical class O=S1(=O)C=CN=N1 LKHDXIBHVSGUHN-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 1
- 150000003573 thiols Chemical group 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- YKSGNOMLAIJTLT-UHFFFAOYSA-N violanthrone Chemical compound C12=C3C4=CC=C2C2=CC=CC=C2C(=O)C1=CC=C3C1=CC=C2C(=O)C3=CC=CC=C3C3=CC=C4C1=C32 YKSGNOMLAIJTLT-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 229940030186 xpect Drugs 0.000 description 1
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- GAWWVVGZMLGEIW-GNNYBVKZSA-L zinc ricinoleate Chemical compound [Zn+2].CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O.CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O GAWWVVGZMLGEIW-GNNYBVKZSA-L 0.000 description 1
- 229940100530 zinc ricinoleate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0003—Monoazo dyes prepared by diazotising and coupling from diazotized anilines
- C09B29/0007—Monoazo dyes prepared by diazotising and coupling from diazotized anilines containing acid groups, e.g. CO2H, SO3H, PO3H2, OSO3H, OPO2H2; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0801—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls
- C09B29/0802—Amino benzenes containing acid groups, e.g. COOH, SO3H, PO3H2, OSO3H, OPO3H2; SO2NHSO2R or salts thereof, R being hydrocarbonyls containing COOH
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
- C09B29/0805—Amino benzenes free of acid groups
- C09B29/0807—Amino benzenes free of acid groups characterised by the amino group
- C09B29/0809—Amino benzenes free of acid groups characterised by the amino group substituted amino group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261612539P | 2012-03-19 | 2012-03-19 | |
| US61/612,539 | 2012-03-19 | ||
| PCT/US2013/032953 WO2013142486A1 (en) | 2012-03-19 | 2013-03-19 | Laundry care compositions containing dyes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2867714A1 true CA2867714A1 (en) | 2013-09-26 |
Family
ID=48048256
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2867714A Abandoned CA2867714A1 (en) | 2012-03-19 | 2013-03-19 | Laundry care compositions containing dyes |
| CA2867361A Active CA2867361C (en) | 2012-03-19 | 2013-03-19 | Carboxylate dyes |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2867361A Active CA2867361C (en) | 2012-03-19 | 2013-03-19 | Carboxylate dyes |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US9187717B2 (enExample) |
| EP (2) | EP2828340A1 (enExample) |
| JP (2) | JP6203812B2 (enExample) |
| CN (2) | CN104350106B (enExample) |
| BR (1) | BR112014023153B1 (enExample) |
| CA (2) | CA2867714A1 (enExample) |
| IN (2) | IN2014DN07573A (enExample) |
| MX (2) | MX361441B (enExample) |
| TR (1) | TR201900214T4 (enExample) |
| WO (2) | WO2013142495A1 (enExample) |
Families Citing this family (180)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5382692B2 (ja) | 2006-07-10 | 2014-01-08 | 学校法人藤田学園 | 抗体の分類法、抗原の同定法、抗体又は抗体セットの取得法、抗体パネルの作成法、並びに抗体又は抗体セット及びその用途 |
| US8715368B2 (en) | 2010-11-12 | 2014-05-06 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
| EP2929005A1 (en) | 2012-12-06 | 2015-10-14 | The Procter & Gamble Company | Soluble pouch comprising hueing dye |
| BR112015028824A2 (pt) | 2013-05-24 | 2017-07-25 | Procter & Gamble | composição de tensoativo concentrada |
| CA2910875C (en) | 2013-05-24 | 2018-11-06 | The Procter & Gamble Company | Low ph detergent composition |
| EP3004307A1 (en) | 2013-05-24 | 2016-04-13 | The Procter & Gamble Company | Low ph detergent composition comprising nonionic surfactants |
| US9834682B2 (en) | 2013-09-18 | 2017-12-05 | Milliken & Company | Laundry care composition comprising carboxylate dye |
| US9267096B2 (en) * | 2013-10-29 | 2016-02-23 | Ecolab USA, Inc. | Use of amino carboxylate for enhancing metal protection in alkaline detergents |
| EP2899260A1 (en) | 2014-01-22 | 2015-07-29 | Unilever PLC | Process to manufacture a liquid detergent formulation |
| JP6542351B2 (ja) | 2014-07-23 | 2019-07-10 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 布地ケア及びホームケア処理組成物 |
| WO2016014733A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| CA2952983C (en) | 2014-07-23 | 2020-04-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| US20160024431A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Treatment compositions |
| WO2016014802A1 (en) * | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| WO2016014732A1 (en) | 2014-07-23 | 2016-01-28 | The Procter & Gamble Company | Fabric and home care treatment compositions |
| US10538719B2 (en) | 2014-07-23 | 2020-01-21 | The Procter & Gamble Company | Treatment compositions |
| US10357410B2 (en) | 2014-11-06 | 2019-07-23 | The Procter & Gamble Company | Pre-strained laminates and methods for making the same |
| EP3303535B1 (en) | 2015-05-27 | 2018-10-03 | Unilever PLC | Laundry detergent composition |
| EP3098295A1 (en) * | 2015-05-29 | 2016-11-30 | The Procter and Gamble Company | Process for making a single or multi-compartment pouch |
| WO2016192905A1 (en) | 2015-06-02 | 2016-12-08 | Unilever Plc | Laundry detergent composition |
| US10208422B2 (en) * | 2015-06-15 | 2019-02-19 | Monosol, Llc | Laundry stain removal device |
| JP2018522119A (ja) * | 2015-07-16 | 2018-08-09 | ザ プロクター アンド ギャンブル カンパニー | 手洗い食器洗浄の方法 |
| EP3356504B1 (en) | 2015-10-01 | 2019-08-14 | Unilever PLC | Powder laundry detergent composition |
| US9745544B2 (en) | 2015-10-13 | 2017-08-29 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
| US9902923B2 (en) * | 2015-10-13 | 2018-02-27 | The Procter & Gamble Company | Polyglycerol dye whitening agents for cellulosic substrates |
| US10597614B2 (en) | 2015-10-13 | 2020-03-24 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
| JP6828043B2 (ja) | 2016-01-25 | 2021-02-10 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 処理組成物 |
| US10689600B2 (en) | 2016-01-25 | 2020-06-23 | The Procter & Gamble Company | Treatment compositions |
| US20170218202A1 (en) * | 2016-01-29 | 2017-08-03 | Milliken & Company | Bis-Azo Colorants For Use As Bluing Agents |
| WO2017140391A1 (en) | 2016-02-17 | 2017-08-24 | Unilever Plc | Whitening composition |
| BR112018016674B1 (pt) | 2016-02-17 | 2022-06-07 | Unilever Ip Holdings B.V. | Composição de detergente para lavagem de roupas e método doméstico de tratamento de um tecido |
| WO2017162378A1 (en) | 2016-03-21 | 2017-09-28 | Unilever Plc | Laundry detergent composition |
| CN108779416B (zh) | 2016-04-08 | 2021-01-05 | 荷兰联合利华有限公司 | 洗衣洗涤剂组合物 |
| ES2985315T3 (es) | 2016-05-17 | 2024-11-05 | Unilever Ip Holdings B V | Composiciones de detergente líquidas para el lavado de ropa |
| CN109196083A (zh) | 2016-05-17 | 2019-01-11 | 荷兰联合利华有限公司 | 液体洗衣洗涤剂组合物 |
| EP3519542B1 (en) | 2016-09-27 | 2020-02-19 | Unilever PLC | Domestic laundering method |
| BR112019007851B1 (pt) | 2016-10-18 | 2022-10-18 | Unilever Ip Holdings B.V. | Composição detergente para lavagem de roupas e método doméstico de tratamento de um tecido |
| EP3555255B1 (en) | 2016-12-15 | 2020-06-24 | Unilever PLC | Laundry detergent composition |
| EP4056158B1 (en) | 2017-02-16 | 2024-03-06 | The Procter & Gamble Company | Absorbent articles with substrates having repeating patterns of apertures comprising a plurality of repeat units |
| US10920177B2 (en) * | 2017-03-16 | 2021-02-16 | Encapsys, Llc | Benefit agent containing delivery particle composition |
| EP3596195A1 (en) * | 2017-03-16 | 2020-01-22 | The Procter and Gamble Company | Benefit agent containing delivery particle |
| ES2981687T3 (es) * | 2017-03-16 | 2024-10-10 | Procter & Gamble | Suspensiones de partículas de suministro que contienen agentes beneficiosos |
| WO2019008036A1 (en) | 2017-07-07 | 2019-01-10 | Unilever Plc | WHITENING COMPOSITION |
| EP3649221B8 (en) | 2017-07-07 | 2024-05-29 | Unilever IP Holdings B.V. | Laundry cleaning composition |
| JP6993503B2 (ja) * | 2017-10-12 | 2022-01-13 | ザ プロクター アンド ギャンブル カンパニー | 洗濯ケア組成物中の青味剤としてのロイコ着色剤 |
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| EP3717616B1 (en) | 2017-11-30 | 2021-10-13 | Unilever IP Holdings B.V. | Detergent composition comprising protease |
| BR112020019253A2 (pt) | 2018-04-03 | 2021-01-12 | Unilever N.V. | Grânulo corante detergente, composição detergente de lavanderia granular, processo para prover uma composição detergente de lavanderia granular e método de tratamento de um tecido |
| US12127925B2 (en) | 2018-04-17 | 2024-10-29 | The Procter & Gamble Company | Webs for absorbent articles and methods of making the same |
| EP3775122A1 (en) | 2018-05-17 | 2021-02-17 | Unilever PLC | Cleaning composition comprising rhamnolipid and alkyl ether carboxylate surfactants |
| BR112020023083A2 (pt) | 2018-05-17 | 2021-02-02 | Unilever N.V. | composição de limpeza fluida, composição detergente líquida para lavanderia e uso de uma combinação de tensoativos |
| EP3578629B1 (de) * | 2018-06-07 | 2023-06-07 | Henkel AG & Co. KGaA | Verfahren zur herstellung eines flüssigen wasch- oder reinigungsmittels mit einer konservierungsmittelfreien farbstofflösung |
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| EP3853330B1 (en) | 2018-09-17 | 2023-06-07 | Unilever Global Ip Limited | Detergent composition |
| US11155771B2 (en) | 2018-11-09 | 2021-10-26 | Henkel Ag & Co. Kgaa | Method for preparing a liquid washing or cleaning agent using a preservative-free dye solution |
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| WO2020104156A1 (en) | 2018-11-20 | 2020-05-28 | Unilever Plc | Detergent composition |
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-
2013
- 2013-03-19 JP JP2015501853A patent/JP6203812B2/ja not_active Expired - Fee Related
- 2013-03-19 US US14/384,409 patent/US9187717B2/en active Active
- 2013-03-19 BR BR112014023153-2A patent/BR112014023153B1/pt not_active IP Right Cessation
- 2013-03-19 IN IN7573DEN2014 patent/IN2014DN07573A/en unknown
- 2013-03-19 MX MX2014011169A patent/MX361441B/es active IP Right Grant
- 2013-03-19 MX MX2014011154A patent/MX2014011154A/es unknown
- 2013-03-19 CN CN201380015293.4A patent/CN104350106B/zh not_active Expired - Fee Related
- 2013-03-19 CA CA2867714A patent/CA2867714A1/en not_active Abandoned
- 2013-03-19 WO PCT/US2013/032967 patent/WO2013142495A1/en not_active Ceased
- 2013-03-19 CN CN201380019701.3A patent/CN104220535B/zh not_active Expired - Fee Related
- 2013-03-19 WO PCT/US2013/032953 patent/WO2013142486A1/en not_active Ceased
- 2013-03-19 EP EP13715509.9A patent/EP2828340A1/en not_active Withdrawn
- 2013-03-19 EP EP13714456.4A patent/EP2828339B1/en active Active
- 2013-03-19 CA CA2867361A patent/CA2867361C/en active Active
- 2013-03-19 IN IN7763DEN2014 patent/IN2014DN07763A/en unknown
- 2013-03-19 JP JP2015501851A patent/JP5911996B2/ja not_active Expired - Fee Related
- 2013-03-19 TR TR2019/00214T patent/TR201900214T4/tr unknown
-
2014
- 2014-09-18 US US14/489,772 patent/US20150000048A1/en not_active Abandoned
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- 2015-11-20 US US14/946,822 patent/US20160075977A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CA2867361A1 (en) | 2013-09-26 |
| CN104350106A (zh) | 2015-02-11 |
| IN2014DN07573A (enExample) | 2015-04-24 |
| CN104220535B (zh) | 2017-03-22 |
| EP2828339A1 (en) | 2015-01-28 |
| US20150099869A1 (en) | 2015-04-09 |
| JP5911996B2 (ja) | 2016-04-27 |
| WO2013142495A1 (en) | 2013-09-26 |
| MX2014011154A (es) | 2014-12-10 |
| JP6203812B2 (ja) | 2017-09-27 |
| JP2015514142A (ja) | 2015-05-18 |
| MX2014011169A (es) | 2016-05-26 |
| TR201900214T4 (tr) | 2019-02-21 |
| IN2014DN07763A (enExample) | 2015-05-15 |
| CN104350106B (zh) | 2017-03-08 |
| CA2867361C (en) | 2017-07-25 |
| MX361441B (es) | 2018-12-06 |
| WO2013142486A1 (en) | 2013-09-26 |
| BR112014023153B1 (pt) | 2021-02-23 |
| CN104220535A (zh) | 2014-12-17 |
| US20160075977A1 (en) | 2016-03-17 |
| EP2828340A1 (en) | 2015-01-28 |
| US9187717B2 (en) | 2015-11-17 |
| JP2015514141A (ja) | 2015-05-18 |
| US20150000048A1 (en) | 2015-01-01 |
| EP2828339B1 (en) | 2018-10-31 |
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