CA2702425C - Dishwasher detergent formulations comprising a mixture of hydrophobically modified polycarboxylates and hydrophilically modified polycarboxylates - Google Patents
Dishwasher detergent formulations comprising a mixture of hydrophobically modified polycarboxylates and hydrophilically modified polycarboxylates Download PDFInfo
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- CA2702425C CA2702425C CA2702425A CA2702425A CA2702425C CA 2702425 C CA2702425 C CA 2702425C CA 2702425 A CA2702425 A CA 2702425A CA 2702425 A CA2702425 A CA 2702425A CA 2702425 C CA2702425 C CA 2702425C
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- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 238000009472 formulation Methods 0.000 title claims abstract description 40
- 229920005646 polycarboxylate Polymers 0.000 title claims abstract description 38
- 239000003599 detergent Substances 0.000 title claims description 46
- 238000004851 dishwashing Methods 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims description 40
- -1 cyclic radical Chemical class 0.000 claims description 28
- 229920000642 polymer Polymers 0.000 claims description 24
- 150000003839 salts Chemical class 0.000 claims description 24
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 20
- 239000007844 bleaching agent Substances 0.000 claims description 20
- 125000004432 carbon atom Chemical group C* 0.000 claims description 20
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 13
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 12
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 12
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 12
- 239000011976 maleic acid Substances 0.000 claims description 12
- 239000012190 activator Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000008139 complexing agent Substances 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 229920002367 Polyisobutene Polymers 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 230000007797 corrosion Effects 0.000 claims description 6
- 238000005260 corrosion Methods 0.000 claims description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002736 nonionic surfactant Substances 0.000 claims description 6
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical compound CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 claims description 5
- 108090000790 Enzymes Proteins 0.000 claims description 5
- 102000004190 Enzymes Human genes 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000000969 carrier Substances 0.000 claims description 5
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000003205 fragrance Substances 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 229940069096 dodecene Drugs 0.000 claims description 3
- 239000006260 foam Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 claims description 2
- DCCWEYXHEXDZQW-BYPYZUCNSA-N (2s)-2-[bis(carboxymethyl)amino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)N(CC(O)=O)CC(O)=O DCCWEYXHEXDZQW-BYPYZUCNSA-N 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 claims description 2
- JPGSFSFMINKKJZ-UHFFFAOYSA-N 2-[1,2-dicarboxyethyl(hydroxy)amino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)N(O)C(CC(O)=O)C(O)=O JPGSFSFMINKKJZ-UHFFFAOYSA-N 0.000 claims description 2
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 claims description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 claims description 2
- 235000013922 glutamic acid Nutrition 0.000 claims description 2
- 239000004220 glutamic acid Substances 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 229960003330 pentetic acid Drugs 0.000 claims description 2
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 10
- 150000001868 cobalt Chemical class 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 229910052783 alkali metal Inorganic materials 0.000 description 9
- 239000000460 chlorine Substances 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
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- 239000000243 solution Substances 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 5
- 235000001465 calcium Nutrition 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 150000002696 manganese Chemical class 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 4
- UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229940088598 enzyme Drugs 0.000 description 4
- 235000013350 formula milk Nutrition 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 235000019589 hardness Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 description 3
- RUZAHKTXOIYZNE-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid;iron(2+) Chemical compound [Fe+2].OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O RUZAHKTXOIYZNE-UHFFFAOYSA-N 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 159000000007 calcium salts Chemical class 0.000 description 3
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- OMXANELYEWRDAW-UHFFFAOYSA-N 1-Hexacosene Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCC=C OMXANELYEWRDAW-UHFFFAOYSA-N 0.000 description 2
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- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 2
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- GGNQRNBDZQJCCN-UHFFFAOYSA-N benzene-1,2,4-triol Chemical compound OC1=CC=C(O)C(O)=C1 GGNQRNBDZQJCCN-UHFFFAOYSA-N 0.000 description 2
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- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
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- 150000004677 hydrates Chemical class 0.000 description 2
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- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 2
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- UYPYRKYUKCHHIB-UHFFFAOYSA-N trimethylamine N-oxide Chemical class C[N+](C)(C)[O-] UYPYRKYUKCHHIB-UHFFFAOYSA-N 0.000 description 2
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- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
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- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
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- FCLPGDSITYLYCH-UHFFFAOYSA-N 2,2,2-trichloroethanamine Chemical compound NCC(Cl)(Cl)Cl FCLPGDSITYLYCH-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- TWDUKWCXYKWSKZ-UHFFFAOYSA-N 2-(7-methyloctanoyloxy)benzenesulfonic acid Chemical class CC(C)CCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O TWDUKWCXYKWSKZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07118356 | 2007-10-12 | ||
| EP07118356.0 | 2007-10-12 | ||
| PCT/EP2008/063646 WO2009050123A2 (de) | 2007-10-12 | 2008-10-10 | Geschirrreinigungsformulierungen enthaltend ein gemisch aus hydrophob modifizierten polycarboxylaten und hydrophil modifizierten polycarboxylaten |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2702425A1 CA2702425A1 (en) | 2009-04-23 |
| CA2702425C true CA2702425C (en) | 2016-02-23 |
Family
ID=40276047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2702425A Expired - Fee Related CA2702425C (en) | 2007-10-12 | 2008-10-10 | Dishwasher detergent formulations comprising a mixture of hydrophobically modified polycarboxylates and hydrophilically modified polycarboxylates |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US8262804B2 (enExample) |
| EP (1) | EP2201090B1 (enExample) |
| JP (1) | JP5606319B2 (enExample) |
| KR (1) | KR101529351B1 (enExample) |
| CN (1) | CN101821370B (enExample) |
| AT (1) | ATE522595T1 (enExample) |
| AU (1) | AU2008313803B2 (enExample) |
| BR (1) | BRPI0818439B1 (enExample) |
| CA (1) | CA2702425C (enExample) |
| ES (1) | ES2371698T3 (enExample) |
| MX (1) | MX2010003792A (enExample) |
| PL (1) | PL2201090T3 (enExample) |
| WO (1) | WO2009050123A2 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009017724A1 (de) * | 2009-04-11 | 2010-10-14 | Clariant International Limited | Bleichmittelgranulate |
| JP5491770B2 (ja) * | 2009-05-29 | 2014-05-14 | 花王株式会社 | 自動食器洗浄機用洗浄剤組成物 |
| JP5491773B2 (ja) * | 2009-06-10 | 2014-05-14 | 花王株式会社 | 自動食器洗浄機用洗浄剤組成物 |
| SG173230A1 (en) * | 2010-01-25 | 2011-08-29 | Rohm & Haas | Laundry detergent bar composition |
| JP5834261B2 (ja) * | 2010-09-30 | 2015-12-16 | サンノプコ株式会社 | 加水分解用助剤及びこれを用いた糖質の加水分解方法 |
| DE102011119332A1 (de) * | 2011-11-25 | 2013-05-29 | Centrum Für Angewandte Nanotechnologie (Can) Gmbh | Verwendung von über radikalische Emulsionspolymerisation erhältlichen Polymeren als Verdicker für Reinigungsmittel |
| ES2744403T3 (es) | 2013-03-15 | 2020-02-25 | Lubrizol Advanced Mat Inc | Copolímeros de ácido itacónico |
| RU2656214C2 (ru) * | 2013-04-02 | 2018-06-01 | Басф Се | Композиции, их применение в качестве или для получения средств для мытья посуды и их получение |
| WO2015042013A1 (en) | 2013-09-18 | 2015-03-26 | Lubrizol Advanced Materials, Inc. | Stable linear polymers |
| MX2016005852A (es) * | 2013-11-11 | 2016-07-13 | Ecolab Usa Inc | Detergente de lavado de utensilios altamente alcalino con control de incrustaciones y dispersion de suciedad mejorados. |
| CN105992813B (zh) * | 2014-02-20 | 2019-01-29 | 荷兰联合利华有限公司 | 机洗餐具组合物 |
| KR102350475B1 (ko) | 2014-03-14 | 2022-01-11 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 이타콘산 폴리머 및 코폴리머 |
| CN104001627B (zh) * | 2014-05-12 | 2016-09-14 | 昆明理工大学 | 一种选择性抑制白钨矿矿石中含钙脉石矿物的抑制剂 |
| BR112017018859B1 (pt) | 2015-03-20 | 2022-12-13 | Rohm And Haas Company | Composição de detergente para lavagem automática de louças e método de limpeza de um artigo em uma máquina de lavar louças automática |
| FR3067718B1 (fr) * | 2017-06-16 | 2020-08-14 | Coatex Sas | Composition detergente polymerique sans phosphate |
| WO2019027635A1 (en) * | 2017-07-31 | 2019-02-07 | Dow Global Technologies Llc | DETERGENT ADDITIVE |
| JP7231611B2 (ja) * | 2017-07-31 | 2023-03-01 | ダウ グローバル テクノロジーズ エルエルシー | 洗剤添加剤 |
| US11840680B2 (en) * | 2018-05-02 | 2023-12-12 | Basf Se | Dishwashing detergent formulations comprising polyaspartic acid and graft polymers based on oligo- and polysaccharides as film inhibiting additives |
| CN109665634A (zh) * | 2019-01-30 | 2019-04-23 | 上海电力学院 | 一种高分子阻垢缓蚀剂及其制备方法和应用 |
| EP3980516B1 (en) * | 2019-06-05 | 2025-09-10 | Dow Global Technologies LLC | Automatic dishwashing compositions and method of cleaning articles |
| CN114269890B (zh) | 2019-08-06 | 2023-05-23 | 埃科莱布美国股份有限公司 | 含有马来酸四元共聚物的洗涤剂组合物 |
| DE102019126683A1 (de) * | 2019-10-02 | 2021-04-08 | Henkel Ag & Co. Kgaa | Copolymere zur Verbesserung der Lagerstabilität von Enzymen in Wasch- und Reinigungsmitteln |
| KR102266427B1 (ko) * | 2019-11-27 | 2021-06-18 | 애경산업(주) | 의류용 액체 세제 조성물 |
| WO2021170427A1 (en) * | 2020-02-28 | 2021-09-02 | Unilever Ip Holdings B.V. | Dishwash detergent product |
| WO2024089079A1 (en) | 2022-10-25 | 2024-05-02 | Symrise Ag | Dish cleaning and/or dish rinsing composition with improved finishing properties |
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| GB8629837D0 (en) | 1986-12-13 | 1987-01-21 | Interox Chemicals Ltd | Bleach activation |
| US5245075A (en) | 1987-11-13 | 1993-09-14 | Ausimont S.R.L. | Peroxy carboxylic amino derivatives |
| US5292447A (en) | 1988-06-14 | 1994-03-08 | Ausimont S.R.L. | Heterocyclic peroxides having n-amidic heteroatoms |
| US5039447A (en) | 1988-12-12 | 1991-08-13 | Monsanto Company | Pourable sulfone peracid compositions |
| GB8908416D0 (en) | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
| GB9003741D0 (en) | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
| US5041232A (en) | 1990-03-16 | 1991-08-20 | Lever Brothers Company, Division Of Conopco, Inc. | Sulfonimines as bleach catalysts |
| US5047163A (en) | 1990-03-16 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Activation of bleach precursors with sulfonimines |
| EP0458397B1 (en) | 1990-05-21 | 1997-03-26 | Unilever N.V. | Bleach activation |
| ATE155165T1 (de) | 1991-07-31 | 1997-07-15 | Ausimont Spa | Verfahren zur erhöhung der bleichwirksamkeit eines inorganischen persalzes |
| EP0544490A1 (en) | 1991-11-26 | 1993-06-02 | Unilever Plc | Detergent bleach compositions |
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| GB9127060D0 (en) | 1991-12-20 | 1992-02-19 | Unilever Plc | Bleach activation |
| GB9305863D0 (en) | 1993-03-22 | 1993-05-12 | Unilever Plc | Peroxyacids |
| DE69419750T2 (de) | 1993-05-20 | 2000-05-31 | The Procter & Gamble Co., Cincinnati | Bleichmittelzusammensetzungen enthaltend n-acylcaprolactam aktivatoren |
| AU6949094A (en) | 1993-05-20 | 1994-12-20 | Procter & Gamble Company, The | Bleaching compounds comprising substituted benzoyl caprolactam bleach activators |
| JP3285871B2 (ja) | 1993-05-20 | 2002-05-27 | ザ、プロクター、エンド、ギャンブル、カンパニー | 手洗いまたは他の低水クリーニングシステムで使用するためのｎ−アシルカプロラクタムを含む漂白コンパウンド |
| US5405413A (en) | 1993-06-24 | 1995-04-11 | The Procter & Gamble Co. | Bleaching compounds comprising acyl valerolactam bleach activators |
| DE4338922A1 (de) | 1993-11-15 | 1995-05-18 | Degussa | Aktivatoren für anorganische Persauerstoffverbindungen |
| DE69419432T2 (de) | 1993-11-25 | 1999-10-28 | Warwick International Group Ltd., Holywell | Bleichmittelzusammensetzungen |
| US5534196A (en) | 1993-12-23 | 1996-07-09 | The Procter & Gamble Co. | Process for making lactam bleach activator containing particles |
| JP2941430B2 (ja) | 1994-04-07 | 1999-08-25 | ザ、プロクター、エンド、ギャンブル、カンパニー | 金属含有漂白触媒を含む漂白組成物 |
| DE4416438A1 (de) | 1994-05-10 | 1995-11-16 | Basf Ag | Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren |
| ATE269392T1 (de) | 1994-07-21 | 2004-07-15 | Ciba Sc Holding Ag | Bleichmittelzusammensetzung für gewebe |
| DE4443177A1 (de) | 1994-12-05 | 1996-06-13 | Henkel Kgaa | Aktivatormischungen für anorganische Perverbindungen |
| WO1996027000A1 (en) * | 1995-02-28 | 1996-09-06 | Kay Chemical Company | Concentrated liquid gel warewash detergent |
| DE19529905A1 (de) | 1995-08-15 | 1997-02-20 | Henkel Kgaa | Aktivatorkomplexe für Persauerstoffverbindungen |
| DE19536082A1 (de) | 1995-09-28 | 1997-04-03 | Henkel Kgaa | Aktivatorkomplexe für Persauerstoffverbindungen |
| EP0778340A3 (en) | 1995-12-06 | 1999-10-27 | Basf Corporation | Improved non-phosphate machine dishwashing compositions containing copolymers of alkylene oxide adducts of allyl alcohol and acrylic acid |
| DE19605688A1 (de) | 1996-02-16 | 1997-08-21 | Henkel Kgaa | Übergangsmetallkomplexe als Aktivatoren für Persauerstoffverbindungen |
| DE19620411A1 (de) | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen |
| DE19613103A1 (de) | 1996-04-01 | 1997-10-02 | Henkel Kgaa | Übergangsmetallkomplex-haltige Systeme als Aktivatoren für Persauerstoffverbindungen |
| DE19616767A1 (de) | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Bleichaktivatoren für Wasch- und Reinigungsmittel |
| DE19616769A1 (de) | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Acylacetale als Bleichaktivatoren für Wasch- und Reinigungsmittel |
| DE19616770A1 (de) | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Acyllactame als Bleichaktivatoren für Wasch- und Reinigungsmittel |
| DE19616693A1 (de) | 1996-04-26 | 1997-11-06 | Henkel Kgaa | Enolester als Bleichaktivatoren für Wasch- und Reinigungsmittel |
| DE19620267A1 (de) | 1996-05-20 | 1997-11-27 | Henkel Kgaa | Katalytisch wirksame Aktivatorkomplexe mit N¶4¶-Liganden für Persauerstoffverbindungen |
| US5837663A (en) | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
| DE19819187A1 (de) | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Festes maschinelles Geschirrspülmittel mit Phosphat und kristallinen schichtförmigen Silikaten |
| AU2002221703A1 (en) * | 2000-10-25 | 2002-05-06 | Unilever Plc | Dish-washing compositions |
| DE10350420A1 (de) | 2003-10-28 | 2005-06-02 | Basf Ag | Verwendung von Alkylenoxideinheiten enthaltenden Copolymeren als belagsinhibierende Additive im Klarspülgang des maschinellen Geschirrspülers |
| DE102004044411A1 (de) * | 2004-09-14 | 2006-03-30 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophob modifizierte Polycarboxylate |
| DE102005041349A1 (de) | 2005-08-31 | 2007-03-01 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophil modifizierte Polycarboxylate |
| DE102005041347A1 (de) * | 2005-08-31 | 2007-03-01 | Basf Ag | Reinigungsformulierungen für die maschinelle Geschirrreinigung enthaltend hydrophil modifizierte Polycarboxylate |
-
2008
- 2008-10-10 CN CN2008801111324A patent/CN101821370B/zh not_active Expired - Fee Related
- 2008-10-10 AT AT08839722T patent/ATE522595T1/de active
- 2008-10-10 ES ES08839722T patent/ES2371698T3/es active Active
- 2008-10-10 KR KR1020107009707A patent/KR101529351B1/ko not_active Expired - Fee Related
- 2008-10-10 CA CA2702425A patent/CA2702425C/en not_active Expired - Fee Related
- 2008-10-10 PL PL08839722T patent/PL2201090T3/pl unknown
- 2008-10-10 BR BRPI0818439-9A patent/BRPI0818439B1/pt not_active IP Right Cessation
- 2008-10-10 JP JP2010528415A patent/JP5606319B2/ja not_active Expired - Fee Related
- 2008-10-10 EP EP08839722A patent/EP2201090B1/de not_active Not-in-force
- 2008-10-10 WO PCT/EP2008/063646 patent/WO2009050123A2/de not_active Ceased
- 2008-10-10 AU AU2008313803A patent/AU2008313803B2/en not_active Ceased
- 2008-10-10 MX MX2010003792A patent/MX2010003792A/es active IP Right Grant
- 2008-10-10 US US12/682,260 patent/US8262804B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US8262804B2 (en) | 2012-09-11 |
| EP2201090A2 (de) | 2010-06-30 |
| AU2008313803B2 (en) | 2014-01-30 |
| MX2010003792A (es) | 2010-07-06 |
| WO2009050123A2 (de) | 2009-04-23 |
| US20100234265A1 (en) | 2010-09-16 |
| KR20100097105A (ko) | 2010-09-02 |
| ATE522595T1 (de) | 2011-09-15 |
| CA2702425A1 (en) | 2009-04-23 |
| CN101821370B (zh) | 2013-01-30 |
| ES2371698T3 (es) | 2012-01-09 |
| JP5606319B2 (ja) | 2014-10-15 |
| KR101529351B1 (ko) | 2015-06-17 |
| JP2011500878A (ja) | 2011-01-06 |
| EP2201090B1 (de) | 2011-08-31 |
| PL2201090T3 (pl) | 2012-01-31 |
| WO2009050123A3 (de) | 2009-06-18 |
| CN101821370A (zh) | 2010-09-01 |
| BRPI0818439B1 (pt) | 2017-07-04 |
| AU2008313803A1 (en) | 2009-04-23 |
| BRPI0818439A2 (pt) | 2015-05-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20131009 |
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| MKLA | Lapsed |
Effective date: 20181010 |