CA2596893C - Targeted duct injection for so3 control - Google Patents

Targeted duct injection for so3 control Download PDF

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Publication number
CA2596893C
CA2596893C CA2596893A CA2596893A CA2596893C CA 2596893 C CA2596893 C CA 2596893C CA 2596893 A CA2596893 A CA 2596893A CA 2596893 A CA2596893 A CA 2596893A CA 2596893 C CA2596893 C CA 2596893C
Authority
CA
Canada
Prior art keywords
reagent
combustion
catalyst
effluent
magnesium hydroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2596893A
Other languages
English (en)
French (fr)
Other versions
CA2596893A1 (en
Inventor
Christopher R. Smyrniotis
William H. Sun
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuel Tech Inc
Original Assignee
Fuel Tech Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuel Tech Inc filed Critical Fuel Tech Inc
Publication of CA2596893A1 publication Critical patent/CA2596893A1/en
Application granted granted Critical
Publication of CA2596893C publication Critical patent/CA2596893C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/505—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound in a spray drying process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/60—Simultaneously removing sulfur oxides and nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B01D53/8609—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Chimneys And Flues (AREA)
CA2596893A 2005-02-04 2006-02-06 Targeted duct injection for so3 control Expired - Fee Related CA2596893C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US65005405P 2005-02-04 2005-02-04
US60/650,054 2005-02-04
PCT/US2006/003976 WO2006086251A2 (en) 2005-02-04 2006-02-06 Targeted duct injection for so3 control

Publications (2)

Publication Number Publication Date
CA2596893A1 CA2596893A1 (en) 2006-08-17
CA2596893C true CA2596893C (en) 2013-04-09

Family

ID=36793586

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2596893A Expired - Fee Related CA2596893C (en) 2005-02-04 2006-02-06 Targeted duct injection for so3 control

Country Status (12)

Country Link
US (1) US7332143B2 (enExample)
EP (1) EP1848524B1 (enExample)
JP (1) JP5165386B2 (enExample)
KR (1) KR101169831B1 (enExample)
CN (1) CN101522287B (enExample)
AU (1) AU2006212947B2 (enExample)
BR (1) BRPI0607004A2 (enExample)
CA (1) CA2596893C (enExample)
ES (1) ES2527422T3 (enExample)
PL (1) PL1848524T3 (enExample)
RU (1) RU2007131784A (enExample)
WO (1) WO2006086251A2 (enExample)

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CL2009001571A1 (es) * 2008-07-11 2010-03-12 Fuel Tech Inc Proceso que limpia y mantiene una camara de combustion debido a la combustion de carbon que tiene un contenido de hierro mayor al 15% basado en el peso de la ceniza y expresado como fe203 y/0 un contenido de calcio mayor al 5% basado en el peso de ceniza y expresado como cao.
US8316647B2 (en) * 2009-01-19 2012-11-27 General Electric Company System and method employing catalytic reactor coatings
US20110017110A1 (en) * 2009-07-24 2011-01-27 Higgins Brian S Methods and systems for improving combustion processes
WO2011106429A1 (en) * 2010-02-23 2011-09-01 Fuel Tech, Inc. Methods, apparatus and systems for improving the operation of cyclone boilers
CN102563595A (zh) * 2011-01-01 2012-07-11 王志凯 黄磷尾气燃烧热能回收装置
CN102179171B (zh) * 2011-03-28 2014-07-02 浙江大学 具有前置流场均匀装置的多级热解耦合脱硝方法及其装置
CN102512952B (zh) * 2011-11-14 2014-04-02 浙江天蓝环保技术股份有限公司 一种基于流化床的烟气联合脱硫脱硝工艺
US8501131B2 (en) * 2011-12-15 2013-08-06 General Electric Company Method and apparatus to inject reagent in SNCR/SCR emission system for boiler
US9291082B2 (en) 2012-09-26 2016-03-22 General Electric Company System and method of a catalytic reactor having multiple sacrificial coatings
US9181888B2 (en) 2013-10-28 2015-11-10 Cummins Inc. Selectively trapping and storing SO3 in an exhaust gas effluent
US8906333B1 (en) * 2013-11-27 2014-12-09 Alstom Technology Ltd Dry scrubber system with air preheater protection
CN103785275B (zh) * 2014-01-23 2015-09-02 冀文平 脱硫、除灰、脱硝一体式烟气净化器
US10055523B2 (en) 2014-04-24 2018-08-21 Toyota Motor Engineering & Manufacturing North America, Inc. Method for analyzing oxidation in an internal combustion engine
CN104474897A (zh) * 2014-12-02 2015-04-01 中国大唐集团科学技术研究院有限公司 脱除燃煤烟气中三氧化硫的方法
WO2017053499A1 (en) * 2015-09-25 2017-03-30 Fuel Tech, Inc. Process and apparatus for reducing plume
CN105879641B (zh) * 2016-06-02 2019-09-13 北京国电龙源环保工程有限公司 一种碱液喷射雾化脱除烟气中三氧化硫的装置及方法
CN106000037A (zh) * 2016-07-06 2016-10-12 北京国电龙源环保工程有限公司 一种脱除烟气中酸性气体并辅助脱硫脱硝的系统和方法
CN106039967A (zh) * 2016-07-19 2016-10-26 中国华电科工集团有限公司 脱除燃煤机组烟道气中so3的装置及方法
CN107008120A (zh) * 2017-04-20 2017-08-04 北京国电龙源环保工程有限公司 利用尿素热解余热的so3脱除系统及其脱除方法
CN107715668A (zh) * 2017-10-30 2018-02-23 东方电气集团东方锅炉股份有限公司 一种烟气高浓度NOx实现超低排放的装置
CN110339686A (zh) * 2018-04-03 2019-10-18 中国电力工程顾问集团华北电力设计院有限公司 通过脱除so3实现全负荷脱硝并提高锅炉效率的方法及装置
CN108607361B (zh) * 2018-07-05 2023-09-19 苏州西热节能环保技术有限公司 一种一体化喷射系统
CN108607362B (zh) * 2018-07-05 2023-09-19 苏州西热节能环保技术有限公司 一种具有一体化喷射系统的脱除烟气中三氧化硫与NOx的装置
CN109289430B (zh) * 2018-11-07 2023-06-30 国能龙源环保南京有限公司 一种干湿耦合一体化烟气消白及除尘装置
CN110180335A (zh) * 2019-05-17 2019-08-30 天津华赛尔传热设备有限公司 一种炉窑含湿烟气消白系统
CN110559852A (zh) * 2019-09-30 2019-12-13 大唐郓城发电有限公司 一种脱除烟气中三氧化硫的方法
CN111054176A (zh) * 2019-12-16 2020-04-24 湖南正明环保股份有限公司 用于工业窑炉烟气除尘消白的一体化系统及方法
CN117437987B (zh) * 2023-12-20 2024-02-23 河北大唐国际王滩发电有限责任公司 串塔式烟气湿法脱硫装置颗粒物协同脱除效果计算方法

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Also Published As

Publication number Publication date
JP2008532734A (ja) 2008-08-21
JP5165386B2 (ja) 2013-03-21
US20060177366A1 (en) 2006-08-10
AU2006212947A1 (en) 2006-08-17
KR20070107728A (ko) 2007-11-07
US7332143B2 (en) 2008-02-19
BRPI0607004A2 (pt) 2009-07-28
EP1848524A2 (en) 2007-10-31
EP1848524B1 (en) 2014-10-15
WO2006086251A3 (en) 2009-04-16
ES2527422T3 (es) 2015-01-23
AU2006212947B2 (en) 2012-02-02
KR101169831B1 (ko) 2012-07-30
RU2007131784A (ru) 2009-03-10
EP1848524A4 (en) 2013-04-17
CN101522287A (zh) 2009-09-02
CA2596893A1 (en) 2006-08-17
PL1848524T3 (pl) 2015-04-30
CN101522287B (zh) 2012-11-21
WO2006086251A2 (en) 2006-08-17

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