CA2457886C - Impact resistant rigid pvc compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers - Google Patents
Impact resistant rigid pvc compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers Download PDFInfo
- Publication number
- CA2457886C CA2457886C CA2457886A CA2457886A CA2457886C CA 2457886 C CA2457886 C CA 2457886C CA 2457886 A CA2457886 A CA 2457886A CA 2457886 A CA2457886 A CA 2457886A CA 2457886 C CA2457886 C CA 2457886C
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- CA
- Canada
- Prior art keywords
- ethylene
- value
- composition
- copolymer
- alpha
- Prior art date
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- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims abstract description 95
- 239000004709 Chlorinated polyethylene Substances 0.000 title claims description 21
- 239000004609 Impact Modifier Substances 0.000 title claims description 9
- 229930195733 hydrocarbon Natural products 0.000 title description 20
- 150000002430 hydrocarbons Chemical class 0.000 title description 20
- 239000004215 Carbon black (E152) Substances 0.000 title description 19
- 229920001971 elastomer Polymers 0.000 title description 19
- 239000005060 rubber Substances 0.000 title description 17
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000005977 Ethylene Substances 0.000 claims abstract description 43
- 229920000642 polymer Polymers 0.000 claims abstract description 35
- 229920000098 polyolefin Polymers 0.000 claims abstract description 33
- 229920001577 copolymer Polymers 0.000 claims abstract description 32
- 239000004711 α-olefin Substances 0.000 claims abstract description 32
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000155 melt Substances 0.000 claims abstract description 23
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000460 chlorine Substances 0.000 claims abstract description 13
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 13
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 12
- 239000011256 inorganic filler Substances 0.000 claims abstract description 7
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 7
- -1 polyethylene Polymers 0.000 claims description 34
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 29
- 229920000573 polyethylene Polymers 0.000 claims description 22
- 239000004698 Polyethylene Substances 0.000 claims description 21
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 15
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 13
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 12
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims description 8
- 150000001336 alkenes Chemical class 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 2
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 44
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 44
- 229940093470 ethylene Drugs 0.000 description 28
- 238000002156 mixing Methods 0.000 description 19
- 238000000034 method Methods 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 15
- 239000000945 filler Substances 0.000 description 13
- 150000001993 dienes Chemical group 0.000 description 11
- 239000004594 Masterbatch (MB) Substances 0.000 description 8
- 239000004614 Process Aid Substances 0.000 description 8
- 239000004209 oxidized polyethylene wax Substances 0.000 description 7
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 7
- 239000003381 stabilizer Substances 0.000 description 7
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 5
- 239000003607 modifier Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000005660 chlorination reaction Methods 0.000 description 4
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 150000005671 trienes Chemical class 0.000 description 4
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 3
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 3
- 239000008116 calcium stearate Substances 0.000 description 3
- 235000013539 calcium stearate Nutrition 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920001897 terpolymer Polymers 0.000 description 3
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical class OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 description 2
- ZTJHDEXGCKAXRZ-FNORWQNLSA-N (3e)-octa-1,3,7-triene Chemical compound C=CCC\C=C\C=C ZTJHDEXGCKAXRZ-FNORWQNLSA-N 0.000 description 2
- TVEFFNLPYIEDLS-VQHVLOKHSA-N (4e)-deca-1,4,9-triene Chemical compound C=CCCC\C=C\CC=C TVEFFNLPYIEDLS-VQHVLOKHSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- AFVDZBIIBXWASR-AATRIKPKSA-N (E)-1,3,5-hexatriene Chemical compound C=C\C=C\C=C AFVDZBIIBXWASR-AATRIKPKSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical class C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 229920002681 hypalon Polymers 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- 150000004291 polyenes Chemical class 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- PPWGXYXJMQAWSX-AATRIKPKSA-N (3e)-2-methylhexa-1,3,5-triene Chemical compound CC(=C)\C=C\C=C PPWGXYXJMQAWSX-AATRIKPKSA-N 0.000 description 1
- BOGRNZQRTNVZCZ-AATRIKPKSA-N (3e)-3-methylpenta-1,3-diene Chemical compound C\C=C(/C)C=C BOGRNZQRTNVZCZ-AATRIKPKSA-N 0.000 description 1
- NDRUXLROLQGDNL-VOTSOKGWSA-N (3e)-5-methylhepta-1,3,6-triene Chemical compound C=CC(C)\C=C\C=C NDRUXLROLQGDNL-VOTSOKGWSA-N 0.000 description 1
- CXHZYOISZDAYCU-FNORWQNLSA-N (3e)-hepta-1,3,6-triene Chemical compound C=CC\C=C\C=C CXHZYOISZDAYCU-FNORWQNLSA-N 0.000 description 1
- HOXGZVUCAYFWGR-KQQUZDAGSA-N (3e,5e)-octa-1,3,5-triene Chemical compound CC\C=C\C=C\C=C HOXGZVUCAYFWGR-KQQUZDAGSA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- BOGRNZQRTNVZCZ-UHFFFAOYSA-N 1,2-dimethyl-butadiene Natural products CC=C(C)C=C BOGRNZQRTNVZCZ-UHFFFAOYSA-N 0.000 description 1
- JVTMVUFBBYUSKS-UHFFFAOYSA-N 1,4-bis(prop-2-enyl)benzene Chemical compound C=CCC1=CC=C(CC=C)C=C1 JVTMVUFBBYUSKS-UHFFFAOYSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
- UUFQTNFCRMXOAE-UHFFFAOYSA-N 1-methylmethylene Chemical compound C[CH] UUFQTNFCRMXOAE-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- CMSUNVGIWAFNBG-UHFFFAOYSA-N 2,4-dimethylpenta-1,3-diene Chemical compound CC(C)=CC(C)=C CMSUNVGIWAFNBG-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- IOHAVGDJBFVWGE-UHFFFAOYSA-N 2-ethylidene-3-propan-2-ylidenebicyclo[2.2.1]hept-5-ene Chemical compound C1C2C=CC1C(=CC)C2=C(C)C IOHAVGDJBFVWGE-UHFFFAOYSA-N 0.000 description 1
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 1
- SBJCJFDJJTZIJO-UHFFFAOYSA-N 2-methylocta-1,3,7-triene Chemical compound CC(=C)C=CCCC=C SBJCJFDJJTZIJO-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- JFLOKYMVJXMYFI-UHFFFAOYSA-N 3-ethylpenta-1,3-diene Chemical compound CCC(=CC)C=C JFLOKYMVJXMYFI-UHFFFAOYSA-N 0.000 description 1
- FPFFMFXHRMUXKQ-UHFFFAOYSA-N 3-methylhepta-1,3,6-triene Chemical compound C=CC(C)=CCC=C FPFFMFXHRMUXKQ-UHFFFAOYSA-N 0.000 description 1
- CPKQGZFNZCGUSO-UHFFFAOYSA-N 3-methylocta-1,3,7-triene Chemical compound C=CC(C)=CCCC=C CPKQGZFNZCGUSO-UHFFFAOYSA-N 0.000 description 1
- VXMJXJAHNOJRAA-UHFFFAOYSA-N 4,7,7-trimethylbicyclo[2.2.1]hepta-2,5-diene Chemical compound C1=CC2(C)C=CC1C2(C)C VXMJXJAHNOJRAA-UHFFFAOYSA-N 0.000 description 1
- VKWACHLRGJKEPI-UHFFFAOYSA-N 4-methylocta-1,3,7-triene Chemical compound C=CC=C(C)CCC=C VKWACHLRGJKEPI-UHFFFAOYSA-N 0.000 description 1
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
- UAKPCRIFCXQISY-UHFFFAOYSA-N 5-prop-2-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(CC=C)CC1C=C2 UAKPCRIFCXQISY-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/12—Rigid pipes of plastics with or without reinforcement
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/286—Chlorinated polyethene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dental Preparations (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
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| US31753001P | 2001-09-06 | 2001-09-06 | |
| US60/317,530 | 2001-09-06 | ||
| US10/210,466 US6706815B2 (en) | 2001-09-06 | 2002-07-31 | Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers |
| US10/210,466 | 2002-07-31 | ||
| PCT/US2002/026871 WO2003022921A2 (en) | 2001-09-06 | 2002-08-23 | Impact resistant rigid pvc compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers |
Publications (2)
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| CA2457886A1 CA2457886A1 (en) | 2003-03-20 |
| CA2457886C true CA2457886C (en) | 2011-07-12 |
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| CA2457886A Expired - Fee Related CA2457886C (en) | 2001-09-06 | 2002-08-23 | Impact resistant rigid pvc compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers |
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| JP (1) | JP4475951B2 (enExample) |
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| MX (1) | MXPA04002126A (enExample) |
| NZ (1) | NZ532155A (enExample) |
| WO (1) | WO2003022921A2 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20060046084A1 (en) * | 2004-08-24 | 2006-03-02 | Building Materials Investment Corporation | Flexible polypropylene roofing membrane |
| CA2645187A1 (en) * | 2006-03-17 | 2007-09-27 | Dow Global Technologies Inc. | An impact resistant rigid vinyl chloride polymer composition and method of making the same |
| US20070260006A1 (en) * | 2006-05-03 | 2007-11-08 | Whitson Russell L | Rigid polyvinyl chloride polymer compositions having improved impact properties |
| CN101472958B (zh) | 2006-06-28 | 2012-08-08 | 陶氏环球技术有限责任公司 | 氯化乙烯基聚合物和组合物及其制品 |
| US7666491B2 (en) * | 2007-01-26 | 2010-02-23 | Building Materials Investment Corporation | Method and use of a stretchable nonreinforced TPO building materials |
| US20080207831A1 (en) * | 2007-02-28 | 2008-08-28 | Stewart Carl Feinberg | Composition comprising polyvinyl chloride and halogenated polyethylene or core-shell resin |
| US20090143535A1 (en) | 2007-11-29 | 2009-06-04 | Dow Global Technologies Inc. | Impact modifier composition, an impact resistant composition, method of producing the same, and articles made therefrom |
| KR20160030328A (ko) | 2008-02-15 | 2016-03-16 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 프탈레이트-가소화된 조성물을 위한 대체 가소제 시스템 |
| JP5031008B2 (ja) * | 2008-09-24 | 2012-09-19 | フクビ化学工業株式会社 | 塩化ビニル樹脂組成物 |
| KR101978520B1 (ko) | 2009-09-30 | 2019-05-14 | 다우 글로벌 테크놀로지스 엘엘씨 | 12-히드록시스테아르산의 아세틸화 글리세리드 및 에폭시드화 지방산 에스테르와의 블렌드 |
| US8859654B2 (en) | 2009-09-30 | 2014-10-14 | Dow Global Technologies Llc | Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer |
| KR101904553B1 (ko) | 2009-09-30 | 2018-10-04 | 다우 글로벌 테크놀로지스 엘엘씨 | 피마자유의 아세틸화 유도체 및 그의 에폭시드화 지방산 에스테르와의 블렌드 |
| US8552098B2 (en) | 2009-09-30 | 2013-10-08 | Dow Global Technologies Llc | Purified acetylated derivatives of castor oil and compositions including same |
| CN102666699A (zh) | 2009-10-07 | 2012-09-12 | Isp投资有限公司 | 增塑的聚合物组合物 |
| JP5797260B2 (ja) | 2010-05-10 | 2015-10-21 | ダウ グローバル テクノロジーズ エルエルシー | 再生可能資源から誘導される可塑剤を用いて作製される可撓性ｐｖｃ組成物 |
| BR112012028158B1 (pt) * | 2010-05-21 | 2020-04-07 | Dow Global Technologies Llc | composição termoplástica e artigo |
| TW201209168A (en) | 2010-07-28 | 2012-03-01 | Dow Global Technologies Llc | Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same |
| JP5729143B2 (ja) * | 2011-06-02 | 2015-06-03 | 株式会社オートネットワーク技術研究所 | 電線被覆材料、絶縁電線及びワイヤーハーネス |
| CN102260397B (zh) * | 2011-07-13 | 2013-03-06 | 山东旭业新材料股份有限公司 | 透明氯化聚乙烯热塑材料 |
| CN102417673A (zh) * | 2011-08-17 | 2012-04-18 | 无锡天马塑胶制品有限公司 | 建筑用模板支撑木 |
| JP6165779B2 (ja) | 2012-02-08 | 2017-07-19 | ダウ グローバル テクノロジーズ エルエルシー | 可塑剤組成物及び可塑剤組成物を製作するための方法 |
| BR112014027887B1 (pt) | 2012-06-22 | 2021-01-05 | Dow Global Technologies Llc | composição polimérica e condutor revestido |
| WO2014003892A2 (en) | 2012-06-26 | 2014-01-03 | Dow Global Technologies Llc | Plasticizers and plasticized polymeric compositions |
| KR101365744B1 (ko) * | 2012-07-26 | 2014-02-20 | (주)피피아이평화 | 고강도 및 내동파성이 우수한 배관용 합성수지 이중 파이프 |
| KR101365743B1 (ko) * | 2012-07-26 | 2014-02-20 | (주)피피아이평화 | 고강도 및 내동파성이 우수한 배관용 ｐ.ｖ.ｃ. 파이프 |
| US9850366B2 (en) | 2012-10-18 | 2017-12-26 | Dow Global Technologies Llc | Epdxidized fatty acid alkyl ester plasticizers and methods for making epdxidized fatty acid alkyl ester plasticizers |
| MX378691B (es) | 2012-11-12 | 2025-03-11 | Dow Global Technologies Llc | Plastificantes de ester de alquilo de acido graso epoxidado y metodos para fabricar plastificantes de ester de alquilo de acido graso epoxidado. |
| CA2891062C (en) | 2012-11-12 | 2020-03-24 | Dow Global Technologies Llc | Methods for making epoxidized fatty acid alkyl esters |
| KR101535943B1 (ko) | 2013-12-09 | 2015-07-10 | 한화케미칼 주식회사 | Pvc계 컴파운드 조성물 |
| CN103865206B (zh) * | 2014-03-20 | 2015-12-30 | 安徽玉发塑业有限公司 | 一种耐高温pvc塑料管材 |
| CN104086918B (zh) * | 2014-07-09 | 2016-08-24 | 安徽宁国市高新管业有限公司 | 一种高强度电力保护管 |
| CN104993433A (zh) * | 2015-07-07 | 2015-10-21 | 常州市拓源电缆成套有限公司 | 一种阻燃抗静电upvc电工管 |
| JP7035867B2 (ja) * | 2018-07-12 | 2022-03-15 | 堺化学工業株式会社 | 塩化ビニル系樹脂組成物および該組成物から形成された成形体 |
| CN110283412B (zh) * | 2019-06-25 | 2021-04-13 | 潍坊亚星化学股份有限公司 | 一种共混改性氯化聚氯乙烯材料及其制备方法 |
| CN110746720B (zh) * | 2019-09-19 | 2021-05-11 | 宜宾天亿新材料科技有限公司 | 高性能pvc-o管材生产方法 |
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-
2002
- 2002-07-31 US US10/210,466 patent/US6706815B2/en not_active Expired - Lifetime
- 2002-08-23 NZ NZ532155A patent/NZ532155A/en not_active IP Right Cessation
- 2002-08-23 BR BRPI0212634-6A patent/BR0212634B1/pt not_active IP Right Cessation
- 2002-08-23 AU AU2002331697A patent/AU2002331697B2/en not_active Ceased
- 2002-08-23 DE DE60230526T patent/DE60230526D1/de not_active Expired - Fee Related
- 2002-08-23 WO PCT/US2002/026871 patent/WO2003022921A2/en not_active Ceased
- 2002-08-23 EP EP02768677A patent/EP1423475B1/en not_active Expired - Lifetime
- 2002-08-23 US US10/488,843 patent/US20040236022A1/en not_active Abandoned
- 2002-08-23 MX MXPA04002126A patent/MXPA04002126A/es active IP Right Grant
- 2002-08-23 KR KR1020047003313A patent/KR100915484B1/ko not_active Expired - Lifetime
- 2002-08-23 CA CA2457886A patent/CA2457886C/en not_active Expired - Fee Related
- 2002-08-23 AT AT02768677T patent/ATE418580T1/de not_active IP Right Cessation
- 2002-08-23 JP JP2003526990A patent/JP4475951B2/ja not_active Expired - Fee Related
- 2002-08-23 CN CNB028174372A patent/CN100372887C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA04002126A (es) | 2004-07-08 |
| WO2003022921A2 (en) | 2003-03-20 |
| BR0212634A (pt) | 2004-08-24 |
| DE60230526D1 (de) | 2009-02-05 |
| BR0212634B1 (pt) | 2012-08-21 |
| US20030050402A1 (en) | 2003-03-13 |
| JP2005502756A (ja) | 2005-01-27 |
| KR20040031052A (ko) | 2004-04-09 |
| KR100915484B1 (ko) | 2009-09-03 |
| NZ532155A (en) | 2005-08-26 |
| US20040236022A1 (en) | 2004-11-25 |
| EP1423475B1 (en) | 2008-12-24 |
| EP1423475A2 (en) | 2004-06-02 |
| AU2002331697B2 (en) | 2007-11-01 |
| CN100372887C (zh) | 2008-03-05 |
| CN1551902A (zh) | 2004-12-01 |
| ATE418580T1 (de) | 2009-01-15 |
| CA2457886A1 (en) | 2003-03-20 |
| US6706815B2 (en) | 2004-03-16 |
| JP4475951B2 (ja) | 2010-06-09 |
| WO2003022921A3 (en) | 2003-10-09 |
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