CA2434645C - Process aid for melt processable polymers - Google Patents
Process aid for melt processable polymers Download PDFInfo
- Publication number
- CA2434645C CA2434645C CA2434645A CA2434645A CA2434645C CA 2434645 C CA2434645 C CA 2434645C CA 2434645 A CA2434645 A CA 2434645A CA 2434645 A CA2434645 A CA 2434645A CA 2434645 C CA2434645 C CA 2434645C
- Authority
- CA
- Canada
- Prior art keywords
- process aid
- aid composition
- interfacial agent
- fluoroelastomer
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000004614 Process Aid Substances 0.000 title claims abstract description 102
- 229920000642 polymer Polymers 0.000 title claims abstract description 89
- 238000001125 extrusion Methods 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims description 152
- 229920001973 fluoroelastomer Polymers 0.000 claims description 89
- 239000003795 chemical substances by application Substances 0.000 claims description 75
- -1 poly(oxyalkylene) Polymers 0.000 claims description 54
- 229920001610 polycaprolactone Polymers 0.000 claims description 27
- 239000004632 polycaprolactone Substances 0.000 claims description 27
- 229920001223 polyethylene glycol Polymers 0.000 claims description 23
- 229920001577 copolymer Polymers 0.000 claims description 19
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 14
- 229920003232 aliphatic polyester Polymers 0.000 claims description 14
- 230000003750 conditioning effect Effects 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 11
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 11
- 229920000570 polyether Polymers 0.000 claims description 11
- 239000000155 melt Substances 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- 229920001169 thermoplastic Polymers 0.000 claims description 10
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 9
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 229920005862 polyol Polymers 0.000 claims description 5
- 150000003077 polyols Chemical class 0.000 claims description 5
- 229920002313 fluoropolymer Polymers 0.000 abstract description 140
- 239000002245 particle Substances 0.000 abstract description 138
- 239000004811 fluoropolymer Substances 0.000 abstract description 135
- 239000004594 Masterbatch (MB) Substances 0.000 description 49
- 238000000034 method Methods 0.000 description 27
- 238000002156 mixing Methods 0.000 description 27
- 239000006185 dispersion Substances 0.000 description 18
- 230000007547 defect Effects 0.000 description 16
- 230000008569 process Effects 0.000 description 15
- 238000012360 testing method Methods 0.000 description 14
- 238000009826 distribution Methods 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 11
- 150000002430 hydrocarbons Chemical class 0.000 description 11
- 239000004698 Polyethylene Substances 0.000 description 10
- 229920000573 polyethylene Polymers 0.000 description 10
- 238000012545 processing Methods 0.000 description 10
- 238000009778 extrusion testing Methods 0.000 description 9
- 230000006872 improvement Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000000654 additive Substances 0.000 description 7
- 230000010006 flight Effects 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 229920006120 non-fluorinated polymer Polymers 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 230000008030 elimination Effects 0.000 description 4
- 238000003379 elimination reaction Methods 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- QAERDLQYXMEHEB-UHFFFAOYSA-N 1,1,3,3,3-pentafluoroprop-1-ene Chemical group FC(F)=CC(F)(F)F QAERDLQYXMEHEB-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000010128 melt processing Methods 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 229920013716 polyethylene resin Polymers 0.000 description 2
- 238000010094 polymer processing Methods 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- ZWVMLYRJXORSEP-LURJTMIESA-N (2s)-hexane-1,2,6-triol Chemical compound OCCCC[C@H](O)CO ZWVMLYRJXORSEP-LURJTMIESA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- JKTORXLUQLQJCM-UHFFFAOYSA-N 4-phosphonobutylphosphonic acid Chemical compound OP(O)(=O)CCCCP(O)(O)=O JKTORXLUQLQJCM-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- YWJUZWOHLHBWQY-UHFFFAOYSA-N decanedioic acid;hexane-1,6-diamine Chemical compound NCCCCCCN.OC(=O)CCCCCCCCC(O)=O YWJUZWOHLHBWQY-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000004446 fluoropolymer coating Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- RSVIRMFSJVHWJV-UHFFFAOYSA-N n,n-dimethyloctan-1-amine oxide Chemical compound CCCCCCCC[N+](C)(C)[O-] RSVIRMFSJVHWJV-UHFFFAOYSA-N 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadecene Natural products CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 238000003921 particle size analysis Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000747 poly(lactic acid) Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/28—Hexyfluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
- C08L83/12—Block- or graft-copolymers containing polysiloxane sequences containing polyether sequences
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26924701P | 2001-02-16 | 2001-02-16 | |
| US60/269,247 | 2001-02-16 | ||
| US09/953,638 | 2001-09-17 | ||
| US09/953,638 US6642310B2 (en) | 2001-02-16 | 2001-09-17 | Process aid for melt processable polymers |
| PCT/US2002/005487 WO2002066544A2 (en) | 2001-02-16 | 2002-02-12 | Process aid for melt processable polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2434645A1 CA2434645A1 (en) | 2002-08-29 |
| CA2434645C true CA2434645C (en) | 2010-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2434645A Expired - Lifetime CA2434645C (en) | 2001-02-16 | 2002-02-12 | Process aid for melt processable polymers |
Country Status (10)
| Country | Link |
|---|---|
| US (9) | US6642310B2 (enExample) |
| EP (2) | EP2070972A1 (enExample) |
| JP (1) | JP4104460B2 (enExample) |
| KR (3) | KR100840094B1 (enExample) |
| CN (1) | CN1286887C (enExample) |
| AU (2) | AU2002255592B2 (enExample) |
| BR (1) | BR0207482B1 (enExample) |
| CA (1) | CA2434645C (enExample) |
| DE (3) | DE60231926D1 (enExample) |
| WO (1) | WO2002066544A2 (enExample) |
Families Citing this family (60)
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| JP3576448B2 (ja) * | 2000-03-21 | 2004-10-13 | 三菱レイヨン株式会社 | 熱可塑性樹脂組成物 |
| US6642310B2 (en) * | 2001-02-16 | 2003-11-04 | Dupont Dow Elastomers L.L.C. | Process aid for melt processable polymers |
| US6599982B2 (en) * | 2001-11-08 | 2003-07-29 | Dupont Dow Elastomers L.L.C. | Process aid for melt processable polymers |
| US7375157B2 (en) | 2003-06-09 | 2008-05-20 | 3M Innovative Properties Company | Melt-processible polymer composition comprising fluoropolymer having long chain branches |
| US7238748B2 (en) * | 2003-08-20 | 2007-07-03 | Dupont Performance Elastomers L.L.C. | Process aid for metallocene catalyzed linear low density polyethylene polymers |
| DE10345647A1 (de) | 2003-10-01 | 2005-04-21 | Merck Patent Gmbh | Pigmentpräparation für Kunststoffe |
| US20050101722A1 (en) * | 2003-11-06 | 2005-05-12 | 3M Innovative Properties Company | Melt processable compositions |
| US20050245687A1 (en) * | 2004-04-30 | 2005-11-03 | Appel Marvin R | Multimodal polyethylene extrusion |
| US20060014904A1 (en) * | 2004-07-13 | 2006-01-19 | Daikin Industries, Ltd. | Polymer compositions and method for producing a molded body |
| FR2873125B1 (fr) * | 2004-07-16 | 2008-09-05 | Arkema Sa | Melange maitre a base de polymere fluore et son utilisation pour l'extrusion des polyolefines |
| US7538156B2 (en) * | 2004-07-16 | 2009-05-26 | Arkema France | Fluoropolymer-based masterbatch and its use for the extrusion of polyolefins |
| US20060025504A1 (en) * | 2004-07-29 | 2006-02-02 | Oriani Steven R | Process aid for melt processable polymers that contain hindered amine light stabilizer |
| BRPI0517149A (pt) * | 2004-12-07 | 2008-09-30 | Dow Global Technologies Inc | composição polimérica tendo propriedades de extrusão de fundido melhoradas |
| JP5148061B2 (ja) * | 2005-08-24 | 2013-02-20 | 出光興産株式会社 | 照明装置用ハウジング構造体、およびその製造方法、該構造体を用いたバックライト装置 |
| US7420010B2 (en) * | 2005-11-02 | 2008-09-02 | Chevron Philips Chemical Company Lp | Polyethylene compositions |
| FR2896250B1 (fr) * | 2006-01-13 | 2012-08-17 | Arkema | Agent d'extrusion a base de pvdf |
| FR2892421A1 (fr) * | 2006-01-13 | 2007-04-27 | Arkema Sa | Melange maitre a base de polymere fluore pour l'extrusion des resines thermoplastiques chargees |
| JP4810660B2 (ja) * | 2006-03-17 | 2011-11-09 | 国立大学法人山形大学 | ダイ内の熱可塑性溶融樹脂の流動状態の解析方法及びそのためのダイ |
| FR2899592B1 (fr) * | 2006-04-05 | 2008-05-23 | Arkema Sa | Agent d'aide a l'extrusion a base de pvdf |
| US20080015285A1 (en) * | 2006-07-14 | 2008-01-17 | Steven Richard Oriani | Process aid for extruded wood composites |
| US20090093591A1 (en) * | 2007-10-09 | 2009-04-09 | Lyons Donald F | Processing aid for melt-extrudable polymers |
| EP2065441A1 (en) * | 2007-11-30 | 2009-06-03 | Solvay Solexis S.p.A. | Fluoroelastomer composition |
| US20090197028A1 (en) * | 2008-01-31 | 2009-08-06 | Lyons Donald F | Fluoropolymers of tetrafluoroethylene and 3,3,3-trifluoropropylene |
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| JP2009263526A (ja) * | 2008-04-25 | 2009-11-12 | Canon Inc | ポリ乳酸樹脂組成物 |
| US7915331B2 (en) * | 2009-01-06 | 2011-03-29 | Dupont Performance Elastomers L.L.C. | Fluoroelastomer processing aid masterbatch and method for producing same |
| US8053526B2 (en) * | 2009-05-20 | 2011-11-08 | Dupont Performance Elastomers Llc | Fluoroelastomer process aid contains polyalkylene oxide and polycaprolactone |
| WO2010138172A1 (en) | 2009-05-29 | 2010-12-02 | Milliken & Company | Polymer compositions, articles made from such compositions, and methods for molding such compositions |
| EP2459651A1 (en) | 2009-07-28 | 2012-06-06 | Chemtura Corporation | Polymer processing aids |
| US11274172B2 (en) * | 2009-08-27 | 2022-03-15 | Daikin Industries, Ltd. | Processing additive, molding composition masterbatch of processing additive and molding article |
| CN102482374B (zh) * | 2009-08-27 | 2014-08-27 | 大金工业株式会社 | 加工助剂、成型用组合物、加工助剂用母料和成型品 |
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| JP6015857B2 (ja) * | 2013-06-21 | 2016-10-26 | ダイキン工業株式会社 | 加工助剤、及び組成物 |
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| EP3362265B1 (en) | 2015-10-15 | 2021-04-21 | Saint-Gobain Ceramics&Plastics, Inc. | Method for forming a three dimensional body from a mixture with a high content of solid particles |
| JP2018533662A (ja) | 2015-11-13 | 2018-11-15 | スリーエム イノベイティブ プロパティズ カンパニー | 非晶質フルオロポリマーのバイモーダルブレンドを含む組成物及びそれらの使用 |
| TW201815845A (zh) | 2016-05-17 | 2018-05-01 | ３Ｍ新設資產公司 | 包括二氟亞乙烯與四氟乙烯的共聚物之組成物及其使用方法 |
| WO2017209991A1 (en) | 2016-05-31 | 2017-12-07 | Milliken & Company | Polymer compositions, articles made from such compositions and methods for molding such compositions |
| KR102636194B1 (ko) * | 2017-07-21 | 2024-02-19 | 생-고뱅 퍼포먼스 플라스틱스 코포레이션 | 3차원 바디를 형성하는 방법 |
| BE1025432B1 (nl) | 2017-12-29 | 2019-02-20 | Combipac B.V. | Werkwijze voor de filmblaasextrusie van polymeren met gebruik van een zeoliethoudend additief |
| US10738182B2 (en) | 2018-04-23 | 2020-08-11 | Dow Global Technologies Llc | Molded articles and methods thereof |
| US11629245B2 (en) | 2018-06-28 | 2023-04-18 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions, wire and cables, and methods for making the same |
| RU2018141773A (ru) * | 2018-11-27 | 2020-05-27 | 3М Инновейтив Пропертиз Компани | Композиции полимерных процессинговых добавок и изделия, полученные с использованием указанных композиций |
| AR117541A1 (es) * | 2019-01-07 | 2021-08-11 | Dow Global Technologies Llc | Auxiliares de procesamiento de polímeros (ppa) para mezclar con polietileno durante la extrusión de película soplada |
| US20230075186A1 (en) | 2020-02-21 | 2023-03-09 | Arkema Inc. | Pvdf extrusion agent containing interfacial agent |
| EP4188705A4 (en) | 2020-07-30 | 2024-03-27 | Dow Global Technologies LLC | MULTILAYER STRUCTURES, LAMINATES AND ASSOCIATED ARTICLES |
| WO2023056208A1 (en) * | 2021-09-30 | 2023-04-06 | Exxonmobil Chemical Patents Inc. | Fluorine-free polymer processing aids including polyethylene glycols |
| CA3239352A1 (en) * | 2021-11-22 | 2023-05-25 | 3M Innovative Properties Company | Synergists for hyperbranched polyol polymer processing additives |
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| CN118496608B (zh) * | 2024-06-05 | 2025-02-07 | 稷昶新材料科技(上海)有限公司 | 用于淤浆法聚乙烯工艺耐高温氟弹性体加工助剂及制备方法 |
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-
2001
- 2001-09-17 US US09/953,638 patent/US6642310B2/en not_active Expired - Lifetime
-
2002
- 2002-02-12 KR KR1020087002654A patent/KR100840094B1/ko not_active Expired - Lifetime
- 2002-02-12 AU AU2002255592A patent/AU2002255592B2/en not_active Ceased
- 2002-02-12 EP EP09156699A patent/EP2070972A1/en not_active Withdrawn
- 2002-02-12 CA CA2434645A patent/CA2434645C/en not_active Expired - Lifetime
- 2002-02-12 JP JP2002566257A patent/JP4104460B2/ja not_active Expired - Lifetime
- 2002-02-12 DE DE60231926T patent/DE60231926D1/de not_active Expired - Lifetime
- 2002-02-12 BR BRPI0207482-6A patent/BR0207482B1/pt not_active IP Right Cessation
- 2002-02-12 KR KR1020037010741A patent/KR100864362B1/ko not_active Expired - Lifetime
- 2002-02-12 WO PCT/US2002/005487 patent/WO2002066544A2/en not_active Ceased
- 2002-02-12 DE DE60233905T patent/DE60233905D1/de not_active Expired - Lifetime
- 2002-02-12 DE DE60222860T patent/DE60222860T2/de not_active Expired - Lifetime
- 2002-02-12 EP EP02724996A patent/EP1366108B1/en not_active Revoked
- 2002-02-12 CN CNB028051149A patent/CN1286887C/zh not_active Expired - Fee Related
- 2002-02-12 KR KR1020087021125A patent/KR100870388B1/ko not_active Expired - Lifetime
-
2003
- 2003-02-11 US US10/364,040 patent/US7001951B2/en not_active Expired - Fee Related
- 2003-06-23 US US10/602,267 patent/US6894118B2/en not_active Expired - Lifetime
- 2003-06-23 US US10/602,255 patent/US6875814B2/en not_active Expired - Fee Related
-
2005
- 2005-12-06 US US11/294,796 patent/US7390848B2/en not_active Expired - Lifetime
- 2005-12-06 US US11/295,073 patent/US7449520B2/en not_active Expired - Lifetime
-
2006
- 2006-12-20 AU AU2006252165A patent/AU2006252165A1/en not_active Abandoned
-
2007
- 2007-06-19 US US11/820,367 patent/US20070244256A1/en not_active Abandoned
- 2007-06-19 US US11/820,369 patent/US7446148B2/en not_active Expired - Fee Related
- 2007-06-19 US US11/820,368 patent/US20070244257A1/en not_active Abandoned
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