CA2373161C - Improved electrical conductivity of silica-filled rubber compositions - Google Patents
Improved electrical conductivity of silica-filled rubber compositions Download PDFInfo
- Publication number
- CA2373161C CA2373161C CA2373161A CA2373161A CA2373161C CA 2373161 C CA2373161 C CA 2373161C CA 2373161 A CA2373161 A CA 2373161A CA 2373161 A CA2373161 A CA 2373161A CA 2373161 C CA2373161 C CA 2373161C
- Authority
- CA
- Canada
- Prior art keywords
- poly
- alkylene oxide
- tire tread
- tire
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 122
- 229920001971 elastomer Polymers 0.000 title claims abstract description 91
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 59
- 239000005060 rubber Substances 0.000 title description 70
- 229920000642 polymer Polymers 0.000 claims abstract description 70
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract description 41
- -1 alkali metal salt Chemical class 0.000 claims abstract description 40
- 239000000806 elastomer Substances 0.000 claims abstract description 21
- 239000002482 conductive additive Substances 0.000 claims abstract description 17
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 15
- 239000012763 reinforcing filler Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 12
- 239000006229 carbon black Substances 0.000 claims description 33
- 239000000178 monomer Substances 0.000 claims description 15
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052744 lithium Inorganic materials 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 6
- 229920001897 terpolymer Polymers 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 125000001931 aliphatic group Chemical class 0.000 claims description 5
- 229910003002 lithium salt Inorganic materials 0.000 claims description 5
- 159000000002 lithium salts Chemical group 0.000 claims description 5
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920001194 natural rubber Polymers 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000005671 trienes Chemical class 0.000 claims description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 2
- 150000008378 aryl ethers Chemical class 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 claims description 2
- 229920005604 random copolymer Polymers 0.000 claims description 2
- 235000019241 carbon black Nutrition 0.000 description 31
- 239000000654 additive Substances 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 18
- 150000008064 anhydrides Chemical class 0.000 description 17
- 230000000996 additive effect Effects 0.000 description 13
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 11
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 229910000077 silane Inorganic materials 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- 239000005077 polysulfide Substances 0.000 description 8
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- 239000005062 Polybutadiene Substances 0.000 description 7
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 7
- 229920002857 polybutadiene Polymers 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 230000003068 static effect Effects 0.000 description 6
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- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920005683 SIBR Polymers 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 239000006236 Super Abrasion Furnace Substances 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 3
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- 229960002447 thiram Drugs 0.000 description 3
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000006238 High Abrasion Furnace Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000006242 Semi-Reinforcing Furnace Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- ZEEBGORNQSEQBE-UHFFFAOYSA-N [2-(3-phenylphenoxy)-6-(trifluoromethyl)pyridin-4-yl]methanamine Chemical compound C1(=CC(=CC=C1)OC1=NC(=CC(=C1)CN)C(F)(F)F)C1=CC=CC=C1 ZEEBGORNQSEQBE-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- UAHWPYUMFXYFJY-UHFFFAOYSA-N beta-myrcene Chemical compound CC(C)=CCCC(=C)C=C UAHWPYUMFXYFJY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229910001416 lithium ion Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OFHMODDLBXETIK-UHFFFAOYSA-N methyl 2,3-dichloropropanoate Chemical compound COC(=O)C(Cl)CCl OFHMODDLBXETIK-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
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- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- AHAREKHAZNPPMI-AATRIKPKSA-N (3e)-hexa-1,3-diene Chemical compound CC\C=C\C=C AHAREKHAZNPPMI-AATRIKPKSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
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- DQGBSPYYYCIELK-UHFFFAOYSA-N 1,1-bis(sulfanylidene)-1,3-benzothiazole Chemical class C1=CC=C2S(=S)(=S)C=NC2=C1 DQGBSPYYYCIELK-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical class C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
- KSCAZPYHLGGNPZ-UHFFFAOYSA-N 3-chloropropyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)CCCCl KSCAZPYHLGGNPZ-UHFFFAOYSA-N 0.000 description 1
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- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
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- 239000011701 zinc Substances 0.000 description 1
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C19/00—Tyre parts or constructions not otherwise provided for
- B60C19/08—Electric-charge-dissipating arrangements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L47/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S152/00—Resilient tires and wheels
- Y10S152/02—Static discharge
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/306,586 US6399692B2 (en) | 1999-05-06 | 1999-05-06 | Electrical conductivity of silica-filled rubber compositions using alkali metal salts dissolved in poly (alkylene oxide) compounds |
| US09/306,586 | 1999-05-06 | ||
| PCT/US2000/012301 WO2000068027A2 (en) | 1999-05-06 | 2000-05-05 | Improved electrical conductivity of silica-filled rubber compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2373161A1 CA2373161A1 (en) | 2000-11-16 |
| CA2373161C true CA2373161C (en) | 2010-08-31 |
Family
ID=23185965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2373161A Expired - Fee Related CA2373161C (en) | 1999-05-06 | 2000-05-05 | Improved electrical conductivity of silica-filled rubber compositions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6399692B2 (enExample) |
| EP (1) | EP1189766B1 (enExample) |
| JP (1) | JP4828026B2 (enExample) |
| CA (1) | CA2373161C (enExample) |
| DE (1) | DE60013824T2 (enExample) |
| ES (1) | ES2228526T3 (enExample) |
| MX (1) | MXPA01010552A (enExample) |
| WO (1) | WO2000068027A2 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1535216A (zh) * | 2001-07-30 | 2004-10-06 | �����ּ�����˾ | 挤制橡胶成型构件,其制造方法和结合该构件的轮胎 |
| US7008979B2 (en) | 2002-04-30 | 2006-03-07 | Hydromer, Inc. | Coating composition for multiple hydrophilic applications |
| US20040214929A1 (en) * | 2003-04-24 | 2004-10-28 | Robert Bradley | Rubber composition containing a silica dispersion agent |
| JP4118307B2 (ja) * | 2006-04-04 | 2008-07-16 | 住友ゴム工業株式会社 | 空気入りタイヤ |
| US20070249775A1 (en) * | 2006-04-19 | 2007-10-25 | Bridgestone Corporation | Tread compositions with improved dynamic storage modulus |
| JP5196882B2 (ja) * | 2007-06-22 | 2013-05-15 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物およびそれを用いたスタッドレスタイヤ |
| KR101351608B1 (ko) * | 2010-11-29 | 2014-01-15 | 한국타이어 주식회사 | 타이어 트레드용 고무 조성물 및 이를 이용하여 제조한 타이어 |
| DE102014214144A1 (de) * | 2014-07-21 | 2016-01-21 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung und Fahrzeugreifen |
| US10526475B2 (en) | 2014-09-24 | 2020-01-07 | Bridgestone Americas Tire Operations, Llc | Silica-containing rubber compositions containing specified coupling agents and related methods |
| US10179479B2 (en) | 2015-05-19 | 2019-01-15 | Bridgestone Americas Tire Operations, Llc | Plant oil-containing rubber compositions, tread thereof and race tires containing the tread |
| DE102017209368A1 (de) * | 2017-01-25 | 2018-07-26 | Icotek Project Gmbh & Co. Kg | Kabeldurchführung mit abschirmenden und abdichtenden Eigenschaften |
| US20200131344A1 (en) * | 2017-07-07 | 2020-04-30 | Birla Carbon U.S.A., Inc. | Epoxidized Natural Rubber Composition |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5077330A (en) * | 1988-08-29 | 1991-12-31 | Armstrong World Industries, Inc. | Conductive polyurethane-urea/polyethylene oxide |
| JPH07228785A (ja) * | 1993-12-24 | 1995-08-29 | Marubishi Yuka Kogyo Kk | 樹脂・ゴム用改質剤 |
| GB9409453D0 (en) | 1994-05-12 | 1994-06-29 | Sumitomo Rubber Ind | tyre tread and tyres incorporating them |
| CA2138726A1 (en) | 1994-09-13 | 1996-03-14 | Bharat Kanchanlal Kansupada | Tire with coated silica reinforced rubber tread |
| US5518055A (en) | 1994-09-20 | 1996-05-21 | Michelin Recherche Et Technique S.A. | Low resistivity tire with silica-rich tread and at least one electrostatic discharge ring |
| JP3462503B2 (ja) | 1994-10-11 | 2003-11-05 | 株式会社ブリヂストン | 帯電性を改良したゴム組成物及びそれを利用した空気入りタイヤ |
| DE69513131T2 (de) | 1994-12-22 | 2000-02-24 | Sumitomo Rubber Industries Ltd., Kobe | Luftreifen mit elektrisch ableitenden Eigenschaften |
| US6044882A (en) | 1995-03-07 | 2000-04-04 | The Goodyear Tire & Rubber Company | Tire having silica reinforced rubber tread with outer cap containing carbon black |
| CA2173917A1 (en) | 1995-07-20 | 1997-01-21 | Manuela Pompei | Silica reinforced treaded tire with conductive shoulder and crown portions |
| DE19625091A1 (de) * | 1996-06-24 | 1998-01-02 | Rhein Chemie Rheinau Gmbh | Verhinderung der elektrostatischen Aufladung von Luftreifen |
| JP3685569B2 (ja) * | 1996-11-19 | 2005-08-17 | 住友ゴム工業株式会社 | タイヤトレッド用ゴム組成物 |
| JPH10237222A (ja) * | 1997-02-24 | 1998-09-08 | Sumitomo Chem Co Ltd | ゴム組成物及び加硫ゴム組成物 |
| DE19726728C2 (de) | 1997-06-24 | 2003-11-27 | Continental Ag | Kautschukmischung für die Herstellung von Gummiprodukten |
| EP0909785A3 (de) * | 1997-10-16 | 1999-08-25 | Ciba SC Holding AG | Antistatisch-ausgerüstete Polymere |
-
1999
- 1999-05-06 US US09/306,586 patent/US6399692B2/en not_active Expired - Lifetime
-
2000
- 2000-05-05 MX MXPA01010552A patent/MXPA01010552A/es active IP Right Grant
- 2000-05-05 DE DE60013824T patent/DE60013824T2/de not_active Expired - Lifetime
- 2000-05-05 EP EP00930392A patent/EP1189766B1/en not_active Expired - Lifetime
- 2000-05-05 WO PCT/US2000/012301 patent/WO2000068027A2/en not_active Ceased
- 2000-05-05 JP JP2000617030A patent/JP4828026B2/ja not_active Expired - Lifetime
- 2000-05-05 CA CA2373161A patent/CA2373161C/en not_active Expired - Fee Related
- 2000-05-05 ES ES00930392T patent/ES2228526T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP4828026B2 (ja) | 2011-11-30 |
| JP2002544329A (ja) | 2002-12-24 |
| WO2000068027A3 (en) | 2001-05-17 |
| EP1189766A2 (en) | 2002-03-27 |
| CA2373161A1 (en) | 2000-11-16 |
| EP1189766B1 (en) | 2004-09-15 |
| DE60013824T2 (de) | 2005-02-03 |
| US6399692B2 (en) | 2002-06-04 |
| ES2228526T3 (es) | 2005-04-16 |
| WO2000068027A2 (en) | 2000-11-16 |
| US20020016393A1 (en) | 2002-02-07 |
| DE60013824D1 (de) | 2004-10-21 |
| MXPA01010552A (es) | 2002-08-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20160505 |