CA2297010C - Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof - Google Patents
Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof Download PDFInfo
- Publication number
- CA2297010C CA2297010C CA002297010A CA2297010A CA2297010C CA 2297010 C CA2297010 C CA 2297010C CA 002297010 A CA002297010 A CA 002297010A CA 2297010 A CA2297010 A CA 2297010A CA 2297010 C CA2297010 C CA 2297010C
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- Prior art keywords
- olefins
- alpha
- modified
- olefin
- product
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 176
- 230000008569 process Effects 0.000 title claims abstract description 148
- -1 vinylidene olefins Chemical class 0.000 title claims abstract description 146
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 122
- 238000004140 cleaning Methods 0.000 title claims abstract description 115
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 153
- 239000000203 mixture Substances 0.000 claims abstract description 146
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 120
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 119
- 238000005804 alkylation reaction Methods 0.000 claims abstract description 111
- 230000029936 alkylation Effects 0.000 claims abstract description 107
- 239000010457 zeolite Substances 0.000 claims abstract description 77
- 150000001336 alkenes Chemical class 0.000 claims abstract description 64
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 55
- 238000004519 manufacturing process Methods 0.000 claims abstract description 54
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 51
- 239000003599 detergent Substances 0.000 claims abstract description 49
- 230000002378 acidificating effect Effects 0.000 claims abstract description 42
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 30
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 17
- 102000004190 Enzymes Human genes 0.000 claims abstract description 16
- 108090000790 Enzymes Proteins 0.000 claims abstract description 16
- 239000004711 α-olefin Substances 0.000 claims description 102
- 238000006243 chemical reaction Methods 0.000 claims description 60
- 238000006471 dimerization reaction Methods 0.000 claims description 54
- 229910052799 carbon Inorganic materials 0.000 claims description 34
- 229910052680 mordenite Inorganic materials 0.000 claims description 33
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 28
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 24
- 239000007844 bleaching agent Substances 0.000 claims description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 20
- 230000015572 biosynthetic process Effects 0.000 claims description 14
- 230000000447 dimerizing effect Effects 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 230000003472 neutralizing effect Effects 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 150000003839 salts Chemical group 0.000 claims description 9
- GGQQNYXPYWCUHG-RMTFUQJTSA-N (3e,6e)-deca-3,6-diene Chemical compound CCC\C=C\C\C=C\CC GGQQNYXPYWCUHG-RMTFUQJTSA-N 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 8
- 230000002152 alkylating effect Effects 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 239000002243 precursor Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 3
- QJRVOJKLQNSNDB-UHFFFAOYSA-N 4-dodecan-3-ylbenzenesulfonic acid Chemical compound CCCCCCCCCC(CC)C1=CC=C(S(O)(=O)=O)C=C1 QJRVOJKLQNSNDB-UHFFFAOYSA-N 0.000 claims description 2
- 239000000539 dimer Substances 0.000 abstract description 28
- 239000011148 porous material Substances 0.000 abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 12
- 241001120493 Arene Species 0.000 abstract description 4
- 238000009472 formulation Methods 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 169
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 36
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 33
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 30
- 229910052782 aluminium Inorganic materials 0.000 description 27
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- 239000000463 material Substances 0.000 description 20
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical group O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 20
- 238000006317 isomerization reaction Methods 0.000 description 19
- 238000012360 testing method Methods 0.000 description 18
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 15
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 14
- 229940088598 enzyme Drugs 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 13
- 239000011521 glass Substances 0.000 description 13
- 239000011541 reaction mixture Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 12
- 239000003518 caustics Substances 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 12
- 230000035484 reaction time Effects 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 10
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 10
- 239000000654 additive Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 239000011734 sodium Substances 0.000 description 10
- 238000004821 distillation Methods 0.000 description 9
- 239000000543 intermediate Substances 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- 159000000000 sodium salts Chemical class 0.000 description 9
- 238000012546 transfer Methods 0.000 description 9
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 8
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 8
- 229940069096 dodecene Drugs 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical class CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 238000002161 passivation Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- ZXVONLUNISGICL-UHFFFAOYSA-N 4,6-dinitro-o-cresol Chemical compound CC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O ZXVONLUNISGICL-UHFFFAOYSA-N 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 108091005804 Peptidases Proteins 0.000 description 6
- 239000004365 Protease Substances 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 238000001354 calcination Methods 0.000 description 6
- 238000004851 dishwashing Methods 0.000 description 6
- 239000006260 foam Substances 0.000 description 6
- 239000000499 gel Substances 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000012263 liquid product Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000006386 neutralization reaction Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 239000003348 petrochemical agent Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- 108010059892 Cellulase Proteins 0.000 description 5
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 5
- 150000003863 ammonium salts Chemical class 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002500 ions Chemical class 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 238000006384 oligomerization reaction Methods 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011833 salt mixture Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 108010065511 Amylases Proteins 0.000 description 4
- 102000013142 Amylases Human genes 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 108090001060 Lipase Proteins 0.000 description 4
- 239000004367 Lipase Substances 0.000 description 4
- 102000004882 Lipase Human genes 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 235000019418 amylase Nutrition 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 238000010960 commercial process Methods 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- PGVOXXHNGYYHHB-UHFFFAOYSA-N dodecan-3-ylbenzene Chemical compound CCCCCCCCCC(CC)C1=CC=CC=C1 PGVOXXHNGYYHHB-UHFFFAOYSA-N 0.000 description 4
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
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- 239000012925 reference material Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- LNDCCSBWZAQAAW-UHFFFAOYSA-M sodium hydrogen sulfate sulfuric acid Chemical compound [Na+].OS(O)(=O)=O.OS([O-])(=O)=O LNDCCSBWZAQAAW-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- POECFFCNUXZPJT-UHFFFAOYSA-M sodium;carbonic acid;hydrogen carbonate Chemical compound [Na+].OC(O)=O.OC([O-])=O POECFFCNUXZPJT-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- WGRULTCAYDOGQK-UHFFFAOYSA-M sodium;sodium;hydroxide Chemical compound [OH-].[Na].[Na+] WGRULTCAYDOGQK-UHFFFAOYSA-M 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical class [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical class NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 238000004809 thin layer chromatography Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- JXVGWAIUCIHLLC-UHFFFAOYSA-K trisodium 2-hydroxypropane-1,2,3-tricarboxylate 2-hydroxypropane-1,2,3-tricarboxylic acid dihydrate Chemical compound O.O.[Na+].[Na+].[Na+].OC(=O)CC(O)(CC(O)=O)C(O)=O.OC(CC([O-])=O)(CC([O-])=O)C([O-])=O JXVGWAIUCIHLLC-UHFFFAOYSA-K 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004457 water analysis Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/08—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with halogenosulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5318697P | 1997-07-21 | 1997-07-21 | |
US60/053,186 | 1997-07-21 | ||
PCT/IB1998/001098 WO1999005241A1 (en) | 1997-07-21 | 1998-07-20 | Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2297010A1 CA2297010A1 (en) | 1999-02-04 |
CA2297010C true CA2297010C (en) | 2003-04-15 |
Family
ID=21982482
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002297010A Expired - Fee Related CA2297010C (en) | 1997-07-21 | 1998-07-20 | Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof |
Country Status (12)
Country | Link |
---|---|
US (1) | US6566319B1 (de) |
EP (1) | EP1002028A1 (de) |
JP (1) | JP2001511471A (de) |
CN (1) | CN1161448C (de) |
AR (1) | AR016367A1 (de) |
AU (1) | AU8124498A (de) |
BR (1) | BR9810780A (de) |
CA (1) | CA2297010C (de) |
MA (1) | MA24616A1 (de) |
MX (1) | MX220724B (de) |
WO (1) | WO1999005241A1 (de) |
ZA (1) | ZA986448B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110639426A (zh) * | 2019-10-10 | 2020-01-03 | 太原理工大学 | 一种支链烷基磺酸盐表面活性剂及其制备工艺 |
Families Citing this family (330)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
PH11998001775B1 (en) | 1997-07-21 | 2004-02-11 | Procter & Gamble | Improved alkyl aryl sulfonate surfactants |
CN100475785C (zh) * | 1997-08-08 | 2009-04-08 | 宝洁公司 | 经吸附分离用于制备表面活性剂的改进方法及其产物 |
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US6187981B1 (en) | 1999-07-19 | 2001-02-13 | Uop Llc | Process for producing arylalkanes and arylalkane sulfonates, compositions produced therefrom, and uses thereof |
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US7189885B1 (en) | 2003-10-07 | 2007-03-13 | Uop Llc | Staged process for producing linear 2-phenyl-alkanes |
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US8334250B2 (en) | 2009-12-18 | 2012-12-18 | The Procter & Gamble Company | Method of making granular detergent compositions comprising amphiphilic graft copolymers |
EP2338961A1 (de) | 2009-12-22 | 2011-06-29 | The Procter & Gamble Company | Alkalisches flüssiges Handgeschirrspülmittel |
ES2444618T3 (es) * | 2009-12-22 | 2014-02-26 | The Procter & Gamble Company | Composición limpiadora y/o de lavado líquida |
WO2011087733A1 (en) * | 2009-12-22 | 2011-07-21 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
WO2011100420A1 (en) | 2010-02-12 | 2011-08-18 | The Procter & Gamble Company | Benefit compositions comprising crosslinked polyglycerol esters |
WO2011100405A1 (en) | 2010-02-12 | 2011-08-18 | The Procter & Gamble Company | Benefit compositions comprising crosslinked polyglycerol esters |
US20110201534A1 (en) | 2010-02-12 | 2011-08-18 | Jennifer Beth Ponder | Benefit compositions comprising polyglycerol esters |
WO2011100411A1 (en) | 2010-02-12 | 2011-08-18 | The Procter & Gamble Company | Benefit compositions comprising polyglycerol esters |
WO2011109322A1 (en) | 2010-03-04 | 2011-09-09 | The Procter & Gamble Company | Detergent composition |
US20110257062A1 (en) | 2010-04-19 | 2011-10-20 | Robert Richard Dykstra | Liquid laundry detergent composition comprising a source of peracid and having a ph profile that is controlled with respect to the pka of the source of peracid |
US20110257069A1 (en) | 2010-04-19 | 2011-10-20 | Stephen Joseph Hodson | Detergent composition |
BR112012026915A2 (pt) | 2010-04-19 | 2016-07-12 | Procter & Gamble Comapny | composição detergente |
US20110257060A1 (en) | 2010-04-19 | 2011-10-20 | Robert Richard Dykstra | Laundry detergent composition comprising bleach particles that are suspended within a continuous liquid phase |
US8889612B2 (en) | 2010-04-19 | 2014-11-18 | The Procter & Gamble Company | Method of laundering fabric using a compacted liquid laundry detergent composition |
RU2530020C2 (ru) | 2010-04-21 | 2014-10-10 | Дзе Проктер Энд Гэмбл Компани | Жидкий чистящий и/или дезинфицирующий состав |
EP3020768B1 (de) | 2010-05-18 | 2018-04-25 | Milliken & Company | Optische aufheller und zusammensetzungen damit |
EP2571973B1 (de) | 2010-05-18 | 2020-04-01 | Milliken & Company | Optische aufheller und zusammensetzungen damit |
US8470760B2 (en) | 2010-05-28 | 2013-06-25 | Milliken 7 Company | Colored speckles for use in granular detergents |
US8476216B2 (en) | 2010-05-28 | 2013-07-02 | Milliken & Company | Colored speckles having delayed release properties |
EP2395070A1 (de) | 2010-06-10 | 2011-12-14 | The Procter & Gamble Company | Flüssiges Waschmittelzusammensetzung mit Lipase bakterieller Herkunft |
WO2011163457A1 (en) | 2010-06-23 | 2011-12-29 | The Procter & Gamble Company | Product for pre-treatment and laundering of stained fabric |
CA2803629C (en) | 2010-07-02 | 2015-04-28 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
RU2607747C1 (ru) | 2010-07-02 | 2017-01-10 | Дзе Проктер Энд Гэмбл Компани | Способ получения пленок из нетканых полотен |
WO2012003365A1 (en) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Filaments comprising an ingestible active agent nonwoven webs and methods for making same |
WO2012003360A2 (en) | 2010-07-02 | 2012-01-05 | The Procter & Gamble Company | Detergent product and method for making same |
MX2012015169A (es) | 2010-07-02 | 2013-05-09 | Procter & Gamble | Filamentos que comprenden un agente activo sin perfume, tramas de tela no tejida y métodos para elaborarlos. |
CN103025930B (zh) | 2010-07-02 | 2014-11-12 | 宝洁公司 | 递送活性剂的方法 |
US8685171B2 (en) | 2010-07-29 | 2014-04-01 | The Procter & Gamble Company | Liquid detergent composition |
EP2412792A1 (de) | 2010-07-29 | 2012-02-01 | The Procter & Gamble Company | Flüssige Reinigungsmittelzusammensetzung |
EP2420558B1 (de) | 2010-08-17 | 2017-08-02 | The Procter & Gamble Company | Stabile nachhaltige Handspülmittel |
EP2606111B1 (de) | 2010-08-17 | 2017-12-06 | The Procter and Gamble Company | Manuelles geschirrspülverahren mit langanhaltendem schaum |
JP2013543543A (ja) | 2010-09-20 | 2013-12-05 | ザ プロクター アンド ギャンブル カンパニー | 非フルオロポリマー表面保護組成物 |
WO2012040171A1 (en) | 2010-09-20 | 2012-03-29 | The Procter & Gamble Company | Non-fluoropolymer surface protection composition |
US20120077725A1 (en) | 2010-09-20 | 2012-03-29 | Xiaoru Jenny Wang | Fabric care formulations and methods |
WO2012040136A1 (en) | 2010-09-21 | 2012-03-29 | The Procter & Gamble Company | Liquid cleaning composition |
EP2431451A1 (de) | 2010-09-21 | 2012-03-21 | The Procter & Gamble Company | Flüssige Reinigungsmittelzusammensetzung mit Schleifpartikeln |
WO2012040143A1 (en) | 2010-09-21 | 2012-03-29 | The Procter & Gamble Company | Liquid cleaning composition |
CN103270118B (zh) | 2010-10-22 | 2015-05-13 | 美利肯公司 | 用作上蓝剂的二偶氮着色剂 |
US20120101018A1 (en) | 2010-10-22 | 2012-04-26 | Gregory Scot Miracle | Bis-azo colorants for use as bluing agents |
WO2012054058A1 (en) | 2010-10-22 | 2012-04-26 | The Procter & Gamble Company | Bis-azo colorants for use as bluing agents |
US8715368B2 (en) | 2010-11-12 | 2014-05-06 | The Procter & Gamble Company | Thiophene azo dyes and laundry care compositions containing the same |
BR112013011604B1 (pt) | 2010-11-12 | 2020-01-07 | Milliken & Company | Corantes de azo tiofeno |
CA2817718C (en) | 2010-11-12 | 2016-02-09 | The Procter & Gamble Company | Laundry care compositions comprising charged thiophene azo dyes |
WO2012075611A1 (en) | 2010-12-10 | 2012-06-14 | The Procter & Gamble Company | Laundry detergents |
EA201390965A1 (ru) * | 2010-12-29 | 2014-04-30 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ и композиция для третичного метода нефтедобычи из пласта, содержащего сырую нефть |
WO2012138423A1 (en) | 2011-02-17 | 2012-10-11 | The Procter & Gamble Company | Compositions comprising mixtures of c10-c13 alkylphenyl sulfonates |
WO2012116014A1 (en) | 2011-02-25 | 2012-08-30 | Milliken & Company | Capsules and compositions comprising the same |
CA2828650C (en) | 2011-03-03 | 2016-11-15 | The Procter & Gamble Company | Dishwashing method |
AU2012240329A1 (en) | 2011-04-04 | 2013-10-10 | The Procter & Gamble Company | Personal care article |
US9163146B2 (en) | 2011-06-03 | 2015-10-20 | Milliken & Company | Thiophene azo carboxylate dyes and laundry care compositions containing the same |
EP2721134A1 (de) | 2011-06-20 | 2014-04-23 | The Procter and Gamble Company | Flüssigreinigung und/oder reinigungszusammensetzung |
US8852643B2 (en) | 2011-06-20 | 2014-10-07 | The Procter & Gamble Company | Liquid cleaning and/or cleansing composition |
JP2014520198A (ja) | 2011-06-20 | 2014-08-21 | ザ プロクター アンド ギャンブル カンパニー | 液体クリーニング及び/又はクレンジング組成物 |
EP2537917A1 (de) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Flüssige Reinigungsmittel mit Schleifpartikeln |
US20120324655A1 (en) | 2011-06-23 | 2012-12-27 | Nalini Chawla | Product for pre-treatment and laundering of stained fabric |
EP2725912A4 (de) | 2011-06-29 | 2015-03-04 | Solae Llc | Backwarenzusammensetzungen mit aus verarbeitungsströmen isolierten sojamolkeproteinen |
WO2013016371A1 (en) | 2011-07-25 | 2013-01-31 | The Procter & Gamble Company | Detergents having acceptable color |
US20130029895A1 (en) | 2011-07-27 | 2013-01-31 | Jean-Luc Phillippe Bettiol | Multiphase liquid detergent composition |
US8853144B2 (en) | 2011-08-05 | 2014-10-07 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage |
US8636918B2 (en) | 2011-08-05 | 2014-01-28 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale |
US8679366B2 (en) | 2011-08-05 | 2014-03-25 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale |
US8841246B2 (en) | 2011-08-05 | 2014-09-23 | Ecolab Usa Inc. | Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage |
JP2014527108A (ja) | 2011-08-15 | 2014-10-09 | ザ プロクター アンド ギャンブル カンパニー | ピリジノール−n−オキシド化合物含有洗剤組成物 |
EP2573157A1 (de) | 2011-09-20 | 2013-03-27 | The Procter and Gamble Company | Flüssiges Reinigungsmittel mit Schleifpartikeln |
AR088758A1 (es) | 2011-09-20 | 2014-07-02 | Procter & Gamble | Composiciones detergentes de facil enjuague que comprenden surfactantes basados en isoprenoides |
US20130072416A1 (en) | 2011-09-20 | 2013-03-21 | The Procter & Gamble Company | High suds detergent compositions comprising isoprenoid-based surfactants |
EP2758503A2 (de) | 2011-09-20 | 2014-07-30 | The Procter and Gamble Company | Waschmittelzusammensetzungen mit spezifischen mischungsverhältnissen von tensiden auf isoprenoidbasis |
MX2014003278A (es) | 2011-09-20 | 2014-05-21 | Procter & Gamble | Composiciones detergentes que comprenden sistemas surfactantes primarios que comprenden surfactantes con base de isoprenoide altamente ramificados y otros surfactantes. |
US20130072414A1 (en) | 2011-09-20 | 2013-03-21 | The Procter & Gamble Company | Detergent compositions comprising sustainable surfactant systems comprising isoprenoid-derived surfactants |
US9051406B2 (en) | 2011-11-04 | 2015-06-09 | Akzo Nobel Chemicals International B.V. | Graft dendrite copolymers, and methods for producing the same |
CN103945828A (zh) | 2011-11-04 | 2014-07-23 | 阿克佐诺贝尔化学国际公司 | 混杂树枝状共聚物、其组合物及其制备方法 |
MX2014005562A (es) | 2011-11-11 | 2014-05-30 | Procter & Gamble | Composiciones de tratamiento de superficie que incluyen sales protectoras. |
EP2594500A1 (de) | 2011-11-18 | 2013-05-22 | The Procter & Gamble Company | Verpackung für eine flüssige Reinigungsmittelzusammensetzung mit Schleifpartikeln |
US20130150276A1 (en) | 2011-12-09 | 2013-06-13 | The Procter & Gamble Company | Method of providing fast drying and/or delivering shine on hard surfaces |
EP3382003B1 (de) | 2011-12-29 | 2021-07-14 | Novozymes A/S | Reinigungsmittelzusammensetzung mit lipase-varianten |
JP6028042B2 (ja) | 2012-01-04 | 2016-11-16 | ザ プロクター アンド ギャンブル カンパニー | 複数の領域を有する活性物質含有繊維性構造体 |
CA2860647C (en) | 2012-01-04 | 2022-06-14 | The Procter & Gamble Company | Active containing fibrous structures with multiple regions having differing densities |
US8877696B2 (en) | 2012-03-26 | 2014-11-04 | The Procter & Gamble Company | Cleaning compositions comprising pH-switchable amine surfactants |
US9068147B2 (en) | 2012-05-11 | 2015-06-30 | Basf Se | Quaternized polyethylenimines with a high quaternization degree |
ES2626505T3 (es) | 2012-05-11 | 2017-07-25 | Basf Se | Polietileniminas cuaternizadas con un alto grado de cuaternización |
US8623806B2 (en) | 2012-05-11 | 2014-01-07 | The Procter & Gamble Company | Liquid detergent composition for improved shine |
US8759271B2 (en) | 2012-05-11 | 2014-06-24 | The Procter & Gamble Company | Liquid detergent composition for improved shine |
ES2634789T3 (es) | 2012-05-11 | 2017-09-29 | Basf Se | Polietileniminas cuaternizadas con un alto grado de etoxilación |
US8754027B2 (en) | 2012-05-11 | 2014-06-17 | Basf Se | Quaternized polyethulenimines with a high ethoxylation degree |
EP2877562B1 (de) | 2012-07-26 | 2018-04-25 | The Procter and Gamble Company | Enzymhaltige flüssige reinigungszusammensetzungen mit niedrigem ph-wert |
US8945314B2 (en) | 2012-07-30 | 2015-02-03 | Ecolab Usa Inc. | Biodegradable stability binding agent for a solid detergent |
US9796952B2 (en) | 2012-09-25 | 2017-10-24 | The Procter & Gamble Company | Laundry care compositions with thiazolium dye |
EP2719752B1 (de) | 2012-10-15 | 2016-03-16 | The Procter and Gamble Company | Flüssige reinigungsmittelzusammensetzung mit schleifpartikeln |
EP2727991A1 (de) | 2012-10-30 | 2014-05-07 | The Procter & Gamble Company | Flüssige Handgeschirrspül-, Reinigungs- und Desinfektionsmittel |
HUE038203T2 (hu) | 2013-01-21 | 2018-10-29 | Procter & Gamble | Mosogatószer |
PL2757144T5 (pl) | 2013-01-21 | 2024-02-12 | The Procter And Gamble Company | Detergent |
HUE036344T2 (hu) | 2013-01-21 | 2018-08-28 | Procter & Gamble | Mosogatószer |
JP6231393B2 (ja) | 2013-02-13 | 2017-11-15 | 花王株式会社 | 内部オレフィンスルホン酸塩組成物 |
EP2978832A1 (de) | 2013-03-26 | 2016-02-03 | The Procter & Gamble Company | Reinigungszusammensetzungen zur reinigung harter oberflächen |
AU2014241193B2 (en) | 2013-03-28 | 2016-10-20 | The Procter And Gamble Company | Cleaning compositions containing a polyetheramine |
EP2832842B1 (de) | 2013-07-30 | 2018-12-19 | The Procter & Gamble Company | Verfahren zur Herstellung von körnigen Reinigungszusammensetzungen mit Tensiden |
EP2832843B1 (de) | 2013-07-30 | 2019-08-21 | The Procter & Gamble Company | Verfahren zur Herstellung von körnigen Reinigungszusammensetzungen mit Polymeren |
EP2832844A1 (de) | 2013-07-30 | 2015-02-04 | The Procter & Gamble Company | Verfahren zur Herstellung von Reinigungszusammensetzungen mit Polymeren |
EP2832841B1 (de) | 2013-07-30 | 2016-08-31 | The Procter & Gamble Company | Verfahren zur Herstellung von Reinigungszusammensetzungen mit Polymeren |
JP6235144B2 (ja) | 2013-08-26 | 2017-11-22 | ザ プロクター アンド ギャンブル カンパニー | 融点が低いアルコキシル化ポリアミンを含む組成物 |
EP3049510A2 (de) | 2013-09-27 | 2016-08-03 | The Procter & Gamble Company | Verbesserte faserstrukturen mit tensiden und verfahren zur herstellung davon |
EP2862921A1 (de) | 2013-10-17 | 2015-04-22 | The Procter and Gamble Company | Flüssige Waschmittelzusammensetzung mit einem alkoxylierten Polymer und einem Abtönungsfarbstoff |
EP2862919A1 (de) | 2013-10-17 | 2015-04-22 | The Procter and Gamble Company | Zusammensetzung mit Abtönungsfarbstoff |
DE112014005598B4 (de) | 2013-12-09 | 2022-06-09 | The Procter & Gamble Company | Faserstrukturen einschließlich einer Wirksubstanz und mit darauf gedruckter Grafik |
EP2899259A1 (de) | 2014-01-22 | 2015-07-29 | The Procter and Gamble Company | Waschmittel |
US20150210964A1 (en) | 2014-01-24 | 2015-07-30 | The Procter & Gamble Company | Consumer Product Compositions |
WO2015139221A1 (en) | 2014-03-19 | 2015-09-24 | Rhodia Operations | New copolymers useful in liquid detergent compositions |
EP3122850A1 (de) | 2014-03-27 | 2017-02-01 | The Procter & Gamble Company | Reinigungszusammensetzungen mit einem polyetheramin |
US9719052B2 (en) | 2014-03-27 | 2017-08-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
EP2924105A1 (de) | 2014-03-28 | 2015-09-30 | The Procter and Gamble Company | Dosierungsartikel für wasserlösliche Einheit |
EP2924106A1 (de) | 2014-03-28 | 2015-09-30 | The Procter and Gamble Company | Dosierungsartikel für wasserlösliche Einheit |
EP2940117B1 (de) | 2014-04-30 | 2020-08-19 | The Procter and Gamble Company | Reinigungszusammensetzung enthaltend ein Polyetheramin |
EP2940112A1 (de) | 2014-04-30 | 2015-11-04 | The Procter and Gamble Company | Reinigungszusammensetzung |
EP2940113A1 (de) | 2014-04-30 | 2015-11-04 | The Procter and Gamble Company | Reinigungszusammensetzung |
EP2940116B1 (de) | 2014-04-30 | 2018-10-17 | The Procter and Gamble Company | Reinigungsmittel |
ES2704092T3 (es) | 2014-04-30 | 2019-03-14 | Procter & Gamble | Composición limpiadora |
US9365805B2 (en) | 2014-05-15 | 2016-06-14 | Ecolab Usa Inc. | Bio-based pot and pan pre-soak |
US9926516B2 (en) | 2014-06-05 | 2018-03-27 | The Procter & Gamble Company | Mono alcohols for low temperature stability of isotropic liquid detergent compositions |
EP3152288A1 (de) | 2014-06-06 | 2017-04-12 | The Procter & Gamble Company | Waschmittelzusammensetzung mit polyalkyleniminpolymeren |
WO2015191434A2 (en) | 2014-06-09 | 2015-12-17 | Stepan Company | Detergents for cold-water cleaning |
ES2710236T5 (es) | 2014-08-07 | 2021-12-09 | Procter & Gamble | Composición de detergente para el lavado de ropa |
CA2955499A1 (en) | 2014-08-07 | 2016-02-11 | The Procter & Gamble Company | Soluble unit dose comprising a laundry detergent composition |
PL2982737T3 (pl) | 2014-08-07 | 2018-11-30 | The Procter & Gamble Company | Kompozycja detergentowa do prania |
EP2982738B2 (de) | 2014-08-07 | 2022-06-29 | The Procter & Gamble Company | Waschmittelzusammensetzung |
CA2956088C (en) | 2014-08-27 | 2019-07-30 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
JP6400837B2 (ja) | 2014-08-27 | 2018-10-03 | ザ プロクター アンド ギャンブル カンパニー | 布地の処理方法 |
WO2016032993A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
WO2016032991A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
WO2016049388A1 (en) | 2014-09-25 | 2016-03-31 | The Procter & Gamble Company | Fabric care compositions containing a polyetheramine |
EP3034593B1 (de) | 2014-12-19 | 2019-06-12 | The Procter and Gamble Company | Flüssige Reinigungsmittelzusammensetzung |
US10570352B2 (en) | 2015-01-08 | 2020-02-25 | Stepan Company | Cold-water laundry detergents |
EP3284811B1 (de) | 2015-06-04 | 2018-12-12 | The Procter & Gamble Company | Flüssige handspülmittelzusammensetzung |
EP3101108B1 (de) | 2015-06-04 | 2018-01-31 | The Procter and Gamble Company | Flüssige handspülmittelzusammensetzung |
ES2704082T3 (es) | 2015-07-13 | 2019-03-14 | Procter & Gamble | Uso de disolventes de glicol éter en composiciones limpiadoras líquidas |
US9777250B2 (en) | 2015-10-13 | 2017-10-03 | Milliken & Company | Whitening agents for cellulosic substrates |
US10155868B2 (en) | 2015-10-13 | 2018-12-18 | Milliken & Company | Whitening agents for cellulosic substrates |
US10597614B2 (en) | 2015-10-13 | 2020-03-24 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
US9902923B2 (en) | 2015-10-13 | 2018-02-27 | The Procter & Gamble Company | Polyglycerol dye whitening agents for cellulosic substrates |
US9745544B2 (en) | 2015-10-13 | 2017-08-29 | The Procter & Gamble Company | Whitening agents for cellulosic substrates |
US9976035B2 (en) | 2015-10-13 | 2018-05-22 | Milliken & Company | Whitening agents for cellulosic substrates |
EP3170884A1 (de) | 2015-11-20 | 2017-05-24 | The Procter and Gamble Company | Alkohole in flüssigen reinigungsmittelzusammensetzungen zur entfernung von flecken von oberflächen |
EP3181680A1 (de) | 2015-12-14 | 2017-06-21 | The Procter & Gamble Company | Dosierungsartikel für wasserlösliche einheit |
US11377625B2 (en) | 2015-12-18 | 2022-07-05 | Basf Se | Cleaning compositions with polyalkanolamines |
US10266795B2 (en) | 2015-12-18 | 2019-04-23 | The Procter & Gamble Company | Cleaning compositions with alkoxylated polyalkanolamines |
US10308900B2 (en) | 2015-12-22 | 2019-06-04 | Milliken & Company | Occult particles for use in granular laundry care compositions |
WO2017127258A1 (en) | 2016-01-21 | 2017-07-27 | The Procter & Gamble Company | Fibrous elements comprising polyethylene oxide |
US9719056B1 (en) | 2016-01-29 | 2017-08-01 | The Procter & Gamble Company | Bis-azo colorants for use as bluing agents |
CN109071682A (zh) | 2016-02-15 | 2018-12-21 | 赫尔克里士有限公司 | 家庭护理组合物 |
US11682319B2 (en) | 2016-03-10 | 2023-06-20 | Intuitive Surgical Operations, Inc. | Fake blood for use in simulated surgical procedures |
PL3556834T3 (pl) | 2016-05-09 | 2021-02-08 | The Procter & Gamble Company | Kompozycja detergentowa zawierająca dekarboksylazę kwasu tłuszczowego |
US10858616B2 (en) | 2016-05-09 | 2020-12-08 | The Procter & Gamble Company | Detergent composition |
PL3243898T3 (pl) | 2016-05-09 | 2019-08-30 | The Procter & Gamble Company | Kompozycja detergentowa zawierająca enzym przekształcający kwas oleinowy |
EP3243894A1 (de) | 2016-05-10 | 2017-11-15 | The Procter and Gamble Company | Reinigungszusammensetzung |
EP3243895A1 (de) | 2016-05-13 | 2017-11-15 | The Procter and Gamble Company | Reinigungszusammensetzung |
US10081783B2 (en) | 2016-06-09 | 2018-09-25 | The Procter & Gamble Company | Cleaning compositions having an enzyme system |
US20170355932A1 (en) | 2016-06-09 | 2017-12-14 | The Procter & Gamble Company | Cleaning compositions including nuclease enzyme and tannins |
US20170355930A1 (en) | 2016-06-09 | 2017-12-14 | The Procter & Gamble Company | Cleaning compositions including nuclease enzyme and amines |
US20170355933A1 (en) | 2016-06-09 | 2017-12-14 | The Procter & Gamble Company | Cleaning compositions including nuclease enzyme and malodor reduction materials |
EP3257924A1 (de) | 2016-06-17 | 2017-12-20 | The Procter and Gamble Company | Flüssige reinigungsmittelzusammensetzung |
EP3257926A1 (de) | 2016-06-17 | 2017-12-20 | The Procter and Gamble Company | Flüssige reinigungsmittelzusammensetzung |
EP3257925B1 (de) | 2016-06-17 | 2019-10-16 | The Procter and Gamble Company | Flüssige reinigungsmittelzusammensetzung |
ES2753724T3 (es) | 2016-07-14 | 2020-04-14 | Procter & Gamble | Composición detergente |
US10421931B2 (en) | 2016-07-21 | 2019-09-24 | The Procter & Gamble Company | Cleaning composition with insoluble quaternized cellulose particles and an external structurant |
US10421932B2 (en) | 2016-07-21 | 2019-09-24 | The Procter & Gamble Company | Cleaning composition with insoluble quaternized cellulose particles and non-anionic performance polymers |
EP3487971A1 (de) | 2016-07-22 | 2019-05-29 | The Procter and Gamble Company | Geschirrspülmittelzusammensetzung |
EP3284805B1 (de) | 2016-08-17 | 2020-02-19 | The Procter & Gamble Company | Reinigungszusammensetzung |
US20180072970A1 (en) | 2016-09-13 | 2018-03-15 | The Procter & Gamble Company | Stable violet-blue to blue imidazolium compounds |
CN109890911A (zh) | 2016-11-01 | 2019-06-14 | 美利肯公司 | 作为洗衣护理组合物中的上蓝剂的隐色聚合物 |
CN109844086B (zh) | 2016-11-01 | 2023-04-28 | 宝洁公司 | 衣物洗涤护理组合物中作为上蓝剂的隐色着色剂 |
ES2827831T3 (es) | 2016-11-01 | 2021-05-24 | Procter & Gamble | Métodos para usar colorantes leuco como agentes azulantes en composiciones para el cuidado durante el lavado de ropa |
EP3535373B1 (de) | 2016-11-01 | 2020-09-09 | The Procter & Gamble Company | Leuko-triphenylmethan-farbstoffe als vergrauungshemmer in wäschepflegezusammensetzungen |
US10711139B2 (en) | 2016-11-01 | 2020-07-14 | Milliken & Company | Leuco polymers as bluing agents in laundry care compositions |
US20180119068A1 (en) | 2016-11-01 | 2018-05-03 | The Procter & Gamble Company | Methods of using leuco colorants as bluing agents in laundry care compositions |
US11299634B2 (en) | 2016-11-01 | 2022-04-12 | Milliken & Company | Reactive leuco compounds and compositions comprising the same |
CA3041529C (en) | 2016-11-01 | 2023-03-14 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
US10577570B2 (en) | 2016-11-01 | 2020-03-03 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
BR112019005736A2 (pt) | 2016-11-01 | 2019-08-13 | Milliken & Co | polímeros leuco como agentes de azulamento em composições para lavagem de roupa |
CN109890910B (zh) | 2016-11-01 | 2022-05-31 | 美利肯公司 | 作为洗衣护理组合物中的上蓝剂的隐色聚合物 |
JP6772375B2 (ja) | 2016-11-01 | 2020-10-21 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 洗濯ケア組成物中の青味剤としてのロイコポリマー |
EP3535372B1 (de) | 2016-11-01 | 2020-09-09 | The Procter & Gamble Company | Leukopolymere als vergrauungshemmer in wäschepflegezusammensetzungen |
US10351709B2 (en) | 2016-11-01 | 2019-07-16 | Milliken & Company | Leuco polymers as bluing agents in laundry care compositions |
EP3535327A1 (de) | 2016-11-01 | 2019-09-11 | Milliken & Company | Leukopolymere als vergrauungshemmer in wäschepflegezusammensetzungen |
EP3535371B1 (de) | 2016-11-01 | 2020-09-09 | The Procter & Gamble Company | Leukopolymere als vergrauungshemmer in wäschepflegezusammensetzungen |
US10385294B2 (en) | 2016-11-01 | 2019-08-20 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
WO2018085306A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
WO2018085303A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Leuco polymers as bluing agents in laundry care compositions |
WO2018085314A1 (en) | 2016-11-01 | 2018-05-11 | The Procter & Gamble Company | Reactive leuco compounds and compositions comprising the same |
WO2018085378A1 (en) | 2016-11-01 | 2018-05-11 | Milliken & Company | Leuco polymers as bluing agents in laundry care compositions |
EP3535320A1 (de) | 2016-11-01 | 2019-09-11 | Milliken & Company | Leukopolymere als vergrauungshemmer bei wäschepflegezusammensetzungen |
US10550443B2 (en) | 2016-12-02 | 2020-02-04 | The Procter & Gamble Company | Cleaning compositions including enzymes |
JP6907317B2 (ja) | 2016-12-02 | 2021-07-21 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 酵素を含む洗浄組成物 |
JP6907318B2 (ja) | 2016-12-02 | 2021-07-21 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 酵素を含む洗浄組成物 |
WO2019075143A1 (en) | 2017-10-12 | 2019-04-18 | The Procter & Gamble Company | LEUCO-COLORANTS AS AZURING AGENTS IN LAUNDRY CARE COMPOSITIONS |
WO2019075147A1 (en) | 2017-10-12 | 2019-04-18 | The Procter & Gamble Company | METHODS OF USING LEUCO-COLORANTS AS AZURING AGENTS IN LAUNDRY CARE COMPOSITIONS |
US20190112481A1 (en) | 2017-10-12 | 2019-04-18 | Milliken & Company | Leuco colorants with extended conjugation |
EP3694968A1 (de) | 2017-10-12 | 2020-08-19 | The Procter and Gamble Company | Leukofarbstoffe als bläuemittel in wäschepflegezusammensetzungen |
WO2019075230A1 (en) | 2017-10-12 | 2019-04-18 | Milliken & Company | LEUCO COMPOUNDS AND COMPOSITIONS COMPRISING THE SAME |
EP3694975A1 (de) | 2017-10-12 | 2020-08-19 | The Procter & Gamble Company | Verfahren zur verwendung von leukofarbstoffen als bläuemittel in wäschepflegemitteln |
CA3074713A1 (en) | 2017-10-12 | 2019-04-18 | The Procter & Gamble Company | Methods of using leuco colorants as bluing agents in laundry care compositions |
EP3694928A1 (de) | 2017-10-12 | 2020-08-19 | Milliken & Company | Leukoverbindungen |
EP3694969B1 (de) | 2017-10-12 | 2021-08-18 | The Procter & Gamble Company | Wäschepflegezusammensetzungen mit leukoverbindungen |
US11230686B2 (en) | 2017-10-12 | 2022-01-25 | The Procter & Gamble Company | Laundry care compositions and methods for determining their age |
TW201922942A (zh) | 2017-10-12 | 2019-06-16 | 美商美力肯及公司 | 三芳基甲烷隱色化合物及包含其之組成物 |
CA3074934A1 (en) | 2017-10-12 | 2019-04-18 | The Procter & Gamble Company | Leuco colorants with extended conjugation as bluing agents in laundry care formulations |
BR112020027032A2 (pt) | 2018-07-27 | 2021-03-30 | Milliken & Company | Antioxidantes poliméricos fenólicos |
WO2020023892A1 (en) | 2018-07-27 | 2020-01-30 | Milliken & Company | Polymeric amine antioxidants |
US11136535B2 (en) | 2018-07-27 | 2021-10-05 | The Procter & Gamble Company | Leuco colorants as bluing agents in laundry care compositions |
US11261403B2 (en) | 2018-07-27 | 2022-03-01 | Milliken & Company | Stabilized compositions comprising leuco compounds |
US20200123472A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11466122B2 (en) | 2018-10-18 | 2022-10-11 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11299591B2 (en) | 2018-10-18 | 2022-04-12 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US11732218B2 (en) | 2018-10-18 | 2023-08-22 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
US20200123319A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US20200123475A1 (en) | 2018-10-18 | 2020-04-23 | Milliken & Company | Polyethyleneimine compounds containing n-halamine and derivatives thereof |
US11518963B2 (en) | 2018-10-18 | 2022-12-06 | Milliken & Company | Polyethyleneimine compounds containing N-halamine and derivatives thereof |
CA3112457A1 (en) | 2018-11-16 | 2020-05-22 | The Procter & Gamble Company | Composition and method for removing stains from fabrics |
US20220306556A1 (en) | 2019-06-20 | 2022-09-29 | Exxonmobil Chemical Patents Inc. | Amphiphilic Reaction Products from Vinylidene Olefins and Methods for Production Thereof |
WO2021178100A1 (en) | 2020-03-02 | 2021-09-10 | Milliken & Company | Composition comprising hueing agent |
US20210269747A1 (en) | 2020-03-02 | 2021-09-02 | Milliken & Company | Composition Comprising Hueing Agent |
US11718814B2 (en) | 2020-03-02 | 2023-08-08 | Milliken & Company | Composition comprising hueing agent |
WO2022023250A1 (en) | 2020-07-27 | 2022-02-03 | Unilever Ip Holdings B.V. | Use of an enzyme and surfactant for inhibiting microorganisms |
WO2022043269A1 (en) | 2020-08-26 | 2022-03-03 | Unilever Ip Holdings B.V. | Detergent composition comprising isethionate surfactant |
EP4247930A1 (de) | 2020-11-19 | 2023-09-27 | The Procter & Gamble Company | Verfahren zum herstellen von waschmittelzusammensetzungen mit parfüm |
AR124324A1 (es) * | 2020-12-15 | 2023-03-15 | Shell Int Research | UN PROCESO PARA PRODUCIR a-OLEFINAS |
WO2022162062A1 (en) | 2021-02-01 | 2022-08-04 | Unilever Ip Holdings B.V. | Detergent composition |
EP4036199A1 (de) | 2021-02-01 | 2022-08-03 | Unilever IP Holdings B.V. | Reinigungsmittelzusammensetzung |
WO2022162221A1 (en) | 2021-02-01 | 2022-08-04 | Unilever Ip Holdings B.V. | Detergent composition |
WO2022197295A1 (en) | 2021-03-17 | 2022-09-22 | Milliken & Company | Polymeric colorants with reduced staining |
WO2022219102A1 (en) | 2021-04-15 | 2022-10-20 | Unilever Ip Holdings B.V. | Solid composition |
BR112023021022A2 (pt) | 2021-04-15 | 2023-12-12 | Unilever Ip Holdings B V | Composição sólida para lavagem de roupas, método de preparação de uma composição sólida para lavagem de roupas e uso de uma composição sólida para lavagem de roupas |
WO2022243533A1 (en) | 2021-05-20 | 2022-11-24 | Nouryon Chemicals International B.V. | Manufactured polymers having altered oligosaccharide or polysaccharide functionality or narrowed oligosaccharide distribution, processes for preparing them, compositions containing them, and methods of using them |
WO2023275269A1 (en) | 2021-06-30 | 2023-01-05 | Nouryon Chemicals International B.V. | Chelate-amphoteric surfactant liquid concentrates and use thereof in cleaning applications |
CA3228918A1 (en) | 2021-08-10 | 2023-02-16 | Nippon Shokubai Co., Ltd. | Polyalkylene-oxide-containing compound |
WO2023025748A1 (en) | 2021-08-27 | 2023-03-02 | Unilever Ip Holdings B.V. | Use of a detergent composition |
WO2023057604A2 (en) | 2021-10-08 | 2023-04-13 | Unilever Ip Holdings B.V. | Laundry composition |
WO2023057367A1 (en) | 2021-10-08 | 2023-04-13 | Unilever Ip Holdings B.V. | Laundry composition |
WO2023057647A1 (en) | 2021-10-08 | 2023-04-13 | Unilever Ip Holdings B.V. | Laundry composition |
WO2023057537A1 (en) | 2021-10-08 | 2023-04-13 | Unilever Ip Holdings B.V. | Laundry composition |
WO2023057437A1 (en) | 2021-10-08 | 2023-04-13 | Unilever Ip Holdings B.V. | Laundry composition |
WO2024107400A1 (en) | 2022-11-15 | 2024-05-23 | Milliken & Company | Optical brightener composition and laundry care composition comprising the same |
Family Cites Families (75)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2477382A (en) | 1946-05-04 | 1949-07-26 | California Research Corp | Aryl substituted alkanes and process of making the same |
FR658428A (fr) | 1947-12-18 | 1929-06-04 | Engrenage | |
BE616998A (de) | 1960-09-23 | |||
US3351654A (en) | 1961-05-19 | 1967-11-07 | Exxon Research Engineering Co | Process of preparing biodegradable alkylbenzene sulfonates by dimerizing an olefin of 5 to 10 carbon atoms with a silica-alumina catalyst |
US3196174A (en) | 1962-03-01 | 1965-07-20 | Exxon Research Engineering Co | Perhydro bis-(isoprenyl) alkyl aryl sulfonates |
NL293486A (de) | 1962-06-01 | |||
NL299229A (de) | 1962-10-16 | |||
US3427342A (en) * | 1962-12-12 | 1969-02-11 | Chemithon Corp | Continuous sulfonation process |
GB1078572A (en) | 1964-01-17 | 1967-08-09 | British Hydrocarbon Chem Ltd | Improvements relating to the production of detergent alkylate |
GB1022959A (en) | 1964-02-25 | 1966-03-16 | British Hydrocarbon Chem Ltd | Improvements relating to the production of olefines |
US3355484A (en) | 1964-08-20 | 1967-11-28 | Universal Oil Prod Co | Process for making biodegradable detergents |
US3492364A (en) | 1966-02-08 | 1970-01-27 | Phillips Petroleum Co | Process for preparing detergent alkylate |
US3491030A (en) | 1968-10-21 | 1970-01-20 | Union Carbide Corp | Alkali metal alkylaryl sulfonate compositions |
US3562797A (en) | 1969-01-09 | 1971-02-09 | Monsanto Co | Production of mono-olefins |
US3674885A (en) | 1970-10-09 | 1972-07-04 | Atlantic Richfield Co | Alkylation of benzene utilizing fischer-tropsch olefin-paraffin mixtures |
US4414130A (en) * | 1976-08-17 | 1983-11-08 | Colgate Palmolive Company | Readily disintegrable agglomerates of insoluble detergent builders and detergent compositions containing them |
US4409136A (en) * | 1977-01-31 | 1983-10-11 | Colgate Palmolive Company | Molecular sieve zeolite-built detergent paste |
EP0001318B1 (de) | 1977-08-04 | 1981-12-02 | Exxon Research And Engineering Company | Überbasische Monoalkyl-o-xylol- und Monoalkyltoluolsulfonate und ihre Anwendung als Schmiermitteladditiv |
US4235810A (en) | 1978-08-03 | 1980-11-25 | Exxon Research & Engineering Co. | Alkylates and sulphonic acids and sulphonates produced therefrom |
US4301316A (en) | 1979-11-20 | 1981-11-17 | Mobil Oil Corporation | Preparing phenylalkanes |
US4301317A (en) | 1979-11-20 | 1981-11-17 | Mobil Oil Corporation | Preparation of 2-phenylalkanes |
GB2083490B (en) | 1980-09-10 | 1984-07-04 | Unilever Plc | Built detergent bars |
JPS59500166A (ja) | 1982-02-17 | 1984-02-02 | コモンウェルス・サイエンティフィック・アンド・インダストリアル・リサ−チ・オ−ガニゼイション | オレフィンのオリゴマ−化および異性化用触媒 |
US4447664A (en) | 1982-09-23 | 1984-05-08 | The Dow Chemical Company | Integrated Fischer-Tropsch and aromatic alkylation process |
US4587374A (en) | 1984-03-26 | 1986-05-06 | Ethyl Corporation | Olefin isomerization process |
US4645623A (en) | 1984-12-17 | 1987-02-24 | Monsanto Company | Alkylaryl sulfonate compositions |
US4962256A (en) | 1988-10-06 | 1990-10-09 | Mobil Oil Corp. | Process for preparing long chain alkyl aromatic compounds |
US4731497A (en) | 1986-12-29 | 1988-03-15 | Atlantic Richfield Company | Alkylation of aromatics with alpha-olefins |
US4959491A (en) | 1987-03-11 | 1990-09-25 | Chevron Research Company | Detergent grade olefins, alkylbenzenes and alkylbenzene sulfonates and processes for preparing |
US4855527A (en) | 1987-10-07 | 1989-08-08 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite |
US4870038A (en) | 1987-10-07 | 1989-09-26 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
US5026933A (en) | 1987-10-07 | 1991-06-25 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
US5243116A (en) | 1987-11-23 | 1993-09-07 | The Dow Chemical Company | Alkylation of aromatic compounds |
US5198595A (en) | 1987-11-23 | 1993-03-30 | The Dow Chemical Company | Alkylation of aromatic compounds |
EP0321177B1 (de) | 1987-12-15 | 1994-08-03 | Uop | Ersatz von Aluminium durch Chrom und/oder Zinn im Gerüst eines Molekularsiebes mittels einer Behandlung mit Fluoridsalzen |
ES2007545A6 (es) | 1988-08-03 | 1989-06-16 | Petroquimica Espanola S A Petr | Proceso de alquilacion catalitica en lecho fijo de hidrocarburos aromaticos. |
CA1339903C (en) | 1988-08-09 | 1998-06-09 | Eugene Frederick Lutz | Process for the preparation of surfactants having improved physical properties |
US5030785A (en) | 1988-10-06 | 1991-07-09 | Mobil Oil Corp. | Process for preparing long chain alkyl aromatic compounds employing Lewis acid-promoted zeolite catalysts |
US5246566A (en) | 1989-02-17 | 1993-09-21 | Chevron Research And Technology Company | Wax isomerization using catalyst of specific pore geometry |
US4990718A (en) | 1989-04-03 | 1991-02-05 | Mobil Oil Corporation | Aromatic alkylation with alpha-olefin dimer |
US4973788A (en) * | 1989-05-05 | 1990-11-27 | Ethyl Corporation | Vinylidene dimer process |
US5245072A (en) | 1989-06-05 | 1993-09-14 | Mobil Oil Corporation | Process for production of biodegradable esters |
FR2648129B1 (fr) | 1989-06-07 | 1991-10-31 | Inst Francais Du Petrole | Procede de production d'alkylbenzenes utilisant des catalyseurs a base de zeolithe y desaluminee |
US4996386A (en) | 1989-12-21 | 1991-02-26 | Shell Oil Company | Concurrent isomerization and disproportionation of olefins |
US5196625A (en) | 1990-04-27 | 1993-03-23 | Chevron Research & Technology Company | Detergent grade to C10 to C28 olefins, (C10 to C28 alkyl) benzenes and (C10 to C28 alkyl) benzene sulfonates and process for preparing same using a phosphite containing catalyst |
US5196624A (en) | 1990-04-27 | 1993-03-23 | Chevron Research And Technology Company | Detergent grade to C10 to C28 olefins, (C10 to C28 alkyl)benzenes and C10 to C28 alkyl) benzene sulfonates and process for preparing same using a phosphine containing catalyst |
FR2664264B1 (fr) * | 1990-07-09 | 1992-09-18 | Inst Francais Du Petrole | Procede de production de 2- et 3-phenylalcanes utilisant un catalyseur a base de mordenite modifiee. |
FR2665436B1 (fr) | 1990-07-31 | 1992-10-16 | Inst Francais Du Petrole | Procede de production de 2- et 3-phenylalcanes utilisant un catalyseur a base d'une mordenite particuliere. |
US5087788A (en) | 1991-03-04 | 1992-02-11 | Ethyl Corporation | Preparation of high purity vinylindene olefin |
US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
US5210060A (en) | 1991-07-30 | 1993-05-11 | Amoco Corporation | Catalyst for converting synthesis gas to paraffin wax |
US5196574A (en) | 1991-12-23 | 1993-03-23 | Uop | Detergent alkylation process using a fluorided silica-alumina |
US5344997A (en) | 1991-12-23 | 1994-09-06 | Uop | Alkylation of aromatics using a fluorided silica-alumina catalyst |
FR2688214B1 (fr) | 1992-03-06 | 1994-04-29 | Inst Francais Du Petrole | Separation de paraffines aliphatiques par adsorption. |
US5258566A (en) | 1992-05-04 | 1993-11-02 | Mobil Oil Corp. | Process for preparing long chain alkylaromatic compounds |
US5334793A (en) | 1992-07-27 | 1994-08-02 | Uop | Increasing catalyst life and improving product linearity in the alkylation of aromatics with linear olefins |
DE4224947A1 (de) | 1992-07-29 | 1994-02-03 | Henkel Kgaa | Enzymhaltiges Waschmittel |
DE4236698A1 (de) | 1992-10-30 | 1994-05-05 | Henkel Kgaa | Enzymhaltiges Waschmittel |
IT1256084B (it) | 1992-07-31 | 1995-11-27 | Eniricerche Spa | Catalizzatore per la idroisomerizzazione di normal-paraffine a catena lunga e procedimento per la sua preparazione |
US5302732A (en) | 1992-09-14 | 1994-04-12 | Uop | Use of ultra-low sodium silica-aluminas in the alkylation of aromatics |
FR2697246B1 (fr) | 1992-10-28 | 1995-01-06 | Inst Francais Du Petrole | Procédé de production de phénylalcanes utilisant un catalyseur à base de zéolithe Y modifiée. |
GB2278125A (en) | 1993-05-17 | 1994-11-23 | Unilever Plc | Detergent composition |
US5510306A (en) | 1993-12-29 | 1996-04-23 | Shell Oil Company | Process for isomerizing linear olefins to isoolefins |
US5648585A (en) | 1993-12-29 | 1997-07-15 | Murray; Brendan Dermot | Process for isomerizing linear olefins to isoolefins |
EP0686177B1 (de) | 1994-02-02 | 1999-09-08 | Chevron Chemical Company LLC | Verfahren zur herstellung von skelettisomerisierten linearen olefinen |
IT1270230B (it) | 1994-06-16 | 1997-04-29 | Enichem Sintesi | Composizione catalitica e processo per l'alchilazione di composti aromatici |
US5491271A (en) | 1994-08-26 | 1996-02-13 | Uop | Detergent alkylation using a regenerable clay catalyst |
EP0835234B1 (de) | 1995-06-29 | 2001-09-26 | Sasol Technology (Proprietary) Limited | Verfahren zur herstellung von sauerstoff enthaltenden verbindungen |
US5625105A (en) * | 1996-02-05 | 1997-04-29 | Amoco Corporation | Production of vinylidene olefins |
US5770782A (en) | 1996-02-08 | 1998-06-23 | Huntsman Petrochemical Corporation | Process and system for alkylation of aromatic compounds |
US5847254A (en) | 1996-02-08 | 1998-12-08 | Huntsman Petrochemical Corporation | Alkylation of benzene to form linear alkylbenzenes using fluorine-containing mordenites |
US5777187A (en) | 1996-02-08 | 1998-07-07 | Huntsman Petrochemical Corporation | Two-step process for alkylation of benzene to form linear alkylbenzenes |
US5866748A (en) | 1996-04-23 | 1999-02-02 | Exxon Research And Engineering Company | Hydroisomerization of a predominantly N-paraffin feed to produce high purity solvent compositions |
CA2204461C (en) | 1996-05-14 | 2006-07-04 | Thomas V. Harris | Process for producing an alkylated, non-oxygen-containing aromatic hydrocarbon |
US5811623A (en) | 1997-06-09 | 1998-09-22 | Catalytic Distillation Technologies | Isomerization of olefins by alkylation and dealkylation of aromatic hydrocarbons |
-
1998
- 1998-07-20 JP JP2000504218A patent/JP2001511471A/ja not_active Withdrawn
- 1998-07-20 CA CA002297010A patent/CA2297010C/en not_active Expired - Fee Related
- 1998-07-20 AU AU81244/98A patent/AU8124498A/en not_active Abandoned
- 1998-07-20 ZA ZA986448A patent/ZA986448B/xx unknown
- 1998-07-20 WO PCT/IB1998/001098 patent/WO1999005241A1/en not_active Application Discontinuation
- 1998-07-20 CN CNB988092565A patent/CN1161448C/zh not_active Expired - Fee Related
- 1998-07-20 BR BR9810780-1A patent/BR9810780A/pt not_active IP Right Cessation
- 1998-07-20 EP EP98930973A patent/EP1002028A1/de not_active Withdrawn
- 1998-07-21 AR ARP980103541A patent/AR016367A1/es not_active Application Discontinuation
- 1998-07-21 MA MA25186A patent/MA24616A1/fr unknown
-
2000
- 2000-01-07 US US09/478,906 patent/US6566319B1/en not_active Expired - Fee Related
- 2000-01-24 MX MXPA00000839 patent/MX220724B/es unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110639426A (zh) * | 2019-10-10 | 2020-01-03 | 太原理工大学 | 一种支链烷基磺酸盐表面活性剂及其制备工艺 |
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AR016367A1 (es) | 2001-07-04 |
WO1999005241A1 (en) | 1999-02-04 |
MX220724B (es) | 2004-06-02 |
JP2001511471A (ja) | 2001-08-14 |
EP1002028A1 (de) | 2000-05-24 |
CN1161448C (zh) | 2004-08-11 |
BR9810780A (pt) | 2001-09-18 |
CA2297010A1 (en) | 1999-02-04 |
CN1270623A (zh) | 2000-10-18 |
US6566319B1 (en) | 2003-05-20 |
ZA986448B (en) | 1999-01-21 |
AU8124498A (en) | 1999-02-16 |
MXPA00000839A (es) | 2001-10-01 |
MA24616A1 (fr) | 1999-04-01 |
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