CA2238035A1 - Multilayer interference pigments - Google Patents

Multilayer interference pigments Download PDF

Info

Publication number
CA2238035A1
CA2238035A1 CA002238035A CA2238035A CA2238035A1 CA 2238035 A1 CA2238035 A1 CA 2238035A1 CA 002238035 A CA002238035 A CA 002238035A CA 2238035 A CA2238035 A CA 2238035A CA 2238035 A1 CA2238035 A1 CA 2238035A1
Authority
CA
Canada
Prior art keywords
layers
metal oxide
refractive index
pigments
low
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002238035A
Other languages
English (en)
French (fr)
Inventor
Johann Dietz
Manfred Parusel
Matthias Schilling
Klaus Ambrosius
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Merck Patent GmbH
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7806427&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2238035(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2238035A1 publication Critical patent/CA2238035A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • C09C1/0024Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a stack of coating layers with alternating high and low refractive indices, wherein the first coating layer on the core surface has the high refractive index
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3417Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/14Colouring matters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/02Ingredients treated with inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0015Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/36Pearl essence, e.g. coatings containing platelet-like pigments for pearl lustre
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/10Interference pigments characterized by the core material
    • C09C2200/102Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/302Thickness of a layer with high refractive material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2200/00Compositional and structural details of pigments exhibiting interference colours
    • C09C2200/30Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
    • C09C2200/303Thickness of a layer with low refractive material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C2220/00Methods of preparing the interference pigments
    • C09C2220/10Wet methods, e.g. co-precipitation
    • C09C2220/106Wet methods, e.g. co-precipitation comprising only a drying or calcination step of the finally coated pigment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Cosmetics (AREA)
  • Paints Or Removers (AREA)
  • Glass Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Optical Filters (AREA)
CA002238035A 1996-09-21 1997-09-06 Multilayer interference pigments Abandoned CA2238035A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19638708.6 1996-09-21
DE19638708A DE19638708A1 (de) 1996-09-21 1996-09-21 Mehrschichtige Interferenzpigmente

Publications (1)

Publication Number Publication Date
CA2238035A1 true CA2238035A1 (en) 1998-03-26

Family

ID=7806427

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002238035A Abandoned CA2238035A1 (en) 1996-09-21 1997-09-06 Multilayer interference pigments

Country Status (11)

Country Link
EP (1) EP0882099B2 (enExample)
JP (1) JP4689771B2 (enExample)
CN (1) CN1081660C (enExample)
AU (1) AU4621197A (enExample)
BR (1) BR9706789A (enExample)
CA (1) CA2238035A1 (enExample)
CZ (1) CZ155598A3 (enExample)
DE (2) DE19638708A1 (enExample)
MX (1) MX204339B (enExample)
TW (1) TW455621B (enExample)
WO (1) WO1998012266A1 (enExample)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6875264B2 (en) 2003-01-17 2005-04-05 Engelhard Corporation Multi-layer effect pigment
US8088214B2 (en) 2005-02-12 2012-01-03 Basf Corporation Transparent goniochromatic multilayer effect pigment
US8268069B2 (en) 2004-08-13 2012-09-18 Merck Patent Gmbh Pearlescent pigments

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19618569A1 (de) 1996-05-09 1997-11-13 Merck Patent Gmbh Mehrschichtige Interferenzpigmente
DE19746067A1 (de) 1997-10-17 1999-04-22 Merck Patent Gmbh Interferenzpigmente
DE19917388A1 (de) * 1999-04-16 2000-10-19 Merck Patent Gmbh Pigmentmischung
DE19947175A1 (de) 1999-10-01 2001-04-05 Merck Patent Gmbh Pigmentpräparation
US6428773B1 (en) * 2000-01-13 2002-08-06 Color Access, Inc. Shadow-effect cosmetic composition
DE10006651A1 (de) * 2000-02-15 2001-08-16 Bayer Ag Zusammensetzung enthaltend Polycarbonat und Pigmente
DE10061178A1 (de) * 2000-12-07 2002-06-20 Merck Patent Gmbh Silberfarbenes Glanzpigment
DE10120179A1 (de) * 2001-04-24 2002-10-31 Merck Patent Gmbh Farbige Pigmente
JP2003003089A (ja) * 2001-06-26 2003-01-08 Kao Corp 被覆粉体
CN101104748B (zh) * 2001-07-12 2012-08-22 默克专利股份有限公司 玻璃鳞片基多层颜料
DE10204336A1 (de) * 2002-02-01 2003-08-14 Merck Patent Gmbh Verwendung von Mehrschichtpigmenten im Lebensmittel- und Pharmabereich
JP4334204B2 (ja) 2002-11-21 2009-09-30 メルク株式会社 高輝度高彩度虹彩顔料およびその製造方法
EP1469042A3 (de) * 2003-03-27 2010-07-07 MERCK PATENT GmbH Pigmentgemisch und dessen Verwendung in der Kosmetik und im Lebensmittel- und Pharmabereich
CN100484907C (zh) * 2003-06-25 2009-05-06 中国科学院大连化学物理研究所 一种生物无机复混肥料
CN1323117C (zh) * 2004-04-19 2007-06-27 付建生 随角异色颜料及其生产方法
CN1266229C (zh) * 2004-08-10 2006-07-26 汕头市龙华珠光颜料有限公司 一种随角异色的多层变色颜料及其生产方法
WO2006021528A2 (en) 2004-08-23 2006-03-02 Ciba Specialty Chemicals Holding Inc. Process for preparing flake-form pigments based on aluminium and on sioz (z=0 . 7-2.0)
DE102004057918A1 (de) 2004-11-30 2006-06-01 Merck Patent Gmbh Laserkennzeichnung von Wertdokumenten
CN100432164C (zh) * 2005-06-09 2008-11-12 上海印钞厂 一种具有偏振效果的光学变色油墨
CN100362057C (zh) * 2005-12-14 2008-01-16 林一中 多层涂覆的随角异色干涉颜料及其制备方法
ATE432964T1 (de) 2007-04-05 2009-06-15 Eckart Gmbh Effektpigmente mit einem substrat aus glasplättchen
EP1977729B1 (en) 2007-04-05 2010-03-03 Eckart GmbH Cosmetic compositions containing pearlescent pigments
WO2008135383A1 (en) * 2007-05-02 2008-11-13 Basf Se Reinforced metal oxide flakes for effect pigments
KR20180016636A (ko) 2007-07-12 2018-02-14 바스프 에스이 펄라이트 플레이크 기재 간섭 안료
AU2008316507A1 (en) 2007-10-26 2009-04-30 Basf Se Security element
CN102015914B (zh) * 2008-05-09 2013-09-25 巴斯夫欧洲公司 涂有金属氧化物/氢氧化物层和丙烯酸类共聚物的珠光颜料
US8936799B2 (en) 2009-10-28 2015-01-20 Basf Se Pigments with improved sparkling effect
CN102741359B (zh) 2010-02-04 2014-12-03 默克专利股份有限公司 效果颜料
WO2011095447A2 (en) 2010-02-04 2011-08-11 Basf Se Pigment compositions with improved sparkling effect
EP2508571A4 (en) * 2010-02-24 2016-06-15 Shantou Longhua Pearl Lustre Pigments Co Ltd NEW FLIP FLOP INTERFERENCE PIGMENTS
TW201139532A (en) 2010-04-30 2011-11-16 Styron Europe Gmbh Improved light diffusing composition
CN103002993B (zh) 2010-07-28 2015-06-03 巴斯夫欧洲公司 珍珠岩基效应颜料在具有古旧或绿锈外观的涂层中的用途
EP2970678A4 (en) * 2013-03-15 2016-09-21 Basf Se UV-REFLECTIVE PIGMENTS AND METHOD FOR THE PREPARATION AND USE THEREOF
DE102013016932A1 (de) 2013-10-11 2015-04-30 Merck Patent Gmbh Pigmente
PL3034563T5 (pl) * 2014-12-19 2025-02-10 Eckart Gmbh Pigmenty efektowe o kolorze złotym o wysokim nasyceniu barwy i wysokim połysku, sposób ich wytwarzania i ich zastosowanie
PL3034562T5 (pl) * 2014-12-19 2022-04-19 Eckart Gmbh Pigmenty do uzyskiwania efektów absorbujących o wysokim nasyceniu barwy i wysokiej jasności, sposób ich wytwarzania i ich zastosowanie
EP3072934A1 (de) * 2015-03-27 2016-09-28 FL Services GmbH Schichtbau, Verfahren zu dessen Herstellung und Verwendung desselben
CN106316444A (zh) * 2016-08-11 2017-01-11 华北水利水电大学 一种多孔莫来石陶瓷的制备方法
CN112004891A (zh) 2018-04-04 2020-11-27 阿尔塔纳股份公司 基于着色水辉石和涂布的着色水辉石的效果颜料及其制造
KR20220035157A (ko) 2019-07-08 2022-03-21 브이디아이 엘엘씨 단방향 및 양방향 파장 선택적 반사색 생성을 위한 유전체 박막 코팅들
CN113861668B (zh) * 2021-11-17 2023-02-28 尼伦化学(上海)有限公司 一种高折光指数、高耐磨tpu粒子及制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2244298C3 (de) 1972-09-09 1975-06-19 Merck Patent Gmbh, 6100 Darmstadt Perlglanzpigmente und Verfahren zu ihrer Herstellung
GB1556272A (en) * 1976-05-26 1979-11-21 Mearl Corp Iron oxide coated mica nacreous pigments
US4879140A (en) * 1988-11-21 1989-11-07 Deposition Sciences, Inc. Method for making pigment flakes
DE3842330A1 (de) * 1988-12-16 1990-06-21 Merck Patent Gmbh Leitfaehige plaettchenfoermige pigmente
JP3073836B2 (ja) 1992-07-02 2000-08-07 メルク・ジヤパン株式会社 耐変色性を有する真珠光沢顔料およびその製造方法
JP3389360B2 (ja) * 1994-01-18 2003-03-24 マツダ株式会社 光干渉材及びそれを含有する塗料
DE4437753A1 (de) * 1994-10-21 1996-04-25 Basf Ag Mehrfach beschichtete metallische Glanzpigmente
DE19525503A1 (de) 1995-07-13 1997-01-16 Basf Ag Goniochromatische Glanzpigmente auf Basis transparenter, nichtmetallischer, plättchenförmiger Substrate
DE19618569A1 (de) 1996-05-09 1997-11-13 Merck Patent Gmbh Mehrschichtige Interferenzpigmente

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6875264B2 (en) 2003-01-17 2005-04-05 Engelhard Corporation Multi-layer effect pigment
US8268069B2 (en) 2004-08-13 2012-09-18 Merck Patent Gmbh Pearlescent pigments
US8088214B2 (en) 2005-02-12 2012-01-03 Basf Corporation Transparent goniochromatic multilayer effect pigment
US8282729B2 (en) 2005-02-12 2012-10-09 Basf Corporation Transparent goniochromatic multilayer effect pigment

Also Published As

Publication number Publication date
DE59711278D1 (de) 2004-03-11
BR9706789A (pt) 1999-04-13
EP0882099A1 (de) 1998-12-09
EP0882099B1 (de) 2004-02-04
MX204339B (en) 2001-09-21
AU4621197A (en) 1998-04-14
MX9803990A (en) 1999-07-31
CZ155598A3 (cs) 1998-09-16
DE19638708A1 (de) 1998-04-16
CN1081660C (zh) 2002-03-27
TW455621B (en) 2001-09-21
JP2000501774A (ja) 2000-02-15
EP0882099B2 (de) 2009-04-08
WO1998012266A1 (de) 1998-03-26
CN1205022A (zh) 1999-01-13
JP4689771B2 (ja) 2011-05-25

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Legal Events

Date Code Title Description
FZDE Discontinued