CA1312094C - Transition metal complex catalyzed reactions - Google Patents

Transition metal complex catalyzed reactions

Info

Publication number
CA1312094C
CA1312094C CA000537549A CA537549A CA1312094C CA 1312094 C CA1312094 C CA 1312094C CA 000537549 A CA000537549 A CA 000537549A CA 537549 A CA537549 A CA 537549A CA 1312094 C CA1312094 C CA 1312094C
Authority
CA
Canada
Prior art keywords
rhodium
hydroformylation
organic polymer
aldehyde
phosphite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000537549A
Other languages
English (en)
French (fr)
Inventor
David Robert Bryant
John Michael Maher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of CA1312094C publication Critical patent/CA1312094C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA000537549A 1986-05-20 1987-05-20 Transition metal complex catalyzed reactions Expired - Lifetime CA1312094C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US865,061 1986-05-20
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions
US046,821 1987-05-11

Publications (1)

Publication Number Publication Date
CA1312094C true CA1312094C (en) 1992-12-29

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000537549A Expired - Lifetime CA1312094C (en) 1986-05-20 1987-05-20 Transition metal complex catalyzed reactions

Country Status (12)

Country Link
US (1) US4774361A (OSRAM)
EP (1) EP0276231B1 (OSRAM)
JP (1) JPS63503385A (OSRAM)
CN (1) CN1010011B (OSRAM)
AU (1) AU613312B2 (OSRAM)
CA (1) CA1312094C (OSRAM)
DE (1) DE3773890D1 (OSRAM)
ES (1) ES2004935A6 (OSRAM)
IN (1) IN169727B (OSRAM)
MX (1) MX166107B (OSRAM)
NO (1) NO166583C (OSRAM)
WO (1) WO1987007261A2 (OSRAM)

Families Citing this family (85)

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DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
KR100988732B1 (ko) * 2002-08-31 2010-10-20 에보니크 옥세노 게엠베하 사이클릭 탄산 에스테르의 존재하에 개질되지 않은 금속 착물에 의해 촉매된 올레핀계 불포화 화합물의 하이드로포밀화에 의해 알데하이드를 제조하는 방법
PL206145B1 (pl) * 2002-08-31 2010-07-30 Oxeno Olefinchemie Gmbhoxeno Olefinchemie Gmbh Sposób hydroformylowania związków nienasyconych olefinowo, w szczególności olefin, w obecności cyklicznych estrów kwasów karboksylowych
ES2345770T3 (es) * 2003-01-16 2010-10-01 Teijin Fibers Limited Hilo compuesto por filamentos combinados de poliester que tienen diferentes coeficientes de contraccion.
CA2530739C (en) 2003-07-03 2012-09-25 Union Carbide Chemicals & Plastics Technology Corporation Minimization of ligand degradation products, or reversion of same to useful phosphine ligands
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
ZA200701001B (en) 2004-08-02 2008-05-28 Union Carbide Chem Plastic Stabilization of a hydroformylation process
BRPI0808297B1 (pt) * 2007-03-20 2017-02-07 Dow Technology Investments Llc processo de hidroformilação
JP5298119B2 (ja) * 2007-04-09 2013-09-25 エルジー・ケム・リミテッド ホスファイト配位子を含む触媒組成物およびこれを用いたヒドロホルミル化方法
MY155290A (en) 2008-07-03 2015-09-30 Basf Se Process of controlling heavies in a recycle catalyst stream
AU2009313838B2 (en) 2008-11-14 2015-02-05 University Of Kansas Polymer-supported transition metal catalyst complexes and methods of use
US8513469B2 (en) 2009-03-31 2013-08-20 Dow Technology Investments Llc Hydroformylation process with doubly open-ended bisphosphite ligand
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
CN102574878A (zh) 2009-10-16 2012-07-11 陶氏技术投资有限责任公司 气相加氢甲酰化方法
EP2722325B2 (en) 2009-12-22 2019-01-16 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
CN102741209B (zh) 2009-12-22 2014-12-03 陶氏技术投资有限责任公司 通过控制烯烃分压来控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
EP2516373B2 (en) 2009-12-22 2020-08-12 Dow Technology Investments LLC Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
US8741173B2 (en) 2010-10-05 2014-06-03 Dow Technology Investments Llc Hydroformylation process
WO2012064586A1 (en) 2010-11-12 2012-05-18 Dow Technology Investments Llc Mitigation of fouling in hydroformylation processes by water addition
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
PL2822921T3 (pl) 2012-03-07 2018-11-30 Basf Se SPOSÓB INTEGRACJI CIEPŁA PRZY UWODORNIANIU I DESTYLACJI C<sub>3</sub>-C<sub>20</sub>- ALDEHYDÓW
SG11201405863QA (en) 2012-04-12 2014-11-27 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
US9174907B2 (en) 2012-06-04 2015-11-03 Dow Technology Investments Llc Hydroformylation process
MX360063B (es) * 2012-08-29 2018-10-22 Dow Technology Investments Llc Proceso de preparacion de catalizador.
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EP2928855A1 (en) 2012-12-06 2015-10-14 Dow Technology Investments LLC Hydroformylation process
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
BR112016013001B1 (pt) 2013-12-19 2020-12-29 Dow Technology Investments Llc processo de hidroformilação
CN106103400B (zh) 2014-03-31 2020-03-03 陶氏技术投资有限责任公司 氢甲酰化方法
JP6694396B2 (ja) 2014-05-14 2020-05-13 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 安定化された有機リン化合物
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
CA3004907C (en) 2015-11-10 2024-01-02 Dow Technology Investments Llc Process for producing aldehydes
US10766839B2 (en) 2016-02-11 2020-09-08 Dow Technology Investments Llc Process for converting olefins to alcohols, ethers, or combinations thereof
CA3018072C (en) 2016-03-18 2024-10-29 Dow Technology Investments Llc HYDROFORMYLATION PROCESS
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
JP7356419B2 (ja) 2017-10-25 2023-10-04 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス中に形成されるアルデヒド化合物を含む溶液中の重質形成を低減する方法
CN111278560B (zh) 2017-11-13 2023-07-21 陶氏技术投资有限责任公司 从氢甲酰化方法回收铑的方法
TWI793216B (zh) 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
CA3100778A1 (en) 2018-05-30 2019-12-05 Dow Technology Investments Llc Methods for slowing deactivation of a catalyst and/or slowing tetraphosphine ligand usage in hydroformylation processes
JP2021525166A (ja) 2018-05-30 2021-09-24 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー モノホスフィン、テトラホスフィン配位子の組み合わせを含む触媒組成物、およびそれを使用するヒドロホルミル化プロセス
KR102756407B1 (ko) 2018-05-30 2025-01-20 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 공정의 제어 방법
EP3887348B1 (en) 2018-11-29 2022-11-02 Dow Technology Investments LLC Hydroformylation process
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
CN114929660A (zh) 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
US20230406801A1 (en) 2020-12-14 2023-12-21 Dow Technology Investments Llc Processes to improve catalytic metal accountability in hydroformylation processes
MX2024005136A (es) 2021-11-11 2024-05-16 Dow Technology Investments Llc Procesos para recuperar rodio a partir de procesos de hidroformilacion.
JP2024545133A (ja) 2021-12-16 2024-12-05 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 化合物、そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス
US20240399349A1 (en) 2021-12-16 2024-12-05 Dow Technology Investments Llc Transition metal complex hydroformylation catalyst precuror compositions comprising such compounds, and hydroformylation processes
EP4634148A1 (en) 2022-12-13 2025-10-22 Dow Technology Investments LLC Process to minimize polyphosphine usage by making use of degradation products
CN121039090A (zh) 2023-05-04 2025-11-28 陶氏技术投资有限责任公司 加氢甲酰化方法
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
CN121194957A (zh) 2023-06-26 2025-12-23 陶氏技术投资有限责任公司 控制加氢甲酰化工艺的方法
WO2025029369A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity
WO2025029349A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Hydroformylation process
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol

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Also Published As

Publication number Publication date
EP0276231A1 (en) 1988-08-03
ES2004935A6 (es) 1989-02-16
JPS63503385A (ja) 1988-12-08
NO880207L (no) 1988-01-19
MX166107B (es) 1992-12-21
NO166583C (no) 1991-08-14
WO1987007261A2 (en) 1987-12-03
CN1010011B (zh) 1990-10-17
EP0276231B1 (en) 1991-10-16
JPH0548215B2 (OSRAM) 1993-07-20
NO166583B (no) 1991-05-06
AU613312B2 (en) 1991-08-01
NO880207D0 (no) 1988-01-19
IN169727B (OSRAM) 1991-12-14
CN87104311A (zh) 1988-06-08
DE3773890D1 (de) 1991-11-21
WO1987007261A3 (en) 1988-04-07
US4774361A (en) 1988-09-27
AU7489887A (en) 1987-12-22

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