NO166583C - Overgangsmetallkompleks-katalysert hydroformulering. - Google Patents

Overgangsmetallkompleks-katalysert hydroformulering.

Info

Publication number
NO166583C
NO166583C NO880207A NO880207A NO166583C NO 166583 C NO166583 C NO 166583C NO 880207 A NO880207 A NO 880207A NO 880207 A NO880207 A NO 880207A NO 166583 C NO166583 C NO 166583C
Authority
NO
Norway
Prior art keywords
hydroformation
catalyzed
transition metal
metal complex
complex
Prior art date
Application number
NO880207A
Other languages
English (en)
Norwegian (no)
Other versions
NO166583B (no
NO880207D0 (no
NO880207L (no
Inventor
John Michael Maher
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/865,061 external-priority patent/US4717775A/en
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of NO880207D0 publication Critical patent/NO880207D0/no
Publication of NO880207L publication Critical patent/NO880207L/no
Publication of NO166583B publication Critical patent/NO166583B/no
Publication of NO166583C publication Critical patent/NO166583C/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
NO880207A 1986-05-20 1988-01-19 Overgangsmetallkompleks-katalysert hydroformulering. NO166583C (no)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/865,061 US4717775A (en) 1984-12-28 1986-05-20 Transition metal complex catalyzed reactions
US07/046,821 US4774361A (en) 1986-05-20 1987-05-11 Transition metal complex catalyzed reactions
PCT/US1987/001124 WO1987007261A2 (en) 1986-05-20 1987-05-19 Transition metal complex catalyzed hydroformulation

Publications (4)

Publication Number Publication Date
NO880207D0 NO880207D0 (no) 1988-01-19
NO880207L NO880207L (no) 1988-01-19
NO166583B NO166583B (no) 1991-05-06
NO166583C true NO166583C (no) 1991-08-14

Family

ID=26724327

Family Applications (1)

Application Number Title Priority Date Filing Date
NO880207A NO166583C (no) 1986-05-20 1988-01-19 Overgangsmetallkompleks-katalysert hydroformulering.

Country Status (12)

Country Link
US (1) US4774361A (OSRAM)
EP (1) EP0276231B1 (OSRAM)
JP (1) JPS63503385A (OSRAM)
CN (1) CN1010011B (OSRAM)
AU (1) AU613312B2 (OSRAM)
CA (1) CA1312094C (OSRAM)
DE (1) DE3773890D1 (OSRAM)
ES (1) ES2004935A6 (OSRAM)
IN (1) IN169727B (OSRAM)
MX (1) MX166107B (OSRAM)
NO (1) NO166583C (OSRAM)
WO (1) WO1987007261A2 (OSRAM)

Families Citing this family (86)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4835299A (en) * 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
IT1237530B (it) * 1989-12-12 1993-06-08 Eniricerche Spa Procedimento per la sintesi diretta di alcoli da olefine,ossidi di carbonio e idrogeno,promossa da un catalizzatore di rodio supportato
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
US5087763A (en) * 1990-11-09 1992-02-11 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
JP2946790B2 (ja) * 1991-03-14 1999-09-06 三菱化学株式会社 アルデヒド類の製造法
US5360938A (en) * 1991-08-21 1994-11-01 Union Carbide Chemicals & Plastics Technology Corporation Asymmetric syntheses
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
US5169981A (en) * 1991-12-06 1992-12-08 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5243099A (en) * 1991-12-06 1993-09-07 Union Carbide Chemicals & Plastics Technology Corporation Synthesis of alpha-substituted alkadienes
US5756855A (en) 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5672766A (en) * 1994-12-12 1997-09-30 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
US5739352A (en) * 1995-10-19 1998-04-14 United Carbide Chemicals & Plastics Technology Corporation Process for preparing carboxylic acids
DE19605435A1 (de) * 1996-02-14 1997-08-21 Basf Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung mit einem Rhodiumkatalysator und Wiedergewinnung des Rhodiumkatalysators durch Extraktion
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
CN1163463C (zh) 1998-12-10 2004-08-25 三菱化学株式会社 醛的制备方法
JP3921853B2 (ja) * 1998-12-10 2007-05-30 三菱化学株式会社 アルデヒド類及びアルコール類の製造方法
GB9918229D0 (en) † 1999-08-04 1999-10-06 Ici Plc Improvements relating to metal-compound catalysed processes
DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
EP1168111A3 (en) 2000-06-27 2009-06-03 Dai Nippon Printing Co., Ltd. Multilayer volume hologram, and label for multilayer volume hologram fabrication
EP1249441A1 (en) 2001-04-13 2002-10-16 Dsm N.V. Continuous hydroformylation process
DE10220801A1 (de) * 2002-05-10 2003-11-20 Oxeno Olefinchemie Gmbh Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste
EP1532094A1 (de) * 2002-08-31 2005-05-25 Oxeno Olefinchemie GmbH Verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen, insbesondere olefinen in gegenwart cyclischer kohlensäureester
BR0313814B1 (pt) * 2002-08-31 2012-11-27 processo para preparação de aldeìdos por hidroformilação de compostos olefinicamente insaturados, catalisado por complexos metálicos não modificados, na presença de ésteres de ácido carbÈnico cìclicos.
ES2345770T3 (es) * 2003-01-16 2010-10-01 Teijin Fibers Limited Hilo compuesto por filamentos combinados de poliester que tienen diferentes coeficientes de contraccion.
CN101654462B (zh) 2003-07-03 2013-05-29 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
DE10349343A1 (de) * 2003-10-23 2005-06-02 Basf Ag Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden
PL209549B1 (pl) 2004-08-02 2011-09-30 Dow Technology Investments Llc Sposób hydroformylowania
RU2458906C2 (ru) * 2007-03-20 2012-08-20 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования с усовершенствованным контролем над изомерами продуктов
US7943801B2 (en) * 2007-04-09 2011-05-17 Lg Chem, Ltd. Catalyst composition including phosphite ligands and hydroformylation method using the same
US8404903B2 (en) 2008-07-03 2013-03-26 Dow Technology Investments, Llc Process of controlling heavies in a recycle catalyst stream
US8921486B2 (en) 2008-11-14 2014-12-30 University Of Kansas Polymer-supported transition metal catalyst complexes and methods of use
JP5603407B2 (ja) 2009-03-31 2014-10-08 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 二重オープンエンド型ビスホスファイトリガンドによるヒドロホルミル化方法
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
US8586800B2 (en) 2009-10-16 2013-11-19 Dow Technology Investments Llc Gas phase hydroformylation process
US8664451B2 (en) 2009-12-22 2014-03-04 Dow Technology Investments Llc Controlling the normal:ISO aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
WO2011087690A1 (en) 2009-12-22 2011-07-21 Dow Technology Investments Llc Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process
PL2516372T5 (pl) 2009-12-22 2020-08-10 Dow Technology Investments Llc Regulowanie stosunku aldehyd normalny : izoaldehyd w procesie hydroformowania z mieszanymi ligandami przez regulowanie ciśnienia cząsteczkowego gazu syntezowego
JP2014502254A (ja) 2010-10-05 2014-01-30 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化の方法
ES2719425T3 (es) 2010-11-12 2019-07-10 Dow Technology Investments Llc Mitigación de incrustación en procedimientos de hidroformilación mediante adición de agua
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
WO2013131936A1 (de) 2012-03-07 2013-09-12 Basf Se Verfahren zur wärmeintegration bei der hydrierung und destillation von c3-c20-aldehyden
SG10201608258PA (en) 2012-04-12 2016-11-29 Basf Se Method for replenishing the catalyst in continuous hydroformylation
US8889917B2 (en) 2012-04-12 2014-11-18 Basf Se Method of supplementing the catalyst in continuous hydroformylation
CN104379258B (zh) 2012-06-04 2017-05-03 陶氏技术投资有限责任公司 加氢甲酰化方法
KR102131204B1 (ko) * 2012-08-29 2020-07-07 다우 테크놀로지 인베스트먼츠 엘엘씨. 촉매 제조 방법
CN104955568B (zh) 2012-09-25 2017-05-03 陶氏技术投资有限责任公司 用于稳定亚磷酸酯配体抵抗降解的方法
EP2740535A1 (en) 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
CN104837800B (zh) 2012-12-06 2017-08-29 陶氏技术投资有限责任公司 氢甲酰化方法
CN104045532B (zh) 2013-03-15 2018-05-25 陶氏技术投资有限责任公司 加氢甲酰化方法
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
US9688598B2 (en) 2013-12-19 2017-06-27 Dow Technology Investments Llc Hydroformylation process
JP6560248B2 (ja) 2014-03-31 2019-08-14 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
JP6694396B2 (ja) 2014-05-14 2020-05-13 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー 安定化された有機リン化合物
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
MX389162B (es) 2015-11-10 2025-03-20 Dow Technology Investments Llc Proceso para producir aldehidos.
WO2017139543A1 (en) 2016-02-11 2017-08-17 Dow Technology Investments Llc Processes for converting olefins to alcohols, ethers, or combinations thereof
JP6889179B2 (ja) 2016-03-18 2021-06-18 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
TWI758353B (zh) 2016-11-08 2022-03-21 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840362A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 使去活化的氫甲醯化催化劑溶液再生的方法
TW201840363A (zh) 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
US10981851B2 (en) 2017-10-25 2021-04-20 Dow Technology Investments Llc Hydroformylation process
US11033890B2 (en) 2017-11-13 2021-06-15 Dow Technology Investments Llc Processes for recovery of rhodium from a hydroformylation process
TWI793216B (zh) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法
KR20250057144A (ko) 2018-05-30 2025-04-28 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 공정에서 촉매의 탈활성화를 느리게 하고/하거나 테트라포스핀 리간드 사용을 느리게 하는 방법
MY207749A (en) 2018-05-30 2025-03-16 Dow Technology Investments Llc Catalyst composition comprising the combination of a monophopsphine, a tetraphosphine ligand and a hydroformylation process using it
KR102756407B1 (ko) 2018-05-30 2025-01-20 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포밀화 공정의 제어 방법
CA3120660A1 (en) 2018-11-29 2020-06-04 Dow Technology Investments Llc Hydroformylation process
EP3990176B1 (en) * 2019-06-27 2024-11-06 Dow Technology Investments LLC Process to prepare solution from hydroformylation process for precious metal recovery
TWI874467B (zh) 2019-11-05 2025-03-01 美商陶氏科技投資有限公司 用於自ｃ６或更高碳數烯烴氫甲醯化製程之催化劑淨化流回收銠之方法
CN114929660A (zh) 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
CN114478214B (zh) * 2020-10-23 2024-05-17 中国石油化工股份有限公司 一种氢甲酰化方法和一种氢甲酰化产物的分离方法
US20230406801A1 (en) 2020-12-14 2023-12-21 Dow Technology Investments Llc Processes to improve catalytic metal accountability in hydroformylation processes
MX2024005136A (es) 2021-11-11 2024-05-16 Dow Technology Investments Llc Procesos para recuperar rodio a partir de procesos de hidroformilacion.
JP2024545069A (ja) 2021-12-16 2024-12-05 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー そのような化合物を含む遷移金属錯体ヒドロホルミル化触媒前駆体組成物、及びヒドロホルミル化プロセス
CN118317834A (zh) 2021-12-16 2024-07-09 陶氏技术投资有限责任公司 化合物、包含此类化合物的过渡金属络合物加氢甲酰化催化剂前体组合物和加氢甲酰化方法
WO2024129290A1 (en) 2022-12-13 2024-06-20 Dow Technology Investments Llc Process to minimize polyphosphine usage by making use of degradation products
KR20260004447A (ko) 2023-05-04 2026-01-08 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포르밀화 공정
GB202307175D0 (en) 2023-05-15 2023-06-28 Johnson Matthey Davy Technologies Ltd Process for hydrogenating a substrate
CN121194957A (zh) 2023-06-26 2025-12-23 陶氏技术投资有限责任公司 控制加氢甲酰化工艺的方法
WO2025029369A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Process for improving rhodium/phosphite- based homogenous hydroformylation catalyst activity
WO2025029349A1 (en) 2023-08-03 2025-02-06 Dow Technology Investments Llc Hydroformylation process
GB202404300D0 (en) 2024-03-26 2024-05-08 Johnson Matthey Davy Technologies Ltd Process for the production of 2-alkylalkanol
CN121178080A (zh) * 2025-11-21 2025-12-23 中海油天津化工研究设计院有限公司 一种高碳烯烃羰基合成制备高碳醛的生产系统及方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE156528C (OSRAM) *
US4482748A (en) * 1967-05-29 1984-11-13 Celanese Corporation Hydrocarbonylation
DE2145532C3 (de) * 1971-09-11 1975-02-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Aufarbeitung von Hydroformylierungsgemischen
DE2326489A1 (de) * 1973-05-24 1974-12-12 Ernst Prof Dr Bayer Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer
JPS5638576B2 (OSRAM) * 1974-07-25 1981-09-08
US4148830A (en) * 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
JPS6022688B2 (ja) * 1976-12-29 1985-06-03 和光純薬工業株式会社 アルデヒド化合物の蒸留方法
DE2966350D1 (en) * 1978-08-17 1983-12-01 Heyl Chem Pharm Polymeric hydrogenation catalysts, process for preparing these catalysts and their use for catalytic hydrogenations
US4235744A (en) * 1978-10-30 1980-11-25 Standard Oil Company (Ohio) Carbonylation of olefinically unsaturated compounds
US4504684A (en) * 1982-01-06 1985-03-12 The Standard Oil Company Metal coordination polymers as hydroformylation and hydrogenation catalysts
DE3372361D1 (en) * 1982-06-11 1987-08-13 Davy Mckee London Hydroformylation process
US4528403A (en) * 1982-10-21 1985-07-09 Mitsubishi Chemical Industries Ltd. Hydroformylation process for preparation of aldehydes and alcohols
US4528404A (en) * 1983-03-16 1985-07-09 Exxon Research And Engineering Co. High temperature hydroformylation in the presence of triarylphosphine rhodium carbonyl hydride complex catalyst systems
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4599456A (en) * 1984-12-20 1986-07-08 Phillips Petroleum Company Novel aldehyde-phosphine compositions and uses therefor
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4613701A (en) * 1985-09-19 1986-09-23 Celanese Corporation Recovery of rhodium from hydroformylation reaction product

Also Published As

Publication number Publication date
US4774361A (en) 1988-09-27
JPH0548215B2 (OSRAM) 1993-07-20
JPS63503385A (ja) 1988-12-08
MX166107B (es) 1992-12-21
CA1312094C (en) 1992-12-29
WO1987007261A2 (en) 1987-12-03
AU7489887A (en) 1987-12-22
CN1010011B (zh) 1990-10-17
NO166583B (no) 1991-05-06
WO1987007261A3 (en) 1988-04-07
EP0276231A1 (en) 1988-08-03
AU613312B2 (en) 1991-08-01
NO880207D0 (no) 1988-01-19
CN87104311A (zh) 1988-06-08
IN169727B (OSRAM) 1991-12-14
DE3773890D1 (de) 1991-11-21
NO880207L (no) 1988-01-19
ES2004935A6 (es) 1989-02-16
EP0276231B1 (en) 1991-10-16

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