CA1235834A - Thermoplastic resin composition comprising a rubber modified copolymer - Google Patents
Thermoplastic resin composition comprising a rubber modified copolymerInfo
- Publication number
- CA1235834A CA1235834A CA000440962A CA440962A CA1235834A CA 1235834 A CA1235834 A CA 1235834A CA 000440962 A CA000440962 A CA 000440962A CA 440962 A CA440962 A CA 440962A CA 1235834 A CA1235834 A CA 1235834A
- Authority
- CA
- Canada
- Prior art keywords
- copolymer
- rubber
- modified
- unsaturated
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 57
- 239000011342 resin composition Substances 0.000 title claims abstract description 18
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 16
- 229920001971 elastomer Polymers 0.000 title claims description 11
- 239000005060 rubber Substances 0.000 title claims description 8
- 229920000098 polyolefin Polymers 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 14
- 150000001875 compounds Chemical class 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 16
- 150000001336 alkenes Chemical class 0.000 claims description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 150000008064 anhydrides Chemical class 0.000 claims description 8
- 150000008360 acrylonitriles Chemical class 0.000 claims description 6
- 229920000578 graft copolymer Polymers 0.000 claims description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- 150000007942 carboxylates Chemical class 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 230000000704 physical effect Effects 0.000 abstract description 7
- -1 aromatic vinyl compound Chemical class 0.000 description 20
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000004593 Epoxy Substances 0.000 description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 6
- 239000011369 resultant mixture Substances 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
- 239000000306 component Substances 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- 229920002554 vinyl polymer Polymers 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052740 iodine Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- CRQSAKXMWFFXJG-UHFFFAOYSA-N 2-[(4-ethenylphenyl)methyl]oxirane Chemical class C1=CC(C=C)=CC=C1CC1OC1 CRQSAKXMWFFXJG-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 125000005521 carbonamide group Chemical group 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- HQGYGGZHZWXFSI-UHFFFAOYSA-N 1,4-cycloheptadiene Chemical compound C1CC=CCC=C1 HQGYGGZHZWXFSI-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- MUUOUUYKIVSIAR-UHFFFAOYSA-N 2-but-3-enyloxirane Chemical compound C=CCCC1CO1 MUUOUUYKIVSIAR-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- JRKURGYOYLHRHT-UHFFFAOYSA-N 2-ethenyl-2,3-dimethyloxirane Chemical compound CC1OC1(C)C=C JRKURGYOYLHRHT-UHFFFAOYSA-N 0.000 description 1
- FVCDMHWSPLRYAB-UHFFFAOYSA-N 2-ethenyl-2-methyloxirane Chemical compound C=CC1(C)CO1 FVCDMHWSPLRYAB-UHFFFAOYSA-N 0.000 description 1
- SZERAFCDZCHRQS-UHFFFAOYSA-N 2-ethenyl-3-methyloxirane Chemical compound CC1OC1C=C SZERAFCDZCHRQS-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- NMSZFQAFWHFSPE-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxycarbonyl)but-3-enoic acid Chemical compound OC(=O)CC(=C)C(=O)OCC1CO1 NMSZFQAFWHFSPE-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- XAYDWGMOPRHLEP-UHFFFAOYSA-N 6-ethenyl-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCCC2OC21C=C XAYDWGMOPRHLEP-UHFFFAOYSA-N 0.000 description 1
- 101150034533 ATIC gene Proteins 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- 102000018361 Contactin Human genes 0.000 description 1
- 108060003955 Contactin Proteins 0.000 description 1
- GXBYFVGCMPJVJX-UHFFFAOYSA-N Epoxybutene Chemical compound C=CC1CO1 GXBYFVGCMPJVJX-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- VGUXWSJVGWCTEC-UHFFFAOYSA-N bicyclo[2.2.1]hept-3-ene Chemical compound C1C(C2)CCC2=C1 VGUXWSJVGWCTEC-UHFFFAOYSA-N 0.000 description 1
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- GOAJGXULHASQGJ-UHFFFAOYSA-N ethene;prop-2-enenitrile Chemical group C=C.C=CC#N GOAJGXULHASQGJ-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23H—WORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
- B23H7/00—Processes or apparatus applicable to both electrical discharge machining and electrochemical machining
- B23H7/02—Wire-cutting
- B23H7/08—Wire electrodes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP199583/1982 | 1982-11-12 | ||
| JP57199583A JPS5989346A (ja) | 1982-11-12 | 1982-11-12 | 熱可塑性樹脂組成物 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1235834A true CA1235834A (en) | 1988-04-26 |
Family
ID=16410256
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000440962A Expired CA1235834A (en) | 1982-11-12 | 1983-11-10 | Thermoplastic resin composition comprising a rubber modified copolymer |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US4554316A (ja) |
| JP (1) | JPS5989346A (ja) |
| KR (1) | KR870001948B1 (ja) |
| AU (1) | AU562488B2 (ja) |
| CA (1) | CA1235834A (ja) |
| DE (1) | DE3340591C2 (ja) |
| FR (1) | FR2536080B1 (ja) |
| GB (1) | GB2131440B (ja) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6018536A (ja) * | 1983-07-08 | 1985-01-30 | Sumitomo Naugatuck Co Ltd | 耐候性熱可塑性樹脂組成物 |
| JPS6160746A (ja) * | 1984-08-31 | 1986-03-28 | Sumitomo Chem Co Ltd | 熱可塑性樹脂組成物 |
| DE3564125D1 (en) * | 1984-10-16 | 1988-09-08 | Sumitomo Naugatuck | Thermoplastic resin composition |
| JPS61218651A (ja) * | 1985-03-25 | 1986-09-29 | Kanegafuchi Chem Ind Co Ltd | 艶消しされた熱可塑性樹脂組成物 |
| FR2581388B1 (fr) * | 1985-05-02 | 1988-01-22 | Charbonnages Ste Chimique | Composition thermoplastique comprenant une matrice de resine styrenique et un terpolymere |
| JPS6253367A (ja) * | 1985-09-02 | 1987-03-09 | Kanegafuchi Chem Ind Co Ltd | 加工性に優れた熱可塑性樹脂組成物 |
| JPS62143957A (ja) * | 1985-12-18 | 1987-06-27 | Sumitomo Chem Co Ltd | スチレン系樹脂組成物 |
| US4687810A (en) * | 1986-01-02 | 1987-08-18 | Monsanto Company | Making rubber blends of diene rubber & EPR or EPDM |
| JPH0611837B2 (ja) * | 1986-09-03 | 1994-02-16 | 住友ダウ株式会社 | 熱可塑性樹脂組成物 |
| JPH0611838B2 (ja) * | 1986-09-10 | 1994-02-16 | 住友ダウ株式会社 | 耐熱性樹脂組成物 |
| JPH0730228B2 (ja) * | 1987-08-18 | 1995-04-05 | 住友ダウ株式会社 | 艶消し熱可塑性樹脂組成物 |
| NL8702049A (nl) * | 1987-09-01 | 1989-04-03 | Stamicarbon | Thermoplastisch polymeermengsel met een lage oppervlakte glans en werkwijze voor de bereiding daartoe. |
| JPH0676534B2 (ja) * | 1987-10-14 | 1994-09-28 | 住友ダウ株式会社 | 熱可塑性樹脂組成物 |
| US4870131A (en) * | 1988-02-22 | 1989-09-26 | Monsanto Company | Low gloss molding composition |
| CA1335125C (en) * | 1988-08-03 | 1995-04-04 | Takuya Ogawa | Thermoplastic resin composition having delustered and pleasing appearance |
| JPH0291157A (ja) * | 1988-09-28 | 1990-03-30 | Nippon Petrochem Co Ltd | 熱可塑性樹脂組成物およびその製造方法 |
| JPH0794590B2 (ja) * | 1988-11-04 | 1995-10-11 | 住友ダウ株式会社 | 溶融滴下を防止してなる難燃性ゴム強化スチレン系樹脂組成物 |
| JP2521807B2 (ja) * | 1989-01-31 | 1996-08-07 | 三井・デュポンポリケミカル株式会社 | アイオノマ―の組成物 |
| JPH02125341U (ja) * | 1989-03-23 | 1990-10-16 | ||
| EP0406906A3 (en) * | 1989-07-07 | 1991-11-27 | Toagosei Chemical Industry Co., Ltd. | Ethylene graft copolymer and molding resin composition containing the same |
| US5216074A (en) * | 1989-07-17 | 1993-06-01 | Japan Synthetic Rubber Co., Ltd. | Thermoplastic elastomer composition |
| US5026777A (en) * | 1989-11-17 | 1991-06-25 | General Electric Company | Low gloss thermoplastic molding compositions |
| US5264487A (en) * | 1991-06-17 | 1993-11-23 | General Electric Company | Compositions derived from recycled polymers |
| TW222660B (ja) * | 1992-02-25 | 1994-04-21 | Gen Electric | |
| US5336701A (en) * | 1992-09-28 | 1994-08-09 | General Electric Company | Process improvement for improved color reduced gloss thermoplastic compositions |
| KR0159585B1 (ko) * | 1993-06-28 | 1999-01-15 | 사공수영 | 내충격성 저광택 abs수지 및 그의 제조방법 |
| US5536780A (en) * | 1993-08-20 | 1996-07-16 | General Electric Company | Process for the manufacture of low gloss resins |
| DE4331805A1 (de) * | 1993-09-18 | 1995-03-23 | Basf Ag | Matte, transparente Thermoplastharze |
| EP0700971A3 (en) | 1994-09-12 | 1996-07-17 | Gen Electric | Polycarbonate mixture for casting objects with low gloss |
| US7557158B2 (en) * | 2004-09-15 | 2009-07-07 | Rohm And Haas Company | Gloss reducing polymer composition |
| US20070232757A1 (en) * | 2006-04-03 | 2007-10-04 | Kevin Cai | Mar resistant, glossy thermoplastic polyolefin blends and articles |
| KR20120075724A (ko) * | 2010-12-29 | 2012-07-09 | 제일모직주식회사 | 내충격성이 우수한 저광성의 난연 ａｂｓ 수지 조성물 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3676526A (en) * | 1967-06-02 | 1972-07-11 | Eugene G Sommerfeld | Polymeric dispersion of a diene-acrylonitrite graft copolymer with a different graft copolymer |
| GB1257512A (ja) * | 1968-06-10 | 1971-12-22 | ||
| DE2046898B2 (de) * | 1969-09-26 | 1977-09-22 | The Japanese Geon Co, Ltd, Tokio | Verfahren zur herstellung von propfmischpolymerisaten und deren verwendung in polyvinylchlorid enthaltenden formkoerpern |
| US3868433A (en) * | 1972-04-03 | 1975-02-25 | Exxon Research Engineering Co | Thermoplastic adhesive compositions |
| US3830888A (en) * | 1972-04-03 | 1974-08-20 | Exxon Research Engineering Co | Compositions comprising a blend of a vinyl resin and grafted olefin polymer |
| JPS5633435B2 (ja) * | 1973-02-21 | 1981-08-04 | ||
| US3883614A (en) * | 1973-07-25 | 1975-05-13 | Dart Ind Inc | ABS/vinyl acetate polymer blends |
| JPS5112859A (ja) * | 1974-07-23 | 1976-01-31 | Sumitomo Chemical Co | Netsukasoseijushisoseibutsu |
| JPS5842207B2 (ja) * | 1975-07-22 | 1983-09-17 | 三井化学株式会社 | ポリオレフインソセイブツノ スイセイブンサンエキノセイゾウホウホウ |
| JPS5280334A (en) * | 1975-12-27 | 1977-07-06 | Mitsui Petrochem Ind Ltd | Method of adhering polyolefin and polar substrate |
| GB1531188A (en) * | 1976-03-04 | 1978-11-01 | Idemitsu Kosan Co | Polypropylene resin compositions containing polypropylene and methods of producing same |
| US4199491A (en) * | 1977-12-23 | 1980-04-22 | Idemitsu Kosan Company Limited | Polyolefin resin composition |
| JPS54132631A (en) * | 1978-04-07 | 1979-10-15 | Mitsui Petrochem Ind Ltd | Powdered coating composition |
| GB2074587B (en) * | 1980-04-28 | 1983-12-21 | Sumitomo Naugatuck | Elastomeric compositions containing graft polymers |
| DE3120803A1 (de) * | 1981-05-25 | 1982-12-16 | Basf Ag, 6700 Ludwigshafen | Schlagzaehne thermoplastische formmassen |
| US4444950A (en) * | 1982-03-15 | 1984-04-24 | Sumitomo Naugatuck Co., Ltd. | Thermoplastic resin composition |
| JP3617999B2 (ja) * | 1993-08-06 | 2005-02-09 | 日機装株式会社 | 人工心肺装置および人工心肺装置における遠心ポンプ装置の配置方法 |
-
1982
- 1982-11-12 JP JP57199583A patent/JPS5989346A/ja active Granted
-
1983
- 1983-11-07 US US06/549,381 patent/US4554316A/en not_active Expired - Lifetime
- 1983-11-08 GB GB08329747A patent/GB2131440B/en not_active Expired
- 1983-11-09 AU AU21102/83A patent/AU562488B2/en not_active Expired
- 1983-11-10 DE DE3340591A patent/DE3340591C2/de not_active Expired - Lifetime
- 1983-11-10 CA CA000440962A patent/CA1235834A/en not_active Expired
- 1983-11-11 KR KR1019830005357A patent/KR870001948B1/ko not_active IP Right Cessation
- 1983-11-14 FR FR8318052A patent/FR2536080B1/fr not_active Expired
-
1986
- 1986-12-31 US US06/948,427 patent/US4835215A/en not_active Expired - Lifetime
-
1988
- 1988-09-07 US US07/241,150 patent/US4900787A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE3340591A1 (de) | 1984-05-17 |
| JPS6355541B2 (ja) | 1988-11-02 |
| AU562488B2 (en) | 1987-06-11 |
| US4900787A (en) | 1990-02-13 |
| FR2536080B1 (fr) | 1986-08-08 |
| KR870001948B1 (ko) | 1987-10-23 |
| FR2536080A1 (fr) | 1984-05-18 |
| GB8329747D0 (en) | 1983-12-14 |
| US4835215A (en) | 1989-05-30 |
| US4554316A (en) | 1985-11-19 |
| AU2110283A (en) | 1984-05-17 |
| DE3340591C2 (de) | 1995-01-26 |
| GB2131440B (en) | 1986-10-01 |
| GB2131440A (en) | 1984-06-20 |
| KR840007098A (ko) | 1984-12-05 |
| JPS5989346A (ja) | 1984-05-23 |
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