CA1119578A - Method of preparing crystalline aluminosilicates - Google Patents
Method of preparing crystalline aluminosilicatesInfo
- Publication number
- CA1119578A CA1119578A CA000297433A CA297433A CA1119578A CA 1119578 A CA1119578 A CA 1119578A CA 000297433 A CA000297433 A CA 000297433A CA 297433 A CA297433 A CA 297433A CA 1119578 A CA1119578 A CA 1119578A
- Authority
- CA
- Canada
- Prior art keywords
- reaction mixture
- silica
- sodium
- ratio
- shear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000323 aluminium silicate Inorganic materials 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000011541 reaction mixture Substances 0.000 claims abstract description 37
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 26
- 229910001868 water Inorganic materials 0.000 claims abstract description 22
- 238000002156 mixing Methods 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 11
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 11
- 239000011734 sodium Substances 0.000 claims abstract description 11
- 239000013078 crystal Substances 0.000 claims abstract description 10
- 229910052681 coesite Inorganic materials 0.000 claims description 12
- 229910052906 cristobalite Inorganic materials 0.000 claims description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims description 12
- 229910052682 stishovite Inorganic materials 0.000 claims description 12
- 229910052905 tridymite Inorganic materials 0.000 claims description 12
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 8
- 239000012452 mother liquor Substances 0.000 claims description 6
- 239000000376 reactant Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 239000000047 product Substances 0.000 description 20
- 239000012013 faujasite Substances 0.000 description 9
- 230000032683 aging Effects 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 5
- 239000008119 colloidal silica Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 description 5
- 150000001768 cations Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052909 inorganic silicate Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- JEWHCPOELGJVCB-UHFFFAOYSA-N aluminum;calcium;oxido-[oxido(oxo)silyl]oxy-oxosilane;potassium;sodium;tridecahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.[Na].[Al].[K].[Ca].[O-][Si](=O)O[Si]([O-])=O JEWHCPOELGJVCB-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000006854 communication Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- -1 hydrogen cations Chemical class 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910001743 phillipsite Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2838—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of faujasite type, or type X or Y (UNION CARBIDE trade names; correspond to GRACE's types Z-14 and Z-14HS, respectively)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77172577A | 1977-02-24 | 1977-02-24 | |
| US771,725 | 1977-02-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1119578A true CA1119578A (en) | 1982-03-09 |
Family
ID=25092779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000297433A Expired CA1119578A (en) | 1977-02-24 | 1978-02-22 | Method of preparing crystalline aluminosilicates |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS53114800A (de) |
| CA (1) | CA1119578A (de) |
| DE (1) | DE2807660A1 (de) |
| ES (1) | ES467225A1 (de) |
| FR (1) | FR2381716A1 (de) |
| GB (1) | GB1598042A (de) |
| IT (1) | IT1095432B (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58112980A (ja) * | 1981-12-22 | 1983-07-05 | 株式会社ブリヂストン | パネル貯槽 |
| IN157422B (de) * | 1982-06-21 | 1986-03-22 | Lever Hindustan Ltd | |
| JPS5996185U (ja) * | 1982-12-20 | 1984-06-29 | 積水プラントシステム株式会社 | 補強されたタンク |
| US4818509A (en) * | 1984-03-23 | 1989-04-04 | Mobil Oil Corporation | Continuous process for manufacturing crystalline zeolites in continuously stirred backmixed crystallizers |
| ZA851734B (en) * | 1984-03-23 | 1986-10-29 | Mobil Oil Corp | A continuous process for manufacturing crystalline zeolites |
| GB8517997D0 (en) * | 1985-07-17 | 1985-08-21 | English Clays Lovering Pochin | Synthesing faujasites |
| CA2032845A1 (en) * | 1989-12-29 | 1991-06-30 | Guenter H. Kuehl | Synthesis of faujasite |
| US5487882A (en) * | 1994-07-19 | 1996-01-30 | Albemarle Corporation | Process for preparation of zeolite "X" |
| FR2750973B1 (fr) * | 1996-07-12 | 1998-10-30 | Ceca Sa | Utilisation d'un reacteur agite par un systeme du type vis d'archimede pour la synthese de faujasite lsx |
| CN103534025B (zh) | 2011-04-15 | 2016-03-09 | 埃克森美孚化学专利公司 | 分子筛材料的制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3433589A (en) * | 1966-04-07 | 1969-03-18 | Mobil Oil Corp | Method of preparing faujasite-type crystalline zeolites |
| JPS4830238A (de) * | 1971-08-20 | 1973-04-21 | ||
| US3733391A (en) * | 1971-11-01 | 1973-05-15 | Nl Industries Inc | Process of preparing high silica faujasite |
| DE2333068C3 (de) * | 1973-06-29 | 1983-06-09 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung eines pulverförmigen kristallinen zeolithischen Molekularsiebes des Typs A und dessen Verwendung |
| DD107428B3 (de) * | 1973-11-05 | 1992-12-10 | Chemie Ag Bittrfeld Wolfen | Verfahren und vorrichtung zur herstellung synthetischer zeolithe |
| US4040972A (en) * | 1975-03-12 | 1977-08-09 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Ion-exchanging aluminum silicate with hydrophilic surfaces |
| DE2533614C2 (de) * | 1975-07-26 | 1985-10-31 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von zeolithischen Alkalialuminiumsilikaten |
| AT356628B (de) * | 1976-02-06 | 1980-05-12 | Henkel Kgaa | Verfahren zur herstellung waesseriger, zur weiterverarbeitung zu wasch- und reinigungs- mitteln geeigneter suspensionen von fein- teiligen, zum kationenaustausch befaehigten, noch gebundenes wasser enthaltenden wasser- unloeslichen silikaten |
-
1978
- 1978-02-22 CA CA000297433A patent/CA1119578A/en not_active Expired
- 1978-02-22 JP JP1955978A patent/JPS53114800A/ja active Granted
- 1978-02-22 ES ES467225A patent/ES467225A1/es not_active Expired
- 1978-02-23 GB GB7235/78A patent/GB1598042A/en not_active Expired
- 1978-02-23 DE DE19782807660 patent/DE2807660A1/de not_active Withdrawn
- 1978-02-24 IT IT20612/78A patent/IT1095432B/it active
- 1978-02-24 FR FR7805374A patent/FR2381716A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1598042A (en) | 1981-09-16 |
| FR2381716A1 (fr) | 1978-09-22 |
| ES467225A1 (es) | 1978-11-16 |
| DE2807660A1 (de) | 1978-08-31 |
| JPS5713493B2 (de) | 1982-03-17 |
| IT7820612A0 (it) | 1978-02-24 |
| FR2381716B1 (de) | 1981-10-30 |
| IT1095432B (it) | 1985-08-10 |
| JPS53114800A (en) | 1978-10-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |