CA1003353A - Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen - Google Patents
Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogenInfo
- Publication number
- CA1003353A CA1003353A CA170,511A CA170511A CA1003353A CA 1003353 A CA1003353 A CA 1003353A CA 170511 A CA170511 A CA 170511A CA 1003353 A CA1003353 A CA 1003353A
- Authority
- CA
- Canada
- Prior art keywords
- alkali metal
- low pressure
- pressure hydrogen
- desulfurization process
- petroleum oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/34—Polysulfides of sodium or potassium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/04—Metals, or metals deposited on a carrier
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/32—Thermal properties
- C01P2006/33—Phase transition temperatures
- C01P2006/34—Melting temperatures
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US25855572A | 1972-06-01 | 1972-06-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1003353A true CA1003353A (en) | 1977-01-11 |
Family
ID=22981078
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA170,511A Expired CA1003353A (en) | 1972-06-01 | 1973-05-07 | Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3787315A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5515514B2 (cg-RX-API-DMAC10.html) |
| CA (1) | CA1003353A (cg-RX-API-DMAC10.html) |
| DE (1) | DE2326696A1 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2186522B1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB1431190A (cg-RX-API-DMAC10.html) |
| IT (1) | IT988819B (cg-RX-API-DMAC10.html) |
| NL (1) | NL7307457A (cg-RX-API-DMAC10.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2822153C1 (ru) * | 2020-10-19 | 2024-07-02 | Чайна Петролиум энд Кемикал Корпорейшн | Способ и система производства нефтяного топлива и их применение, а также нефтяное топливо и его применение |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51123160A (en) * | 1975-04-21 | 1976-10-27 | Hitachi Ltd | Electronic photograph device |
| JPS51123161A (en) * | 1975-04-21 | 1976-10-27 | Hitachi Ltd | Electronic photograph device |
| US4007109A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Combined desulfurization and hydroconversion with alkali metal oxides |
| US4076613A (en) * | 1975-04-28 | 1978-02-28 | Exxon Research & Engineering Co. | Combined disulfurization and conversion with alkali metals |
| US3976559A (en) * | 1975-04-28 | 1976-08-24 | Exxon Research And Engineering Company | Combined catalytic and alkali metal hydrodesulfurization and conversion process |
| US4007111A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Residua desulfurization and hydroconversion with sodamide and hydrogen |
| US4007110A (en) * | 1975-04-28 | 1977-02-08 | Exxon Research And Engineering Company | Residua desulfurization with sodium oxide and hydrogen |
| US4003824A (en) * | 1975-04-28 | 1977-01-18 | Exxon Research And Engineering Company | Desulfurization and hydroconversion of residua with sodium hydride and hydrogen |
| US4003823A (en) * | 1975-04-28 | 1977-01-18 | Exxon Research And Engineering Company | Combined desulfurization and hydroconversion with alkali metal hydroxides |
| US4017381A (en) * | 1975-04-28 | 1977-04-12 | Exxon Research And Engineering Company | Process for desulfurization of residua with sodamide-hydrogen and regeneration of sodamide |
| US4087348A (en) * | 1975-06-02 | 1978-05-02 | Exxon Research & Engineering Co. | Desulfurization and hydroconversion of residua with alkaline earth metal compounds and hydrogen |
| US4018572A (en) * | 1975-06-23 | 1977-04-19 | Rollan Swanson | Desulfurization of fossil fuels |
| JPS604464B2 (ja) * | 1975-08-21 | 1985-02-04 | キヤノン株式会社 | 画像形成装置 |
| US4366045A (en) * | 1980-01-22 | 1982-12-28 | Rollan Swanson | Process for conversion of coal to gaseous hydrocarbons |
| DE3114766A1 (de) * | 1980-04-15 | 1982-06-16 | Rollan Dr. 89316 Eureka Nev. Swanson | Verfahren zum umwandeln von kohle oder torf in gasfoermige kohlenwasserstoffe oder fluechtige destillate oder gemische hiervon |
| US4606812A (en) * | 1980-04-15 | 1986-08-19 | Chemroll Enterprises, Inc. | Hydrotreating of carbonaceous materials |
| ES8203951A1 (es) * | 1980-04-15 | 1982-04-01 | Swanson Rollan | Procedimiento para hidrotratar material carbonoso |
| US4468316A (en) * | 1983-03-03 | 1984-08-28 | Chemroll Enterprises, Inc. | Hydrogenation of asphaltenes and the like |
| JP2706994B2 (ja) * | 1990-04-09 | 1998-01-28 | 行正 佐藤 | オイルスラッジ及び含油廃水の処理方法とその装置 |
| US5935421A (en) * | 1995-05-02 | 1999-08-10 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
| US5695632A (en) * | 1995-05-02 | 1997-12-09 | Exxon Research And Engineering Company | Continuous in-situ combination process for upgrading heavy oil |
| US5602186A (en) * | 1995-10-27 | 1997-02-11 | Exxon Research And Engineering Company | Rubber devulcanization process |
| US5798394A (en) * | 1995-10-27 | 1998-08-25 | Exxon Research And Engineering Company | Rubber devulcanization process |
| US6210564B1 (en) | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
| US20040206670A1 (en) * | 2002-12-11 | 2004-10-21 | Paul Baskis | Carbon transforming process |
| US7192516B2 (en) * | 2003-04-17 | 2007-03-20 | Trans Ionics Corporation | Desulfurization of petroleum streams using metallic sodium |
| US7897028B2 (en) * | 2004-01-26 | 2011-03-01 | Ceramatec, Inc. | Process for the recovery of materials from a desulfurization reaction |
| US7507327B2 (en) * | 2004-09-30 | 2009-03-24 | Exxonmobil Research And Engineering Company | Desulfurizing organosulfur heterocycles in feeds with supported sodium |
| CA2531262A1 (en) * | 2005-12-21 | 2007-06-21 | Imperial Oil Resources Limited | Very low sulfur heavy crude oil and process for the production thereof |
| WO2007095501A2 (en) * | 2006-02-10 | 2007-08-23 | Parallel Synthesis Technologies, Inc. | Authentication and anticounterfeiting methods and devices |
| WO2008133642A2 (en) * | 2006-10-13 | 2008-11-06 | Ceramatec, Inc. | Advanced metal-air battery having a ceramic membrane electrolyte |
| US8771879B2 (en) * | 2007-09-05 | 2014-07-08 | Ceramatec, Inc. | Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer |
| US8012621B2 (en) | 2007-11-26 | 2011-09-06 | Ceramatec, Inc. | Nickel-metal hydride battery using alkali ion conducting separator |
| US9209445B2 (en) | 2007-11-26 | 2015-12-08 | Ceramatec, Inc. | Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator |
| WO2009070600A2 (en) | 2007-11-27 | 2009-06-04 | Ceramatec, Inc. | Substantially solid, flexible electrolyte for alkili-metal-ion batteries |
| CA2705270C (en) | 2007-11-27 | 2016-07-26 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| WO2009073436A2 (en) * | 2007-11-28 | 2009-06-11 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
| US10320033B2 (en) | 2008-01-30 | 2019-06-11 | Enlighten Innovations Inc. | Alkali metal ion battery using alkali metal conductive ceramic separator |
| US20090189567A1 (en) * | 2008-01-30 | 2009-07-30 | Joshi Ashok V | Zinc Anode Battery Using Alkali Ion Conducting Separator |
| WO2010009082A1 (en) * | 2008-07-14 | 2010-01-21 | Saudi Arabian Oil Company | A prerefining process for the hydrodesulfurization of heavy sour crude oils to produce sweeter lighter crudes using moving catalyst system |
| US9260671B2 (en) * | 2008-07-14 | 2016-02-16 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
| US8372267B2 (en) * | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
| US8323817B2 (en) * | 2008-09-12 | 2012-12-04 | Ceramatec, Inc. | Alkali metal seawater battery |
| US9475998B2 (en) | 2008-10-09 | 2016-10-25 | Ceramatec, Inc. | Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides |
| KR20110139197A (ko) * | 2009-03-16 | 2011-12-28 | 세라마테크, 인코오포레이티드 | 실질적으로 비다공성 멤브레인을 구비한 나트륨-황 배터리 및 개선된 캐소드 활용방법 |
| US8491779B2 (en) * | 2009-06-22 | 2013-07-23 | Saudi Arabian Oil Company | Alternative process for treatment of heavy crudes in a coking refinery |
| US9546325B2 (en) | 2009-11-02 | 2017-01-17 | Field Upgrading Limited | Upgrading platform using alkali metals |
| US9688920B2 (en) * | 2009-11-02 | 2017-06-27 | Field Upgrading Limited | Process to separate alkali metal salts from alkali metal reacted hydrocarbons |
| BR112012010344A2 (pt) * | 2009-11-02 | 2016-03-29 | Ceramatec Inc | aprimoramento de cargas de óleo de petróleo utilizando metais alcalinos e hidrocarbonetos |
| US9512368B2 (en) | 2009-11-02 | 2016-12-06 | Field Upgrading Limited | Method of preventing corrosion of oil pipelines, storage structures and piping |
| US9441170B2 (en) * | 2012-11-16 | 2016-09-13 | Field Upgrading Limited | Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane |
| WO2011057135A2 (en) | 2009-11-05 | 2011-05-12 | Ceramatec, Inc | Solid-state sodium-based secondary cell having a sodium ion conductive ceramic separator |
| US8771855B2 (en) | 2010-08-11 | 2014-07-08 | Ceramatec, Inc. | Alkali metal aqueous battery |
| JP6041809B2 (ja) | 2010-12-01 | 2016-12-14 | セラマテック・インク | 中温作動ナトリウム電池 |
| KR101946791B1 (ko) * | 2011-03-23 | 2019-02-13 | 아디트야 비를라 사이언스 앤 테크놀로지 컴퍼니 리미티드 | 석유의 탈황 방법 |
| ES2692320T3 (es) | 2011-07-15 | 2018-12-03 | Field Upgrading Limited | Plataforma de mejoramiento utilizando metales alcalinos |
| JP2015501361A (ja) | 2011-10-24 | 2015-01-15 | アディティア ビルラ ヌーヴォ リミテッドAditya Birla Nuvo Limited | カーボンブラックを生成するための改善されたプロセス |
| KR101926905B1 (ko) | 2012-02-03 | 2018-12-07 | 필드 업그레이딩 리미티드 | 석유 공급원료의 탈황화 방법 |
| KR102049003B1 (ko) * | 2012-03-30 | 2019-11-27 | 아디트야 비를라 사이언스 앤 테크놀로지 컴퍼니 리미티드 | 황 함량이 감소된 카본 블랙 분말을 얻기 위한 방법 |
| KR102090358B1 (ko) * | 2013-04-15 | 2020-03-17 | 필드 업그레이딩 리미티드 | 알칼리금속과 반응시킨 탄화수소들로부터 알칼리금속염들을 분리하는 방법 |
| DE102014012110A1 (de) | 2014-08-19 | 2016-02-25 | Dr. Bilger Umweltconsulting Gmbh | Verfahren zur Entfernung von unerwünschten Verbindungen aus Mineralöl und Vorrichtung zur Durchführung des Verfahres |
| CA2995082C (en) | 2015-05-25 | 2020-10-27 | Technology Holding, Llc | Processing alkali metal-sulfide or alkaline earth metal-sulfide to obtain the alkali metal or alkaline earth metal |
| US10435631B2 (en) | 2016-10-04 | 2019-10-08 | Enlighten Innovations, Inc. | Process for separating particles containing alkali metal salts from liquid hydrocarbons |
| CN113881454A (zh) * | 2021-09-30 | 2022-01-04 | 中国石油化工股份有限公司 | 一种从渣油中分离硫化钠的方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US213661A (en) * | 1879-03-25 | Improvement in plows | ||
| US1729943A (en) * | 1921-06-14 | 1929-10-01 | Firm Of Internationale Bergin | Treatment by pressure and heat of heavy mineral oils and carbon material |
| US2020661A (en) * | 1923-06-20 | 1935-11-12 | Phillips Petroleum Co | Process for treating hydrocarbon oils |
| US3004912A (en) * | 1959-04-13 | 1961-10-17 | Nat Distillers Chem Corp | Desulfurization process utilizing metallic sodium and recycling of sludge |
| US3093575A (en) * | 1959-11-25 | 1963-06-11 | Exxon Research Engineering Co | Treatment of petroleum residua with sodium alloys |
| US3164545A (en) * | 1962-12-26 | 1965-01-05 | Exxon Research Engineering Co | Desulfurization process |
| US3404036A (en) * | 1965-10-22 | 1968-10-01 | Ford Motor Co | Energy conversion device comprising a solid crystalline electrolyte and a solid reaction zone separator |
| US3475225A (en) * | 1966-11-21 | 1969-10-28 | Ford Motor Co | Method for preparing solid state ionic conductor |
| US3446677A (en) * | 1966-11-21 | 1969-05-27 | Ford Motor Co | Method of making a solid ionic conductor |
| US3488271A (en) * | 1966-12-02 | 1970-01-06 | Ford Motor Co | Method for separating a metal from a salt thereof |
| US3468709A (en) * | 1967-04-03 | 1969-09-23 | Ford Motor Co | Secondary battery employing an electronically - insulative,cationically-conductive solid electrolyte with anodic and cathodic feeder means |
| US3565792A (en) * | 1968-06-07 | 1971-02-23 | Frank B Haskett | Cyclic process for desulfurizing crude petroleum fractions with sodium |
-
1972
- 1972-06-01 US US00258555A patent/US3787315A/en not_active Expired - Lifetime
-
1973
- 1973-05-07 CA CA170,511A patent/CA1003353A/en not_active Expired
- 1973-05-11 GB GB2261973A patent/GB1431190A/en not_active Expired
- 1973-05-25 DE DE2326696A patent/DE2326696A1/de active Pending
- 1973-05-29 NL NL7307457A patent/NL7307457A/xx unknown
- 1973-05-30 FR FR7319906A patent/FR2186522B1/fr not_active Expired
- 1973-05-30 IT IT24851/73A patent/IT988819B/it active
- 1973-06-01 JP JP6105073A patent/JPS5515514B2/ja not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2822153C1 (ru) * | 2020-10-19 | 2024-07-02 | Чайна Петролиум энд Кемикал Корпорейшн | Способ и система производства нефтяного топлива и их применение, а также нефтяное топливо и его применение |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7307457A (cg-RX-API-DMAC10.html) | 1973-12-04 |
| JPS5515514B2 (cg-RX-API-DMAC10.html) | 1980-04-24 |
| US3787315A (en) | 1974-01-22 |
| FR2186522B1 (cg-RX-API-DMAC10.html) | 1978-09-29 |
| IT988819B (it) | 1975-04-30 |
| JPS4942703A (cg-RX-API-DMAC10.html) | 1974-04-22 |
| DE2326696A1 (de) | 1973-12-20 |
| FR2186522A1 (cg-RX-API-DMAC10.html) | 1974-01-11 |
| GB1431190A (en) | 1976-04-07 |
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