BRPI0921502B1 - CATALISADOR PARA OXIDAR AMÔNIA EM NITROGÊNIO E NOx, MÉTODO PARA TRATAR EMISSÕES PRODUZIDAS NA CORRENTE DE GÁS DE DESCARGA DE UM VEÍCULO A DIESEL OU DE QUEIMA POBRE, E, SISTEMA PARA TRATAR UMA CORRENTE DE GÁS DE DESCARGA - Google Patents
CATALISADOR PARA OXIDAR AMÔNIA EM NITROGÊNIO E NOx, MÉTODO PARA TRATAR EMISSÕES PRODUZIDAS NA CORRENTE DE GÁS DE DESCARGA DE UM VEÍCULO A DIESEL OU DE QUEIMA POBRE, E, SISTEMA PARA TRATAR UMA CORRENTE DE GÁS DE DESCARGA Download PDFInfo
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- BRPI0921502B1 BRPI0921502B1 BRPI0921502-6A BRPI0921502A BRPI0921502B1 BR PI0921502 B1 BRPI0921502 B1 BR PI0921502B1 BR PI0921502 A BRPI0921502 A BR PI0921502A BR PI0921502 B1 BRPI0921502 B1 BR PI0921502B1
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- Prior art keywords
- catalyst
- copper
- fact
- platinum
- ammonia
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9436—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8634—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/068—Noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
- B01J29/072—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
- B01J29/14—Iron group metals or copper
- B01J29/146—Y-type faujasite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
- B01J29/46—Iron group metals or copper
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7615—Zeolite Beta
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/7676—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
- B01D2258/012—Diesel engines and lean burn gasoline engines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/263,864 US10632423B2 (en) | 2008-11-03 | 2008-11-03 | Bimetallic catalysts for selective ammonia oxidation |
| US12/263864 | 2008-11-03 | ||
| PCT/US2009/063045 WO2010062733A2 (en) | 2008-11-03 | 2009-11-03 | Bimetallic catalysts for selective ammonia oxidation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0921502A2 BRPI0921502A2 (pt) | 2016-09-27 |
| BRPI0921502B1 true BRPI0921502B1 (pt) | 2018-07-03 |
Family
ID=42131638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0921502-6A BRPI0921502B1 (pt) | 2008-11-03 | 2009-11-03 | CATALISADOR PARA OXIDAR AMÔNIA EM NITROGÊNIO E NOx, MÉTODO PARA TRATAR EMISSÕES PRODUZIDAS NA CORRENTE DE GÁS DE DESCARGA DE UM VEÍCULO A DIESEL OU DE QUEIMA POBRE, E, SISTEMA PARA TRATAR UMA CORRENTE DE GÁS DE DESCARGA |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10632423B2 (cg-RX-API-DMAC7.html) |
| EP (2) | EP3854479A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6289797B2 (cg-RX-API-DMAC7.html) |
| KR (2) | KR20110086720A (cg-RX-API-DMAC7.html) |
| CN (2) | CN107051574B (cg-RX-API-DMAC7.html) |
| BR (1) | BRPI0921502B1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2010062733A2 (cg-RX-API-DMAC7.html) |
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| DE102010050312A1 (de) * | 2010-11-03 | 2012-05-03 | Süd-Chemie AG | Ammoniak-Oxidationskatalysator mit geringer N2O Nebenproduktbildung |
| US8845974B2 (en) * | 2010-11-24 | 2014-09-30 | Basf Corporation | Advanced catalyzed soot filters and method of making and using the same |
| KR101986388B1 (ko) * | 2011-03-07 | 2019-06-05 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | Egr 회로에서 암모니아 슬립 촉매를 가지는 배기 시스템 |
| US8101146B2 (en) * | 2011-04-08 | 2012-01-24 | Johnson Matthey Public Limited Company | Catalysts for the reduction of ammonia emission from rich-burn exhaust |
| US9114376B2 (en) | 2011-06-05 | 2015-08-25 | Johnson Matthey Public Limited Company | Platinum group metal (PGM) catalyst for treating exhaust gas |
| CN102600735B (zh) * | 2012-03-29 | 2014-09-03 | 吉林大学 | 一种无机相分离膜及其在油水分离中的应用 |
| DE102012006541A1 (de) * | 2012-04-02 | 2013-10-02 | Clariant Produkte (Deutschland) Gmbh | Wasserstoffoxidationskatalysator, Verwendung desselben und Verfahren zur Wasserstoffrekombination |
| US8992869B2 (en) | 2012-12-20 | 2015-03-31 | Caterpillar Inc. | Ammonia oxidation catalyst system |
| KR101481600B1 (ko) * | 2013-05-02 | 2015-01-14 | 희성촉매 주식회사 | 선택적 촉매 환원 (scr) 시스템에서의 암모니아 산화촉매 |
| EP3015167A1 (en) * | 2014-10-31 | 2016-05-04 | Heesung Catalysts Corporation | Ammonia oxidation catalyst in scr system |
| CN105749960A (zh) * | 2016-03-10 | 2016-07-13 | 镇江翰宏新材料科技有限公司 | 一种用于氨选择性催化还原脱除NOx的催化剂的制备方法 |
| CN105772098B (zh) * | 2016-05-04 | 2018-09-14 | 宁波富锴净化器有限公司 | 用于氨选择性催化还原脱除NOx的催化剂及其制备方法 |
| GB201705289D0 (en) * | 2017-03-31 | 2017-05-17 | Johnson Matthey Catalysts (Germany) Gmbh | Selective catalytic reduction catalyst |
| DE102018100833A1 (de) * | 2018-01-16 | 2019-07-18 | Umicore Ag & Co. Kg | Verfahren zur Herstellung eines SCR-Katalysators |
| CN108246360B (zh) * | 2018-02-27 | 2021-02-12 | 南开大学 | 一种用于氨氧化的氧化物分子筛复合催化剂 |
| US10953366B2 (en) * | 2018-04-20 | 2021-03-23 | GM Global Technology Operations LLC | Nitrogen oxides and hydrocarbon storage catalyst and methods of using the same |
| KR102224335B1 (ko) | 2018-09-19 | 2021-03-08 | 주식회사 씨비비 | 가스상 암모니아를 질소로 전환하는 선택적 산화촉매 및 그 그 제조방법 |
| CN110102338A (zh) * | 2019-04-30 | 2019-08-09 | 昆明贵研催化剂有限责任公司 | 一种高氮气选择性的氨氧化催化剂及其制备方法 |
| EP3974059A1 (de) * | 2020-09-24 | 2022-03-30 | UMICORE AG & Co. KG | Verfahren zur herstellung eines katalysators zur oxidation von ammoniak |
| KR20220057376A (ko) | 2020-10-29 | 2022-05-09 | 한국화학연구원 | 암모니아의 질소전환용 비백금계 금속 산화물 촉매 및 이를 이용한 암모니아의 질소전환방법 |
| CN113107647B (zh) * | 2021-04-28 | 2022-02-01 | 一汽解放汽车有限公司 | 一种发动机运行模式的控制方法 |
| WO2023028928A1 (zh) * | 2021-09-01 | 2023-03-09 | 宁波吉利罗佑发动机零部件有限公司 | 氨吸附催化剂及其制备方法和应用 |
| JP2023079713A (ja) | 2021-11-29 | 2023-06-08 | 株式会社キャタラー | 排ガス浄化触媒装置 |
| CN115532304B (zh) * | 2022-09-21 | 2024-01-19 | 中国科学院生态环境研究中心 | 一种氨内燃机氨净化的分子筛催化剂及制备方法和用途 |
| CN115445654B (zh) * | 2022-09-21 | 2024-02-02 | 中国科学院生态环境研究中心 | 一种柴油车尾气氨净化分子筛催化剂及制备方法和用途 |
| JP2025156915A (ja) * | 2024-04-02 | 2025-10-15 | エヌ・イーケムキャット株式会社 | アンモニア分解触媒 |
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| US7998423B2 (en) * | 2007-02-27 | 2011-08-16 | Basf Corporation | SCR on low thermal mass filter substrates |
| MX2009009095A (es) | 2007-02-27 | 2009-09-14 | Basf Catalysts Llc | Catalizadores de zeolita cha de cobre. |
| KR20090114480A (ko) * | 2007-02-27 | 2009-11-03 | 바스프 카탈리스트 엘엘씨 | 선택적 암모니아 산화를 위한 이원기능 촉매 |
-
2008
- 2008-11-03 US US12/263,864 patent/US10632423B2/en not_active Expired - Fee Related
-
2009
- 2009-11-03 CN CN201610927292.2A patent/CN107051574B/zh not_active Expired - Fee Related
- 2009-11-03 BR BRPI0921502-6A patent/BRPI0921502B1/pt not_active IP Right Cessation
- 2009-11-03 KR KR1020117012640A patent/KR20110086720A/ko not_active Ceased
- 2009-11-03 WO PCT/US2009/063045 patent/WO2010062733A2/en not_active Ceased
- 2009-11-03 JP JP2011534869A patent/JP6289797B2/ja not_active Expired - Fee Related
- 2009-11-03 EP EP21155134.6A patent/EP3854479A1/en not_active Withdrawn
- 2009-11-03 CN CN2009801534817A patent/CN102271810A/zh active Pending
- 2009-11-03 EP EP09829668A patent/EP2364211A4/en not_active Ceased
- 2009-11-03 KR KR1020177022251A patent/KR102126248B1/ko not_active Expired - Fee Related
-
2020
- 2020-03-24 US US16/828,668 patent/US20200222853A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20200222853A1 (en) | 2020-07-16 |
| JP2012507400A (ja) | 2012-03-29 |
| JP6289797B2 (ja) | 2018-03-07 |
| BRPI0921502A2 (pt) | 2016-09-27 |
| US10632423B2 (en) | 2020-04-28 |
| EP2364211A4 (en) | 2012-08-08 |
| CN107051574A (zh) | 2017-08-18 |
| WO2010062733A3 (en) | 2010-07-29 |
| KR20110086720A (ko) | 2011-07-29 |
| EP2364211A2 (en) | 2011-09-14 |
| CN102271810A (zh) | 2011-12-07 |
| KR20170095405A (ko) | 2017-08-22 |
| EP3854479A1 (en) | 2021-07-28 |
| WO2010062733A2 (en) | 2010-06-03 |
| KR102126248B1 (ko) | 2020-06-24 |
| US20100111791A1 (en) | 2010-05-06 |
| CN107051574B (zh) | 2021-02-19 |
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