BRPI0800224A2 - processos de alcoxilação de alta produtividade - Google Patents
processos de alcoxilação de alta produtividadeInfo
- Publication number
- BRPI0800224A2 BRPI0800224A2 BRPI0800224-0A BRPI0800224A BRPI0800224A2 BR PI0800224 A2 BRPI0800224 A2 BR PI0800224A2 BR PI0800224 A BRPI0800224 A BR PI0800224A BR PI0800224 A2 BRPI0800224 A2 BR PI0800224A2
- Authority
- BR
- Brazil
- Prior art keywords
- continuous
- catalyst
- continuous reactor
- reactor
- initiator
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2651—Alkaline earth metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/266—Metallic elements not covered by group C08G65/2648 - C08G65/2645, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PROCESSOS DE ALCOXILAçãO DE ALTA PRODUTIVIDADE. A presente invenção refere-se a um processo contínuo para a preparação de um produto de pai jéter de polioxialquileno, de peso molecular médio numérico N, empregando a adição contínua do iniciador, envolvendo as etapas de: (a) estabelecer em um reator contínuo uma primeira porção de uma mistura de catalisador/iniciador, a qual é efetiva para iniciar a polioxial-quilação do iniciador de partida, após a introdução do óxido de alquileno dentro do reator contínuo; (b) introduzir continuamente dentro do reator contínuo um ou mais óxidos de alquileno; (c) introduzir continuamente dentro do reator contínuo um ou mais iniciadores adicionados continuamente, os quais podem ser idênticos ou diferentes do dito iniciador de partida; (d) introduzir continuamente dentro do reator um catalisador recém-preparado e/ou adicional mistura de catalisador/iniciador, de modo que a atividade catalítica seja mantida, em que o catalisador é selecionado do grupo que consiste em óxidos modificados e hidróxidos de cálcio, estróncio e bário, fosfatos de lantânio ou fosfatos da série das lantanidas (terra rara), e hidrotalcitas e hidrotalcitas sintéticas; (e) introduzir iniciadores combinados de polioxialquilação através da contínua prática de pelo menos as etapas (b) a (d), até que seja obtido um produto de poliéter de polioxialquileno de peso molecular médio numérico N; e (f) remover continuamente o produto de poliéter de polioxialqulleno do reator contínuo. Catalisadores modificados por hidróxido de cálcio ou óxido de cálcio e à base de fosfatos de lantânio exibem propriedades cinéticas de pega e são de utilidade na produção de óxidos de polialquileno usando processos contínuos ou o processo de CAOS.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87921207P | 2007-01-08 | 2007-01-08 | |
US11/893,452 US20080167501A1 (en) | 2007-01-08 | 2007-08-16 | High productivity alkoxylation processes |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0800224A2 true BRPI0800224A2 (pt) | 2009-03-17 |
Family
ID=39284296
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0800224-0A BRPI0800224A2 (pt) | 2007-01-08 | 2008-01-08 | processos de alcoxilação de alta produtividade |
Country Status (8)
Country | Link |
---|---|
US (1) | US20080167501A1 (pt) |
EP (2) | EP1942126A1 (pt) |
JP (1) | JP5459962B2 (pt) |
KR (1) | KR101521295B1 (pt) |
BR (1) | BRPI0800224A2 (pt) |
ES (1) | ES2388834T3 (pt) |
MX (1) | MX2008000080A (pt) |
SG (2) | SG177147A1 (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008051882A1 (de) * | 2008-10-16 | 2010-04-29 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyetheresterpolyolen |
DE102008043245A1 (de) | 2008-10-29 | 2010-05-06 | Evonik Goldschmidt Gmbh | Siliconpolyether-Copolymersysteme sowie Verfahren zu deren Herstellung durch Alkoxylierungsreaktion |
KR102333890B1 (ko) * | 2014-07-03 | 2021-12-02 | 코베스트로 도이칠란트 아게 | 폴리에테르 카르보네이트 폴리올의 제조 방법 |
US20170260441A1 (en) * | 2016-03-11 | 2017-09-14 | Conocophillips Company | Preflush chemicals for scale inhibitor squeeze |
CN106496541B (zh) * | 2016-11-16 | 2019-12-13 | 宁波远利化工有限公司 | 一种异构十三醇聚氧乙烯醚的生产工艺 |
CN116606188B (zh) * | 2023-04-14 | 2024-03-29 | 浙江大学 | 一种甲醇制烯烃的方法 |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
DE1770548A1 (de) | 1967-06-02 | 1972-02-10 | Gen Tire & Rubber Co | Polyester und ihre Herstellung |
US3900518A (en) | 1967-10-20 | 1975-08-19 | Gen Tire & Rubber Co | Hydroxyl or thiol terminated telomeric ethers |
US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
US4472860A (en) | 1981-01-13 | 1984-09-25 | Oesterlind Hans C E | Device for retaining cord-like objects, preferably flexible electrical cords and the like |
US4453022A (en) * | 1982-04-21 | 1984-06-05 | Union Carbide Corporation | Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts |
CA1247649A (en) * | 1982-12-30 | 1988-12-28 | James H. Mccain | Barium hydroxide/lower alcohol catalysts for oxyalkylation reactions |
WO1985000365A1 (en) | 1983-07-05 | 1985-01-31 | Union Carbide Corporation | Alkoxylation using calcium catalysts and products therefrom |
JPS61134335A (ja) * | 1984-12-04 | 1986-06-21 | Sanyo Chem Ind Ltd | アルキレンオキサイド付加物の製造法 |
US4775653A (en) | 1987-04-28 | 1988-10-04 | Vista Chemical Company | Alkoxylation process using calcium based catalysts |
DE3833076A1 (de) | 1987-09-29 | 1989-04-06 | Lion Corp | Alkoxylierungskatalysator |
US5057628A (en) * | 1987-12-17 | 1991-10-15 | Shell Oil Company | Alkoxylation process catalyzed by compounds of the rare earth elements |
US5059719A (en) * | 1987-12-17 | 1991-10-22 | Shell Oil Company | Alkoxylation process using catalyst of the lanthanum series |
CA1339379C (en) * | 1987-12-17 | 1997-08-26 | Charles Lee Edwards | Alkoxylation process using catalysts of the lanthanum series |
US5057627A (en) * | 1988-06-09 | 1991-10-15 | Shell Oil Company | Alkoxylation process catalyzed by phosphate salts of the rare earth elements |
US5070125A (en) * | 1988-11-18 | 1991-12-03 | The Dow Chemical Company | Production of polyether polyols with reduced unsaturation |
AR243911A1 (es) * | 1988-11-18 | 1993-09-30 | Dow Chemical Co | Un proceso para la preparacion de un poliol que tiene un peso equivalente de 200 a 4000 mediante la reaccion de un compuesto monoepoxi. |
US5118570A (en) | 1989-02-08 | 1992-06-02 | Xerox Corporation | Ink jet transparencies and papers |
JP3097854B2 (ja) | 1989-05-12 | 2000-10-10 | 旭硝子株式会社 | ポリウレタン類の製造方法 |
DE4010606A1 (de) | 1990-04-02 | 1991-10-10 | Henkel Kgaa | Verwendung von hydrophobierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung |
US5210325A (en) | 1990-04-23 | 1993-05-11 | Shell Oil Company | Alkoxylation process catalyzed by supported rare earth elements |
US5191104A (en) | 1990-09-20 | 1993-03-02 | Union Carbide Chemicals & Plastics Technology Corporation | Alkoxylation of carboxylated compounds |
JPH0688944B2 (ja) | 1991-01-18 | 1994-11-09 | ライオン株式会社 | 脂肪酸ポリオキシアルキレンアルキルエーテルの製造方法 |
DE4110835A1 (de) | 1991-04-04 | 1992-10-08 | Henkel Kgaa | Verfahren zur herstellung hydrophobierter doppelschichthydroxid-verbindungen |
DE4341576A1 (de) | 1993-12-07 | 1995-06-08 | Hoechst Ag | Verfahren zur Herstellung von Alkoxylaten unter Verwendung von Esterverbindungen als Katalysator |
US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
US5777177A (en) * | 1996-02-07 | 1998-07-07 | Arco Chemical Technology, L.P. | Preparation of double metal cyanide-catalyzed polyols by continuous addition of starter |
US5689012A (en) * | 1996-07-18 | 1997-11-18 | Arco Chemical Technology, L.P. | Continuous preparation of low unsaturation polyoxyalkylene polyether polyols with continuous additon of starter |
DE19807991A1 (de) | 1998-02-26 | 1999-09-02 | Clariant Gmbh | Alkoxylierungskatalysator |
US6504061B1 (en) | 1998-06-10 | 2003-01-07 | Lion Corporation | Alkoxylation catalyst and method for producing the same, and method for producing alkylene oxide adduct using the catalyst |
JP2000212272A (ja) * | 1999-01-28 | 2000-08-02 | Kawaken Fine Chem Co Ltd | アルキレンオキシド付加体の製造方法 |
DE19909272A1 (de) * | 1999-03-03 | 2000-09-07 | Cognis Deutschland Gmbh | Verfahren zur Herstellung alkoxylierter nichtionischer Tenside |
US6514898B2 (en) | 2000-12-15 | 2003-02-04 | Shell Oil Company | Process of preparing a fluid rare earth alkoxylation catalyst |
CN1310998C (zh) * | 2002-01-22 | 2007-04-18 | 旭硝子株式会社 | 聚醚类的连续制备方法 |
US6953766B2 (en) | 2002-08-23 | 2005-10-11 | Shell Oil Company | Preparation of efficient REPO and LAPO catalysts |
DE102004031836A1 (de) * | 2004-06-30 | 2006-01-19 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
US20070060770A1 (en) | 2005-09-01 | 2007-03-15 | Matheson Kenneth L | Process for preparing alkoxylation catalyst and alkoxylation process |
-
2007
- 2007-08-16 US US11/893,452 patent/US20080167501A1/en not_active Abandoned
- 2007-12-18 SG SG2011088242A patent/SG177147A1/en unknown
- 2007-12-18 SG SG200718835-2A patent/SG144805A1/en unknown
- 2007-12-28 ES ES11154052T patent/ES2388834T3/es active Active
- 2007-12-28 EP EP07025168A patent/EP1942126A1/en not_active Withdrawn
- 2007-12-28 EP EP11154052A patent/EP2325230B1/en not_active Not-in-force
-
2008
- 2008-01-07 MX MX2008000080A patent/MX2008000080A/es active IP Right Grant
- 2008-01-07 KR KR1020080001602A patent/KR101521295B1/ko not_active IP Right Cessation
- 2008-01-08 JP JP2008001123A patent/JP5459962B2/ja not_active Expired - Fee Related
- 2008-01-08 BR BRPI0800224-0A patent/BRPI0800224A2/pt not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR101521295B1 (ko) | 2015-05-18 |
SG177147A1 (en) | 2012-01-30 |
ES2388834T3 (es) | 2012-10-19 |
MX2008000080A (es) | 2009-02-23 |
EP1942126A1 (en) | 2008-07-09 |
EP2325230B1 (en) | 2012-07-04 |
JP2008169392A (ja) | 2008-07-24 |
EP2325230A1 (en) | 2011-05-25 |
SG144805A1 (en) | 2008-08-28 |
KR20080065232A (ko) | 2008-07-11 |
JP5459962B2 (ja) | 2014-04-02 |
US20080167501A1 (en) | 2008-07-10 |
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Free format text: REFERENTE A 8A ANUIDADE. |
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B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2342 DE 24-11-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |