BRPI0614075B1 - composição poliolefínica, artigo moldado, método para preparar uma composição - Google Patents
composição poliolefínica, artigo moldado, método para preparar uma composição Download PDFInfo
- Publication number
- BRPI0614075B1 BRPI0614075B1 BRPI0614075A BRPI0614075A BRPI0614075B1 BR PI0614075 B1 BRPI0614075 B1 BR PI0614075B1 BR PI0614075 A BRPI0614075 A BR PI0614075A BR PI0614075 A BRPI0614075 A BR PI0614075A BR PI0614075 B1 BRPI0614075 B1 BR PI0614075B1
- Authority
- BR
- Brazil
- Prior art keywords
- ethylene
- olefin
- weight
- composition
- hdt
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 180
- 238000000034 method Methods 0.000 title claims description 25
- 229920000098 polyolefin Polymers 0.000 title claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 123
- 239000005977 Ethylene Substances 0.000 claims abstract description 123
- 239000004711 α-olefin Substances 0.000 claims abstract description 94
- 229920001384 propylene homopolymer Polymers 0.000 claims abstract description 53
- 239000000454 talc Substances 0.000 claims abstract description 53
- 229910052623 talc Inorganic materials 0.000 claims abstract description 53
- 239000000945 filler Substances 0.000 claims abstract description 22
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims description 27
- 229920001519 homopolymer Polymers 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 18
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 16
- 239000003063 flame retardant Substances 0.000 claims description 15
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 15
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- 238000005299 abrasion Methods 0.000 claims description 14
- 230000000694 effects Effects 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 13
- 238000002844 melting Methods 0.000 claims description 13
- 230000008018 melting Effects 0.000 claims description 13
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 11
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000049 pigment Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 230000003678 scratch resistant effect Effects 0.000 claims description 6
- 238000007707 calorimetry Methods 0.000 claims description 5
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004566 building material Substances 0.000 claims description 4
- -1 for example Substances 0.000 abstract description 95
- 230000003014 reinforcing effect Effects 0.000 abstract description 9
- 229920000642 polymer Polymers 0.000 description 83
- 239000004743 Polypropylene Substances 0.000 description 67
- 229920001155 polypropylene Polymers 0.000 description 67
- 235000012222 talc Nutrition 0.000 description 50
- 229920001971 elastomer Polymers 0.000 description 26
- 229920001577 copolymer Polymers 0.000 description 23
- 239000000806 elastomer Substances 0.000 description 21
- 239000000126 substance Substances 0.000 description 20
- 229920002397 thermoplastic olefin Polymers 0.000 description 19
- 150000001993 dienes Chemical class 0.000 description 18
- 229920000573 polyethylene Polymers 0.000 description 18
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 16
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 16
- 239000000178 monomer Substances 0.000 description 15
- 239000004698 Polyethylene Substances 0.000 description 14
- 239000003054 catalyst Substances 0.000 description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 14
- 230000008569 process Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 238000009826 distribution Methods 0.000 description 9
- 238000012986 modification Methods 0.000 description 9
- 230000004048 modification Effects 0.000 description 9
- 239000004793 Polystyrene Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 229920002223 polystyrene Polymers 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 239000012141 concentrate Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- 239000002667 nucleating agent Substances 0.000 description 7
- 239000004417 polycarbonate Substances 0.000 description 7
- 230000002787 reinforcement Effects 0.000 description 7
- 238000002347 injection Methods 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000011068 loading method Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 239000006085 branching agent Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000006911 nucleation Effects 0.000 description 5
- 238000010899 nucleation Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 4
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 4
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 4
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- 239000011342 resin composition Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000012963 UV stabilizer Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 229910000000 metal hydroxide Inorganic materials 0.000 description 3
- 150000004692 metal hydroxides Chemical class 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 229920002959 polymer blend Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- RINCXYDBBGOEEQ-UHFFFAOYSA-N succinic anhydride Chemical group O=C1CCC(=O)O1 RINCXYDBBGOEEQ-UHFFFAOYSA-N 0.000 description 3
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 2
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 2
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- ZSFDBVJMDCMTBM-UHFFFAOYSA-N ethane-1,2-diamine;phosphoric acid Chemical compound NCCN.OP(O)(O)=O ZSFDBVJMDCMTBM-UHFFFAOYSA-N 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001862 ultra low molecular weight polyethylene Polymers 0.000 description 2
- KEMUGHMYINTXKW-NQOXHWNZSA-N (1z,5z)-cyclododeca-1,5-diene Chemical compound C1CCC\C=C/CC\C=C/CC1 KEMUGHMYINTXKW-NQOXHWNZSA-N 0.000 description 1
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
- QEOSCXACXNFJCY-AKHDSKFASA-N (2R,3R,4S,5R)-6-benzyl-7-phenylheptane-1,2,3,4,5,6-hexol Chemical compound C(C1=CC=CC=C1)C(O)([C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)CC1=CC=CC=C1 QEOSCXACXNFJCY-AKHDSKFASA-N 0.000 description 1
- ZGXMNEKDFYUNDQ-GQCTYLIASA-N (5e)-hepta-1,5-diene Chemical compound C\C=C\CCC=C ZGXMNEKDFYUNDQ-GQCTYLIASA-N 0.000 description 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- SJFNJMCYFVSADL-UHFFFAOYSA-N 1,1,1,3-tetrabromononane Chemical compound CCCCCCC(Br)CC(Br)(Br)Br SJFNJMCYFVSADL-UHFFFAOYSA-N 0.000 description 1
- BZQKBFHEWDPQHD-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-[2-(2,3,4,5,6-pentabromophenyl)ethyl]benzene Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1CCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br BZQKBFHEWDPQHD-UHFFFAOYSA-N 0.000 description 1
- UZOSVZSBPTTWIG-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-chlorocyclohexane Chemical compound ClC1C(Br)C(Br)C(Br)C(Br)C1Br UZOSVZSBPTTWIG-UHFFFAOYSA-N 0.000 description 1
- YUAPUIKGYCAHGM-UHFFFAOYSA-N 1,2-dibromo-3-(2,3-dibromopropoxy)propane Chemical compound BrCC(Br)COCC(Br)CBr YUAPUIKGYCAHGM-UHFFFAOYSA-N 0.000 description 1
- PQRRSJBLKOPVJV-UHFFFAOYSA-N 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane Chemical compound BrCC(Br)C1CCC(Br)C(Br)C1 PQRRSJBLKOPVJV-UHFFFAOYSA-N 0.000 description 1
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical class O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- HKORUDUNMQUYRD-UHFFFAOYSA-N 2,4-dimethylocta-1,7-diene Chemical compound CC(=C)CC(C)CCC=C HKORUDUNMQUYRD-UHFFFAOYSA-N 0.000 description 1
- YXRZFCBXBJIBAP-UHFFFAOYSA-N 2,6-dimethylocta-1,7-diene Chemical compound C=CC(C)CCCC(C)=C YXRZFCBXBJIBAP-UHFFFAOYSA-N 0.000 description 1
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 description 1
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 1
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 1
- PBQSTXCCVHCVHS-UHFFFAOYSA-N 2-methylnona-2,7-diene Chemical compound CC=CCCCC=C(C)C PBQSTXCCVHCVHS-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical class C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 1
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 description 1
- UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
- DYIZJUDNMOIZQO-UHFFFAOYSA-N 4,5,6,7-tetrabromo-2-[2-(4,5,6,7-tetrabromo-1,3-dioxoisoindol-2-yl)ethyl]isoindole-1,3-dione Chemical compound O=C1C(C(=C(Br)C(Br)=C2Br)Br)=C2C(=O)N1CCN1C(=O)C2=C(Br)C(Br)=C(Br)C(Br)=C2C1=O DYIZJUDNMOIZQO-UHFFFAOYSA-N 0.000 description 1
- IZLXZVWFPZWXMZ-UHFFFAOYSA-N 5-cyclohexylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1=CC2CC1CC2=C1CCCCC1 IZLXZVWFPZWXMZ-UHFFFAOYSA-N 0.000 description 1
- BDEXHIMNEUYKBS-UHFFFAOYSA-N 5-cyclopent-2-en-1-ylbicyclo[2.2.1]hept-2-ene Chemical compound C1=CCCC1C1C(C=C2)CC2C1 BDEXHIMNEUYKBS-UHFFFAOYSA-N 0.000 description 1
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 1
- CJQNJRMLJAAXOS-UHFFFAOYSA-N 5-prop-1-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=CC)CC1C=C2 CJQNJRMLJAAXOS-UHFFFAOYSA-N 0.000 description 1
- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- HPGAXSAGNBYYTH-UHFFFAOYSA-N C(CC(=O)O)(=O)O.C(C(=O)NC1=CC=CC=C1)(=O)NC1=CC=CC=C1 Chemical compound C(CC(=O)O)(=O)O.C(C(=O)NC1=CC=CC=C1)(=O)NC1=CC=CC=C1 HPGAXSAGNBYYTH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 241000276425 Xiphophorus maculatus Species 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 125000000649 benzylidene group Chemical group [H]C(=[*])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001941 electron spectroscopy Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920005673 polypropylene based resin Polymers 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007430 reference method Methods 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- DBUNJGCQDDXVGO-UHFFFAOYSA-N sulfanyl(sulfanyloxy)silane Chemical compound SO[SiH2]S DBUNJGCQDDXVGO-UHFFFAOYSA-N 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 229920006029 tetra-polymer Polymers 0.000 description 1
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000007970 thio esters Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Instrument Panels (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69415005P | 2005-06-24 | 2005-06-24 | |
| US60/694,150 | 2005-06-24 | ||
| PCT/US2006/024527 WO2007002436A1 (en) | 2005-06-24 | 2006-06-23 | Filled tpo compositions, methods of making the same, and articles prepared from the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0614075A2 BRPI0614075A2 (pt) | 2011-03-09 |
| BRPI0614075B1 true BRPI0614075B1 (pt) | 2017-04-11 |
Family
ID=37395849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0614075A BRPI0614075B1 (pt) | 2005-06-24 | 2006-06-23 | composição poliolefínica, artigo moldado, método para preparar uma composição |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7714057B2 (enExample) |
| EP (2) | EP1896538B1 (enExample) |
| JP (2) | JP2008546891A (enExample) |
| KR (2) | KR101257967B1 (enExample) |
| CN (2) | CN101365748A (enExample) |
| AT (1) | ATE491746T1 (enExample) |
| AU (2) | AU2006261995B2 (enExample) |
| BR (1) | BRPI0614075B1 (enExample) |
| CA (2) | CA2612231A1 (enExample) |
| DE (1) | DE602006018914D1 (enExample) |
| MX (1) | MX2007016391A (enExample) |
| WO (2) | WO2007002436A1 (enExample) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| KR20080012897A (ko) * | 2005-04-27 | 2008-02-12 | 가부시키가이샤 프라임 폴리머 | 프로필렌계 수지 압출 발포 복합체 |
| CA2612231A1 (en) * | 2005-06-24 | 2007-01-04 | Dow Global Technologies Inc. | Filled tpo compositions, methods of making the same, and articles prepared from the same |
| US8080607B2 (en) | 2006-08-16 | 2011-12-20 | Dow Global Technologies Llc | Polymeric material and process for forming and using same |
| JP5663137B2 (ja) | 2006-11-14 | 2015-02-04 | セルミド リミテッド | ミッドカインのｃ−ドメインを認識する抗体 |
| CN101558116B (zh) * | 2006-12-15 | 2012-02-01 | 住友化学株式会社 | 聚丙烯树脂组合物 |
| WO2008079998A1 (en) * | 2006-12-21 | 2008-07-03 | Dow Global Technologies Inc. | Filled tpo compositions, methods of making the same, and articles prepared from the same |
| US7862671B2 (en) | 2007-01-11 | 2011-01-04 | Dow Global Technologies Inc. | Welding of a polymeric material and structures formed thereby |
| JP5390194B2 (ja) * | 2007-01-18 | 2014-01-15 | 株式会社プライムポリマー | 応力耐久成形体用のプロピレン単独重合体、および該重合体を含む組成物、並びにこれらから得られる応力耐久成形体 |
| WO2008109093A1 (en) * | 2007-03-06 | 2008-09-12 | Exxonmobil Research And Engineering Company | Fiber reinforced polypropylene composite front end modules |
| EP1988122A1 (en) * | 2007-05-04 | 2008-11-05 | Total Petrochemicals Research Feluy | Blend for use in automobile application |
| US8445595B2 (en) | 2007-08-24 | 2013-05-21 | Total Petrochemicals Research Feluy | Polypropylene prepared with a single-site catalyst and poly(hydroxyl carboxylic acid) blends |
| BRPI0815429B1 (pt) * | 2007-09-07 | 2018-12-11 | Dow Global Technologies Inc | composição de poliolefina termoplástica com carga e artigo moldado |
| US20090095096A1 (en) * | 2007-10-10 | 2009-04-16 | Charles Edwin Dean | Hazardous materials sensing robot |
| EP2055738A1 (en) * | 2007-10-31 | 2009-05-06 | Borealis Technology Oy | Impact-modified polypropylene |
| EP2108679A1 (en) | 2008-04-10 | 2009-10-14 | Borealis Technology Oy | Low emission polymer composition |
| RU2464288C2 (ru) * | 2008-07-14 | 2012-10-20 | Бореалис Аг | Полиолефиновое соединение с низким коэффициентом теплового линейного расширения |
| WO2010088488A1 (en) | 2009-01-30 | 2010-08-05 | Dow Global Technologies Inc. | Polymeric compositions and filled tpo articles having improved aesthetics |
| US9018310B2 (en) * | 2009-04-06 | 2015-04-28 | Polyone Designed Structures And Solutions Llc | Polymer blend composition for automotive flooring applications |
| EP2275476A1 (en) * | 2009-06-09 | 2011-01-19 | Borealis AG | Automotive material with excellent flow, high stiffness, excellent ductility and low CLTE |
| JP2011099092A (ja) * | 2009-09-30 | 2011-05-19 | Sumitomo Chemical Co Ltd | エチレン系重合体 |
| JP5331754B2 (ja) * | 2010-06-08 | 2013-10-30 | 日本ポリプロ株式会社 | 押出成形用ポリプロピレン樹脂組成物およびその塗装樹脂成形体 |
| US8178623B2 (en) * | 2010-06-10 | 2012-05-15 | Dow Global Technologies Llc | High stiffness high impact propylene impact copolymers field of the invention |
| JP5643432B2 (ja) * | 2010-09-22 | 2014-12-17 | ダウ グローバル テクノロジーズ エルエルシー | 改良された消音性充填材入り熱可塑性ポリオレフィン組成物 |
| JP5900089B2 (ja) | 2011-03-29 | 2016-04-06 | 住友化学株式会社 | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１−ヘキセンの製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
| JP2012214457A (ja) | 2011-03-29 | 2012-11-08 | Sumitomo Chemical Co Ltd | 遷移金属錯体、該遷移金属錯体の製造方法、三量化用触媒、１−ヘキセンの製造方法、置換シクロペンタジエン化合物、及び、該置換シクロペンタジエン化合物の製造方法 |
| CN102206383A (zh) * | 2011-06-30 | 2011-10-05 | 广州市聚赛龙工程塑料有限公司 | 一种汽车保险杆用的聚丙烯复合材料及其制备方法 |
| EP2669329A1 (en) * | 2012-06-01 | 2013-12-04 | Basell Poliolefine Italia S.r.l. | Mineral-filled polypropylene composition for foaming |
| US9580586B2 (en) | 2012-12-12 | 2017-02-28 | Asahi Kasei Plastics North America, Inc. | Polypropylene compounds with enhanced haptics |
| EP3039071B1 (en) | 2013-08-28 | 2019-04-10 | SABIC Global Technologies B.V. | Soft touch compositions and articles thereof |
| CN104558808B (zh) * | 2013-10-22 | 2017-03-08 | 中国石油化工股份有限公司 | 丙烯聚合物组合物和由其制备的制品 |
| WO2015108634A1 (en) | 2014-01-15 | 2015-07-23 | Exxonmobil Chemical Patents Inc. | Propylene-based impact copolymers |
| BR112016030108B1 (pt) | 2014-06-23 | 2021-08-24 | Dow Global Technologies Llc | Artigo pintado |
| EP3172277B1 (en) * | 2014-07-25 | 2020-06-24 | G.T. Line S.R.L. | High-resiliency rigid composite materials, and use and production thereof |
| CN106289596A (zh) * | 2015-05-29 | 2017-01-04 | 鸿富锦精密工业（深圳）有限公司 | 压力感测器 |
| CN105061901A (zh) * | 2015-08-28 | 2015-11-18 | 合肥会通新材料有限公司 | 一种无缝仪表板用聚丙烯复合材料及其制备方法 |
| CN108350107B (zh) | 2016-02-05 | 2021-01-26 | 株式会社Lg化学 | 可光固化和可热固化树脂组合物以及阻焊干膜 |
| EP3497393A4 (en) | 2016-08-08 | 2020-03-18 | Ticona LLC | Thermally conductive polymer composition for a heat sink |
| CA2975803C (en) | 2016-09-02 | 2023-06-20 | University Of Guelph | Toughened polyolefin and biocarbon based light-weight biocomposites and method of making the same. |
| WO2018046097A1 (en) * | 2016-09-09 | 2018-03-15 | Leoni Kabel Gmbh | Polymer composition with high flexibility and flame retardancy |
| EP3510096B1 (en) * | 2016-09-09 | 2023-11-01 | LEONI Kabel GmbH | Strand-shaped elements and polymer composition for preparing same |
| US11584838B2 (en) | 2017-10-10 | 2023-02-21 | Dart Container Corporation | Polyolefin-based composition for a lid and methods of making and using |
| CN111356728A (zh) * | 2017-11-16 | 2020-06-30 | 3M创新有限公司 | 包含吸热颗粒的聚合物基质复合材料及其制备方法 |
| JP2019182926A (ja) * | 2018-04-03 | 2019-10-24 | トヨタ車体株式会社 | 樹脂組成物、及び車両の内装樹脂部品 |
| US11242180B2 (en) | 2018-05-25 | 2022-02-08 | Dart Container Corporation | Drink lid for a cup |
| KR20210127954A (ko) * | 2019-02-20 | 2021-10-25 | 피나 테크놀러지, 인코포레이티드 | 휨이 적은 중합체 조성물 |
| JP7462731B2 (ja) * | 2019-09-30 | 2024-04-05 | エルジー・ケム・リミテッド | ポリプロピレン系複合材 |
| CN110746703A (zh) * | 2019-10-30 | 2020-02-04 | 中国石油化工股份有限公司 | 一种高刚高韧聚丙烯组合物及其制备方法 |
| US12338344B2 (en) | 2019-12-24 | 2025-06-24 | Sabic Global Technologies B.V. | Polymer composition with a high heat deflection temperature |
| EP4081593B1 (en) | 2019-12-24 | 2024-02-07 | SABIC Global Technologies B.V. | Heterophasic propylene copolymer composition with low gloss |
| JP2021155511A (ja) * | 2020-03-25 | 2021-10-07 | 富士フイルムビジネスイノベーション株式会社 | 樹脂組成物及び樹脂成形体 |
| JP2023146472A (ja) * | 2022-03-29 | 2023-10-12 | 東洋製罐グループホールディングス株式会社 | 螺子キャップ用ポリプロピレン組成物 |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5286776A (en) | 1990-11-08 | 1994-02-15 | Kanesi Corporation | Reinforced polypropylene resin composition containing glass fiber, mica and copolymer additives |
| JPH0827328A (ja) * | 1994-07-11 | 1996-01-30 | Tonen Chem Corp | ポリプロピレン樹脂組成物 |
| US5747592A (en) * | 1994-12-16 | 1998-05-05 | Exxon Chemical Patents, Inc. | Thermoplastic polymer compositions and their production and use |
| DE19635503A1 (de) | 1996-09-02 | 1998-03-05 | Basf Ag | Weißbrucharme, zähmodifizierte Propylenpolymerisate |
| US6506842B1 (en) | 1997-01-29 | 2003-01-14 | Dupont Dow Elastomers L.L.C. | Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom |
| DE69826985T2 (de) | 1997-03-07 | 2005-11-10 | Dupont Dow Elastomers L.L.C., Wilmington | Elastomerzusammensetzungen mit verbesserter abriebfestigkeit, reibungskoeffizienten und grünfestigkeiten |
| US6759475B2 (en) | 1997-04-24 | 2004-07-06 | Mitsui Chemicals, Inc. | Resin composition based on crystalline polypropylene |
| GB9713526D0 (en) | 1997-06-26 | 1997-09-03 | Dow Deutschland Inc | Flame retardant laminating formulations |
| US6680361B1 (en) | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| JP3572343B2 (ja) | 1999-06-23 | 2004-09-29 | 出光石油化学株式会社 | 自動車部品用ポリプロピレン組成物 |
| EP1153978B1 (en) | 1999-11-11 | 2004-03-10 | Japan Polychem Corporation | Propylene resin composition and method for molding the same |
| US6737131B1 (en) | 1999-11-12 | 2004-05-18 | Cerowa, Inc. | Non-flammable hazardous fluid tanks |
| US6300419B1 (en) * | 1999-12-08 | 2001-10-09 | The Dow Chemical Company | Propylene polymer composition |
| AU2001280682A1 (en) | 2000-08-08 | 2002-02-18 | The Dow Chemical Company | Flame retardant foam from blends of vinyl aromatic and olefinic polymers |
| US6498214B2 (en) | 2000-08-22 | 2002-12-24 | Dupont Dow Elastomers L.L.C. | Soft touch TPO compositions comprising polypropylene and low crystalline ethylene copolymers |
| US6548600B2 (en) | 2000-09-22 | 2003-04-15 | Dupont Dow Elastomers L.L.C. | Thermoplastic elastomer compositions rheology-modified using peroxides and free radical coagents |
| EP1363772B1 (de) | 2001-02-06 | 2004-10-06 | Fagerdala Deutschland GmbH | Verbundmaterial aus einer polypropylen-deckschicht sowie einer polypropylen-schaumfolie |
| US6403692B1 (en) * | 2001-04-19 | 2002-06-11 | Dow Global Technologies Inc. | Filled thermoplastic composition |
| GB2395719B (en) | 2001-08-31 | 2006-01-11 | Honda Motor Co Ltd | Thermoplastic elastomer composition for core-back type system foam injection molding and foam injection molding method using the same |
| EP1434820A1 (en) * | 2001-10-01 | 2004-07-07 | Dow Global Technologies Inc. | Blow moldable propylene polymer compositions |
| US20050070673A1 (en) * | 2001-10-01 | 2005-03-31 | Novak Leo R. | Thermoformable propylene polymer compositions |
| JP4041705B2 (ja) | 2002-07-19 | 2008-01-30 | 日産自動車株式会社 | 自動車内装成形品 |
| US7338994B2 (en) | 2002-10-01 | 2008-03-04 | Dow Global Technologies Inc. | Rheology-modified thermoplastic elastomer compositions for extruded profiles |
| ATE459663T1 (de) | 2002-10-07 | 2010-03-15 | Dow Global Technologies Inc | Hochkristallines polypropylen mit niedriger xylollöslichkeit |
| CA2423078A1 (en) | 2002-10-22 | 2004-04-22 | Nicholas A. Farkas | Scratch and mar resistant soft ethylene elastomer compositions |
| JP2004231924A (ja) * | 2003-02-03 | 2004-08-19 | Mitsui Chemicals Inc | プロピレン系樹脂組成物、成形体、成形体の用途 |
| US20040188885A1 (en) | 2003-03-31 | 2004-09-30 | Luis Lorenzo | Instrument panel assembly and method of forming same |
| US7737205B2 (en) | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
| JP5216215B2 (ja) | 2003-09-05 | 2013-06-19 | ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー | 優れた加工性を有する難燃性組成物 |
| US20050209403A1 (en) | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
| US7906586B2 (en) * | 2003-12-09 | 2011-03-15 | Dow Global Technologies Llc | Thermoplastic olefinic compositions |
| KR101215809B1 (ko) | 2004-11-16 | 2012-12-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 고속 시트 압출 적용을 위한 개선된 넥킹 내성이 있는엘라스토머 조성물 |
| CA2606584A1 (en) | 2005-05-12 | 2006-11-23 | Dow Global Technologies Inc. | Thermoformed, extruded sheeting with reduced gloss |
| CA2612231A1 (en) | 2005-06-24 | 2007-01-04 | Dow Global Technologies Inc. | Filled tpo compositions, methods of making the same, and articles prepared from the same |
-
2006
- 2006-06-23 CA CA002612231A patent/CA2612231A1/en not_active Abandoned
- 2006-06-23 KR KR1020077029827A patent/KR101257967B1/ko active Active
- 2006-06-23 CN CNA2006800227983A patent/CN101365748A/zh active Pending
- 2006-06-23 BR BRPI0614075A patent/BRPI0614075B1/pt active IP Right Grant
- 2006-06-23 WO PCT/US2006/024527 patent/WO2007002436A1/en not_active Ceased
- 2006-06-23 KR KR1020087001788A patent/KR20080041185A/ko not_active Withdrawn
- 2006-06-23 CA CA002612228A patent/CA2612228A1/en not_active Abandoned
- 2006-06-23 AU AU2006261995A patent/AU2006261995B2/en not_active Expired - Fee Related
- 2006-06-23 JP JP2008518449A patent/JP2008546891A/ja active Pending
- 2006-06-23 JP JP2008518450A patent/JP5118030B2/ja active Active
- 2006-06-23 DE DE602006018914T patent/DE602006018914D1/de active Active
- 2006-06-23 AT AT06773864T patent/ATE491746T1/de not_active IP Right Cessation
- 2006-06-23 MX MX2007016391A patent/MX2007016391A/es active IP Right Grant
- 2006-06-23 EP EP06773863A patent/EP1896538B1/en not_active Not-in-force
- 2006-06-23 EP EP06773864A patent/EP1896539B1/en active Active
- 2006-06-23 WO PCT/US2006/024526 patent/WO2007002435A1/en not_active Ceased
- 2006-06-23 US US11/473,706 patent/US7714057B2/en active Active
- 2006-06-23 US US11/473,705 patent/US7741398B2/en active Active
- 2006-06-23 AU AU2006261996A patent/AU2006261996A1/en not_active Abandoned
- 2006-06-23 CN CNA2006800227771A patent/CN101223226A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| KR20080040636A (ko) | 2008-05-08 |
| JP5118030B2 (ja) | 2013-01-16 |
| US7741398B2 (en) | 2010-06-22 |
| US7714057B2 (en) | 2010-05-11 |
| WO2007002436A1 (en) | 2007-01-04 |
| BRPI0614075A2 (pt) | 2011-03-09 |
| WO2007002435A1 (en) | 2007-01-04 |
| US20070037913A1 (en) | 2007-02-15 |
| US20070037914A1 (en) | 2007-02-15 |
| AU2006261995A1 (en) | 2007-01-04 |
| CN101223226A (zh) | 2008-07-16 |
| EP1896539A1 (en) | 2008-03-12 |
| AU2006261995B2 (en) | 2011-12-08 |
| CA2612231A1 (en) | 2007-01-04 |
| CN101365748A (zh) | 2009-02-11 |
| KR101257967B1 (ko) | 2013-04-24 |
| ATE491746T1 (de) | 2011-01-15 |
| JP2008544071A (ja) | 2008-12-04 |
| DE602006018914D1 (de) | 2011-01-27 |
| EP1896539B1 (en) | 2010-12-15 |
| JP2008546891A (ja) | 2008-12-25 |
| EP1896538B1 (en) | 2012-05-23 |
| KR20080041185A (ko) | 2008-05-09 |
| AU2006261996A1 (en) | 2007-01-04 |
| MX2007016391A (es) | 2008-03-07 |
| CA2612228A1 (en) | 2007-01-04 |
| EP1896538A1 (en) | 2008-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BRPI0614075B1 (pt) | composição poliolefínica, artigo moldado, método para preparar uma composição | |
| JP5340292B2 (ja) | 良好な低温延性を有する充填材入りｔｐｏ組成物 | |
| JP5721773B2 (ja) | 充填されたｔｐｏ組成物、それを作成する方法、およびそれから調製された物品 | |
| EP2731988B1 (en) | High flow polyolefin composition with low shrinkage and clte | |
| CN103881232B (zh) | 聚合物材料及形成和使用该聚合物材料的方法 | |
| BRPI1011003B1 (pt) | composição que apresenta fluxo excelente, alta tenacidade, excelente ductilidade e baixo clte, seu uso e seu processo de preparação, e artigo automotivo | |
| KR101650637B1 (ko) | 균형잡힌 특성 프로파일을 갖는 저 충전된 폴리프로필렌 조성물 | |
| BR112012007696B1 (pt) | Composição de polipropileno reforçada com fibra, artigo automotivo, uso da composição reforçada com fibra e processo para a preparação da composição reforçada com fibra | |
| MXPA06012719A (es) | Composicion de polimero de propileno resistente al rayado. | |
| EP2744858A1 (en) | Heterophasic system with improved surface properties | |
| EP2084223A1 (en) | Polyolefin compositions | |
| JP5416220B2 (ja) | 充填ポリオレフィン組成物 | |
| US20090093576A1 (en) | Appearance Propylene Polymer Composition | |
| JP2001151960A (ja) | ポリプロピレン系樹脂組成物および容器 | |
| BRPI0717679B1 (pt) | Composições poliolefínicas, artigos moldados por injeção e filmes | |
| KR101196201B1 (ko) | 내스크래치성 프로필렌 중합체 조성물 | |
| BRPI0613841A2 (pt) | peça automotiva |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 11/04/2017, OBSERVADAS AS CONDICOES LEGAIS. |