BRPI0605169A - processo para a produção de polióis à base de óleos naturais - Google Patents
processo para a produção de polióis à base de óleos naturaisInfo
- Publication number
- BRPI0605169A BRPI0605169A BRPI0605169-3A BRPI0605169A BRPI0605169A BR PI0605169 A BRPI0605169 A BR PI0605169A BR PI0605169 A BRPI0605169 A BR PI0605169A BR PI0605169 A BRPI0605169 A BR PI0605169A
- Authority
- BR
- Brazil
- Prior art keywords
- converting
- natural oils
- hydrogen peroxide
- carboxylic acid
- polyol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fats And Perfumes (AREA)
- Polyethers (AREA)
- Steroid Compounds (AREA)
- Epoxy Compounds (AREA)
- Lubricants (AREA)
Abstract
"PROCESSO PARA A PRODUçãO DE POLIóIS à BASE DE óLEOS NATURAIS". A presente invenção refere-se a um processo para a produção de polióis à base de óleos insaturados naturais.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005056432A DE102005056432A1 (de) | 2005-11-26 | 2005-11-26 | Verfahren zur Herstellung von Polyolen auf Basis natürlicher Öle |
Publications (1)
Publication Number | Publication Date |
---|---|
BRPI0605169A true BRPI0605169A (pt) | 2007-09-04 |
Family
ID=37663378
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0605169-3A BRPI0605169A (pt) | 2005-11-26 | 2006-11-27 | processo para a produção de polióis à base de óleos naturais |
Country Status (12)
Country | Link |
---|---|
US (1) | US20070123725A1 (pt) |
EP (1) | EP1790678B1 (pt) |
JP (1) | JP2007146163A (pt) |
KR (1) | KR20070055956A (pt) |
CN (1) | CN1974526B (pt) |
AT (1) | ATE444983T1 (pt) |
BR (1) | BRPI0605169A (pt) |
CA (1) | CA2568765A1 (pt) |
DE (2) | DE102005056432A1 (pt) |
ES (1) | ES2333038T3 (pt) |
MX (1) | MXPA06013551A (pt) |
SG (1) | SG132645A1 (pt) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10240186A1 (de) * | 2002-08-28 | 2004-03-11 | Basf Ag | Verfahren zur Herstellung von emissionsarmen Polyurethan-Weichschaumstoffen |
KR20090068216A (ko) * | 2006-09-27 | 2009-06-25 | 아사히 가라스 가부시키가이샤 | 연질 폴리우레탄폼의 제조 방법 |
JP5287246B2 (ja) * | 2006-09-27 | 2013-09-11 | 旭硝子株式会社 | 天然油脂由来物含有ポリエーテルポリオールの製造方法 |
US8097739B2 (en) * | 2007-04-18 | 2012-01-17 | BioBases Technologies, LLC | Process for the manufacture of natural oil hydroxylates |
EP2161289A4 (en) * | 2007-06-22 | 2010-07-07 | Asahi Glass Co Ltd | PROCESS FOR PREPARING POLYMER-DISPERSED POLYOL AND METHOD FOR PRODUCING FLEXIBLE POLYURETHANEUM FOAM |
US20100197878A1 (en) * | 2007-08-06 | 2010-08-05 | Dow Global Technologies Inc. | Polyol blends for use in making polymers |
BRPI0907096A2 (pt) * | 2008-01-29 | 2015-07-07 | Basf Se | Processos para preparar poliéter álcoois e para produzir poliuretanos, e, poliéter álcool |
DE102008011683A1 (de) * | 2008-02-28 | 2009-09-03 | Bayer Materialscience Ag | Verfahren zur Herstellung von Polyolen |
US20110218264A1 (en) * | 2008-11-14 | 2011-09-08 | Dow Global Technologies Llc | Modified natural oils and products made therefrom |
US20100317824A1 (en) * | 2009-06-15 | 2010-12-16 | Dow Global Technologies Inc. | Polyether derivatives of secondary hydroxy fatty acids and derivatives thereof |
US20120108780A1 (en) * | 2009-07-10 | 2012-05-03 | Basf Se | Method for producing polyols on the basis of renewable resources |
MY165657A (en) * | 2009-07-10 | 2018-04-18 | Basf Se | Method for producing polyols on the basis of renewable resources |
US8580984B2 (en) | 2009-07-10 | 2013-11-12 | Dow Global Technologies Llc | Esters of secondary hydroxy fatty acid oligomers and preparation thereof |
US20110213170A1 (en) * | 2010-02-26 | 2011-09-01 | Daniele Vinci | Estolide derivatives useful as biolubricants |
KR20130091631A (ko) | 2010-04-23 | 2013-08-19 | 바이엘 머티리얼싸이언스 엘엘씨 | 재생가능한 자원의 함량이 높은 고온 성형 발포체의 제조에 적절한 폴리올 |
WO2011136906A1 (en) | 2010-04-29 | 2011-11-03 | Dow Global Technologies Llc | Oligomerized ester alkoxylate compositions |
KR20130060213A (ko) | 2010-04-30 | 2013-06-07 | 바스프 에스이 | 폴리에테르 폴리올, 폴리에테르 폴리올의 제조 방법, 및 폴리우레탄 제조를 위한 그의 용도 |
US9115246B2 (en) | 2010-04-30 | 2015-08-25 | Basf Se | Polyether polyols, process for preparing polyether polyols and their use for producing polyurethanes |
CN101967222B (zh) * | 2010-09-19 | 2012-04-25 | 中国林业科学研究院林产化学工业研究所 | 一种环氧化蓖麻油改性的水性聚氨酯的制备方法 |
CN102181049B (zh) * | 2011-03-08 | 2012-12-26 | 江苏绿源新材料有限公司 | 麻疯树油制备的生物基聚醚多元醇及制备方法和用途 |
SG10201604976RA (en) | 2011-12-20 | 2016-08-30 | Bayer Ip Gmbh | Hydroxy-aminopolymers and method for producing same |
CN103113553A (zh) * | 2013-01-30 | 2013-05-22 | 上海市医药保健品进出口有限公司 | 一种纯植物油基多元醇及其制备方法 |
US10787550B2 (en) | 2014-06-26 | 2020-09-29 | Covestro Deutschland Ag | Composite components on the basis of hydrophobic polyols |
CN105646225B (zh) * | 2014-12-05 | 2018-10-12 | 中国石油化工股份有限公司 | 一种桐油基多元醇及制备方法 |
WO2017020124A1 (en) | 2015-07-31 | 2017-02-09 | The Governors Of The University Of Alberta | Synthesis of polyols suitable for castor oil replacement |
EP3526272B1 (en) * | 2016-10-14 | 2023-08-23 | Covation Inc. | Process for preparing poly(trimethylene furandicarboxylate) |
WO2019028433A1 (en) * | 2017-08-03 | 2019-02-07 | The Regents Of The University Of California | PROCESS FOR PRODUCING POLYOL COMPOSITIONS |
CN111057228A (zh) * | 2019-12-13 | 2020-04-24 | 张家港美景荣化学工业有限公司 | 一种低分子量聚醚多元醇的制备方法 |
CN111253549A (zh) * | 2020-03-25 | 2020-06-09 | 上海应用技术大学 | 一种含磷棕榈油基纯水性聚氨酯纳米乳液及制备方法 |
EP4446353A1 (de) | 2023-04-14 | 2024-10-16 | Covestro Deutschland AG | Polyurethanschaumstoff mit verbesserter dimensionsstabilität |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3630264A1 (de) * | 1986-09-05 | 1988-03-17 | Henkel Kgaa | Verfahren zur herstellung neuer, massiver polyurethanwerkstoffe im giessverfahren |
JPS63139993A (ja) * | 1986-12-02 | 1988-06-11 | ミヨシ油脂株式会社 | 制菌及び防虫効果並びに界面活性を有する油脂誘導体 |
JPH05163342A (ja) * | 1991-12-11 | 1993-06-29 | Asahi Glass Co Ltd | ポリエーテル類の製造方法 |
DE19812174A1 (de) * | 1998-03-19 | 1999-09-23 | Basf Ag | Verfahren zur Herstellung von Polyesterpolyolen |
US20030191274A1 (en) * | 2001-10-10 | 2003-10-09 | Kurth Thomas M. | Oxylated vegetable-based polyol having increased functionality and urethane material formed using the polyol |
US20020058774A1 (en) * | 2000-09-06 | 2002-05-16 | Kurth Thomas M. | Transesterified polyol having selectable and increased functionality and urethane material products formed using the polyol |
US6107433A (en) * | 1998-11-06 | 2000-08-22 | Pittsburg State University | Process for the preparation of vegetable oil-based polyols and electroninsulating casting compounds created from vegetable oil-based polyols |
US6433121B1 (en) * | 1998-11-06 | 2002-08-13 | Pittsburg State University | Method of making natural oil-based polyols and polyurethanes therefrom |
US6420443B1 (en) * | 1999-09-09 | 2002-07-16 | Crompton Corporation | Additives for enhanced hydrocarbon compatibility in rigid polyurethane foam systems |
US6399698B1 (en) * | 2000-10-26 | 2002-06-04 | Pittsburg State University | Process for the synthesis of epoxidized natural oil-based isocyanate prepolymers for application in polyurethanes |
MXPA00011394A (es) * | 2000-11-21 | 2003-03-12 | Resinas Y Materiales S A De C | Proceso mejorado para la obtencion de polioles oleoquimicos. |
US7977424B2 (en) * | 2001-08-13 | 2011-07-12 | Zoran Petrovic | Polymer concrete and method for preparation thereof |
JP3906464B2 (ja) * | 2002-12-10 | 2007-04-18 | アイカ工業株式会社 | ウレタン樹脂組成物 |
US20050159608A1 (en) * | 2004-01-20 | 2005-07-21 | Turner Robert B. | Method of preparing an epoxidized functional vegetable oil |
MY142614A (en) * | 2004-04-21 | 2010-12-15 | Malaysian Palm Oil Board | Palm-based hydroxy fatty acid |
JP2005320431A (ja) * | 2004-05-10 | 2005-11-17 | Honda Motor Co Ltd | 大豆油由来の軟質ポリウレタンフォームからなる自動車シート用クッション |
WO2006012344A1 (en) * | 2004-06-25 | 2006-02-02 | Pittsburg State University | Modified vegetable oil-based polyols |
US20060036107A1 (en) * | 2004-08-13 | 2006-02-16 | Casper David M | Method for producing soy bean oil diols |
AR050605A1 (es) * | 2004-08-23 | 2006-11-08 | Biobased Chemicals Llc | Proceso para la preparacion de aceites vegetales hidroxi-funcionales |
US20060041155A1 (en) * | 2004-08-23 | 2006-02-23 | Biobased Chemical | Method of preparing a hydroxy functional vegetable oil |
-
2005
- 2005-11-26 DE DE102005056432A patent/DE102005056432A1/de not_active Withdrawn
-
2006
- 2006-11-15 EP EP06023775A patent/EP1790678B1/de not_active Not-in-force
- 2006-11-15 ES ES06023775T patent/ES2333038T3/es active Active
- 2006-11-15 AT AT06023775T patent/ATE444983T1/de not_active IP Right Cessation
- 2006-11-15 DE DE502006005023T patent/DE502006005023D1/de active Active
- 2006-11-21 US US11/602,787 patent/US20070123725A1/en not_active Abandoned
- 2006-11-22 MX MXPA06013551A patent/MXPA06013551A/es active IP Right Grant
- 2006-11-23 CA CA002568765A patent/CA2568765A1/en not_active Abandoned
- 2006-11-23 SG SG200608163-2A patent/SG132645A1/en unknown
- 2006-11-24 KR KR1020060116783A patent/KR20070055956A/ko not_active Application Discontinuation
- 2006-11-27 BR BRPI0605169-3A patent/BRPI0605169A/pt not_active IP Right Cessation
- 2006-11-27 JP JP2006318146A patent/JP2007146163A/ja not_active Ceased
- 2006-11-27 CN CN2006101625284A patent/CN1974526B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE444983T1 (de) | 2009-10-15 |
ES2333038T3 (es) | 2010-02-16 |
CN1974526B (zh) | 2012-01-18 |
SG132645A1 (en) | 2007-06-28 |
KR20070055956A (ko) | 2007-05-31 |
CA2568765A1 (en) | 2007-05-26 |
CN1974526A (zh) | 2007-06-06 |
DE502006005023D1 (de) | 2009-11-19 |
MXPA06013551A (es) | 2008-10-09 |
US20070123725A1 (en) | 2007-05-31 |
EP1790678B1 (de) | 2009-10-07 |
EP1790678A1 (de) | 2007-05-30 |
DE102005056432A1 (de) | 2007-05-31 |
JP2007146163A (ja) | 2007-06-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BRPI0605169A (pt) | processo para a produção de polióis à base de óleos naturais | |
ZA200210027B (en) | Composition for the oxidation dyeing of keratin fibres, comprising an oxyalkylenated carboxylic acid ether, an associative polymer and an unsaturated fatty alcohol. | |
ATE317683T1 (de) | Durchscheinende nanoemulsion, verfahren zur deren herstellung, und deren verwendungen in kosmetika, dermatologie und/oder ophthalmologie | |
CA2398764A1 (en) | Method for the production of hydrocarbon fuels with ultra-low sulfur content | |
MY117968A (en) | Process for the production of an aqueous monoester peroxycarboxylic acid solution, the solution obtainable by this process, and its use as disinfectant | |
CA2465926A1 (en) | A traction apparatus | |
MX2007000022A (es) | Polioles basados en aceite vegetal modificado. | |
HK1092834A1 (en) | Process for producing symmetrical triglyceride | |
WO2010101637A3 (en) | Conversion of sugar, sugar alcohol, or glycerol to valuable chemicals using a promoted zirconium oxide supported catalyst | |
WO2007070609A3 (en) | Production of peracids using an enzyme having perhydrolysis activity | |
WO2007042313A3 (de) | Verfahren zur herstellung organischer peroxide mittels mikroreaktionstechnik | |
ATE282601T1 (de) | Verfahren zur herstellung von propylenoxid | |
WO2007044666A3 (en) | Enzymatic production of peracids using lactobacilli having perhydrolysis activity | |
AR070952A1 (es) | Procedimiento para la esterificacion catalizada heterogeneamente de acidos grasos | |
EP1281750A3 (en) | Conjugated fatty acid containing monoglycerides and process for producing them | |
WO2011087600A3 (en) | Process for the conversion of alcohols to olefins | |
WO2007017167A3 (de) | Mehrstufiges verfahren zur herstellung von fettsäurealkylestern aus fettsäuren und aliphatischen alkoholen unter verwendung von esterasen im ersten schritt und chemischen katalysatoren in einem weiteren schritt | |
BR0100469A (pt) | Processos para a preparação de um catalisador, e, para a preparação de um aldeìdo ou ácido carboxìlico insaturado | |
AR033669A1 (es) | Un procedimiento para hidroxilar cataliticamente compuestos alifaticos, saturados o insaturados | |
EP1182184A4 (en) | METHOD FOR PRODUCING TETRAFLUORO-BENZOL METHANOLS | |
EP1078907A4 (en) | PROCESS FOR THE PREPARATION OF ALDEHYDE | |
DK1443827T3 (da) | Fremgangsmåde til fremstilling af et fermenteret mejeriprodukt | |
BR0115224B1 (pt) | processo para a peparaÇço de Ácido acÉtico. | |
CN103288631A (zh) | 一种苯甲酸的制备方法 | |
ES2192991B1 (es) | Un procedimiento para la conversion de aldehidos usando un tamiz molecular y uso del tamiz molecular como catalizador en el procedimiento. |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A ANUIDADE. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: NAO APRESENTADA A GUIA DE CUMPRIMENTO DE EXIGENCIA. REFERENTE A 5A ANUIDADE. |