BR112022008102A2 - Complexo de metal bisfenol, método para preparar o complexo de metal bisfenol e uso do complexo de metal bisfenol - Google Patents

Complexo de metal bisfenol, método para preparar o complexo de metal bisfenol e uso do complexo de metal bisfenol

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Publication number
BR112022008102A2
BR112022008102A2 BR112022008102A BR112022008102A BR112022008102A2 BR 112022008102 A2 BR112022008102 A2 BR 112022008102A2 BR 112022008102 A BR112022008102 A BR 112022008102A BR 112022008102 A BR112022008102 A BR 112022008102A BR 112022008102 A2 BR112022008102 A2 BR 112022008102A2
Authority
BR
Brazil
Prior art keywords
metal complex
bisphenol metal
bisphenol
independently selected
hydrocarbyl
Prior art date
Application number
BR112022008102A
Other languages
English (en)
Inventor
Han Shuliang
Li Haokun
Song Wenbo
Jin Zhao
Wang Lusheng
Fang Yuanyuan
Original Assignee
China Petroleum & Chem Corp
Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum & Chem Corp, Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp filed Critical China Petroleum & Chem Corp
Publication of BR112022008102A2 publication Critical patent/BR112022008102A2/pt

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/64003—Titanium, zirconium, hafnium or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/64006—Bidentate ligand
    • C08F4/64068—Dianionic ligand
    • C08F4/64079—OO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

COMPLEXO DE METAL BISFENOL, MÉTODO PARA PREPARAR O COMPLEXO DE METAL BISFENOL E USO DO COMPLEXO DE METAL BISFENOL. É descrito um complexo de metal bisfenol. A sua estrutura é representada pela fórmula I, em que R1 e R1' são, cada um, independentemente selecionados dentre hidrogênio e um hidrocarbil C1-C20 substituído ou não substituído; R3-R7, R3'-R7' são, cada um, independentemente selecionados dentre hidrogênio e um hidrocarbil C1-C20 substituído ou não substituído, quaisquer dois grupos adjacentes de R3-R7 são opcionalmente ligados para formar um anel e quaisquer dois grupos adjacentes de R3'- R7' também estão opcionalmente ligados para formar um anel; M e M' são selecionados independentemente dos metais do Grupo 4; cada X é independentemente selecionado do grupo consistindo de um hidrocarbil com 1 a 20 átomos de carbono, hidreto, amido, alcóxido, alquil sulfeto, alquil fosfeto, haleto, dieno, amina, fosfina, éter e combinações dos mesmos; m e n são independentemente um número inteiro de 1 a 4; e L é um grupo de ligação bivalente.
BR112022008102A 2019-10-28 2020-10-28 Complexo de metal bisfenol, método para preparar o complexo de metal bisfenol e uso do complexo de metal bisfenol BR112022008102A2 (pt)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
CN201911032074 2019-10-28
CN201911032096 2019-10-28
CN201911033277 2019-10-28
CN201911032105 2019-10-28
CN201911033274 2019-10-28
PCT/CN2020/124376 WO2021083207A1 (zh) 2019-10-28 2020-10-28 一种双苯酚金属配合物及其制备方法和应用

Publications (1)

Publication Number Publication Date
BR112022008102A2 true BR112022008102A2 (pt) 2022-07-19

Family

ID=75714575

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112022007933A BR112022007933A2 (pt) 2019-10-28 2020-10-28 Catalisador para polimerização de olefinas, uso do catalisador para polimerização de olefinas, processo de homopolimerização de etileno, processo de copolimerização de etileno e polímero de olefina
BR112022008102A BR112022008102A2 (pt) 2019-10-28 2020-10-28 Complexo de metal bisfenol, método para preparar o complexo de metal bisfenol e uso do complexo de metal bisfenol

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BR112022007933A BR112022007933A2 (pt) 2019-10-28 2020-10-28 Catalisador para polimerização de olefinas, uso do catalisador para polimerização de olefinas, processo de homopolimerização de etileno, processo de copolimerização de etileno e polímero de olefina

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US (2) US20220380397A1 (pt)
EP (2) EP4053168A4 (pt)
JP (2) JP2023501197A (pt)
KR (2) KR20220092932A (pt)
CN (2) CN114599685B (pt)
BR (2) BR112022007933A2 (pt)
CA (2) CA3159350A1 (pt)
WO (2) WO2021083207A1 (pt)

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CN113264963A (zh) * 2021-05-19 2021-08-17 青岛科技大学 一种耐高温高活性限定几何构型催化剂的制备与应用

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KR100287955B1 (ko) * 1998-06-08 2001-05-02 유현식 올레핀계 또는 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한 중합방법
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Also Published As

Publication number Publication date
WO2021083194A1 (zh) 2021-05-06
BR112022007933A2 (pt) 2022-07-12
US20220372177A1 (en) 2022-11-24
KR20220092932A (ko) 2022-07-04
EP4053168A4 (en) 2023-11-29
US20220380397A1 (en) 2022-12-01
CA3159336A1 (en) 2021-05-06
CA3159350A1 (en) 2021-05-06
EP4053167A1 (en) 2022-09-07
CN114599685B (zh) 2023-11-24
JP2023501197A (ja) 2023-01-18
WO2021083207A1 (zh) 2021-05-06
CN114945602A (zh) 2022-08-26
CN114945602B (zh) 2024-06-11
CN114599685A (zh) 2022-06-07
EP4053167A4 (en) 2023-11-29
EP4053168A1 (en) 2022-09-07
KR20220093147A (ko) 2022-07-05
JP2023501196A (ja) 2023-01-18

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