BR112016017322A2 - Complexo metálico, sistema de catalisador, processo para a preparação de um polímero - Google Patents

Complexo metálico, sistema de catalisador, processo para a preparação de um polímero

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Publication number
BR112016017322A2
BR112016017322A2 BR112016017322A BR112016017322A BR112016017322A2 BR 112016017322 A2 BR112016017322 A2 BR 112016017322A2 BR 112016017322 A BR112016017322 A BR 112016017322A BR 112016017322 A BR112016017322 A BR 112016017322A BR 112016017322 A2 BR112016017322 A2 BR 112016017322A2
Authority
BR
Brazil
Prior art keywords
ligand
formula
range
metal
polymer
Prior art date
Application number
BR112016017322A
Other languages
English (en)
Other versions
BR112016017322B1 (pt
Inventor
Gerardus Henricus Josephus Doremaele Van
Berthoud Alexandra
Quiroga Norambuena Victor
Rupnicki Leszek
Karbaum Peter
Original Assignee
Arlanxeo Netherlands Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arlanxeo Netherlands Bv filed Critical Arlanxeo Netherlands Bv
Publication of BR112016017322A2 publication Critical patent/BR112016017322A2/pt
Publication of BR112016017322B1 publication Critical patent/BR112016017322B1/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/02—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings
    • C08F32/04—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings having one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

COMPLEXO METÁLICO, SISTEMA DE CATALISADOR, PROCESSO PARA A PREPARAÇÃO DE UM POLÍMERO. A presente invenção se refere a um complexo metálico A da fórmula (1), CyYMLjXn (fórmula 1), em que Cy é um ligante do tipo ciclopentadienila; M é um metal do grupo 4; L é um ligante base de Lewis neutro em que o número dos ditos ligantes neutros "j" está na faixa de 0 até a quantidade que satisfaz a regra dos 18 elétrons; X é um ligante aniônico; n é um número inteiro que denota o número de ligantes aniônicos X e é 1 ou 2, de preferência, é 2; Y é uma porção química de ligante que contém amidina cíclica representada pela fórmula (2), em que o ligante que contém amidina é covalentemente ligado ao metal M por meio do átomo de hidrogênio N2 da imina; S é uma unidade -CH2-, e t é o número inteiro que denota o número de S e está na faixa de 1 a 4, mais preferencialmente, na faixa de 1 a 2, com máxima preferência, é 1; Sub1 é um substituinte linear ou cíclico alifático que compreende um átomo do grupo 14 através do qual o Sub1 é ligado ao átomo de hidrogênio N1 da amina; Sub2 é uma unidade C2 opcionalmente substituída, em que os 2 átomos de carbono podem ser hibridizados em sp2 ou sp3.
BR112016017322-8A 2014-01-29 2015-01-27 complexo metálico, sistema de catalisador, processo para a preparação de um polímero BR112016017322B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14153077.4A EP2902420B1 (en) 2014-01-29 2014-01-29 Metal complex with a cyclic amidine ligand
EP14153077.4 2014-01-29
PCT/EP2015/051571 WO2015113957A1 (en) 2014-01-29 2015-01-27 Metal complex with a cyclic amidine ligand

Publications (2)

Publication Number Publication Date
BR112016017322A2 true BR112016017322A2 (pt) 2017-08-08
BR112016017322B1 BR112016017322B1 (pt) 2021-06-08

Family

ID=50033344

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112016017322-8A BR112016017322B1 (pt) 2014-01-29 2015-01-27 complexo metálico, sistema de catalisador, processo para a preparação de um polímero

Country Status (8)

Country Link
US (1) US9994647B2 (pt)
EP (1) EP2902420B1 (pt)
JP (1) JP6363719B2 (pt)
KR (1) KR102398933B1 (pt)
CN (1) CN105940008B (pt)
BR (1) BR112016017322B1 (pt)
CA (1) CA2937416C (pt)
WO (1) WO2015113957A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3272761A1 (en) 2016-07-22 2018-01-24 Arlanxeo Netherlands B.V. Metall complex comprising amidine and substituted cyclopentadienyl ligands
CN111032772B (zh) 2017-06-14 2022-07-15 埃克森美孚化学专利公司 用于交联应用的乙烯共聚物共混物
WO2019132687A1 (en) * 2017-12-25 2019-07-04 Arlanxeo Netherlands B.V. Metal complex comprising amidine and thiophene fused cyclopentadienyl ligands
JP7175692B2 (ja) * 2018-03-26 2022-11-21 三井化学株式会社 オレフィン重合用触媒、およびオレフィン重合体の製造方法
WO2019203676A1 (en) * 2018-04-16 2019-10-24 Arlanxeo Netherlands B.V. Metal complex comprising amidine and indole fused cyclopentadienyl ligands
CN111377950B (zh) * 2020-04-26 2022-05-17 江苏理工学院 一种具有催化性能的磷酸-嘧啶二氯化锌配合物及其制备方法和应用
CN114249801A (zh) * 2021-12-06 2022-03-29 南开大学 一种环肽化合物及其制备方法和应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5502128A (en) * 1994-12-12 1996-03-26 University Of Massachusetts Group 4 metal amidinate catalysts and addition polymerization process using same
US7053157B2 (en) * 2001-07-20 2006-05-30 University Of Maryland, College Park Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity
DE60234353D1 (de) * 2001-09-14 2009-12-24 Sumitomo Chemical Co Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben
US7183364B2 (en) * 2002-12-20 2007-02-27 University Of Maryland, College Park Process for preparation of polyolefins via degenerative transfer polymerization
WO2005090418A1 (en) 2004-03-17 2005-09-29 Dsm Ip Assets B.V. Polimerization catalyst comprising an amidine ligand
KR20120042971A (ko) * 2009-07-14 2012-05-03 레르 리키드 쏘시에떼 아노님 뿌르 레？드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 고온에서의 ⅳ족 금속 함유 막의 퇴적
EP2319874A1 (en) * 2009-11-06 2011-05-11 DSM IP Assets B.V. Catalyst component for the polymerization of olefins having a guanidinate ligand
EP2336204A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand
EP2336205A1 (en) * 2009-12-21 2011-06-22 DSM IP Assets B.V. TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
US20130131294A1 (en) * 2011-11-21 2013-05-23 John R. Hagadorn Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom
EP2801579B1 (en) * 2013-05-08 2016-10-19 Arlanxeo Netherlands B.V. Metal complex with a Lewis base ligand
EP2857423B1 (en) * 2013-10-07 2020-09-16 Arlanxeo Netherlands B.V. Catalyst system

Also Published As

Publication number Publication date
CN105940008A (zh) 2016-09-14
JP6363719B2 (ja) 2018-07-25
CA2937416C (en) 2022-08-23
US20160347873A1 (en) 2016-12-01
EP2902420B1 (en) 2019-06-12
KR102398933B1 (ko) 2022-05-17
JP2017509595A (ja) 2017-04-06
CN105940008B (zh) 2019-06-25
BR112016017322B1 (pt) 2021-06-08
EP2902420A1 (en) 2015-08-05
US9994647B2 (en) 2018-06-12
CA2937416A1 (en) 2015-08-06
WO2015113957A1 (en) 2015-08-06
KR20160114600A (ko) 2016-10-05

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Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 27/01/2015, OBSERVADAS AS CONDICOES LEGAIS.