BR112015027980A8 - Complexo de metal, processo para produzir o complexo de metal, sistema de catalisador, e processo para preparar um polímero - Google Patents
Complexo de metal, processo para produzir o complexo de metal, sistema de catalisador, e processo para preparar um polímeroInfo
- Publication number
- BR112015027980A8 BR112015027980A8 BR112015027980A BR112015027980A BR112015027980A8 BR 112015027980 A8 BR112015027980 A8 BR 112015027980A8 BR 112015027980 A BR112015027980 A BR 112015027980A BR 112015027980 A BR112015027980 A BR 112015027980A BR 112015027980 A8 BR112015027980 A8 BR 112015027980A8
- Authority
- BR
- Brazil
- Prior art keywords
- metal complex
- ligand
- metal
- group
- preparing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
- C07F7/28—Titanium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Inorganic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
COMPLEXO DE METAL, PROCESSO PARA PRODUZIR O COMPLEXO DE METAL, SISTEMA DE CATALISADOR, E PROCESSO PARA PREPARAR UM POLÍMERO. Um complexo de metal da fórmula (1) CyAMX(L)n em que Cy representa um ligante do tipo ciclopentadienila, M é um metal do grupo 4; A é uma fração de ligante contendo amidina, representada pela fórmula 2: em que o ligante contendo amidina está covalentemente ligado ao metal M através do átomo de nitrogênio da imina, e Sub1 é um substituinte compreendendo um átomo do grupo 14, através do qual Sub1 é ligado ao átomo de carbono da imina e Sub2 é um substituinte compreendendo um heteroátomo do grupo 15, por meio do qual Sub2 é ligado ao átomo de carbono imina; X é um ligante de borato de alila derivado de um ligante de dieno conjugado, D, e um borano, B e L é um ligante básico de Lewis neutro, em que o número dos ditos ligantes de metal "n" está na faixa de 1 à quantidade que especifica a regra dos 18 elétrons.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13167138.0 | 2013-05-08 | ||
EP13167138.0A EP2801579B1 (en) | 2013-05-08 | 2013-05-08 | Metal complex with a Lewis base ligand |
PCT/EP2014/059354 WO2014180913A1 (en) | 2013-05-08 | 2014-05-07 | Metal complex with a lewis base ligand |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112015027980A2 BR112015027980A2 (pt) | 2017-09-05 |
BR112015027980A8 true BR112015027980A8 (pt) | 2017-10-03 |
BR112015027980B1 BR112015027980B1 (pt) | 2021-04-13 |
Family
ID=48236797
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015027980-5A BR112015027980B1 (pt) | 2013-05-08 | 2014-05-07 | Complexo de metal, processo para produzir o complexo de metal, sistema de catalisador, e processo para preparar um polímero |
Country Status (9)
Country | Link |
---|---|
US (1) | US9546233B2 (pt) |
EP (1) | EP2801579B1 (pt) |
JP (1) | JP6243517B2 (pt) |
KR (1) | KR102200242B1 (pt) |
CN (1) | CN105209473A (pt) |
BR (1) | BR112015027980B1 (pt) |
CA (1) | CA2909927C (pt) |
SA (1) | SA515370102B1 (pt) |
WO (1) | WO2014180913A1 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2902420B1 (en) * | 2014-01-29 | 2019-06-12 | Arlanxeo Netherlands B.V. | Metal complex with a cyclic amidine ligand |
EP3272761A1 (en) * | 2016-07-22 | 2018-01-24 | Arlanxeo Netherlands B.V. | Metall complex comprising amidine and substituted cyclopentadienyl ligands |
KR101927184B1 (ko) | 2016-12-09 | 2018-12-10 | 현대자동차 주식회사 | 엔진 시스템의 진단 방법 및 장치 |
EP3638730B1 (en) | 2017-06-14 | 2024-05-01 | ExxonMobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
US11132621B2 (en) * | 2017-11-15 | 2021-09-28 | International Business Machines Corporation | Correction of reaction rules databases by active learning |
WO2019203676A1 (en) * | 2018-04-16 | 2019-10-24 | Arlanxeo Netherlands B.V. | Metal complex comprising amidine and indole fused cyclopentadienyl ligands |
CN112703208B (zh) * | 2018-09-18 | 2023-02-24 | 阿朗新科荷兰有限公司 | 催化剂混合物 |
KR102509512B1 (ko) * | 2020-06-29 | 2023-03-14 | 포리프라스틱 가부시키가이샤 | 환상 올레핀 공중합체의 제조방법, 및 노보넨 단량체와 에틸렌의 공중합용 촉매 조성물 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6100414A (en) * | 1998-04-02 | 2000-08-08 | Eastman Chemical Company | Cyclopentadienyl transition metal compounds useful as polymerization catalysts |
CN1409729A (zh) * | 1999-12-10 | 2003-04-09 | 陶氏环球技术公司 | 取代的第4族金属配合物,催化剂和烯烃聚合方法 |
ATE448237T1 (de) * | 2001-09-14 | 2009-11-15 | Sumitomo Chemical Co | Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben |
KR101289564B1 (ko) | 2004-03-17 | 2013-07-24 | 란세스 엘라스토머즈 비.브이. | 아미딘 리간드를 포함하는 중합촉매 |
EP2336205A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | TI catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand |
EP2336204A1 (en) * | 2009-12-21 | 2011-06-22 | DSM IP Assets B.V. | Borane activated ti catalyst system comprising amidine and diene ligand |
KR101827023B1 (ko) * | 2010-02-19 | 2018-02-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 금속-리간드 착체 및 촉매 |
DE102011105918A1 (de) * | 2010-06-29 | 2012-01-05 | Sumitomo Chemical Company, Limited | Übergangsmetallverbindung und Katalysator zur Olefinpolymerisation |
-
2013
- 2013-05-08 EP EP13167138.0A patent/EP2801579B1/en active Active
-
2014
- 2014-05-07 BR BR112015027980-5A patent/BR112015027980B1/pt active IP Right Grant
- 2014-05-07 JP JP2016512365A patent/JP6243517B2/ja active Active
- 2014-05-07 CN CN201480026296.2A patent/CN105209473A/zh active Pending
- 2014-05-07 WO PCT/EP2014/059354 patent/WO2014180913A1/en active Application Filing
- 2014-05-07 US US14/889,596 patent/US9546233B2/en active Active
- 2014-05-07 CA CA2909927A patent/CA2909927C/en active Active
- 2014-05-07 KR KR1020157031675A patent/KR102200242B1/ko active IP Right Grant
-
2015
- 2015-11-05 SA SA515370102A patent/SA515370102B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
BR112015027980A2 (pt) | 2017-09-05 |
US9546233B2 (en) | 2017-01-17 |
SA515370102B1 (ar) | 2016-12-18 |
CN105209473A (zh) | 2015-12-30 |
EP2801579B1 (en) | 2016-10-19 |
KR20160016775A (ko) | 2016-02-15 |
WO2014180913A1 (en) | 2014-11-13 |
JP6243517B2 (ja) | 2017-12-06 |
CA2909927A1 (en) | 2014-11-13 |
CA2909927C (en) | 2021-10-19 |
US20160115265A1 (en) | 2016-04-28 |
EP2801579A1 (en) | 2014-11-12 |
JP2016527182A (ja) | 2016-09-08 |
BR112015027980B1 (pt) | 2021-04-13 |
KR102200242B1 (ko) | 2021-01-11 |
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Legal Events
Date | Code | Title | Description |
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B25D | Requested change of name of applicant approved |
Owner name: ARLANXEO NETHERLANDS B.V. (NL) |
|
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/05/2014, OBSERVADAS AS CONDICOES LEGAIS. |