WO2014180913A1 - Metal complex with a lewis base ligand - Google Patents

Metal complex with a lewis base ligand Download PDF

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Publication number
WO2014180913A1
WO2014180913A1 PCT/EP2014/059354 EP2014059354W WO2014180913A1 WO 2014180913 A1 WO2014180913 A1 WO 2014180913A1 EP 2014059354 W EP2014059354 W EP 2014059354W WO 2014180913 A1 WO2014180913 A1 WO 2014180913A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
metal complex
borane
ligand
formula
Prior art date
Application number
PCT/EP2014/059354
Other languages
English (en)
French (fr)
Inventor
Richard Thomas William SCOTT
Martin Alexander Zuideveld
Philip Mountford
Original Assignee
Lanxess Elastomers B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Elastomers B.V. filed Critical Lanxess Elastomers B.V.
Priority to KR1020157031675A priority Critical patent/KR102200242B1/ko
Priority to CA2909927A priority patent/CA2909927C/en
Priority to JP2016512365A priority patent/JP6243517B2/ja
Priority to US14/889,596 priority patent/US9546233B2/en
Priority to CN201480026296.2A priority patent/CN105209473A/zh
Priority to BR112015027980-5A priority patent/BR112015027980B1/pt
Publication of WO2014180913A1 publication Critical patent/WO2014180913A1/en
Priority to SA515370102A priority patent/SA515370102B1/ar

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/28—Titanium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Inorganic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
PCT/EP2014/059354 2013-05-08 2014-05-07 Metal complex with a lewis base ligand WO2014180913A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1020157031675A KR102200242B1 (ko) 2013-05-08 2014-05-07 루이스 염기 리간드를 갖는 금속 착물
CA2909927A CA2909927C (en) 2013-05-08 2014-05-07 Metal complex with a lewis base ligand
JP2016512365A JP6243517B2 (ja) 2013-05-08 2014-05-07 ルイス塩基配位子を含む金属錯体
US14/889,596 US9546233B2 (en) 2013-05-08 2014-05-07 Metal complex with a lewis base ligand
CN201480026296.2A CN105209473A (zh) 2013-05-08 2014-05-07 具有路易斯碱配体的金属络合物
BR112015027980-5A BR112015027980B1 (pt) 2013-05-08 2014-05-07 Complexo de metal, processo para produzir o complexo de metal, sistema de catalisador, e processo para preparar um polímero
SA515370102A SA515370102B1 (ar) 2013-05-08 2015-11-05 حفاز مزود بمركب لويس ترابطي قاعدي

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13167138.0A EP2801579B1 (en) 2013-05-08 2013-05-08 Metal complex with a Lewis base ligand
EP13167138.0 2013-05-08

Publications (1)

Publication Number Publication Date
WO2014180913A1 true WO2014180913A1 (en) 2014-11-13

Family

ID=48236797

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/059354 WO2014180913A1 (en) 2013-05-08 2014-05-07 Metal complex with a lewis base ligand

Country Status (9)

Country Link
US (1) US9546233B2 (pt)
EP (1) EP2801579B1 (pt)
JP (1) JP6243517B2 (pt)
KR (1) KR102200242B1 (pt)
CN (1) CN105209473A (pt)
BR (1) BR112015027980B1 (pt)
CA (1) CA2909927C (pt)
SA (1) SA515370102B1 (pt)
WO (1) WO2014180913A1 (pt)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2902420B1 (en) * 2014-01-29 2019-06-12 Arlanxeo Netherlands B.V. Metal complex with a cyclic amidine ligand
EP3272761A1 (en) * 2016-07-22 2018-01-24 Arlanxeo Netherlands B.V. Metall complex comprising amidine and substituted cyclopentadienyl ligands
KR101927184B1 (ko) 2016-12-09 2018-12-10 현대자동차 주식회사 엔진 시스템의 진단 방법 및 장치
US11132621B2 (en) * 2017-11-15 2021-09-28 International Business Machines Corporation Correction of reaction rules databases by active learning
WO2019203676A1 (en) * 2018-04-16 2019-10-24 Arlanxeo Netherlands B.V. Metal complex comprising amidine and indole fused cyclopentadienyl ligands
JP2022500534A (ja) 2018-09-18 2022-01-04 アランセオ・ネザーランズ・ベー・フェー 触媒混合物
US11795256B2 (en) * 2020-06-29 2023-10-24 Polyplastics Co., Ltd. Production method for cyclic olefin copolymer and catalyst composition for copolymerization of norbornene monomer and ethylene

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005090418A1 (en) 2004-03-17 2005-09-29 Dsm Ip Assets B.V. Polimerization catalyst comprising an amidine ligand
WO2011076775A1 (en) 2009-12-21 2011-06-30 Dsm Ip Assets B.V. Ti catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
WO2011076772A1 (en) 2009-12-21 2011-06-30 Dsm Ip Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6100414A (en) * 1998-04-02 2000-08-08 Eastman Chemical Company Cyclopentadienyl transition metal compounds useful as polymerization catalysts
WO2001042315A1 (en) * 1999-12-10 2001-06-14 Dow Global Technologies Inc. Substituted group 4 metal complexes, catalysts and olefin polymerization process
WO2003024983A1 (fr) * 2001-09-14 2003-03-27 Sumitomo Chemical Company, Limited Complexe de metal de transition, catalyseur pour la polymerisation d'olefines et procede de production de polymere olefinique
JP5837514B2 (ja) * 2010-02-19 2015-12-24 ダウ グローバル テクノロジーズ エルエルシー 金属−配位子錯体及び触媒
DE102011105918A1 (de) * 2010-06-29 2012-01-05 Sumitomo Chemical Company, Limited Übergangsmetallverbindung und Katalysator zur Olefinpolymerisation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005090418A1 (en) 2004-03-17 2005-09-29 Dsm Ip Assets B.V. Polimerization catalyst comprising an amidine ligand
WO2011076775A1 (en) 2009-12-21 2011-06-30 Dsm Ip Assets B.V. Ti catalyst system comprising substituted cyclopentadienyl, amidine and diene ligand
WO2011076772A1 (en) 2009-12-21 2011-06-30 Dsm Ip Assets B.V. Borane activated ti catalyst system comprising amidine and diene ligand

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
COWLEY ET AL., ORGANOMETALLICS, vol. 20, 2001, pages 177
E. Y-X. CHEN; T.J. MARKS, CHEM. REV., vol. 100, 2000, pages 1391
ERKER ET AL., ADV. ORGANOMET. CHEM., vol. 24, 1985, pages 1
KISSOUNKO D A ET AL: "Synthesis and characterization of cationic and zwitterionic allyl zirconium complexes derived from trimethylenemethane (TMM) cyclopentadienylzirconium acetamidinates", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 683, no. 1, 7 October 2003 (2003-10-07), pages 29 - 38, XP004460550, ISSN: 0022-328X, DOI: 10.1016/S0022-328X(03)00315-2 *
YASUDA ET AL., ACC. CHEM. RES., vol. 18, 1985, pages 120
YASUDA ET AL., ORGANOMETALLICS, vol. 1, 1982, pages 388

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018231224A1 (en) 2017-06-14 2018-12-20 Exxonmobil Chemical Patents Inc. Ethylene copolymer blends for cross-linking applications

Also Published As

Publication number Publication date
CA2909927A1 (en) 2014-11-13
JP2016527182A (ja) 2016-09-08
BR112015027980A8 (pt) 2017-10-03
SA515370102B1 (ar) 2016-12-18
BR112015027980A2 (pt) 2017-09-05
KR102200242B1 (ko) 2021-01-11
CA2909927C (en) 2021-10-19
CN105209473A (zh) 2015-12-30
KR20160016775A (ko) 2016-02-15
EP2801579B1 (en) 2016-10-19
US9546233B2 (en) 2017-01-17
BR112015027980B1 (pt) 2021-04-13
US20160115265A1 (en) 2016-04-28
EP2801579A1 (en) 2014-11-12
JP6243517B2 (ja) 2017-12-06

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