BR112019005028A2 - processo para produção de ácido glicólico ou um derivado do mesmo - Google Patents

processo para produção de ácido glicólico ou um derivado do mesmo

Info

Publication number
BR112019005028A2
BR112019005028A2 BR112019005028A BR112019005028A BR112019005028A2 BR 112019005028 A2 BR112019005028 A2 BR 112019005028A2 BR 112019005028 A BR112019005028 A BR 112019005028A BR 112019005028 A BR112019005028 A BR 112019005028A BR 112019005028 A2 BR112019005028 A2 BR 112019005028A2
Authority
BR
Brazil
Prior art keywords
glycolic acid
product stream
sulfur
reactor
alkyl glycolate
Prior art date
Application number
BR112019005028A
Other languages
English (en)
Other versions
BR112019005028B1 (pt
Inventor
John Watson David
Roberts Dena
Swinney John
Original Assignee
Johnson Matthey Davy Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson Matthey Davy Technologies Ltd filed Critical Johnson Matthey Davy Technologies Ltd
Publication of BR112019005028A2 publication Critical patent/BR112019005028A2/pt
Publication of BR112019005028B1 publication Critical patent/BR112019005028B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/145—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide with simultaneous oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/01—Saturated compounds having only one carboxyl group and containing hydroxy or O-metal groups
    • C07C59/06—Glycolic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
    • C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
    • C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

um processo para a produção de ácido glicólico ou um derivado do mesmo compreende: reagir formaldeído com monóxido de carbono e água em um reator de carbonilação na presença de um catalisador de enxofre, o dito reator operando sob condições adequadas, de modo que ácido glicólico é formado; recuperar uma primeira corrente de produto compreendendo ácido glicólico, impurezas e uma espécie de enxofre no reator de carbonilação; passar a primeira corrente de produto para um reator de esterificação onde ela é submetida a esterificação para formar um glicolato de alquila e em que a esterificação é catalisada pela espécie de enxofre recuperada na primeira corrente de produto; recuperar uma segunda corrente de produto que compreende o glicolato de alquila, a espécie de enxofre e as impurezas do reator de esterificação; separar a espécie de enxofre da segunda corrente de produto e reciclá-la para o reator de carbonilação na etapa (a) para formar uma segunda corrente de produto com enxofre empobrecido; separar o glicolato de alquila a partir da segunda corrente de produto com enxofre empobrecido em uma zona de destilação; e recuperar o glicolato de alquila e converter o glicolato de alquila em ácido glicólico.
BR112019005028-0A 2016-09-16 2017-09-15 Processo para produção de ácido glicólico ou um derivado do mesmo BR112019005028B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1615762.0 2016-09-16
GBGB1615762.0A GB201615762D0 (en) 2016-09-16 2016-09-16 Process
PCT/GB2017/052740 WO2018051115A1 (en) 2016-09-16 2017-09-15 Process for the production of glycolic acid

Publications (2)

Publication Number Publication Date
BR112019005028A2 true BR112019005028A2 (pt) 2019-06-18
BR112019005028B1 BR112019005028B1 (pt) 2022-12-13

Family

ID=57288828

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112019005028-0A BR112019005028B1 (pt) 2016-09-16 2017-09-15 Processo para produção de ácido glicólico ou um derivado do mesmo

Country Status (11)

Country Link
US (2) US10640443B2 (pt)
EP (1) EP3512828B1 (pt)
JP (1) JP6953518B2 (pt)
KR (1) KR102449054B1 (pt)
CN (1) CN109715596B (pt)
AU (1) AU2017327999B2 (pt)
BR (1) BR112019005028B1 (pt)
EA (1) EA036428B1 (pt)
GB (2) GB201615762D0 (pt)
WO (1) WO2018051115A1 (pt)
ZA (1) ZA201901641B (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3116451C (en) * 2018-10-29 2023-05-23 Pujing Chemical Industry Co., Ltd Glycolide production with low solid residue
US20220306563A1 (en) * 2019-06-27 2022-09-29 Rhodia Operations Method for preparing glycolic acid
CN112521265B (zh) * 2020-12-09 2022-08-09 浙江联盛化学股份有限公司 一种连续化生产乙醇酸的方法
CN114853605B (zh) * 2021-02-03 2024-03-19 中国科学院大连化学物理研究所 甲氧基乙酸甲酯和甲氧基乙酸水解制取乙醇酸和乙醇酸甲酯的方法
CN113952906A (zh) * 2021-10-27 2022-01-21 南京延长反应技术研究院有限公司 一种制备羟基乙酸的微界面反应装置及方法
CN114057564B (zh) * 2021-12-09 2023-10-03 上海卓笙环保科技有限公司 一种基于碳酸体系作为无痕催化剂水解乙醇酸酯的方法
GB202201979D0 (en) 2022-02-15 2022-03-30 Johnson Matthey Plc Process
CN115160122A (zh) * 2022-08-26 2022-10-11 东华工程科技股份有限公司 一种乙醇酸甲酯水解制乙醇酸的新工艺

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2152852A (en) 1936-12-31 1939-04-04 Du Pont Process for manufacture of glycolic acid
US2285444A (en) 1940-06-14 1942-06-09 American Automatic Typewriter Link connection for automatic typewriters
US2443482A (en) 1946-08-06 1948-06-15 Du Pont Continuous glycolic acid process
US3859349A (en) * 1973-02-15 1975-01-07 Du Pont Purification of hydroxyacetic acid
US3911003A (en) 1974-06-19 1975-10-07 Chevron Res Process for the production of glycolic acid and oxydiacetic acid
US4016208A (en) 1974-06-19 1977-04-05 Chevron Research Company Acid production
IT1017804B (it) 1974-08-01 1977-08-10 Montedison Spa Procedimento per la preparazione di acido glicolico e suoi polimeri
CA1077517A (en) 1975-04-23 1980-05-13 Ppg Industries, Inc. Process for the preparation of hydroxy-carboxylic acids and derivatives
US4087470A (en) 1976-06-23 1978-05-02 Chevron Research Company Process for the production of ethylene glycol
DE2652072A1 (de) 1976-11-15 1978-05-24 Hoechst Ag Verfahren zur herstellung von glykolsaeureestern
US4188494A (en) 1977-04-25 1980-02-12 Chevron Research Company Hydrogen fluoride removal from glycolic acid
US4136112A (en) 1977-06-24 1979-01-23 Chevron Research Company Process for preparing glycolic acid from formaldehyde using acetic acid
US4140866A (en) 1978-03-30 1979-02-20 Ppg Industries, Inc. Preparation of sulfate free glycolic acid ester
JPS5673042A (en) 1979-11-20 1981-06-17 Mitsubishi Gas Chem Co Inc Preparation of glycolic acid
US4431997A (en) 1981-02-18 1984-02-14 Motorola Inc. Compound element for image element antennas
DE3133353C2 (de) 1981-08-22 1985-07-18 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Glykolsäure oder ihrer Ester
US4431486A (en) 1982-04-12 1984-02-14 E. I. Du Pont De Nemours And Company Azeotropic distillation of hydroxyacetic acid
JPS59139341A (ja) 1983-01-20 1984-08-10 Mitsubishi Gas Chem Co Inc ヒドロキシカルボン酸誘導体の製造方法
JPS60260538A (ja) * 1984-06-07 1985-12-23 Agency Of Ind Science & Technol グリコ−ル酸エステルの製造法
US4824997A (en) * 1988-01-25 1989-04-25 Monsanto Company Method for preparation of alkyl glycolates
KR950011114B1 (ko) 1991-07-19 1995-09-28 포항종합제철주식회사 메틸글리콜레이트의 제조공정
KR950013078B1 (ko) 1992-10-28 1995-10-24 포항종합제철주식회사 글리콜산 및 글리콜산 에스테르의 제조방법
JP2503178B2 (ja) 1993-01-29 1996-06-05 日揮株式会社 グリコ―ル酸、グリコ―ル酸エステルまたはポリグリコリドの製造方法
KR0124821B1 (ko) 1993-12-24 1997-12-01 조말수 산성 반응 용액중의 메틸글리콜레이트 분리방법
CN1075142C (zh) 1994-04-19 2001-11-21 日本化药株式会社 分散染料组合物及用该组合物对疏水性纤维材料进行染色的方法
KR0155273B1 (ko) 1995-05-24 1998-12-15 김광호 대역 통과 필터 기능을 겸비한 위상 변위 장치 및 그 방법
JPH11335319A (ja) * 1998-05-19 1999-12-07 Nippon Shokubai Co Ltd α−ヒドロキシカルボン酸の製造方法
US6376723B2 (en) 1999-12-29 2002-04-23 Shell Oil Company Process for the carbonylation of formaldehyde
GB0100470D0 (en) 2001-01-09 2001-02-21 Queen Mary & Westfield College Organopolysiloxanes containing phosphonic groups, methods for the production and use thereof
US7005536B2 (en) 2002-07-12 2006-02-28 Nippon Shokubai Co., Ltd. Method for producing diol derivatives
JP3772238B2 (ja) * 2002-07-12 2006-05-10 株式会社日本触媒 α−ヒドロキシカルボン酸の製造方法
JP2004043682A (ja) * 2002-07-12 2004-02-12 Nippon Shokubai Co Ltd ポリグリコール酸の製造方法
JP4195934B2 (ja) * 2004-03-01 2008-12-17 独立行政法人産業技術総合研究所 イオン性液体を用いたグリコール酸およびそのエステルの製造方法
GB0417344D0 (en) 2004-08-04 2004-09-08 Phosphonics Ltd Substituted organopolysiloxanes and use thereof
EP1786850B1 (en) 2004-08-04 2008-11-26 Phosphonics LTD Substituted organopolysiloxanes and use thereof
GB0602811D0 (en) 2006-02-10 2006-03-22 Phosphonics Ltd Substituted Organopolysiloxanes And Use Thereof
GB0720579D0 (en) 2007-10-20 2007-11-28 Phosphonics Ltd Functionalised materials and uses thereof
CN102099323B (zh) 2008-05-20 2016-04-06 中国科学院大连化学物理研究所 乙醇酸的生产方法
WO2009140787A1 (en) 2008-05-20 2009-11-26 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences Process for production of glycolic acid
WO2013148497A1 (en) 2012-03-27 2013-10-03 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
CN103833548A (zh) * 2012-11-20 2014-06-04 中国科学院兰州化学物理研究所 一种乙醇酸甲酯的制备方法
GB201505981D0 (en) 2015-04-08 2015-05-20 Johnson Matthey Davy Technologies Ltd Process
GB201505977D0 (en) 2015-04-08 2015-05-20 Johnson Matthey Davy Technologies Ltd Catalyst system and process

Also Published As

Publication number Publication date
BR112019005028B1 (pt) 2022-12-13
AU2017327999A1 (en) 2019-03-21
JP6953518B2 (ja) 2021-10-27
US20190248724A1 (en) 2019-08-15
EP3512828A1 (en) 2019-07-24
AU2017327999B2 (en) 2020-11-26
CN109715596B (zh) 2022-05-17
US11053186B2 (en) 2021-07-06
GB201615762D0 (en) 2016-11-02
JP2019529422A (ja) 2019-10-17
US20200239395A1 (en) 2020-07-30
US10640443B2 (en) 2020-05-05
GB2559641B (en) 2019-12-04
EA036428B1 (ru) 2020-11-10
EP3512828B1 (en) 2020-11-11
GB201714877D0 (en) 2017-11-01
CN109715596A (zh) 2019-05-03
ZA201901641B (en) 2021-06-30
KR102449054B1 (ko) 2022-09-30
KR20190047019A (ko) 2019-05-07
EA201990731A1 (ru) 2019-08-30
GB2559641A (en) 2018-08-15
WO2018051115A1 (en) 2018-03-22

Similar Documents

Publication Publication Date Title
BR112019005028A2 (pt) processo para produção de ácido glicólico ou um derivado do mesmo
BR112014019944A8 (pt) Método para a produção contínua de um anidrido de ácido
MY156043A (en) Hydrodeoxygenation process
BR112017002723A2 (pt) método para produzir furfural a partir de material de biomassa contendo pentosana.
BR112012010816A2 (pt) processo contínuo para fabricação de policarbonato alifático a partir de dióxido de carbono e compostos epóxido
BR112017005850A2 (pt) processo e aparelho para preparação de um diéster tereftálico.
BR112012028566A2 (pt) processo para produção de álcool integrando corrente de alimentação de ácido acético que compreende água do processo de carbonilação
BR112015009800A2 (pt) processo melhorado de conversão de uma carga contendo a biomassa para a produção de hidrocarbonetos por via de síntese fischer-tropsch
BR112015014162A2 (pt) processo para recuperar e usar ácidos carboxílicos a partir de um caldo de fermentação; método de esterificação para um ácido policarboxílico; e método de processar um produto agrícola ou biomassa
JP2019529422A5 (pt)
BR112012006477A2 (pt) desidratação catalítica de álcoois usando catalisadores ácidos não voláteis.
BR112012025603A2 (pt) sistema e métodos para reciclar plástico.
DE602007002743D1 (de) Verfahren zur Trennung und Reinigung von xanthophyll-Fettsäurestern aus dem Fettharz von Ringelblumen
BR112019007508A2 (pt) processo para a produção de 2-alquilalcanol a partir de um aldeído.
BR112015019829A2 (pt) processo para o preparo de éster de ácido succínico
BR112015019271A2 (pt) processo para o preparo de éster de ácido succínico
BR112018001168A2 (pt) método para produzir um éster alquílico de ácido graxo leve
BRPI0505195A (pt) processo para produção de ésteres salicìlicos
BR112014001306A2 (pt) processo oxo aperfeiçoado e método para produzir gás de síntese de óleo residual
BR112015027995A2 (pt) processos para a preparação contínua dos succinatos de dialquila c1-c3 e para a separação do efluente do reator
BR112013003893A2 (pt) processo de purga de ácido tereftálico
BR112018015652A2 (pt) processo de produção de ésteres (met)acrílicos
BR112017017640A2 (pt) processo de esterificação de um diol usando uma destilação reativa
BR112013003890A2 (pt) processo para aperfeiçoar taxa de filtração de purga de ácido tereftálico
BR112013011438A2 (pt) processo para refinar uma mistura de acetilas bruta

Legal Events

Date Code Title Description
B350 Update of information on the portal [chapter 15.35 patent gazette]
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/09/2017, OBSERVADAS AS CONDICOES LEGAIS