BR112018016979A2 - sistemas e métodos para produção de nitrilas - Google Patents
sistemas e métodos para produção de nitrilasInfo
- Publication number
- BR112018016979A2 BR112018016979A2 BR112018016979A BR112018016979A BR112018016979A2 BR 112018016979 A2 BR112018016979 A2 BR 112018016979A2 BR 112018016979 A BR112018016979 A BR 112018016979A BR 112018016979 A BR112018016979 A BR 112018016979A BR 112018016979 A2 BR112018016979 A2 BR 112018016979A2
- Authority
- BR
- Brazil
- Prior art keywords
- present disclosure
- acid
- methods
- molecule
- production systems
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 150000002825 nitriles Chemical class 0.000 title abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
- ALRHLSYJTWAHJZ-UHFFFAOYSA-N 3-hydroxypropionic acid Chemical compound OCCC(O)=O ALRHLSYJTWAHJZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- -1 ammonium anhydride Chemical class 0.000 abstract 1
- 150000008064 anhydrides Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- UKDLORMZNPQILV-UHFFFAOYSA-N ethyl 3-hydroxypropanoate Chemical compound CCOC(=O)CCO UKDLORMZNPQILV-UHFFFAOYSA-N 0.000 abstract 1
- 229940116333 ethyl lactate Drugs 0.000 abstract 1
- 239000004310 lactic acid Substances 0.000 abstract 1
- 235000014655 lactic acid Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/22—Preparation of carboxylic acid nitriles by reaction of ammonia with carboxylic acids with replacement of carboxyl groups by cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
um aspeto da presente revelação é um método que inclui uma primeira reação de uma molécula de pelo menos um de um ácido carboxílico, um éster de um ácido carboxílico e/ou um anidrido com amônia para formar um nitrila, onde a primeira reação é catalisada usando um catalisador ácido. em algumas modalidades da presente revelação, a molécula pode incluir pelo menos um de ácido acético, ácido lático e/ou ácido 3-hidroxipropriônico (3-hpa). em algumas modalidades da presente revelação, a molécula pode incluir, pelo menos, um de acetato de metila, lactato de etila e/ou 3-hidroxipropanoato de etila (etil 3-hp). em algumas modalidades da presente revelação, o anidrido pode ser anidrido acético.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201662297187P | 2016-02-19 | 2016-02-19 | |
US62/297,187 | 2016-02-19 | ||
US201662437303P | 2016-12-21 | 2016-12-21 | |
US62/437,303 | 2016-12-21 | ||
PCT/US2017/018272 WO2017143124A1 (en) | 2016-02-19 | 2017-02-17 | Systems and methods for producing nitriles |
Publications (3)
Publication Number | Publication Date |
---|---|
BR112018016979A2 true BR112018016979A2 (pt) | 2019-01-15 |
BR112018016979B1 BR112018016979B1 (pt) | 2022-03-15 |
BR112018016979B8 BR112018016979B8 (pt) | 2023-01-10 |
Family
ID=59625443
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018016979A BR112018016979B8 (pt) | 2016-02-19 | 2017-02-17 | Sistemas e métodos para produção de nitrilas |
BR112023022441A BR112023022441A2 (pt) | 2016-02-19 | 2022-03-01 | Sistemas e métodos para produção de nitrilas |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112023022441A BR112023022441A2 (pt) | 2016-02-19 | 2022-03-01 | Sistemas e métodos para produção de nitrilas |
Country Status (5)
Country | Link |
---|---|
US (4) | US11046642B2 (pt) |
EP (2) | EP3416941A4 (pt) |
CN (2) | CN108698983A (pt) |
BR (2) | BR112018016979B8 (pt) |
WO (2) | WO2017143124A1 (pt) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2017143124A1 (en) * | 2016-02-19 | 2017-08-24 | Alliance For Sustainable Energy, Llc | Systems and methods for producing nitriles |
US11732385B2 (en) * | 2018-04-30 | 2023-08-22 | Alliance For Sustainable Energy, Llc | Emulsion polymerization of nitriles and other compounds |
CN111250113A (zh) * | 2018-11-30 | 2020-06-09 | 中国科学院大连化学物理研究所 | 超强酸催化剂在己二酸直接合成己二腈中的应用 |
CN113304764B (zh) * | 2021-05-08 | 2023-09-26 | 大连和源化学科技开发有限公司 | 一种用于乙酸甲酯氨化脱水制乙腈的催化剂及其制备方法 |
CN115819278A (zh) * | 2021-09-17 | 2023-03-21 | 中国石油化工股份有限公司 | 一种制备丁二腈的工艺及系统 |
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JPH03220166A (ja) | 1989-11-30 | 1991-09-27 | Mitsui Toatsu Chem Inc | α,β―不飽和ニトリルの製造方法 |
US5210296A (en) | 1990-11-19 | 1993-05-11 | E. I. Du Pont De Nemours And Company | Recovery of lactate esters and lactic acid from fermentation broth |
JP2893216B2 (ja) * | 1990-11-30 | 1999-05-17 | ライオン株式会社 | 脂肪族ニトリルの製造方法 |
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JP4219483B2 (ja) * | 1998-06-25 | 2009-02-04 | 花王株式会社 | 脂肪族ニトリルの製造方法 |
JP4219484B2 (ja) * | 1998-06-25 | 2009-02-04 | 花王株式会社 | 脂肪族ニトリルの製造方法 |
US6005134A (en) * | 1998-06-25 | 1999-12-21 | Kao Corporation | Process for the preparation of aliphatic nitriles |
JP2002284753A (ja) * | 2001-03-23 | 2002-10-03 | Koei Chem Co Ltd | ニトリル類の製造方法 |
US6982342B2 (en) * | 2002-05-16 | 2006-01-03 | Standard Oil Company | Ammoxidation of carboxylic acids to a mixture of nitriles |
JP4409238B2 (ja) | 2003-09-17 | 2010-02-03 | 花王株式会社 | 脂肪族ニトリルの製造方法 |
WO2007102448A1 (en) * | 2006-03-08 | 2007-09-13 | Kao Corporation | Process for producing aliphatic nitriles |
DE102006039203B4 (de) | 2006-08-22 | 2014-06-18 | Evonik Degussa Gmbh | Verfahren zur Herstellung von durch Kristallisation gereinigter Acrylsäure aus Hydroxypropionsäure sowie Vorrichtung dazu |
FR2912742B1 (fr) | 2007-02-16 | 2010-03-05 | Arkema France | Procede de synthese d'acrylonitrile a partir de glycerol |
MX2012003604A (es) | 2009-09-27 | 2012-09-12 | Opx Biotechnologies Inc | Metodo para producir acido 3-hidroxipropionico y otros productos. |
RU2440331C1 (ru) * | 2010-07-14 | 2012-01-20 | Государственное образовательное учреждение высшего профессионального образования "Томский государственный университет" (ТГУ) | Способ получения ацетонитрила из аммиака и соединений, содержащих ацетильную группу |
EP2598641B1 (en) | 2010-07-26 | 2014-05-21 | Sapphire Energy, Inc. | Process for the recovery of oleaginous compounds from biomass |
EP2614152A4 (en) | 2010-09-07 | 2015-04-15 | Myriant Corp | CATALYTIC DEHYDRATION OF MILKY ACID AND MILKIC ACID ESTERS |
CN103562398A (zh) * | 2011-03-22 | 2014-02-05 | Opx生物工艺学公司 | 化学产品的微生物生产以及相关的组合物、方法和系统 |
FR2983477B1 (fr) | 2011-12-01 | 2013-12-27 | Arkema France | Procede de coupure de chaines grasses insaturees |
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TWI654177B (zh) * | 2013-10-31 | 2019-03-21 | 德商巴斯夫歐洲公司 | 製備羧酸酯的方法及其作爲塑化劑的用途 |
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WO2017143124A1 (en) * | 2016-02-19 | 2017-08-24 | Alliance For Sustainable Energy, Llc | Systems and methods for producing nitriles |
CN113614064A (zh) * | 2019-03-08 | 2021-11-05 | 诺沃梅尔公司 | 用于产生酰胺和腈化合物的集成方法和系统 |
-
2017
- 2017-02-17 WO PCT/US2017/018272 patent/WO2017143124A1/en active Application Filing
- 2017-02-17 CN CN201780011904.6A patent/CN108698983A/zh active Pending
- 2017-02-17 BR BR112018016979A patent/BR112018016979B8/pt active IP Right Grant
- 2017-02-17 US US15/775,632 patent/US11046642B2/en active Active
- 2017-02-17 EP EP17753876.6A patent/EP3416941A4/en active Pending
- 2017-02-17 CN CN202311461547.7A patent/CN117567319A/zh active Pending
-
2021
- 2021-04-23 US US17/239,064 patent/US20210253515A1/en active Pending
- 2021-04-29 US US17/244,172 patent/US20210253516A1/en active Pending
-
2022
- 2022-03-01 BR BR112023022441A patent/BR112023022441A2/pt unknown
- 2022-03-01 EP EP22796322.0A patent/EP4330225A1/en active Pending
- 2022-03-01 WO PCT/US2022/018345 patent/WO2022231697A1/en active Application Filing
-
2024
- 2024-05-17 US US18/666,987 patent/US20240343683A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
US11046642B2 (en) | 2021-06-29 |
CN108698983A (zh) | 2018-10-23 |
US20240343683A1 (en) | 2024-10-17 |
EP3416941A4 (en) | 2019-10-16 |
US20180346411A1 (en) | 2018-12-06 |
EP3416941A1 (en) | 2018-12-26 |
BR112023022441A2 (pt) | 2023-12-26 |
US20210253516A1 (en) | 2021-08-19 |
CN117567319A (zh) | 2024-02-20 |
WO2017143124A1 (en) | 2017-08-24 |
BR112018016979B8 (pt) | 2023-01-10 |
EP4330225A1 (en) | 2024-03-06 |
US20210253515A1 (en) | 2021-08-19 |
BR112018016979B1 (pt) | 2022-03-15 |
WO2022231697A1 (en) | 2022-11-03 |
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