BR112018013543A2 - processo para a preparação de etilenoglicol de açúcares - Google Patents
processo para a preparação de etilenoglicol de açúcaresInfo
- Publication number
- BR112018013543A2 BR112018013543A2 BR112018013543A BR112018013543A BR112018013543A2 BR 112018013543 A2 BR112018013543 A2 BR 112018013543A2 BR 112018013543 A BR112018013543 A BR 112018013543A BR 112018013543 A BR112018013543 A BR 112018013543A BR 112018013543 A2 BR112018013543 A2 BR 112018013543A2
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- ethylene glycol
- composition
- compounds
- sugars ethylene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
- C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/202—Ethylene glycol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/205—1,3-Propanediol; 1,2-Propanediol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
- C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
- B01J2219/00277—Apparatus
- B01J2219/00452—Means for the recovery of reactants or products
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
um processo para a preparação de etilenoglicol e outros compostos hidroxi c1-c3 compreendendo as etapas de hidrogenação de uma composição compreendendo compostos oxigenados c1-c3. em particular, o processo é adequado para a hidrogenação de uma composição compreendendo diferentes compostos oxigenados c1-c3, tais como o produto de uma fragmentação termolítica de uma composição de açúcar.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201600008 | 2016-01-07 | ||
DKPA201600008 | 2016-01-07 | ||
PCT/EP2017/050183 WO2017118686A1 (en) | 2016-01-07 | 2017-01-05 | Process for the preparation of ethylene glycol from sugars |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018013543A2 true BR112018013543A2 (pt) | 2018-12-04 |
BR112018013543B1 BR112018013543B1 (pt) | 2022-02-08 |
Family
ID=59273360
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018013543-7A BR112018013543B1 (pt) | 2016-01-07 | 2017-01-05 | Processos para a preparação do composto hidroxi c1-c3 e sistema para executar continuamente os referidos processos |
Country Status (16)
Country | Link |
---|---|
US (1) | US10759726B2 (pt) |
EP (1) | EP3400208B1 (pt) |
JP (1) | JP6975152B2 (pt) |
KR (1) | KR20180100613A (pt) |
CN (1) | CN108473401B (pt) |
AU (1) | AU2017205265B2 (pt) |
BR (1) | BR112018013543B1 (pt) |
CA (1) | CA3010748C (pt) |
DK (1) | DK3400208T3 (pt) |
MX (1) | MX2018007750A (pt) |
PL (1) | PL3400208T3 (pt) |
RU (1) | RU2737159C2 (pt) |
TW (1) | TWI739786B (pt) |
UA (1) | UA123827C2 (pt) |
WO (1) | WO2017118686A1 (pt) |
ZA (1) | ZA201803648B (pt) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102019113135A1 (de) * | 2019-05-17 | 2020-11-19 | Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen | Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen |
CA3154686A1 (en) | 2019-09-24 | 2021-04-01 | Iowa Corn Promotion Board | Methods for operating continuous, unmodulated, multiple catalytic step processes |
US11680031B2 (en) | 2020-09-24 | 2023-06-20 | T. EN Process Technology, Inc. | Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2054601C3 (de) * | 1970-11-06 | 1980-02-14 | Ruhrchemie Ag, 4200 Oberhausen- Holten | Verfahren zur Herstellung von zweiwertigen Alkoholen |
US4200765A (en) | 1976-09-17 | 1980-04-29 | National Distillers And Chemical Corporation | Glycol aldehyde and ethylene glycol processes |
EP0002908B1 (en) | 1977-12-16 | 1982-05-12 | Monsanto Company | Hydroformylation of formaldehyde with rhodium catalyst |
US4321141A (en) * | 1979-06-01 | 1982-03-23 | Corning Glass Works | Method for processing waste |
US4317946A (en) * | 1980-06-27 | 1982-03-02 | The Halcon Sd Group, Inc. | Process for producing ethylene glycol via catalytic hydrogenation of glycolaldehyde |
US4321414A (en) * | 1980-08-26 | 1982-03-23 | The Halcon Sd Group, Inc. | Catalytic hydrogenation of glycolaldehyde to produce ethylene glycol |
US4496781A (en) * | 1984-04-05 | 1985-01-29 | The Halcon Sd Group, Inc. | Process for the production of ethylene glycol through the hydroformylation of glycol aldehyde |
US4762817A (en) | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
US5210337A (en) | 1988-12-15 | 1993-05-11 | Hoechst Celanese Corporation | Formaldehyde resistant catalyst for hydrogenation and hydrogenolysis of aldehydes, acetals, and esters |
US5252188A (en) | 1990-03-26 | 1993-10-12 | Red Arrow Products Company, Inc. | Process for producing hydroxyacetaldehyde |
DE4014261A1 (de) | 1990-05-04 | 1991-11-07 | Basf Ag | Expandierbare styrolpolymerisate |
DE4218282A1 (de) * | 1992-06-03 | 1993-12-09 | Degussa | Verfahren zur Herstellung von 1,3-Propandiol |
FI102474B1 (fi) | 1996-12-30 | 1998-12-15 | Neste Oy | Menetelmä moniarvoisten alkoholien valmistamiseksi |
EP1109767B1 (en) * | 1998-09-04 | 2003-03-26 | E.I. Du Pont De Nemours And Company | Two-stage process for the production of 1,3-propanediol by catalytic hydrogenation of 3-hydroxypropanal |
FR2789683B1 (fr) | 1999-02-17 | 2002-02-15 | Roquette Freres | Procede continu de preparation d'un ose hydrogene de haute purete par hydrogenation catalytique |
CA2326471A1 (en) * | 2000-11-20 | 2002-05-20 | Resource Transforms International Ltd. | Production of glycolaldehyde by hydrous thermolysis of sugars |
AU2002240870A1 (en) * | 2000-12-23 | 2002-07-08 | Degussa Ag | Method for producing alcohols by hydrogenating carbonyl compounds |
US7663004B2 (en) * | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
MXPA06003819A (es) * | 2003-10-07 | 2006-08-11 | Shell Int Research | Proceso para la produccion de 1,3-propanodiol por hidrogenacion catalitica de 3-hidroxipropanal en la presencia de un co-catalizador de hidratacion. |
CA2549456A1 (en) | 2003-12-16 | 2005-06-30 | Shell Internationale Research Maatschappij B.V. | Process of preparing glycolaldehyde |
US7619119B2 (en) | 2006-06-07 | 2009-11-17 | The Procter & Gamble Company | Processes for converting glycerol to amino alcohols |
US20080045749A1 (en) | 2006-06-07 | 2008-02-21 | The Procter & Gamble Company | Process for the alternating conversion of glycerol to propylene glycol or amino alcohols |
US7928148B2 (en) | 2006-10-23 | 2011-04-19 | Archer Daniels Midland Company | Hydrogenolysis of glycerol and products produced therefrom |
CN100497274C (zh) * | 2007-01-25 | 2009-06-10 | 中国林业科学研究院林产化学工业研究所 | 一种甘油法制备1,3-丙二醇的方法 |
FR2925046A1 (fr) | 2007-12-14 | 2009-06-19 | Rhodia Poliamida E Especialidades Ltda | Procede d'obtention d'alcool a partir d'un aldehyde |
US20140024769A1 (en) | 2012-05-11 | 2014-01-23 | Metabolix, Inc. | Process for making chemical derivatives |
EP2539309B1 (en) * | 2010-02-26 | 2016-08-03 | Council Of Scientific&industrial Research (An Indian Registered body incorporated under the Registration of Societies Act(Act XXXI of 1860) | A process for preparation of hydroxyacetone or propylene glycol |
CN102190562B (zh) | 2010-03-17 | 2014-03-05 | 中国科学院大连化学物理研究所 | 一种多羟基化合物制乙二醇的方法 |
CN102649081B (zh) | 2011-02-25 | 2014-11-26 | 中国石油化工股份有限公司 | 草酸酯加氢制备乙二醇催化剂还原的方法 |
CN103402955B (zh) | 2011-03-14 | 2016-02-10 | 阿彻丹尼尔斯米德兰德公司 | 用于产生生物衍生的丙二醇的改进的方法 |
US8969632B2 (en) | 2012-03-23 | 2015-03-03 | Eastman Chemical Company | Passivation of a homogeneous hydrogenation catalyst for the production of ethylene glycol |
ITTO20130833A1 (it) | 2013-10-16 | 2015-04-17 | Biochemtex Spa | Procedimento per la produzione di polioli |
CN106573860B (zh) * | 2014-04-09 | 2020-10-27 | 马来西亚国家石油公司 | 含糖类的原料选择性转化为乙二醇的方法 |
TWI508937B (zh) | 2014-04-30 | 2015-11-21 | Chien An Chen | 使用甲醇為原料經由甲醛、乙醇醛的中間產物而合成乙二醇的製造方法 |
CA2949512C (en) * | 2014-05-19 | 2020-08-18 | Iowa Corn Promotion Board | Process for the continuous production of ethylene glycol from carbohydrates |
DK3160927T3 (da) | 2014-06-30 | 2022-06-13 | Haldor Topsoe As | Fremgangsmåde til fremstilling af ethylenglycol ud fra sukker |
EP3240870A4 (en) | 2014-12-18 | 2019-05-01 | Inaeris Technologies, LLC. | PROCESS FOR THE THERMOLYSIS OF BIOMASS IN THE PRESENCE OF SULFUR HYDROGEN |
-
2017
- 2017-01-05 MX MX2018007750A patent/MX2018007750A/es unknown
- 2017-01-05 CA CA3010748A patent/CA3010748C/en active Active
- 2017-01-05 CN CN201780005913.4A patent/CN108473401B/zh active Active
- 2017-01-05 US US16/068,581 patent/US10759726B2/en active Active
- 2017-01-05 DK DK17700115.3T patent/DK3400208T3/da active
- 2017-01-05 PL PL17700115T patent/PL3400208T3/pl unknown
- 2017-01-05 JP JP2018535315A patent/JP6975152B2/ja active Active
- 2017-01-05 RU RU2018128473A patent/RU2737159C2/ru active
- 2017-01-05 KR KR1020187022285A patent/KR20180100613A/ko not_active Application Discontinuation
- 2017-01-05 AU AU2017205265A patent/AU2017205265B2/en active Active
- 2017-01-05 BR BR112018013543-7A patent/BR112018013543B1/pt active IP Right Grant
- 2017-01-05 WO PCT/EP2017/050183 patent/WO2017118686A1/en active Application Filing
- 2017-01-05 EP EP17700115.3A patent/EP3400208B1/en active Active
- 2017-01-05 UA UAA201808545A patent/UA123827C2/uk unknown
- 2017-01-06 TW TW106100431A patent/TWI739786B/zh active
-
2018
- 2018-05-31 ZA ZA2018/03648A patent/ZA201803648B/en unknown
Also Published As
Publication number | Publication date |
---|---|
US10759726B2 (en) | 2020-09-01 |
RU2737159C2 (ru) | 2020-11-25 |
AU2017205265B2 (en) | 2021-05-27 |
CA3010748A1 (en) | 2017-07-13 |
BR112018013543B1 (pt) | 2022-02-08 |
US20190010104A1 (en) | 2019-01-10 |
CA3010748C (en) | 2023-08-22 |
JP2019501193A (ja) | 2019-01-17 |
WO2017118686A1 (en) | 2017-07-13 |
AU2017205265A1 (en) | 2018-06-21 |
JP6975152B2 (ja) | 2021-12-01 |
EP3400208B1 (en) | 2021-07-28 |
RU2018128473A (ru) | 2020-02-07 |
TW201739729A (zh) | 2017-11-16 |
RU2018128473A3 (pt) | 2020-03-18 |
CN108473401A (zh) | 2018-08-31 |
EP3400208A1 (en) | 2018-11-14 |
ZA201803648B (en) | 2022-12-21 |
UA123827C2 (uk) | 2021-06-09 |
DK3400208T3 (da) | 2021-09-20 |
KR20180100613A (ko) | 2018-09-11 |
MX2018007750A (es) | 2018-11-14 |
PL3400208T3 (pl) | 2021-12-27 |
TWI739786B (zh) | 2021-09-21 |
CN108473401B (zh) | 2021-08-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
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