BR112018007427A2 - composição, processo para produzir poliuretano e espuma de poliuretano à base de poliéster - Google Patents
composição, processo para produzir poliuretano e espuma de poliuretano à base de poliésterInfo
- Publication number
- BR112018007427A2 BR112018007427A2 BR112018007427A BR112018007427A BR112018007427A2 BR 112018007427 A2 BR112018007427 A2 BR 112018007427A2 BR 112018007427 A BR112018007427 A BR 112018007427A BR 112018007427 A BR112018007427 A BR 112018007427A BR 112018007427 A2 BR112018007427 A2 BR 112018007427A2
- Authority
- BR
- Brazil
- Prior art keywords
- polyurethane
- polymers
- sulfite
- foam
- salts
- Prior art date
Links
- 229920002635 polyurethane Polymers 0.000 title abstract 11
- 239000004814 polyurethane Substances 0.000 title abstract 11
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 3
- 239000011496 polyurethane foam Substances 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title 1
- 229920000728 polyester Polymers 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 10
- 239000003054 catalyst Substances 0.000 abstract 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 2
- -1 alkali metal salts Chemical class 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 abstract 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical group CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000000443 aerosol Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000005210 alkyl ammonium group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000004202 carbamide Chemical group 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- BBLSYMNDKUHQAG-UHFFFAOYSA-L dilithium;sulfite Chemical compound [Li+].[Li+].[O-]S([O-])=O BBLSYMNDKUHQAG-UHFFFAOYSA-L 0.000 abstract 1
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 abstract 1
- 235000019252 potassium sulphite Nutrition 0.000 abstract 1
- 239000011253 protective coating Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000565 sealant Substances 0.000 abstract 1
- 235000010265 sodium sulphite Nutrition 0.000 abstract 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 abstract 1
- FDALDWWTCHMERF-UHFFFAOYSA-L tetramethylazanium;sulfite Chemical compound [O-]S([O-])=O.C[N+](C)(C)C.C[N+](C)(C)C FDALDWWTCHMERF-UHFFFAOYSA-L 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
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- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
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- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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Abstract
a presente invenção descreve o uso de sais de sulfito como catalisadores para produzir polímeros de poliuretano. em particular, a presente invenção descreve o uso de sais de metal tais como sais de metal álcali assim como de sais de alquil amônio tais como sais de tetra-alquil-amônio como catalisadores para produzir polímeros de poliuretano. os sais de sulfito são úteis para produzir polímeros de poliuretano e produtos de polímero de espuma de poliuretano tais como polímeros de espuma de poliuretano flexível, polímeros de poliuretano de espuma rígida, polímero de poliuretano semirrígido, polímero de poliuretano microcelular e polímero de poliuretano de espuma em aerossol e qualquer material polimérico que precise da ajuda de catalisadores para estimular a formação de ligações de uretano e ureia tais como aquelas encontradas em emulsões de poliuretano para tintas, revestimentos, revestimentos protetores, verniz de laca, bem como outros materiais de poliuretano ou que contém poliuretano tais como polímeros termoplásticos, polímeros de poliuretano termoplásticos, elastômeros, adesivos, vedantes, etc. os exemplos de catalisadores adequados incluem sulfito de sódio, sulfito de potássio, sulfito de lítio, sulfito de tetrametilamônio e semelhantes.
Applications Claiming Priority (5)
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US201462063109P | 2014-10-13 | 2014-10-13 | |
US14/881,544 | 2015-10-13 | ||
US14/881,544 US10472459B2 (en) | 2014-10-13 | 2015-10-13 | Polyurethane catalysts from a sulfur based salts |
US15/097,734 US10570245B2 (en) | 2014-10-13 | 2016-04-13 | Polyurethane catalysts from sulfur based salts |
PCT/US2016/027319 WO2017065832A1 (en) | 2014-10-13 | 2016-04-13 | Polyurethane catalysts from sulfur based salts |
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BR112018007427A2 true BR112018007427A2 (pt) | 2018-10-16 |
BR112018007427B1 BR112018007427B1 (pt) | 2022-08-02 |
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BR112018007427-6A BR112018007427B1 (pt) | 2014-10-13 | 2016-04-13 | Composição, processo para produzir poliuretano e espuma de poliuretano à base de poliéster |
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EP (2) | EP3207071B1 (pt) |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016061068A1 (en) | 2014-10-13 | 2016-04-21 | Air Products And Chemicals, Inc. | Polyurethane catalysts from sulfur based salts |
US20160138267A1 (en) * | 2014-11-19 | 2016-05-19 | Richard Ettinger | Polyurethane foam building members for residential and/or commercial buildings |
US11370875B2 (en) | 2016-12-08 | 2022-06-28 | Sekisui Chemical Co., Ltd. | Urethane resin composition |
US20190300642A1 (en) | 2016-12-15 | 2019-10-03 | Dow Global Technologies Llc | Polyurethane product with sulfur-containing polyol |
CN108659195B (zh) * | 2017-03-28 | 2022-05-24 | 科思创德国股份有限公司 | 一种制备聚氨酯高回弹软质海绵的方法 |
US10233278B1 (en) | 2017-09-14 | 2019-03-19 | Fxi, Inc. | Cesium and rubidium derivatives as catalysts for polyurethane foams |
CN108097311B (zh) * | 2017-12-14 | 2020-03-20 | 吉林师范大学 | 一种非均相多金属氧酸盐催化剂及其制备方法和应用 |
CN110408361A (zh) * | 2019-06-21 | 2019-11-05 | 李勇 | 一种防水耐污瓷砖美缝剂的制备方法 |
US20210015269A1 (en) * | 2019-07-19 | 2021-01-21 | Evonik Operations Gmbh | Shaped pu foam articles |
CN110964173B (zh) * | 2019-12-13 | 2022-07-12 | 万华化学(北京)有限公司 | 用于蜂窝复合材料的聚氨酯组合物及其制备方法、聚氨酯泡沫及其应用 |
CN111607061B (zh) * | 2020-04-15 | 2022-04-15 | 黎明化工研究设计院有限责任公司 | 一种无阻燃剂高阻燃低气味全水自结皮聚氨酯泡沫及其制备方法 |
CN111518259B (zh) * | 2020-05-06 | 2022-08-19 | 长华化学科技股份有限公司 | 高回弹性的聚氨酯微孔弹性体及其制备方法和应用 |
CN114774061B (zh) * | 2022-06-07 | 2023-09-22 | 广州市盛邦康体场地材料有限公司 | 一种预制型橡胶跑道粘合用胶粘剂 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB871291A (en) | 1957-01-14 | 1961-06-28 | Rohm & Haas | Production of hydrophilic polyester-urethane foamed or cellular products |
US3053778A (en) * | 1959-12-09 | 1962-09-11 | Allied Chem | Polyurethane foam resistant to discoloration and process for making same |
DE1173240B (de) | 1961-06-09 | 1964-07-02 | Gen Tire & Rubber Co | Verfahren zur Herstellung von Polyurethanschaumstoffen |
US4394491A (en) | 1980-10-08 | 1983-07-19 | The Dow Chemical Company | Addition polymerizable adduct of a polymeric monoahl and an unsaturated isocyanate |
DE3638148A1 (de) | 1986-11-08 | 1988-05-11 | Bayer Ag | Verfahren zur herstellung von feinteiligen harnstoffgruppen enthaltenden polyisocyanaten |
EP0672696B1 (en) * | 1994-03-18 | 1999-05-19 | Air Products And Chemicals, Inc. | Low odor amine catalysts for polyurethane flexible slabstock foams based on polyester polyols |
US5874483A (en) * | 1995-09-27 | 1999-02-23 | Air Products And Chemicals, Inc. | Aminopropylbis (aminoethyl) ether compositions for the production of polyurethanes |
US5858551A (en) * | 1997-01-31 | 1999-01-12 | Seydel Research, Inc. | Water dispersible/redispersible hydrophobic polyester resins and their application in coatings |
US5902835A (en) * | 1998-05-28 | 1999-05-11 | Air Products And Chemicals, Inc. | Group IVB metal blowing catalyst compositions for the production of polyurethane foams |
DE19917897A1 (de) * | 1999-04-20 | 2000-10-26 | Basf Ag | Verfahren zur Herstellung von Polyurethanen |
CA2399835C (en) | 2000-02-10 | 2009-11-03 | The Dow Chemical Company | Low emission polyurethane polymers made with autocatalytic polyols |
TW592813B (en) | 2001-08-15 | 2004-06-21 | Dow Global Technologies Inc | Process to manufacture polyurethane products |
TWI315730B (en) | 2001-08-15 | 2009-10-11 | Dow Global Technologies Inc | Process to manufacture polyurethane products |
WO2003055930A1 (en) | 2001-12-21 | 2003-07-10 | Dow Global Technologies Inc. | Tertiary amine modified polyols and polyurethane products made therefrom |
WO2004060956A1 (en) | 2002-12-17 | 2004-07-22 | Dow Global Technologies Inc. | Amine-epoxy autocatalytic polymers and polyurethane products made therefrom |
US6825238B2 (en) * | 2003-01-29 | 2004-11-30 | Air Products And Chemicals, Inc. | Low acid organometallic catalyst for the production of flexible, semi-flexible and rigid polyurethane foams |
BRPI0411861A (pt) * | 2003-06-24 | 2006-08-08 | Ppg Ind Ohio Inc | dispersões aquosas de micropartìculas tendo uma fase nanoparticulada; composições de revestimento contendo a mesma; método de preparação destas e substrato revestido |
DE10338827A1 (de) * | 2003-08-21 | 2005-04-21 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
JP2005154599A (ja) * | 2003-11-26 | 2005-06-16 | Mitsui Takeda Chemicals Inc | 揮発アルデヒドが低減されたポリウレタンフォームの製造方法 |
EP1837360A4 (en) * | 2003-12-03 | 2011-08-03 | Konishi Co Ltd | VINYL-URETHANE COPOLYMER AND METHOD FOR PREPARING THE SAME |
EP1888666B1 (en) | 2005-04-25 | 2017-06-21 | Cargill, Incorporated | Polyurethane foams comprising oligomeric polyols |
CN1986594A (zh) * | 2005-12-21 | 2007-06-27 | 花王株式会社 | 聚氨酯泡沫的制造方法 |
JP4724149B2 (ja) | 2007-05-09 | 2011-07-13 | 住化バイエルウレタン株式会社 | ポリウレタン樹脂の製造法およびそのポリウレタン成形品 |
DE102007038041A1 (de) * | 2007-08-10 | 2009-02-12 | Kronotec Ag | Verfahren zur Vermeidung der Emission von Aldehyden und flüchtigen organischen Verbindungen aus Holzwerkstoffen |
US8367870B2 (en) | 2007-09-19 | 2013-02-05 | Air Products And Chemicals, Inc. | Autocatalytic polyols |
US8980965B2 (en) * | 2007-10-26 | 2015-03-17 | Tosoh Corporation | Method for producing polyester type flexible polyurethane foam, and catalyst composition to be used therefor |
CN101323701B (zh) | 2008-05-23 | 2010-06-23 | 南京林业大学 | 长玻璃纤维增强的硬质聚氨酯合成材料轨枕及其制备方法 |
CN101864671B (zh) | 2010-06-18 | 2011-10-12 | 辽宁恒星精细化工(集团)有限公司 | 一种纺织品用防水透湿聚氨酯涂料及制备方法 |
US20120202907A1 (en) * | 2011-02-05 | 2012-08-09 | Kurt Kurple | Lignin based polyol from black liquor and glycerine |
CN102351774B (zh) * | 2011-08-31 | 2014-03-26 | 常州市阳光药业有限公司 | 吲哚-4-甲醛的制备方法 |
US10066047B2 (en) * | 2012-02-02 | 2018-09-04 | Covestro Llc | Polyurethane foams with decreased aldehyde emissions, a process for preparing these foams and a method for decreasing aldehyde in polyurethane foams |
KR102090467B1 (ko) | 2012-09-24 | 2020-03-18 | 알케마 인코포레이티드 | 할로겐화 올레핀 발포제를 함유한 폴리우레탄 폴리올 배합물의 안정성 개선 |
WO2016061068A1 (en) | 2014-10-13 | 2016-04-21 | Air Products And Chemicals, Inc. | Polyurethane catalysts from sulfur based salts |
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