BR112018003193A2 - catalistador de desidrogenação oxidativa melhorado - Google Patents

catalistador de desidrogenação oxidativa melhorado

Info

Publication number
BR112018003193A2
BR112018003193A2 BR112018003193A BR112018003193A BR112018003193A2 BR 112018003193 A2 BR112018003193 A2 BR 112018003193A2 BR 112018003193 A BR112018003193 A BR 112018003193A BR 112018003193 A BR112018003193 A BR 112018003193A BR 112018003193 A2 BR112018003193 A2 BR 112018003193A2
Authority
BR
Brazil
Prior art keywords
oxidative dehydrogenation
dehydrogenation catalyst
improved oxidative
catalyst precursor
ethylene
Prior art date
Application number
BR112018003193A
Other languages
English (en)
Other versions
BR112018003193B1 (pt
Inventor
KUCHEROV Aleksey
Sullivan David
FINASHINA Elena
DRAG Hanna
KUSTOV Leonid
Simanzhenkov Vasily
Gao Xiaoliang
Original Assignee
Nova Chem Int Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chem Int Sa filed Critical Nova Chem Int Sa
Publication of BR112018003193A2 publication Critical patent/BR112018003193A2/pt
Publication of BR112018003193B1 publication Critical patent/BR112018003193B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/009—Preparation by separation, e.g. by filtration, decantation, screening
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50—Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/55—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/50—Constitutive chemical elements of heterogeneous catalysts of Group V (VA or VB) of the Periodic Table
    • B01J2523/56—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60—Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/64—Tellurium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/60—Constitutive chemical elements of heterogeneous catalysts of Group VI (VIA or VIB) of the Periodic Table
    • B01J2523/68—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/10—Solid density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/90—Other properties not specified above
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/20—Vanadium, niobium or tantalum
    • C07C2523/22—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/057—Selenium or tellurium; Compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

os catalisadores de desidrogenação oxidativa compreendendo movnbteo tendo uma consistência melhorada da composição e uma conversão de 25% de etileno a menos do que 420 ºc e uma seletividade para o etileno de mais do que 95% são preparados por tratamento do precursor de catalisador com h2o2 em uma quantidade equivalente a 0,30 a 2,8 ml de h2o2 de uma solução a 30% por grama de precursor de catalisador antes da calcinação.
BR112018003193-3A 2015-08-20 2016-08-04 Método para melhorar a consistência de um catalisador de desidrogenação oxidativa e método para a desidrogenação oxidativa de uma alimentação mista de etano e oxigênio BR112018003193B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CA2900775A CA2900775C (en) 2015-08-20 2015-08-20 Improved oxidative dehydrogenation catalyst
CA2900775 2015-08-20
PCT/IB2016/054717 WO2017029572A2 (en) 2015-08-20 2016-08-04 Improved oxidative dehydrogenation catalyst

Publications (2)

Publication Number Publication Date
BR112018003193A2 true BR112018003193A2 (pt) 2018-09-25
BR112018003193B1 BR112018003193B1 (pt) 2021-07-20

Family

ID=56842976

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018003193-3A BR112018003193B1 (pt) 2015-08-20 2016-08-04 Método para melhorar a consistência de um catalisador de desidrogenação oxidativa e método para a desidrogenação oxidativa de uma alimentação mista de etano e oxigênio

Country Status (10)

Country Link
US (3) US10350582B2 (pt)
EP (1) EP3337775A2 (pt)
JP (1) JP6995741B2 (pt)
KR (1) KR20180041148A (pt)
CN (1) CN107848910B (pt)
BR (1) BR112018003193B1 (pt)
CA (1) CA2900775C (pt)
MX (1) MX2018001963A (pt)
TW (1) TW201718091A (pt)
WO (1) WO2017029572A2 (pt)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2900775C (en) * 2015-08-20 2023-10-10 Nova Chemicals Corporation Improved oxidative dehydrogenation catalyst
CA2936448C (en) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Controlled pressure hydrothermal treatment of odh catalyst
CA2953954A1 (en) 2017-01-06 2018-07-06 Nova Chemicals Corporation Double peroxide treatment of oxidative dehydrogenation catalyst
US11813592B2 (en) * 2017-06-15 2023-11-14 North Carolina State University Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof
CA2975144A1 (en) * 2017-08-03 2019-02-03 Nova Chemicals Corporation Agglomerated odh catalyst
CA2975140A1 (en) * 2017-08-03 2019-02-03 Nova Chemicals Corporation Agglomerated odh catalyst
CA2993683A1 (en) * 2018-02-02 2019-08-02 Nova Chemicals Corporation Method for in situ high activity odh catalyst
WO2019175732A1 (en) 2018-03-13 2019-09-19 Nova Chemicals (International) S.A. Process to produce ethylene and vinyl acetate monomer and derivatives thereof
CA3102596A1 (en) 2018-03-13 2019-09-19 Nova Chemicals Corporation Mitigating oxygen, carbon dioxide and/or acetylene output from an odh process
CA2999092A1 (en) 2018-03-26 2019-09-26 Nova Chemicals Corporation Calcination process to produce enhanced odh catlyst
CA3008612A1 (en) * 2018-06-18 2019-12-18 Nova Chemicals Corporation Removing and cleaning dehydrogenation catalysts
WO2020016828A2 (en) 2018-07-19 2020-01-23 Nova Chemicals (International) S.A. Catalysts for the oxidative dehydrogenation of alkanes
CA3050720A1 (en) 2018-08-03 2020-02-03 Nova Chemicals Corporation Oxidative dehydrogenation catalyst compositions
CA3050795A1 (en) 2018-08-03 2020-02-03 Nova Chemicals Corporation Oxidative dehydrogenation catalysts
RU2714316C1 (ru) * 2019-10-25 2020-02-14 Общество с ограниченной ответственностью "Газпром нефтехим Салават" (ООО "Газпром нефтехим Салават") Катализатор окислительного дегидрирования этана в этилен и способ его получения
CN110882689B (zh) * 2019-12-11 2022-08-02 中国天辰工程有限公司 一种用于环己烷脱氢制环己烯的催化剂的制备及其应用
US11890594B2 (en) 2021-12-30 2024-02-06 Uop Llc Chemical homogeneity and catalytic performance of mixed-metal oxide catalysts

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CA2900775C (en) * 2015-08-20 2023-10-10 Nova Chemicals Corporation Improved oxidative dehydrogenation catalyst
CA2936448C (en) * 2016-07-19 2024-02-20 Nova Chemicals Corporation Controlled pressure hydrothermal treatment of odh catalyst
CA2945435A1 (en) * 2016-10-18 2018-04-18 Nova Chemicals Corporation Low pressure gas release hydrothermal and peroxide treatment of odh catalyst
CA2953954A1 (en) * 2017-01-06 2018-07-06 Nova Chemicals Corporation Double peroxide treatment of oxidative dehydrogenation catalyst
CA2975144A1 (en) * 2017-08-03 2019-02-03 Nova Chemicals Corporation Agglomerated odh catalyst
CA2993683A1 (en) * 2018-02-02 2019-08-02 Nova Chemicals Corporation Method for in situ high activity odh catalyst

Also Published As

Publication number Publication date
KR20180041148A (ko) 2018-04-23
CA2900775A1 (en) 2017-02-20
MX2018001963A (es) 2018-06-19
US20170050178A1 (en) 2017-02-23
JP6995741B2 (ja) 2022-02-04
TW201718091A (zh) 2017-06-01
WO2017029572A2 (en) 2017-02-23
CA2900775C (en) 2023-10-10
US10695754B2 (en) 2020-06-30
WO2017029572A3 (en) 2017-04-06
US20200282383A1 (en) 2020-09-10
US10350582B2 (en) 2019-07-16
CN107848910A (zh) 2018-03-27
US20190275502A1 (en) 2019-09-12
EP3337775A2 (en) 2018-06-27
CN107848910B (zh) 2021-06-25
US11077430B2 (en) 2021-08-03
BR112018003193B1 (pt) 2021-07-20
JP2018525222A (ja) 2018-09-06

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