BR112017003159A2 - processo para converter hidroximetilfurfural em produtos furânicos - Google Patents

processo para converter hidroximetilfurfural em produtos furânicos

Info

Publication number
BR112017003159A2
BR112017003159A2 BR112017003159A BR112017003159A BR112017003159A2 BR 112017003159 A2 BR112017003159 A2 BR 112017003159A2 BR 112017003159 A BR112017003159 A BR 112017003159A BR 112017003159 A BR112017003159 A BR 112017003159A BR 112017003159 A2 BR112017003159 A2 BR 112017003159A2
Authority
BR
Brazil
Prior art keywords
hydroxymethylfurfural
converting
furanedicarboxylic acid
fur products
aqueous solution
Prior art date
Application number
BR112017003159A
Other languages
English (en)
Other versions
BR112017003159B1 (pt
Inventor
Sanborn Alexandra
Original Assignee
Archer Daniels Midland Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Archer Daniels Midland Co filed Critical Archer Daniels Midland Co
Publication of BR112017003159A2 publication Critical patent/BR112017003159A2/pt
Publication of BR112017003159B1 publication Critical patent/BR112017003159B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40Radicals substituted by oxygen atoms
    • C07D307/42Singly bound oxygen atoms
    • C07D307/44Furfuryl alcohol
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

é descrito um processo para converter hidroximetilfurfural em produtos furânicos, inclusive de ácido 2,5-furanodicarboxílico, que compreende a combinação de uma quantidade de hidroximetilfurfural com água para fornecer uma solução aquosa contendo pelo menos cinco porcento em peso de hidroximetilfurfural, e a combinação da solução aquosa com uma fonte de oxigênio na presença de um catalisador heterogêneo à base de rutênio e sob condições que são eficazes para oxidar hidroximetilfurfural a produtos furânicos de oxidação, inclusive de ácido 2,5-furanodicarboxílico, mas na ausência substancial de qualquer solvente para o hidroximetilfurfural ou o ácido 2,5-furanodicarboxílico para além da água.
BR112017003159-0A 2014-08-19 2015-08-05 Processo para converter hidroximetilfurfural em produtos furânicos BR112017003159B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462038923P 2014-08-19 2014-08-19
US62/038,923 2014-08-19
PCT/US2015/043710 WO2016028488A1 (en) 2014-08-19 2015-08-05 Catalyst and process for producing 2,5-furandicarboxylic acid from hydromethylfurfural in water

Publications (2)

Publication Number Publication Date
BR112017003159A2 true BR112017003159A2 (pt) 2017-11-28
BR112017003159B1 BR112017003159B1 (pt) 2021-10-05

Family

ID=55351124

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017003159-0A BR112017003159B1 (pt) 2014-08-19 2015-08-05 Processo para converter hidroximetilfurfural em produtos furânicos

Country Status (12)

Country Link
US (1) US9957244B2 (pt)
EP (2) EP4086243A1 (pt)
JP (1) JP6695322B2 (pt)
KR (1) KR102196777B1 (pt)
CN (1) CN106795130B (pt)
AU (1) AU2015303871B2 (pt)
BR (1) BR112017003159B1 (pt)
CA (1) CA2956953C (pt)
ES (1) ES2911178T3 (pt)
HU (1) HUE058236T2 (pt)
MX (1) MX2017002188A (pt)
WO (1) WO2016028488A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017190316A (ja) * 2016-04-15 2017-10-19 三菱ケミカル株式会社 2,5−フランジカルボン酸の精製方法
CN106008416B (zh) * 2016-07-04 2019-02-19 浙江大学 一种2,5-呋喃二甲醛的制备方法
CN106565647B (zh) * 2016-10-29 2020-01-10 华东理工大学 一种催化氧化5-羟甲基糠醛制备2,5-呋喃二甲酸的方法
EP3498699A1 (en) 2017-12-13 2019-06-19 Basf Se Chromatography method for the purification of furfural derivatives
CN112830915B (zh) * 2019-11-19 2021-11-23 中国科学院宁波材料技术与工程研究所 一种2,5-呋喃二甲酸的低温制备方法
IT201900025096A1 (it) 2019-12-20 2021-06-20 Novamont Spa Processo per la sintesi di acido 2,5-furandicarbossilico
CN113117705B (zh) * 2019-12-31 2024-05-07 中国石油化工股份有限公司 一种改性钌基催化剂及由其催化制备2,5-呋喃二羧酸的方法
CN113117706B (zh) * 2019-12-31 2024-04-12 中国石油化工股份有限公司 一种金属改性的钌基催化剂及由其催化制备2,5-呋喃二羧酸的方法
FR3109778A1 (fr) * 2020-04-29 2021-11-05 IFP Energies Nouvelles Procede d’oxydation du 5-hydroxymethylfurfural
CN116063258A (zh) * 2021-10-29 2023-05-05 中国石油化工股份有限公司 一种连续生产5-羟甲基糠醛和2,5-呋喃二甲酸的方法

Family Cites Families (21)

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Publication number Priority date Publication date Assignee Title
GB621971A (en) 1946-11-12 1949-04-25 James Gordon Napier Drewitt Improvements in polymers
JPH03130247A (ja) * 1989-10-16 1991-06-04 Mitsui Petrochem Ind Ltd 芳香族カルボン酸の製造方法
US5622655A (en) 1995-04-10 1997-04-22 Hydro-Thermal Corporation Sanitary direct contact steam injection heater and method
US5842497A (en) 1996-05-20 1998-12-01 Hydro-Thermal Corporation Adjustable shear direct contact steam injection heater
US6082712A (en) 1998-07-09 2000-07-04 Hydro-Thermal Corporation Direct contact steam injection heater
US7317116B2 (en) 2004-12-10 2008-01-08 Archer-Daniels-Midland-Company Processes for the preparation and purification of hydroxymethylfuraldehyde and derivatives
US7152851B2 (en) 2005-02-04 2006-12-26 Hydro-Thermal Corporation Steam injection heater with dual-sealing assembly
US7678950B2 (en) 2005-12-16 2010-03-16 Conocophillips Company Process for converting carbohydrates to hydrocarbons
US7700788B2 (en) 2006-10-31 2010-04-20 Battelle Memorial Institute Hydroxymethyl furfural oxidation methods
WO2008157617A1 (en) 2007-06-18 2008-12-24 Archer Daniels-Midland Company Method for purifying hydroxymethyl-furfural using non-functional polymeric resins
JP5207677B2 (ja) 2007-07-17 2013-06-12 キヤノン株式会社 2,5−フランジカルボン酸の製造方法
MX2010006504A (es) 2007-12-12 2010-08-31 Archer Daniels Midland Co Conversion de carbohidratos a hidroxi-metilfurfural (hmf) y derivado.
CN104744414B (zh) * 2009-05-14 2017-04-12 阿彻丹尼尔斯米德兰德公司 糠醛化合物的氧化
DE102009028976A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Ester der 2,5-Furandicarbonsäure mit isomeren Decanolen und ihre Verwendung
DE102009028975A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Esterderivate der 2,5-Furandicarbonsäure und ihre Verwendung als Weichmacher
EP3666764A1 (en) 2009-10-07 2020-06-17 Furanix Technologies B.V Method for the preparation of 2,5-furandicarboxylic acid and for the preparation of the dialkyl ester of 2,5-furandicarboxylic acid
PT2750789T (pt) 2011-08-31 2018-10-30 Archer Daniels Midland Co Processo de oxidação em spray para produzir ácido 2,5- furandicarboxílico a partir de hidroxi-metilfurfural
BR112014004592A2 (pt) * 2011-08-31 2017-03-28 Univ Kansas processo para efetuar uma oxidação em um suprimento
US20140315262A1 (en) * 2012-01-10 2014-10-23 Archer Daniels Midland Company Process for making hmf and hmf derivatives from sugars, with recovery of unreacted sugars suitable for direct fermentation to ethanol
JP2013203666A (ja) * 2012-03-27 2013-10-07 Kao Corp 5−ヒドロキシメチルフルフラール酸化物の製造方法
US8772515B2 (en) * 2012-10-11 2014-07-08 Wisconsin Alumni Research Foundation Method to convert biomass to 5-(hydroxymethyl)-furfural (HMF) and furfural using lactones, furans, and pyrans as solvents

Also Published As

Publication number Publication date
KR102196777B1 (ko) 2020-12-30
EP3183241A4 (en) 2018-01-24
KR20170040807A (ko) 2017-04-13
CN106795130B (zh) 2021-01-22
US20170217917A1 (en) 2017-08-03
US9957244B2 (en) 2018-05-01
BR112017003159B1 (pt) 2021-10-05
CA2956953C (en) 2021-06-29
WO2016028488A1 (en) 2016-02-25
JP6695322B2 (ja) 2020-05-20
EP3183241B1 (en) 2022-03-16
AU2015303871A1 (en) 2017-02-23
CN106795130A (zh) 2017-05-31
EP3183241A1 (en) 2017-06-28
EP4086243A1 (en) 2022-11-09
AU2015303871B2 (en) 2018-11-29
CA2956953A1 (en) 2016-02-25
JP2017525689A (ja) 2017-09-07
MX2017002188A (es) 2017-05-03
ES2911178T3 (es) 2022-05-18
HUE058236T2 (hu) 2022-07-28

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/08/2015, OBSERVADAS AS CONDICOES LEGAIS.