BR112015001309A2 - processo para a preparação de polipropileno com produtividade melhorada - Google Patents
processo para a preparação de polipropileno com produtividade melhoradaInfo
- Publication number
- BR112015001309A2 BR112015001309A2 BR112015001309A BR112015001309A BR112015001309A2 BR 112015001309 A2 BR112015001309 A2 BR 112015001309A2 BR 112015001309 A BR112015001309 A BR 112015001309A BR 112015001309 A BR112015001309 A BR 112015001309A BR 112015001309 A2 BR112015001309 A2 BR 112015001309A2
- Authority
- BR
- Brazil
- Prior art keywords
- polypropylene
- polymerization
- improved productivity
- catalyst
- ziegler
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
- C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Abstract
resumo processo para a preparação de polipropileno com produtividade melhorada a presente invenção refere-se a um processo para a preparação de um polipropileno em um processo de polimerização sequencial compreendendo pelo menos dois reatores de polimerização conectados em série, em que a polimerização nos pelo menos dois reatores de polimerização ocorre na presença de um catalisador ziegler-natta e o dito catalisador ziegler-natta compreende (a) um pró-catalisador compreendendo (a1) um composto de um metal de transição, (a2) um composto de um metal cujo metal é selecionado de um dos grupos 1 a 3 da tabela periódica (iupac), (a3) um doador de elétrons interno, (b) um co-catalisador e (c) um doador externo, em que a razão da taxa de alimentação do catalisador para a taxa de alimentação do propileno (c3) no primeiro reator de polimerização (r1) é 1,0 a 4,5 g/t.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12179547 | 2012-08-07 | ||
PCT/EP2013/065944 WO2014023603A1 (en) | 2012-08-07 | 2013-07-30 | Process for the preparation of polypropylene with improved productivity |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112015001309A2 true BR112015001309A2 (pt) | 2017-07-04 |
Family
ID=48900988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015001309A BR112015001309A2 (pt) | 2012-08-07 | 2013-07-30 | processo para a preparação de polipropileno com produtividade melhorada |
Country Status (12)
Country | Link |
---|---|
US (1) | US9353203B2 (pt) |
EP (1) | EP2882782B1 (pt) |
JP (1) | JP6027240B2 (pt) |
KR (1) | KR101706000B1 (pt) |
CN (1) | CN104487463B (pt) |
AU (1) | AU2013301726B2 (pt) |
BR (1) | BR112015001309A2 (pt) |
CA (1) | CA2878439C (pt) |
IN (1) | IN2015DN00186A (pt) |
RU (1) | RU2015104883A (pt) |
WO (1) | WO2014023603A1 (pt) |
ZA (1) | ZA201501080B (pt) |
Families Citing this family (37)
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JP6152219B2 (ja) * | 2013-04-09 | 2017-06-21 | ボレアリス・アクチェンゲゼルシャフトBorealis Ag | ポリプロピレンの製造方法 |
WO2015022127A1 (en) | 2013-08-14 | 2015-02-19 | Borealis Ag | Propylene composition with improved impact resistance at low temperature |
ES2715385T3 (es) | 2013-08-21 | 2019-06-04 | Borealis Ag | Composición de poliolefina de alto flujo con alta rigidez y tenacidad |
WO2015024891A1 (en) | 2013-08-21 | 2015-02-26 | Borealis Ag | High flow polyolefin composition with high stiffness and toughness |
PT2853563T (pt) | 2013-09-27 | 2016-07-14 | Borealis Ag | Filmes adequados para processamento de bopp a partir de polímeros com xs elevada e tm elevado |
ES2568615T3 (es) | 2013-10-11 | 2016-05-03 | Borealis Ag | Película para etiquetas orientada en la dirección de la máquina |
ES2574428T3 (es) | 2013-10-24 | 2016-06-17 | Borealis Ag | Artículo moldeado por soplado basado en copolímero al azar bimodal |
CN105612188B (zh) | 2013-10-24 | 2018-09-28 | 北欧化工公司 | 具有高含量的区域错误和高分子量的低熔点pp均聚物 |
WO2015062936A1 (en) | 2013-10-29 | 2015-05-07 | Borealis Ag | Solid single site catalysts with high polymerisation activity |
MX368147B (es) | 2013-11-22 | 2019-09-20 | Borealis Ag | Homopolímero de propileno de baja emisión con alto flujo de masa fundida. |
ES2929491T3 (es) | 2013-12-04 | 2022-11-29 | Borealis Ag | Homopolímeros de PP libre de ftalato para fibras sopladas en estado fundido |
US9637602B2 (en) | 2013-12-18 | 2017-05-02 | Borealis Ag | BOPP film with improved stiffness/toughness balance |
US9745431B2 (en) | 2013-12-18 | 2017-08-29 | Borealis Ag | BOPP film having low shrinkage |
CN105829364B (zh) | 2014-01-17 | 2017-11-10 | 博里利斯股份公司 | 用于制备丙烯/1‑丁烯共聚物的方法 |
JP6474417B2 (ja) | 2014-02-06 | 2019-02-27 | ボレアリス エージー | 軟質及び透明衝撃コポリマー |
US10100185B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft copolymers with high impact strength |
EP2907841A1 (en) | 2014-02-14 | 2015-08-19 | Borealis AG | Polypropylene composite |
CN104974369B (zh) * | 2014-04-04 | 2018-01-23 | 中国石油化工股份有限公司 | 一种聚丙烯发泡珠粒的制备方法 |
CN104974368B (zh) * | 2014-04-04 | 2018-01-23 | 中国石油化工股份有限公司 | 一种抗静电聚丙烯发泡珠粒的制备方法 |
CN104974367B (zh) * | 2014-04-04 | 2018-01-23 | 中国石油化工股份有限公司 | 一种抗静电聚丙烯发泡板材或片材的制备方法 |
ES2659731T3 (es) | 2014-05-20 | 2018-03-19 | Borealis Ag | Composición de polipropileno para aplicaciones en interiores de automóviles |
WO2016114855A1 (en) * | 2015-01-14 | 2016-07-21 | Exxonmobil Chemical Patents Inc. | Adhesive compositions made from propylene-based polymers and crystalline c2/c3 homopolymer |
US10155828B2 (en) | 2015-11-17 | 2018-12-18 | Borealis Ag | High flow TPO composition with excellent low temperature impact |
CN108350242A (zh) | 2015-11-17 | 2018-07-31 | 博里利斯股份公司 | 具有优异的断裂拉伸应变和低粉粘性的高流动性tpo组合物 |
EP3170864B1 (en) | 2015-11-17 | 2018-10-17 | Borealis AG | High flow tpo composition with excellent balance in mechanical properties for automotive interior |
US11591458B2 (en) | 2016-08-30 | 2023-02-28 | W.R. Grace & Co.-Conn. | Polyolefins with low ash content and method of making same |
ES2952512T3 (es) | 2016-12-15 | 2023-10-31 | Borealis Ag | Composición de polipropileno con excelente adhesión de la pintura |
EP3489296B1 (en) | 2017-11-28 | 2021-09-01 | Borealis AG | Polymer composition with improved paint adhesion |
ES2886432T3 (es) | 2017-11-28 | 2021-12-20 | Borealis Ag | Composición de polímero con adherencia de la pintura mejorada |
EP3604425A1 (en) | 2018-07-31 | 2020-02-05 | Borealis AG | Foamed polypropylene composition comprising polymeric fibers |
CN112175118B (zh) * | 2019-07-02 | 2023-11-14 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法 |
CN112175117B (zh) * | 2019-07-02 | 2023-07-21 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分及其制备方法和用于烯烃聚合的催化剂及烯烃聚合的方法 |
CN112175119B (zh) * | 2019-07-02 | 2023-08-15 | 中国石油化工股份有限公司 | 烯烃聚合用固体催化剂组分及其制备方法、烯烃聚合催化剂和烯烃聚合的方法 |
CN112175115B (zh) * | 2019-07-02 | 2023-07-21 | 中国石油化工股份有限公司 | 烯烃聚合催化剂的固体催化剂组分及其制备方法和烯烃聚合催化剂及烯烃聚合的方法 |
US11180587B2 (en) | 2019-12-13 | 2021-11-23 | Chevron Phillips Chemical Company Lp | Polymerization of propylene |
WO2022162694A1 (en) | 2021-01-27 | 2022-08-04 | Hindustan Petroleum Corporation Limited | Graft copolymer and method of preparation thereof |
WO2023180266A1 (en) | 2022-03-23 | 2023-09-28 | Borealis Ag | Polypropylene composition for automotive applications |
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FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
FI86866C (fi) | 1990-12-19 | 1992-10-26 | Neste Oy | Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner |
FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
FI88048C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator |
FI88047C (fi) | 1991-05-09 | 1993-03-25 | Neste Oy | Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner |
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FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
FI111846B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi |
FI111847B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä propeenin kopolymeerien valmistamiseksi |
FI980342A0 (fi) | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
FI974175A (fi) | 1997-11-07 | 1999-05-08 | Borealis As | Menetelmä polypropeenin valmistamiseksi |
FI991057A0 (fi) | 1999-05-07 | 1999-05-07 | Borealis As | Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi |
AU2002323878A1 (en) | 2002-06-25 | 2004-01-06 | Borealis Technology Oy | Polyolefin with improved scratch resistance and process for producing the same |
EP1484343A1 (en) | 2003-06-06 | 2004-12-08 | Universiteit Twente | Process for the catalytic polymerization of olefins, a reactor system and its use in the same process |
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EP2070954A1 (en) * | 2007-12-14 | 2009-06-17 | Total Petrochemicals Research Feluy | Process for the production of a propylene polymer having a broad molecular weight distribution and a low ash content |
ATE536390T1 (de) * | 2008-10-29 | 2011-12-15 | Borealis Ag | Feste zusammensetzung für lebensmittelanwendungen |
EP2368937A1 (en) * | 2010-03-22 | 2011-09-28 | Borealis AG | Heterophasic polypropylene with excellent creep performance |
KR20130008631A (ko) | 2010-05-12 | 2013-01-22 | 보레알리스 아게 | 특수 커패시터용 특정 칼슘 스테아레이트 함량을 갖는 폴리프로필렌 |
-
2013
- 2013-07-30 US US14/416,121 patent/US9353203B2/en active Active
- 2013-07-30 AU AU2013301726A patent/AU2013301726B2/en not_active Ceased
- 2013-07-30 EP EP13742453.7A patent/EP2882782B1/en active Active
- 2013-07-30 CA CA2878439A patent/CA2878439C/en active Active
- 2013-07-30 WO PCT/EP2013/065944 patent/WO2014023603A1/en active Application Filing
- 2013-07-30 RU RU2015104883A patent/RU2015104883A/ru not_active Application Discontinuation
- 2013-07-30 KR KR1020157003912A patent/KR101706000B1/ko active IP Right Grant
- 2013-07-30 BR BR112015001309A patent/BR112015001309A2/pt not_active IP Right Cessation
- 2013-07-30 CN CN201380038758.8A patent/CN104487463B/zh active Active
- 2013-07-30 JP JP2015525818A patent/JP6027240B2/ja active Active
- 2013-07-30 IN IN186DEN2015 patent/IN2015DN00186A/en unknown
-
2015
- 2015-02-17 ZA ZA2015/01080A patent/ZA201501080B/en unknown
Also Published As
Publication number | Publication date |
---|---|
JP2015528517A (ja) | 2015-09-28 |
IN2015DN00186A (pt) | 2015-06-12 |
ZA201501080B (en) | 2016-01-27 |
EP2882782B1 (en) | 2018-09-05 |
CA2878439A1 (en) | 2014-02-13 |
WO2014023603A1 (en) | 2014-02-13 |
CN104487463A (zh) | 2015-04-01 |
KR101706000B1 (ko) | 2017-02-10 |
CN104487463B (zh) | 2017-04-05 |
EP2882782A1 (en) | 2015-06-17 |
AU2013301726A1 (en) | 2015-01-29 |
AU2013301726B2 (en) | 2015-09-17 |
CA2878439C (en) | 2016-08-30 |
JP6027240B2 (ja) | 2016-11-16 |
KR20150036619A (ko) | 2015-04-07 |
RU2015104883A (ru) | 2016-10-10 |
US9353203B2 (en) | 2016-05-31 |
US20150152203A1 (en) | 2015-06-04 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] | ||
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |