WO2012134719A3 - Novel catalysts and methods of use thereof to produce vinyl terminated polymers - Google Patents

Novel catalysts and methods of use thereof to produce vinyl terminated polymers Download PDF

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Publication number
WO2012134719A3
WO2012134719A3 PCT/US2012/027685 US2012027685W WO2012134719A3 WO 2012134719 A3 WO2012134719 A3 WO 2012134719A3 US 2012027685 W US2012027685 W US 2012027685W WO 2012134719 A3 WO2012134719 A3 WO 2012134719A3
Authority
WO
WIPO (PCT)
Prior art keywords
independently
group
fused ring
hydrogen
saturated
Prior art date
Application number
PCT/US2012/027685
Other languages
French (fr)
Other versions
WO2012134719A8 (en
WO2012134719A2 (en
Inventor
Donna J. Crowther
Patrick Brant
Carlos U. De Gracia
Jacqueline A. Lovell
Original Assignee
Exxonmobil Chemical Patents Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/072,280 external-priority patent/US8455597B2/en
Application filed by Exxonmobil Chemical Patents Inc. filed Critical Exxonmobil Chemical Patents Inc.
Priority to CN201280016041.9A priority Critical patent/CN103502281A/en
Priority to EP12763666.0A priority patent/EP2688916A4/en
Priority to JP2014501092A priority patent/JP5848815B2/en
Publication of WO2012134719A2 publication Critical patent/WO2012134719A2/en
Publication of WO2012134719A3 publication Critical patent/WO2012134719A3/en
Publication of WO2012134719A8 publication Critical patent/WO2012134719A8/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

This invention relates to a homogenous process for making a vinyl terminated propylene polymer, wherein the process comprises: contacting, propylene, under polymerization conditions, with a catalyst system comprising an activator and at least one metallocene compound, where the metallocene compound is represented by the formula (I) where: M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, (two X's may form a part of a fused ring or a ring system); each R1 is, independently, a C1 Cto C10 alkyl group; each R2 is, independently, a C1 to C10 alkyl group; each R3 is, independently, hydrogen; each R4, R5, and R6, is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, a heteroatom or heteroatom containing group; T is a bridging group; each R7 is, independently, hydrogen, halogen, or a C1 to C20 hydrocarbyl, and two R7 can form a cyclic structure including aromatic, partially saturated, or saturated cyclic or fused ring system; and further provided that any of adjacent R4, R5, and R6 groups may form a fused ring or multicenter fused ring system where the rings may be aromatic, partially saturated or saturated.
PCT/US2012/027685 2011-03-25 2012-03-05 Novel catalysts and methods of use thereof to produce vinyl terminated polymers WO2012134719A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201280016041.9A CN103502281A (en) 2011-03-25 2012-03-05 Novel catalysts and methods of use thereof to produce vinyl terminated polymers
EP12763666.0A EP2688916A4 (en) 2011-03-25 2012-03-05 Novel catalysts and methods of use thereof to produce vinyl terminated polymers
JP2014501092A JP5848815B2 (en) 2011-03-25 2012-03-05 NOVEL CATALYST FOR PRODUCING VINYL-TERMINATE POLYMER AND USE THEREOF

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US13/072,280 US8455597B2 (en) 2011-03-25 2011-03-25 Catalysts and methods of use thereof to produce vinyl terminated polymers
US13/072,280 2011-03-25
EP11167019.6 2011-05-23
EP11167019 2011-05-23
EP1167019.6 2011-05-23

Publications (3)

Publication Number Publication Date
WO2012134719A2 WO2012134719A2 (en) 2012-10-04
WO2012134719A3 true WO2012134719A3 (en) 2012-11-22
WO2012134719A8 WO2012134719A8 (en) 2014-03-27

Family

ID=49773114

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/027685 WO2012134719A2 (en) 2011-03-25 2012-03-05 Novel catalysts and methods of use thereof to produce vinyl terminated polymers

Country Status (4)

Country Link
EP (1) EP2688916A4 (en)
JP (1) JP5848815B2 (en)
CN (1) CN103502281A (en)
WO (1) WO2012134719A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102964371B (en) * 2012-12-17 2015-08-12 上海化工研究院 A kind of preparation method of silicon bridge vicinal resistance type cyclopentadiene compounds
EP3301119B1 (en) 2013-07-17 2021-03-17 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
WO2020184421A1 (en) 2019-03-12 2020-09-17 三井化学株式会社 Olefin-based resin, product of crosslinking thereof, and production methods therefor
EP4110834B1 (en) * 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
KR20220017200A (en) * 2020-08-04 2022-02-11 주식회사 엘지화학 Hybride supported metallocene catalyst and method for preparing polypropylene using the same
KR20220046892A (en) * 2020-10-08 2022-04-15 주식회사 엘지화학 Novel metallocene compound, catalyst composition comprising the same, and method for preparing olefin polymer using the same
US20240191068A1 (en) 2021-03-31 2024-06-13 Mitsui Chemicals, Inc. Ethylene resin composition and shaped article
US20240191011A1 (en) 2021-03-31 2024-06-13 Mitsui Chemicals, Inc. ETHYLENE-alpha-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, AND FILM
WO2022210843A1 (en) 2021-03-31 2022-10-06 三井化学株式会社 ETHYLENE-α-OLEFIN COPOLYMER, THERMOPLASTIC RESIN COMPOSITION, FILM, AND LAMINATE

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000038420A (en) * 1998-07-24 2000-02-08 Idemitsu Petrochem Co Ltd Propylene copolymer and its production
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998043989A1 (en) * 1997-03-29 1998-10-08 Montell Technology Company B.V. Metallocenes and catalysts for polymerization of olefins
EP1062219B1 (en) * 1998-03-11 2002-08-28 The Dow Chemical Company Integrated process for preparation of diene complexes
JP2000038411A (en) * 1998-07-24 2000-02-08 Idemitsu Petrochem Co Ltd Catalyst for olefin polymerization and production of polyolefin
JP4667901B2 (en) * 2005-02-18 2011-04-13 出光興産株式会社 Process for producing unsaturated hydrocarbon compounds
US7943711B2 (en) * 2007-05-14 2011-05-17 Exxonmobil Chemical Patents Inc. Ethylene elastomer compositions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
JP2000038420A (en) * 1998-07-24 2000-02-08 Idemitsu Petrochem Co Ltd Propylene copolymer and its production
US20060052553A1 (en) * 2002-12-04 2006-03-09 Basell Polyolefine Gmbh Process for preparing 1-butene polymers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
See also references of EP2688916A4 *
WENG, W. ET AL.: "Long Chain Branched Isotactic Polypropylene.", MACROMOLECULES, vol. 35, 2002, pages 3838 - 3843, XP002668104 *

Also Published As

Publication number Publication date
JP2014513735A (en) 2014-06-05
WO2012134719A8 (en) 2014-03-27
JP5848815B2 (en) 2016-01-27
EP2688916A2 (en) 2014-01-29
WO2012134719A2 (en) 2012-10-04
CN103502281A (en) 2014-01-08
EP2688916A4 (en) 2014-10-22

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