BR112014026599A2 - processo para a produção de polímero de olefina - Google Patents
processo para a produção de polímero de olefinaInfo
- Publication number
- BR112014026599A2 BR112014026599A2 BR112014026599A BR112014026599A BR112014026599A2 BR 112014026599 A2 BR112014026599 A2 BR 112014026599A2 BR 112014026599 A BR112014026599 A BR 112014026599A BR 112014026599 A BR112014026599 A BR 112014026599A BR 112014026599 A2 BR112014026599 A2 BR 112014026599A2
- Authority
- BR
- Brazil
- Prior art keywords
- production
- compound
- olefin
- olefin polymer
- polymerization
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
Abstract
resumo processo para a produção de polímero de olefina problema fornecer um processo para a produção de um polímero de olefina que torne possível usar, como um solvente para uso na preparação de catalisador, e semelhantes, um solvente de hidrocarboneto alifático ao invés de um solvente de hidrocarboneto aromático que causa grande carga ambiental, e que possua boa atividade de polimerização de olefina. solução um processo para a produção de um polímero de olefina, caracterizado por ter uma etapa que compreende a alimentação de uma solução catalisadora de polimerização de olefina, que é obtida por misturação de (a) um composto de metaloceno, (b) um composto que reage com o composto de metaloceno (a) para formar um par de íons e (c) pelo menos um composto selecionado de (c-1) um composto de organoalumínio e (c-2) um composto de óxi organoalumínio com (d) um solvente de hidrocarboneto saturado, a um reator de polimerização e polimerização em solução de uma olefina no reator de polimerização.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012101600 | 2012-04-26 | ||
PCT/JP2013/061953 WO2013161833A1 (ja) | 2012-04-26 | 2013-04-23 | オレフィン重合体の製造方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112014026599A2 true BR112014026599A2 (pt) | 2017-07-18 |
Family
ID=49483142
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112014026599A BR112014026599A2 (pt) | 2012-04-26 | 2013-04-23 | processo para a produção de polímero de olefina |
Country Status (8)
Country | Link |
---|---|
US (1) | US9340628B2 (pt) |
EP (1) | EP2842972B1 (pt) |
JP (1) | JP5795119B2 (pt) |
KR (1) | KR101584027B1 (pt) |
CN (1) | CN104254546B (pt) |
BR (1) | BR112014026599A2 (pt) |
SG (1) | SG11201406929RA (pt) |
WO (1) | WO2013161833A1 (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105622805B (zh) * | 2014-10-30 | 2018-05-15 | 中国石油化工股份有限公司 | 一种1-丁烯聚合物的制备方法 |
CN106046211A (zh) * | 2015-01-26 | 2016-10-26 | 苏州亚培克生物科技有限公司 | 合成润滑油基础油用茂金属聚‑α烯烃催化剂及其制备方法和应用 |
WO2017088279A1 (zh) * | 2015-11-25 | 2017-06-01 | 亚培烯科技(嘉兴)有限公司 | 合成润滑油基础油用茂金属聚-α烯烃催化剂及其制备方法和应用 |
US10544246B2 (en) | 2016-08-10 | 2020-01-28 | Exxonmobil Chemical Patents Inc. | Methods for supplying solid catalysts to a solution polymerization reactor |
WO2018031157A1 (en) | 2016-08-10 | 2018-02-15 | Exxonmobil Chemical Patents Inc. | Methods for supplying solid catalysts to a solution polymerization reactor |
JP7130644B2 (ja) * | 2016-12-15 | 2022-09-05 | ボレアリス エージー | 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系 |
WO2018182860A1 (en) * | 2017-03-27 | 2018-10-04 | Exxonmobil Chemical Patents Inc. | Solution process to make ethylene copolymers |
US11028192B2 (en) * | 2017-03-27 | 2021-06-08 | Exxonmobil Chemical Patents Inc. | Solution process to make ethylene copolymers |
CN111918717B (zh) | 2018-03-30 | 2024-04-09 | 陶氏环球技术有限责任公司 | 烯烃聚合活化剂 |
BR112020019547B1 (pt) | 2018-03-30 | 2023-11-28 | Dow Global Technologies Llc | Processo para polimerizar olefinas |
BR112020019520A2 (pt) | 2018-03-30 | 2020-12-29 | Dow Global Technologies Llc | Sistema de catalisador, e, processo de polimerização. |
ES2932265T3 (es) | 2018-03-30 | 2023-01-17 | Dow Global Technologies Llc | Activadores de polimerización de olefinas binucleares |
WO2020219050A1 (en) * | 2019-04-25 | 2020-10-29 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type benzimidazolium activators |
US11059791B2 (en) | 2019-04-25 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type benzimidazolium activators |
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JPH11302312A (ja) * | 1998-04-24 | 1999-11-02 | Mitsui Chem Inc | オレフィン重合用触媒およびオレフィンの重合方法 |
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JP4554133B2 (ja) | 1999-10-08 | 2010-09-29 | 三井化学株式会社 | メタロセン化合物、メタロセン化合物の製造方法、オレフィン重合触媒、ポリオレフィンの製造方法およびポリオレフィン |
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KR20030048456A (ko) | 2000-11-06 | 2003-06-19 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용의 플루오르화된 양쪽이온성 조촉매 활성화제 |
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JP5688236B2 (ja) | 2010-05-25 | 2015-03-25 | 出光興産株式会社 | 触媒組成物及び当該触媒組成物を用いるオレフィン系重合体の製造方法 |
JP5750240B2 (ja) * | 2010-06-18 | 2015-07-15 | 三井化学株式会社 | エチレン系ワックスの製造方法 |
JP5574916B2 (ja) | 2010-10-26 | 2014-08-20 | 三井化学株式会社 | オレフィン重合体の製造方法 |
JP5750271B2 (ja) | 2011-01-20 | 2015-07-15 | 三井化学株式会社 | オレフィン重合体の製造方法 |
-
2013
- 2013-04-23 SG SG11201406929RA patent/SG11201406929RA/en unknown
- 2013-04-23 KR KR1020147028998A patent/KR101584027B1/ko active IP Right Grant
- 2013-04-23 CN CN201380022021.7A patent/CN104254546B/zh active Active
- 2013-04-23 US US14/396,509 patent/US9340628B2/en active Active
- 2013-04-23 JP JP2014512622A patent/JP5795119B2/ja active Active
- 2013-04-23 EP EP13781228.5A patent/EP2842972B1/en active Active
- 2013-04-23 WO PCT/JP2013/061953 patent/WO2013161833A1/ja active Application Filing
- 2013-04-23 BR BR112014026599A patent/BR112014026599A2/pt active Search and Examination
Also Published As
Publication number | Publication date |
---|---|
US20150094434A1 (en) | 2015-04-02 |
EP2842972A4 (en) | 2015-06-24 |
KR20140138966A (ko) | 2014-12-04 |
EP2842972A1 (en) | 2015-03-04 |
KR101584027B1 (ko) | 2016-01-08 |
US9340628B2 (en) | 2016-05-17 |
JPWO2013161833A1 (ja) | 2015-12-24 |
EP2842972B1 (en) | 2017-08-30 |
WO2013161833A1 (ja) | 2013-10-31 |
CN104254546B (zh) | 2016-11-02 |
SG11201406929RA (en) | 2014-11-27 |
CN104254546A (zh) | 2014-12-31 |
JP5795119B2 (ja) | 2015-10-14 |
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