BR112012032634B1 - processo para a produção de microcápsulas - Google Patents
processo para a produção de microcápsulas Download PDFInfo
- Publication number
- BR112012032634B1 BR112012032634B1 BR112012032634-1A BR112012032634A BR112012032634B1 BR 112012032634 B1 BR112012032634 B1 BR 112012032634B1 BR 112012032634 A BR112012032634 A BR 112012032634A BR 112012032634 B1 BR112012032634 B1 BR 112012032634B1
- Authority
- BR
- Brazil
- Prior art keywords
- microcapsules
- isocyanate
- isocyanates
- emulsion
- water
- Prior art date
Links
- 239000003094 microcapsule Substances 0.000 title claims abstract description 74
- 238000000034 method Methods 0.000 title claims abstract description 43
- 230000008569 process Effects 0.000 title claims abstract description 38
- 239000000839 emulsion Substances 0.000 claims abstract description 30
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 15
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 11
- 239000012948 isocyanate Substances 0.000 claims description 75
- 150000002513 isocyanates Chemical class 0.000 claims description 73
- 239000000203 mixture Substances 0.000 claims description 61
- 239000000243 solution Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
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- 238000003756 stirring Methods 0.000 claims description 15
- 229920002873 Polyethylenimine Polymers 0.000 claims description 14
- 230000001588 bifunctional effect Effects 0.000 claims description 13
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 11
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- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 7
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- NHZLNPMOSADWGC-UHFFFAOYSA-N 4-amino-N-(2-quinoxalinyl)benzenesulfonamide Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=CN=C(C=CC=C2)C2=N1 NHZLNPMOSADWGC-UHFFFAOYSA-N 0.000 description 5
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- 239000001993 wax Substances 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
- FJBGIXKIXPUXBY-UHFFFAOYSA-N {2-[3-(4-chlorophenyl)propyl]-2,4,4-trimethyl-1,3-oxazolidin-3-yl}(imidazol-1-yl)methanone Chemical compound C1=CN=CN1C(=O)N1C(C)(C)COC1(C)CCCC1=CC=C(Cl)C=C1 FJBGIXKIXPUXBY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/71—Monoisocyanates or monoisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Polyurethanes Or Polyureas (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB10167305.1 | 2010-06-25 | ||
| EP10167305.1A EP2399667B1 (en) | 2010-06-25 | 2010-06-25 | Process for producing microcapsules |
| PCT/EP2011/001098 WO2011160733A1 (en) | 2010-06-25 | 2011-03-05 | Process for producing microcapsules |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112012032634A2 BR112012032634A2 (pt) | 2018-01-23 |
| BR112012032634B1 true BR112012032634B1 (pt) | 2018-12-26 |
Family
ID=43242849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012032634-1A BR112012032634B1 (pt) | 2010-06-25 | 2011-03-05 | processo para a produção de microcápsulas |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20130095158A1 (enExample) |
| EP (1) | EP2399667B1 (enExample) |
| JP (1) | JP5934703B2 (enExample) |
| KR (1) | KR101925269B1 (enExample) |
| CN (1) | CN102958597B (enExample) |
| BR (1) | BR112012032634B1 (enExample) |
| CA (1) | CA2803420C (enExample) |
| ES (1) | ES2628087T3 (enExample) |
| MX (1) | MX341671B (enExample) |
| RU (1) | RU2572889C2 (enExample) |
| WO (1) | WO2011160733A1 (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3120923A3 (en) | 2011-07-06 | 2017-03-01 | President and Fellows of Harvard College | Article comprising a particle having a shell and a fluid |
| CN104755162B (zh) * | 2012-08-28 | 2018-01-09 | 奇华顿股份有限公司 | 芳香剂的载体体系 |
| JP2014221012A (ja) * | 2013-05-13 | 2014-11-27 | 清水建設株式会社 | 模擬粉体、粉体飛散状態評価方法、及び粉体取扱い施設 |
| JP6143078B2 (ja) * | 2013-05-13 | 2017-06-07 | 清水建設株式会社 | 模擬粉体の製造方法、及び粉体飛散状態評価方法 |
| CN103933014B (zh) * | 2013-12-31 | 2016-03-09 | 杭州师范大学 | 一种肿瘤细胞靶向载药微胶囊 |
| GB2509431B (en) * | 2014-03-26 | 2016-09-14 | Rotam Agrochem Int Co Ltd | Herbicidal composition, a method for its preparation and the use thereof |
| WO2015165834A1 (en) * | 2014-04-29 | 2015-11-05 | Basf Se | Anionic polyvinyl alcohol copolymer as protective colloid for pesticidal polyurea microcapsules |
| RU2619331C2 (ru) * | 2014-10-10 | 2017-05-15 | Александр Александрович Кролевец | Способ получения нанокапсул умифеновира (Арбидола) в альгинате натрия |
| WO2016061095A1 (en) * | 2014-10-14 | 2016-04-21 | President And Fellows Of Harvard College | Microcapsules and uses thereof |
| RU2599885C2 (ru) * | 2014-11-05 | 2016-10-20 | Александр Александрович Кролевец | Способ получения нанокапсул умифеновира (арбидола) в каррагинане |
| WO2016071149A1 (en) | 2014-11-07 | 2016-05-12 | Givaudan Sa | Improvements in or relating to organic compounds |
| BR112017007586B1 (pt) | 2014-11-07 | 2020-12-01 | Givaudan Sa | composição para perfume encapsulado, seu método de formação e produto para higiene pessoal sem enxague |
| US10201795B2 (en) | 2014-11-07 | 2019-02-12 | Basf Se | Microcapsules comprising hydroxyalkyl cellulose |
| WO2016071152A1 (en) | 2014-11-07 | 2016-05-12 | Basf Se | Process for preparing microcapsules having a polyurea shell and a lipophilic core material |
| JP6971517B2 (ja) * | 2015-11-17 | 2021-11-24 | ユニリーバー・ナームローゼ・ベンノートシヤープ | クリンバゾールマイクロカプセルならびに界面活性剤およびクリンバゾールを含むヘアケア組成物 |
| WO2017085033A1 (en) | 2015-11-18 | 2017-05-26 | Basf Se | Improvements in or relating to organic compounds |
| EP3170552A1 (en) | 2015-11-23 | 2017-05-24 | Basf Se | Microcapsule comprising a polymeric shell and a hydrophilic or hydrophobic core material |
| GB201615905D0 (en) * | 2016-09-19 | 2016-11-02 | Givaudan Sa | Improvements in or relating to organic compounds |
| EP3295929A1 (en) * | 2016-09-19 | 2018-03-21 | S.P.C.M. Sa | Use of an ampholyte copolymer as colloidal stabilizer in a process of encapsulating fragrance |
| CN110121535B (zh) * | 2016-12-27 | 2022-04-29 | 富士胶片株式会社 | 水分散物及其制造方法、以及图像形成方法 |
| CN107698865B (zh) * | 2017-09-14 | 2020-04-03 | 陕西理工大学 | 一种注塑机螺杆清洗料的制备方法 |
| GB201804038D0 (en) | 2018-03-14 | 2018-04-25 | Givaudan Sa | Improvements in or realating to organic compounds |
| WO2019181988A1 (ja) * | 2018-03-23 | 2019-09-26 | 富士フイルム株式会社 | 中空粒子の製造方法、並びに、造孔材の製造方法、化粧料用粒子の製造方法、及び軽量化材の製造方法 |
| WO2019206404A1 (en) * | 2018-04-24 | 2019-10-31 | Symrise Ag | Core-shell capsules prepared with linear and cyclic aliphatic polyisocyanates |
| CN109231400B (zh) * | 2018-10-08 | 2021-09-21 | 华南理工大学 | 一种用于处理水体富营养化的悬浮木质素微胶囊及制备方法 |
| JP7267439B2 (ja) * | 2019-02-13 | 2023-05-01 | シムライズ アーゲー | マイクロカプセルの調製のためのプロセス |
| EP3845304A1 (en) | 2019-12-30 | 2021-07-07 | Bayer AG | Capsule suspension concentrates based on polyisocyanates and biodegradable amine based cross-linker |
| CN111226923B (zh) * | 2020-03-09 | 2022-04-22 | 上海生农生化制品股份有限公司 | 一种吡唑醚菌酯·喹啉铜微胶囊悬浮-悬浮剂及其制备方法 |
| GB202003883D0 (en) | 2020-03-18 | 2020-05-06 | Givaudan Sa | Consumer product |
| US20230247986A1 (en) | 2020-06-26 | 2023-08-10 | Bayer Aktiengesellschaft | Aqueous capsule suspension concentrates comprising biodegradable ester groups |
| US12434215B2 (en) | 2020-07-31 | 2025-10-07 | Morishita Jintan Co., Ltd. | Microcapsule production method |
| WO2022028706A1 (de) | 2020-08-06 | 2022-02-10 | Symrise Ag | Bioabbaubare polyharnstoff/polyurethan-mikrokapseln |
| ES2985530T3 (es) | 2020-08-06 | 2024-11-06 | Symrise Ag | Microcápsulas de poliurea/poliuretano |
| CN116507204A (zh) | 2020-08-06 | 2023-07-28 | 西姆莱斯股份公司 | 用于制备微胶囊的方法 |
| GB202114226D0 (en) | 2021-10-05 | 2021-11-17 | Iberchem S A U | Microcapsules |
| EP4472763A1 (de) | 2022-02-02 | 2024-12-11 | Symrise AG | Verfahren zur herstellung von mikrokapseln |
| WO2023147855A2 (de) | 2022-02-02 | 2023-08-10 | Symrise Ag | Verfahren zur herstellung von mikrokapseln |
| EP4576268A1 (en) * | 2022-08-19 | 2025-06-25 | Panasonic Intellectual Property Management Co., Ltd. | Negative electrode slurry for lithium-ion secondary battery, negative electrode for lithium-ion secondary battery, and lithium-ion secondary battery |
| CN117296839B (zh) * | 2023-11-27 | 2024-02-23 | 山东华实药业有限公司 | 免活化稳定性二氧化氯消毒剂及其生产工艺 |
| CN119257955B (zh) * | 2024-08-16 | 2025-09-23 | 广东丸美生物技术股份有限公司 | 含美妆功能物质水溶液的微胶囊及其制备方法、化妆品 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3886085A (en) * | 1971-08-31 | 1975-05-27 | Fuji Photo Film Co Ltd | Process for producing fine oil-containing microcapsules having strong protective shells and microcapsules produced thereby |
| US4643764A (en) * | 1984-01-09 | 1987-02-17 | Stauffer Chemical Company | Multiple types of microcapsules and their production |
| EP0214936B1 (de) * | 1985-09-13 | 1992-07-08 | Ciba-Geigy Ag | Verfahren zur Herstellung von Mikrokapseln |
| FR2591124B1 (fr) * | 1985-12-10 | 1988-02-12 | Rhone Poulenc Spec Chim | Procede de microencapsulation par polyaddition-interfaciale. |
| DE3771446D1 (de) * | 1986-10-23 | 1991-08-22 | Ciba Geigy Ag | Bekaempfung von ektoparasiten. |
| FR2610537A1 (fr) * | 1987-02-11 | 1988-08-12 | Rhone Poulenc Chimie | Procede ameliore de microencapsulation par polyaddition interfaciale |
| JP2929294B2 (ja) * | 1989-05-30 | 1999-08-03 | 大日本インキ化学工業株式会社 | 顔料化されたポリウレタンポリ尿素粒子およびその製造方法 |
| US5011885A (en) * | 1989-10-27 | 1991-04-30 | The Mead Corporation | Methods for the production of microcapsules using functionalized isocyanate |
| US5225118A (en) * | 1990-08-15 | 1993-07-06 | Boise Cascade Corporation | Process for manufacturing polyurea microcapsules and product therefrom |
| DE4130743A1 (de) | 1991-09-16 | 1993-03-18 | Bayer Ag | Mikrokapseln aus isocyanaten mit polyethylenoxidhaltigen gruppen |
| CA2176513C (en) * | 1993-11-15 | 2004-04-13 | Herbert Benson Scher | Microcapsules containing suspensions of biologically active compounds |
| US5925595A (en) * | 1997-09-05 | 1999-07-20 | Monsanto Company | Microcapsules with readily adjustable release rates |
| US6653256B1 (en) * | 1999-08-24 | 2003-11-25 | Bayer Aktiengesellschaft | Microcapsule formulations |
| KR100854530B1 (ko) * | 2000-06-05 | 2008-08-26 | 신젠타 리미티드 | 신규한 마이크로캡슐 |
| CA2311192A1 (en) * | 2000-06-12 | 2001-12-12 | Harald D. H. Stover | Encapsulation process using isocyanate moieties |
| DE10117784A1 (de) * | 2001-04-10 | 2002-10-17 | Bayer Ag | Mikrokapseln |
| US6992047B2 (en) * | 2001-04-11 | 2006-01-31 | Monsanto Technology Llc | Method of microencapsulating an agricultural active having a high melting point and uses for such materials |
| DE10156672A1 (de) * | 2001-11-17 | 2003-05-28 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von Mikrokapseln |
| JP2005528200A (ja) * | 2002-05-31 | 2005-09-22 | マクマスター・ユニバーシテイ | ポリウレアカプセル中に疎水性有機分子をカプセル化する方法 |
| RU2347608C2 (ru) * | 2003-05-11 | 2009-02-27 | Бен-Гурион Юниверсити Оф Дзе Негев Рисерч Энд Дивелопмент Оторити | Инкапсулированные эфирные масла |
| GB0319071D0 (en) * | 2003-08-14 | 2003-09-17 | Avecia Ltd | Catalyst and process |
| GB0526416D0 (en) * | 2005-12-23 | 2006-02-08 | Syngenta Ltd | Formulation |
| GB0603501D0 (en) * | 2006-02-22 | 2006-04-05 | Reaxa Ltd | Catalyst |
| US8143345B2 (en) * | 2007-12-06 | 2012-03-27 | Prc Desoto International, Inc. | Water dispersible, hydroxyl-terminated, fluorinated polyurethanes and method of preparing the same |
-
2010
- 2010-06-25 ES ES10167305.1T patent/ES2628087T3/es active Active
- 2010-06-25 EP EP10167305.1A patent/EP2399667B1/en not_active Not-in-force
-
2011
- 2011-03-05 JP JP2013515739A patent/JP5934703B2/ja not_active Expired - Fee Related
- 2011-03-05 CN CN201180031169.8A patent/CN102958597B/zh not_active Expired - Fee Related
- 2011-03-05 US US13/805,549 patent/US20130095158A1/en not_active Abandoned
- 2011-03-05 KR KR1020127033516A patent/KR101925269B1/ko not_active Expired - Fee Related
- 2011-03-05 RU RU2013101538/05A patent/RU2572889C2/ru active
- 2011-03-05 MX MX2012015042A patent/MX341671B/es active IP Right Grant
- 2011-03-05 CA CA2803420A patent/CA2803420C/en not_active Expired - Fee Related
- 2011-03-05 BR BR112012032634-1A patent/BR112012032634B1/pt not_active IP Right Cessation
- 2011-03-05 WO PCT/EP2011/001098 patent/WO2011160733A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP2399667B1 (en) | 2017-03-08 |
| JP5934703B2 (ja) | 2016-06-15 |
| JP2013537472A (ja) | 2013-10-03 |
| WO2011160733A1 (en) | 2011-12-29 |
| EP2399667A1 (en) | 2011-12-28 |
| CA2803420C (en) | 2018-05-01 |
| ES2628087T3 (es) | 2017-08-01 |
| CN102958597A (zh) | 2013-03-06 |
| KR20130121697A (ko) | 2013-11-06 |
| MX341671B (es) | 2016-08-30 |
| RU2013101538A (ru) | 2014-07-27 |
| US20130095158A1 (en) | 2013-04-18 |
| BR112012032634A2 (pt) | 2018-01-23 |
| CA2803420A1 (en) | 2011-12-29 |
| MX2012015042A (es) | 2013-06-28 |
| RU2572889C2 (ru) | 2016-01-20 |
| CN102958597B (zh) | 2015-05-13 |
| KR101925269B1 (ko) | 2018-12-05 |
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Legal Events
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| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 05/03/2011, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2712 DE 27-12-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |