BR112012020716A2 - processo para a preparação de polióis de poliéter de carbonato com catalisadores de cianeto de duplo metal e na presença de sais de metal. - Google Patents
processo para a preparação de polióis de poliéter de carbonato com catalisadores de cianeto de duplo metal e na presença de sais de metal.Info
- Publication number
- BR112012020716A2 BR112012020716A2 BR112012020716A BR112012020716A BR112012020716A2 BR 112012020716 A2 BR112012020716 A2 BR 112012020716A2 BR 112012020716 A BR112012020716 A BR 112012020716A BR 112012020716 A BR112012020716 A BR 112012020716A BR 112012020716 A2 BR112012020716 A2 BR 112012020716A2
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- polyether polyols
- metal salts
- cyanide catalysts
- carbonate
- Prior art date
Links
- 239000002184 metal Substances 0.000 title abstract 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title abstract 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title abstract 3
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229920000570 polyether Polymers 0.000 title abstract 3
- 229920005862 polyol Polymers 0.000 title abstract 3
- 150000003077 polyols Chemical class 0.000 title abstract 3
- 150000003839 salts Chemical class 0.000 title abstract 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/205—General preparatory processes characterised by the apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2696—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the process or apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyethers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010008410A DE102010008410A1 (de) | 2010-02-18 | 2010-02-18 | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| PCT/EP2011/052337 WO2011101403A1 (de) | 2010-02-18 | 2011-02-17 | Verfahren zur herstellung von polyethercarbonatpolyolen mit doppelmetallcyanidkatalysatoren und in gegenwart von metallsalzen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112012020716A2 true BR112012020716A2 (pt) | 2016-04-26 |
Family
ID=43760092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012020716A BR112012020716A2 (pt) | 2010-02-18 | 2011-02-17 | processo para a preparação de polióis de poliéter de carbonato com catalisadores de cianeto de duplo metal e na presença de sais de metal. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9080010B2 (https=) |
| EP (1) | EP2536778B1 (https=) |
| JP (1) | JP2013519770A (https=) |
| KR (1) | KR20120138232A (https=) |
| CN (1) | CN102869699B (https=) |
| BR (1) | BR112012020716A2 (https=) |
| CA (1) | CA2790038A1 (https=) |
| DE (1) | DE102010008410A1 (https=) |
| ES (1) | ES2471398T3 (https=) |
| MX (1) | MX2012009552A (https=) |
| PL (1) | PL2536778T3 (https=) |
| PT (1) | PT2536778E (https=) |
| SG (1) | SG183223A1 (https=) |
| WO (1) | WO2011101403A1 (https=) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2012011003A (es) * | 2010-03-24 | 2012-10-15 | Bayer Ip Gmbh | Procedimiento para la preparacion de polioletercarbonatos. |
| SG191340A1 (en) | 2010-12-27 | 2013-08-30 | Dow Global Technologies Llc | Alkylene oxide polymerization using a double metal cyanide catalyst complex and a magnesium, group 3-group 15 metal or lanthanide series metal compound |
| EP2548908A1 (de) * | 2011-07-18 | 2013-01-23 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyetherpolyolen |
| SG11201403156XA (en) * | 2011-12-18 | 2014-07-30 | Dow Global Technologies Llc | Process for making hybrid polyester-polyether polyols |
| WO2014072336A1 (de) * | 2012-11-09 | 2014-05-15 | Bayer Materialscience Ag | Verfahren zur herstellung von polyethercarbonatpolyolen |
| CN103214666B (zh) * | 2013-04-28 | 2015-06-10 | 北京旭阳化工技术研究院有限公司 | 连续溶液聚合法制备脂肪族聚碳酸酯的方法 |
| EP2837648A1 (en) * | 2013-08-12 | 2015-02-18 | Repsol, S.A. | Process for preparing polyether carbonate polyols |
| JP2016539231A (ja) * | 2013-11-27 | 2016-12-15 | コベストロ、ドイチュラント、アクチエンゲゼルシャフトＣｏｖｅｓｔｒｏ Ｄｅｕｔｓｃｈｌａｎｄ Ａｇ | ポリウレタンソフト発泡体を製造するためのポリエーテルカーボネートポリオールとポリエーテルポリオールとの混合物 |
| EP2894180A1 (en) * | 2014-01-08 | 2015-07-15 | Bayer MaterialScience AG | Polymer Polyols comprising a Polyether Carbonate Polyol as the Base Polyol |
| KR101466803B1 (ko) * | 2014-02-14 | 2014-11-28 | 부산대학교 산학협력단 | 이중금속시안염 촉매 및 이를 제조하는 방법 |
| US9527958B2 (en) | 2014-05-02 | 2016-12-27 | Covestro Llc | Process for purification of polyether carbonate polyols |
| WO2016120399A1 (en) | 2015-01-28 | 2016-08-04 | Repsol, S.A. | A thermoplastic polyurethane based on polyether carbonate polyol |
| WO2016120406A1 (en) | 2015-01-28 | 2016-08-04 | Repsol, S.A. | A polyurethane adhesive formulation based on polyether carbonate polyol |
| EP3283547B1 (en) | 2015-04-13 | 2021-05-19 | Repsol, S.A. | New formulations for polyurethane applications |
| AR104981A1 (es) * | 2015-06-20 | 2017-08-30 | Dow Global Technologies Llc | Proceso continuo para producir polioles de poliéter que tienen un elevado contenido de óxido de etileno polimerizado, mediante el uso de un complejo catalizador de cianuro de metal doble y un compuesto metálico de la serie de lantanida o metal del grupo 3 - grupo 15, magnesio |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| US10040903B2 (en) | 2016-09-13 | 2018-08-07 | Covestro Llc | Polymer polyol quality |
| EP3538588B1 (en) * | 2016-11-11 | 2023-01-25 | Dow Global Technologies LLC | Polycarbonate based polyols |
| GB201703323D0 (en) * | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyols |
| GB201703331D0 (en) * | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polycarbonate ether polyols |
| PL3622003T3 (pl) * | 2017-05-10 | 2025-02-24 | Dow Global Technologies Llc | Proces polimeryzacji polieterowej |
| GB201717441D0 (en) * | 2017-10-24 | 2017-12-06 | Econic Tech Ltd | A polymerisation process |
| US20190119444A1 (en) * | 2017-10-25 | 2019-04-25 | Covestro Llc | Process to remove dmc catalysts from polyether carbonate polyols |
| EP3546493A1 (en) | 2018-03-28 | 2019-10-02 | Covestro Deutschland AG | Aqueous dispersion |
| WO2019209348A1 (en) | 2018-04-28 | 2019-10-31 | Liang Wang | Polyurethane elastomer with high ultimate elongation |
| MX2021006016A (es) * | 2018-11-22 | 2021-07-06 | Basf Coatings Gmbh | Copolímeros de organoestaño como catalizadores reticulantes poliméricos. |
| CN110922577B (zh) * | 2019-12-10 | 2022-08-23 | 长华化学科技股份有限公司 | 聚醚碳酸酯多元醇的制备方法 |
| CN213739255U (zh) * | 2020-03-23 | 2021-07-20 | 杭州普力材料科技有限公司 | 一种管道化连续生产聚碳酸酯聚醚多元醇的设备 |
| CN112029083B (zh) * | 2020-08-26 | 2022-06-24 | 烟台大学 | 一种聚醚碳酸酯多元醇及其制备方法 |
| CN114425335B (zh) * | 2020-09-16 | 2023-07-04 | 中国石油化工股份有限公司 | 一种合成聚醚胺的双金属催化剂及其制备方法和应用 |
| CN112111056A (zh) * | 2020-09-22 | 2020-12-22 | 河北工业大学 | 一种高活性制备聚醚多元醇或聚醚酯多元醇的双组分催化体系及应用 |
| CN113493563A (zh) * | 2021-07-14 | 2021-10-12 | 扬州工业职业技术学院 | 一种聚醚多元醇及其制备方法、应用 |
| CN113801314B (zh) * | 2021-11-03 | 2023-01-10 | 中国科学院过程工程研究所 | 一种聚碳酸酯的制备方法 |
| CN114054099B (zh) * | 2021-12-06 | 2023-07-11 | 万华化学集团股份有限公司 | 一种Fe3O4@SiO2-2N-CoCl2催化剂、制备方法及其应用 |
| CN116333294B (zh) * | 2023-05-04 | 2023-12-29 | 辽宁奥克药业股份有限公司 | 一种制备嵌段聚醚的催化剂、嵌段聚醚的制备方法 |
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| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| AU552988B2 (en) * | 1982-03-31 | 1986-06-26 | Shell Internationale Research Maatschappij B.V. | Polymerizing epoxides and catalyst suspensions for this |
| GB8528071D0 (en) | 1985-11-14 | 1985-12-18 | Shell Int Research | Polycarbonates |
| US4686276A (en) * | 1985-12-30 | 1987-08-11 | The Dow Chemical Company | Process for preparing poly (alkylene carbonates) |
| JP2653236B2 (ja) | 1990-10-05 | 1997-09-17 | 旭硝子株式会社 | ポリエーテル化合物の製造方法 |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5712216A (en) | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5470813A (en) | 1993-11-23 | 1995-11-28 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5545601A (en) | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5714428A (en) | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
| US5952261A (en) | 1998-03-20 | 1999-09-14 | Arco Chemical Technology, L.P. | Double metal cyanide complex catalysts modified with Group IIA compounds |
| DE19905611A1 (de) | 1999-02-11 | 2000-08-17 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19958355A1 (de) | 1999-12-03 | 2001-06-07 | Bayer Ag | Verfahren zur Herstellung von DMC-Katalysatoren |
| AU2001260217A1 (en) | 2000-04-20 | 2001-11-07 | Bayer Aktiengesellschaft | Method for producing double metal cyanide (dmc) catalysts |
| DE10147712A1 (de) * | 2001-09-27 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung aliphatischer Polycarbonate |
| DE10219028A1 (de) | 2002-04-29 | 2003-11-06 | Bayer Ag | Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten |
| JP4145123B2 (ja) | 2002-11-18 | 2008-09-03 | 株式会社オンダ製作所 | 継手 |
| US7378559B2 (en) | 2003-03-07 | 2008-05-27 | Dow Global Technologies Inc. | Continuous process and system of producing polyether polyols |
| DE502005007676D1 (de) * | 2004-12-10 | 2009-08-20 | Basf Se | Herstellung und verwendung von ultrahochmolekularen polycarbonaten |
| US7268204B2 (en) * | 2005-03-29 | 2007-09-11 | Basf Corporation | Complex of a multimetal cyanide compound and methods of forming polyethercarbonate polyols |
| US20060223979A1 (en) * | 2005-04-04 | 2006-10-05 | Thomas Ostrowski | Process for preparing polyether polyols |
| US8093351B2 (en) * | 2006-08-24 | 2012-01-10 | Cornell Research Foundation, Inc. | Copolymerization of propylene oxide and carbon dioxide and homopolymerization of propylene oxide |
| CN101611074B (zh) * | 2007-01-30 | 2012-07-25 | 巴斯夫欧洲公司 | 制备聚醚碳酸酯多元醇的方法 |
-
2010
- 2010-02-18 DE DE102010008410A patent/DE102010008410A1/de not_active Withdrawn
-
2011
- 2011-02-17 JP JP2012553314A patent/JP2013519770A/ja active Pending
- 2011-02-17 PT PT117042226T patent/PT2536778E/pt unknown
- 2011-02-17 EP EP11704222.6A patent/EP2536778B1/de not_active Not-in-force
- 2011-02-17 MX MX2012009552A patent/MX2012009552A/es active IP Right Grant
- 2011-02-17 ES ES11704222.6T patent/ES2471398T3/es active Active
- 2011-02-17 US US13/579,222 patent/US9080010B2/en not_active Expired - Fee Related
- 2011-02-17 KR KR1020127021541A patent/KR20120138232A/ko not_active Withdrawn
- 2011-02-17 BR BR112012020716A patent/BR112012020716A2/pt not_active IP Right Cessation
- 2011-02-17 SG SG2012058707A patent/SG183223A1/en unknown
- 2011-02-17 WO PCT/EP2011/052337 patent/WO2011101403A1/de not_active Ceased
- 2011-02-17 CN CN201180019729.8A patent/CN102869699B/zh not_active Expired - Fee Related
- 2011-02-17 CA CA2790038A patent/CA2790038A1/en not_active Abandoned
- 2011-02-17 PL PL11704222T patent/PL2536778T3/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES2471398T3 (es) | 2014-06-26 |
| DE102010008410A1 (de) | 2011-08-18 |
| SG183223A1 (en) | 2012-09-27 |
| PT2536778E (pt) | 2014-06-24 |
| EP2536778A1 (de) | 2012-12-26 |
| KR20120138232A (ko) | 2012-12-24 |
| MX2012009552A (es) | 2012-09-12 |
| JP2013519770A (ja) | 2013-05-30 |
| US9080010B2 (en) | 2015-07-14 |
| EP2536778B1 (de) | 2014-04-23 |
| US20130190462A1 (en) | 2013-07-25 |
| CN102869699B (zh) | 2015-06-17 |
| CN102869699A (zh) | 2013-01-09 |
| CA2790038A1 (en) | 2011-08-25 |
| WO2011101403A1 (de) | 2011-08-25 |
| PL2536778T3 (pl) | 2014-09-30 |
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