BR112012014147A2 - processo de produção de acroleína e/ou de ácido acrílico, a partir de glicerol - Google Patents

processo de produção de acroleína e/ou de ácido acrílico, a partir de glicerol

Info

Publication number
BR112012014147A2
BR112012014147A2 BR112012014147A BR112012014147A BR112012014147A2 BR 112012014147 A2 BR112012014147 A2 BR 112012014147A2 BR 112012014147 A BR112012014147 A BR 112012014147A BR 112012014147 A BR112012014147 A BR 112012014147A BR 112012014147 A2 BR112012014147 A2 BR 112012014147A2
Authority
BR
Brazil
Prior art keywords
acrolein
glycerol
acrylic acid
production process
dehydration
Prior art date
Application number
BR112012014147A
Other languages
English (en)
Inventor
Jean-Paul Combet
Jean-Francois Devaux
Michel Fauconet
Nabil Tlili
Philippe Haller
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BR112012014147A2 publication Critical patent/BR112012014147A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C07C45/85—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/52—Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"processo de produção de acroleína e/ou de ácido acrílico, a partir de glicerol". a presente invenção refere-se à produção de acroleína e de ácido acrílico biorrecorridos a partir de glicerol, como matéria-prima e se inscreve mais particularmente no âmbito de um processo de produção de acroleína e de ácido acrílico, segundo o qual se efetua a reação de desidratação de glicerol em acroleína e utiliza-se uma etapa de oxidação de uma fase rica em água separada do meio reacional, oriundo dessa reação de desidratação, antes de sua reciclagem na etapa de desidratação do glicerol. esse tratamento de oxidação permite evitar o acúmulo de impurezas orgânicas no decorrer do processo, minimizando o consumo de água e a rejeição de fluxo aquosos poluídos.
BR112012014147A 2009-12-14 2010-12-13 processo de produção de acroleína e/ou de ácido acrílico, a partir de glicerol BR112012014147A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0958937A FR2953830B1 (fr) 2009-12-14 2009-12-14 Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
US31423410P 2010-03-16 2010-03-16
PCT/FR2010/052692 WO2011080447A1 (fr) 2009-12-14 2010-12-13 Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol

Publications (1)

Publication Number Publication Date
BR112012014147A2 true BR112012014147A2 (pt) 2017-01-24

Family

ID=42270078

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012014147A BR112012014147A2 (pt) 2009-12-14 2010-12-13 processo de produção de acroleína e/ou de ácido acrílico, a partir de glicerol

Country Status (12)

Country Link
US (1) US8609904B2 (pt)
EP (1) EP2513027B1 (pt)
JP (1) JP5784627B2 (pt)
KR (1) KR101802543B1 (pt)
CN (1) CN102639478B (pt)
BR (1) BR112012014147A2 (pt)
FR (1) FR2953830B1 (pt)
IN (1) IN2012DN04890A (pt)
MY (1) MY157406A (pt)
SG (1) SG181693A1 (pt)
TW (1) TWI468383B (pt)
WO (1) WO2011080447A1 (pt)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2953829B1 (fr) * 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
JP2013075842A (ja) * 2011-09-29 2013-04-25 Nippon Shokubai Co Ltd アクロレインの製造方法、アクリル酸の製造方法、および親水性樹脂の製造方法
CN103827070A (zh) * 2011-09-29 2014-05-28 株式会社日本触媒 丙烯醛、丙烯酸及其衍生物的制备方法
KR102044428B1 (ko) 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN106622040B (zh) * 2017-01-18 2019-10-18 中国科学院过程工程研究所 一种采用移动床反应器制备丙烯酸和/或丙烯酸酯的系统及其制备方法
CN109304190B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油制丙烯醛用催化剂
CN108409044B (zh) 2018-04-04 2019-04-16 蓝星安迪苏南京有限公司 用于处理丙烯醛反应器废水的方法及装置
TWI756748B (zh) * 2020-07-22 2022-03-01 華懋科技股份有限公司 節能型雙轉輪冷側旁通過溫控制系統及其方法
US12031719B2 (en) 2020-07-22 2024-07-09 Desiccant Technology Corporation System and method to prevent the oxidizer overheating using cold side bypass during high input for a VOCS treatment system with series rotor
TWI823017B (zh) * 2020-07-22 2023-11-21 華懋科技股份有限公司 節能型雙轉輪高濃度冷側旁通過溫控制系統及其方法
CN114653306B (zh) * 2022-03-14 2023-07-21 北京奥科瑞丰新能源股份有限公司 一种用于糠醛生产的具有自动加碱机构的中和反应釜

Family Cites Families (32)

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FR695931A (fr) 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
US2558520A (en) 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
US3433840A (en) 1966-12-29 1969-03-18 Sumitomo Chemical Co Process for recovering acrolein by quenching,absorption and plural distillation
BE786398A (fr) 1971-07-21 1973-01-18 Basf Ag Procede de preparation de l'acide acrylique anhydre
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE4308087C2 (de) 1993-03-13 1997-02-06 Basf Ag Verfahren zur Abtrennung von Acrylsäure aus den Reaktionsgasen der katalytischen Oxidation von Propylen und/oder Acrolein
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FR2775685B1 (fr) * 1998-03-05 2000-12-29 Rhone Poulenc Fibres Procede de separation et de purification de l'acide adipique
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DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
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FR2835831B1 (fr) 2002-02-12 2006-09-01 Aventis Animal Nutrition Sa Procede de purification de l'acroleine
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JP5006507B2 (ja) 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
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FR2882053B1 (fr) 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
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EP1847522A1 (en) * 2006-04-18 2007-10-24 INEOS Phenol GmbH & Co. KG Process for removal of hydroxyacetone from phenol
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FR2909999B1 (fr) * 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol
BRPI0704952A2 (pt) 2007-04-04 2008-11-18 Rohm & Haas mÉtodo para a purificaÇço de glicerol
FR2921361B1 (fr) 2007-09-20 2012-10-12 Arkema France Procede de fabrication d'acroleine a partir de glycerol
FR2928648B1 (fr) 2008-03-12 2012-03-02 Arkema France Systeme de compression

Also Published As

Publication number Publication date
SG181693A1 (en) 2012-07-30
CN102639478A (zh) 2012-08-15
FR2953830A1 (fr) 2011-06-17
US20120302797A1 (en) 2012-11-29
WO2011080447A1 (fr) 2011-07-07
TWI468383B (zh) 2015-01-11
CN102639478B (zh) 2015-04-01
US8609904B2 (en) 2013-12-17
EP2513027B1 (fr) 2014-08-13
KR101802543B1 (ko) 2017-11-28
MY157406A (en) 2016-06-15
FR2953830B1 (fr) 2012-01-20
KR20120105029A (ko) 2012-09-24
JP2013513593A (ja) 2013-04-22
JP5784627B2 (ja) 2015-09-24
TW201136887A (en) 2011-11-01
IN2012DN04890A (pt) 2015-09-25
EP2513027A1 (fr) 2012-10-24

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B11B Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements