BR0203782A - Processo para produçao de ácido acrìlico - Google Patents

Processo para produçao de ácido acrìlico

Info

Publication number
BR0203782A
BR0203782A BR0203782-3A BR0203782A BR0203782A BR 0203782 A BR0203782 A BR 0203782A BR 0203782 A BR0203782 A BR 0203782A BR 0203782 A BR0203782 A BR 0203782A
Authority
BR
Brazil
Prior art keywords
catalyst
acrylic acid
indicates
element selected
group
Prior art date
Application number
BR0203782-3A
Other languages
English (en)
Inventor
Hiromi Yunoki
Original Assignee
Nippon Catalytic Chem Ind
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Catalytic Chem Ind filed Critical Nippon Catalytic Chem Ind
Publication of BR0203782A publication Critical patent/BR0203782A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA PRODUçãO DE áCIDO ACRìLICO". A presente invenção provê um processo para produção de ácido acrílico, que resolva o problema da deterioração mais rápida do catalisador introduzido no lado da entrada de gás do que o colocado no lado de saída do gás, para tornar possível a utilização estável do mesmo por um período longo de tempo. O processo para produção de ácido acrílico de acordo com a presente invenção, compreende a etapa de realizar oxidação catalítica em fase gasosa com um reator de casco e tubo de leito fixo com recheio de catalisador, utilizando como catalisador um óxido com a seguinte fórmula geral Mo~ a~V~ b~A~c~B~d~C~ e~O~f~ (1) (em que A indica pelo menos um elemento selecionado do grupo que consiste em nióbio e tungstênio; B indica pelo menos um elemento selecionado do grupo que consiste em cromo, manganês, ferro, cobalto, níquel, cobre, zinco e bismuto; C indica pelo menos um elemento selecionado do grupo que consiste em fósforo, estanho, antimónio, e telúrio); tendo pelo menos duas zonas de reação constituídas pela divisão do interior de cada tubo de reação do reator casco e tubo de leito fixo, na direção axial, recheadas com o catalisador, com ajuste do tipo e/ou montante do componente A e/ou do tipo e/ou montante do componente B.
BR0203782-3A 2001-09-19 2002-09-17 Processo para produçao de ácido acrìlico BR0203782A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001285033A JP5134745B2 (ja) 2001-09-19 2001-09-19 アクリル酸の製造方法

Publications (1)

Publication Number Publication Date
BR0203782A true BR0203782A (pt) 2003-06-03

Family

ID=19108250

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0203782-3A BR0203782A (pt) 2001-09-19 2002-09-17 Processo para produçao de ácido acrìlico

Country Status (9)

Country Link
US (1) US6949675B2 (pt)
EP (1) EP1295636B1 (pt)
JP (1) JP5134745B2 (pt)
KR (1) KR100585288B1 (pt)
CN (1) CN1266106C (pt)
BR (1) BR0203782A (pt)
DE (1) DE60229194D1 (pt)
MY (1) MY129367A (pt)
TW (1) TW583022B (pt)

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US7381413B1 (en) * 1998-04-17 2008-06-03 University Of Vermont And State Agricultural College Methods and products related to metabolic interactions in disease
JP4646684B2 (ja) * 2005-04-18 2011-03-09 株式会社日本触媒 気相酸化触媒およびそれを用いたアクリル酸の製造方法
JP4947917B2 (ja) * 2005-04-18 2012-06-06 株式会社日本触媒 気相接触酸化用の固定床反応器およびアクロレインまたはアクリル酸の製造方法
WO2007004662A1 (ja) * 2005-07-05 2007-01-11 Mitsubishi Rayon Co., Ltd. 触媒の製造方法
CN100386300C (zh) * 2006-05-19 2008-05-07 湖南大学 烯烃氧化制备α-烯酸的方法
US8394377B2 (en) * 2008-02-21 2013-03-12 The Regents Of The University Of Colorado Methods for treating cancer using combination therapy
JP2011116660A (ja) * 2008-03-18 2011-06-16 Nippon Shokubai Co Ltd 接触気相酸化方法
US20110112325A1 (en) * 2008-09-30 2011-05-12 Michio Tanimoto Catalyst for producing acrolein and/or acrylic acid and process for producing acrolein and/or acrylic acid using the catalyst
JP5548132B2 (ja) * 2008-09-30 2014-07-16 株式会社日本触媒 アクリル酸製造用の触媒および該触媒を用いたアクリル酸の製造方法
JP5680373B2 (ja) * 2010-11-01 2015-03-04 日本化薬株式会社 触媒及びアクリル酸の製造方法
CN104185617B (zh) * 2012-03-29 2016-03-16 株式会社日本触媒 使用固定床多管式反应器的丙烯酸的制备方法
CN105582950B (zh) * 2014-10-21 2017-11-07 中国石油化工股份有限公司 一种用于生产丙烯酸的催化剂及其制备和使用方法
TWI592209B (zh) 2016-03-31 2017-07-21 國立清華大學 反應器及其溫度的控制方法
CN109304155B (zh) * 2017-07-28 2021-07-30 中国石油化工股份有限公司 丙烯酸合成用催化剂
CN109304157A (zh) * 2017-07-28 2019-02-05 中国石油化工股份有限公司 丙烯醛氧化制丙烯酸的催化剂
CN109305905B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 丙烯酸合成的方法
CN110586121A (zh) * 2018-06-12 2019-12-20 中国石油化工股份有限公司 负载型丙烯酸催化剂
WO2021055220A1 (en) * 2019-09-18 2021-03-25 Rohm And Haas Company Production of acrolein or acrylic acid from allyl alcohol with high yield and low impurity
WO2021145233A1 (ja) 2020-01-14 2021-07-22 株式会社日本触媒 アクリル酸の製造方法

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JP4426069B2 (ja) * 2000-06-12 2010-03-03 株式会社日本触媒 アクリル酸の製造方法

Also Published As

Publication number Publication date
DE60229194D1 (de) 2008-11-20
KR20030025184A (ko) 2003-03-28
US20030125580A1 (en) 2003-07-03
EP1295636A2 (en) 2003-03-26
US6949675B2 (en) 2005-09-27
EP1295636A3 (en) 2003-08-06
TW583022B (en) 2004-04-11
CN1266106C (zh) 2006-07-26
CN1408700A (zh) 2003-04-09
JP2003089671A (ja) 2003-03-28
MY129367A (en) 2007-03-30
JP5134745B2 (ja) 2013-01-30
EP1295636B1 (en) 2008-10-08
KR100585288B1 (ko) 2006-05-30

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE 7A. ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2055 DE 25/05/2010.