BG63505B1 - Формовъчна смес, метод за получаване и използването й - Google Patents
Формовъчна смес, метод за получаване и използването й Download PDFInfo
- Publication number
- BG63505B1 BG63505B1 BG101975A BG10197597A BG63505B1 BG 63505 B1 BG63505 B1 BG 63505B1 BG 101975 A BG101975 A BG 101975A BG 10197597 A BG10197597 A BG 10197597A BG 63505 B1 BG63505 B1 BG 63505B1
- Authority
- BG
- Bulgaria
- Prior art keywords
- weight
- ethylene
- methyl methacrylate
- molding mixture
- polymerization
- Prior art date
Links
- 238000000465 moulding Methods 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 239000004576 sand Substances 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000005977 Ethylene Substances 0.000 claims abstract description 37
- 239000000203 mixture Substances 0.000 claims abstract description 35
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000178 monomer Substances 0.000 claims abstract description 18
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims description 20
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 10
- 239000003999 initiator Substances 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- 238000005469 granulation Methods 0.000 claims description 2
- 230000003179 granulation Effects 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 claims 1
- 238000009757 thermoplastic moulding Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 229920001577 copolymer Polymers 0.000 description 12
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 10
- 239000004926 polymethyl methacrylate Substances 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000007334 copolymerization reaction Methods 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- -1 polyethylene Polymers 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 229920000193 polymethacrylate Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- CWERGRDVMFNCDR-UHFFFAOYSA-N alpha-mercaptoacetic acid Natural products OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- AGEZXYOZHKGVCM-UHFFFAOYSA-N benzyl bromide Chemical compound BrCC1=CC=CC=C1 AGEZXYOZHKGVCM-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- VKLYZBPBDRELST-UHFFFAOYSA-N ethene;methyl 2-methylprop-2-enoate Chemical group C=C.COC(=O)C(C)=C VKLYZBPBDRELST-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- YLOWTPHXXDJBAH-UHFFFAOYSA-N methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.COC(=O)C(C)=C YLOWTPHXXDJBAH-UHFFFAOYSA-N 0.000 description 1
- LDTLDBDUBGAEDT-UHFFFAOYSA-N methyl 3-sulfanylpropanoate Chemical compound COC(=O)CCS LDTLDBDUBGAEDT-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Mold Materials And Core Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Graft Or Block Polymers (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19607003A DE19607003C2 (de) | 1996-02-24 | 1996-02-24 | Thermoplastisch verarbeitbare Formmasse auf Polymethylmethacrylat-Basis mit Ethylen-Comonomer und Verfahren zu ihrer Herstellung |
| PCT/EP1997/000503 WO1997031043A1 (de) | 1996-02-24 | 1997-02-05 | Polymethacrylat-formmasse mit ethylen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BG101975A BG101975A (en) | 1998-05-29 |
| BG63505B1 true BG63505B1 (bg) | 2002-03-29 |
Family
ID=7786353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG101975A BG63505B1 (bg) | 1996-02-24 | 1997-10-15 | Формовъчна смес, метод за получаване и използването й |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5872202A (cs) |
| EP (1) | EP0830399B1 (cs) |
| JP (1) | JPH11504678A (cs) |
| AT (1) | ATE224407T1 (cs) |
| AU (1) | AU1600797A (cs) |
| BG (1) | BG63505B1 (cs) |
| CZ (1) | CZ291351B6 (cs) |
| DE (2) | DE19607003C2 (cs) |
| DK (1) | DK0830399T3 (cs) |
| ES (1) | ES2180924T3 (cs) |
| SK (1) | SK284035B6 (cs) |
| TW (1) | TW389771B (cs) |
| WO (1) | WO1997031043A1 (cs) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6407179B1 (en) * | 1999-11-02 | 2002-06-18 | Denki Kagaku Kogyo Kabushiki Kaisha | Acrylic rubber and its composition |
| JP4742647B2 (ja) * | 2005-03-31 | 2011-08-10 | 住友化学株式会社 | 極性モノマー−オレフィン共重合体の製造方法 |
| CN105255084B (zh) * | 2015-10-27 | 2017-07-21 | 上海锦湖日丽塑料有限公司 | 一种具有优异外观性能的高韧性pmma树脂 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE607096A (cs) * | 1960-08-22 | |||
| NL293879A (cs) * | 1963-01-03 | |||
| US3770627A (en) * | 1971-12-07 | 1973-11-06 | Phillips Petroleum Co | Containing and removing oil spills on water |
| GB1423288A (en) * | 1972-08-15 | 1976-02-04 | Mitsubishi Rayon Co | Process for the production of methacrylate polymer moulding materials |
| DE2941586A1 (de) * | 1979-10-13 | 1981-04-23 | Bayer Ag, 5090 Leverkusen | Kontaktlinsen aus methacrylsaeuremethylester-copolymerisaten |
| JPS57149313A (en) * | 1981-03-13 | 1982-09-14 | Asahi Chem Ind Co Ltd | Methacrylic resin having good mold flow and its production |
| JPH0699521B2 (ja) * | 1984-06-11 | 1994-12-07 | 出光興産株式会社 | エチレン共重合体の製造法 |
| DE68912075T2 (de) * | 1988-10-31 | 1994-07-07 | Japan Synthetic Rubber Co Ltd | Estergruppen enthaltende (Meth-)acrylsäureester, ihre (Co-)polymere, den (Co)polymer enthaltende Komposition und die Estergruppe aufweisende (Meth)acrylsäureester enthaltende Komposition. |
| US5506322A (en) * | 1991-01-28 | 1996-04-09 | Toyoda Gosei Co., Ltd. | Acrylic rubber composition and rubber hose obtained using the same |
| DE4219129A1 (de) * | 1992-06-11 | 1993-12-16 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten des Ethylens mit Acrylsäureestern |
| DE4219983A1 (de) * | 1992-06-19 | 1993-12-23 | Basf Ag | Verfahren zur Herstellung von Copolymerisaten des Ethylens mit Acrylsäureestern oder Acrylsäure |
-
1996
- 1996-02-24 DE DE19607003A patent/DE19607003C2/de not_active Expired - Fee Related
-
1997
- 1997-02-05 JP JP9529739A patent/JPH11504678A/ja active Pending
- 1997-02-05 DE DE59708249T patent/DE59708249D1/de not_active Expired - Lifetime
- 1997-02-05 AU AU16007/97A patent/AU1600797A/en not_active Abandoned
- 1997-02-05 DK DK97902324T patent/DK0830399T3/da active
- 1997-02-05 CZ CZ19973359A patent/CZ291351B6/cs not_active IP Right Cessation
- 1997-02-05 WO PCT/EP1997/000503 patent/WO1997031043A1/de not_active Ceased
- 1997-02-05 EP EP97902324A patent/EP0830399B1/de not_active Expired - Lifetime
- 1997-02-05 AT AT97902324T patent/ATE224407T1/de not_active IP Right Cessation
- 1997-02-05 SK SK1433-97A patent/SK284035B6/sk unknown
- 1997-02-05 US US08/945,268 patent/US5872202A/en not_active Expired - Fee Related
- 1997-02-05 ES ES97902324T patent/ES2180924T3/es not_active Expired - Lifetime
- 1997-02-21 TW TW086102100A patent/TW389771B/zh not_active IP Right Cessation
- 1997-10-15 BG BG101975A patent/BG63505B1/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JPH11504678A (ja) | 1999-04-27 |
| SK284035B6 (sk) | 2004-08-03 |
| WO1997031043A1 (de) | 1997-08-28 |
| ES2180924T3 (es) | 2003-02-16 |
| TW389771B (en) | 2000-05-11 |
| DE59708249D1 (de) | 2002-10-24 |
| SK143397A3 (en) | 1998-02-04 |
| EP0830399A1 (de) | 1998-03-25 |
| US5872202A (en) | 1999-02-16 |
| CZ291351B6 (cs) | 2003-02-12 |
| DK0830399T3 (da) | 2003-01-27 |
| DE19607003A1 (de) | 1997-08-28 |
| DE19607003C2 (de) | 1998-09-24 |
| EP0830399B1 (de) | 2002-09-18 |
| AU1600797A (en) | 1997-09-10 |
| CZ335997A3 (cs) | 1998-03-18 |
| ATE224407T1 (de) | 2002-10-15 |
| BG101975A (en) | 1998-05-29 |
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