BG107646A - Метод за отделяне на малки количества органична сяра от въглеводородни горива - Google Patents
Метод за отделяне на малки количества органична сяра от въглеводородни горива Download PDFInfo
- Publication number
- BG107646A BG107646A BG107646A BG10764603A BG107646A BG 107646 A BG107646 A BG 107646A BG 107646 A BG107646 A BG 107646A BG 10764603 A BG10764603 A BG 10764603A BG 107646 A BG107646 A BG 107646A
- Authority
- BG
- Bulgaria
- Prior art keywords
- sulfur
- oxidation
- fuel
- hydrogen peroxide
- acid
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 73
- 238000000034 method Methods 0.000 title claims abstract description 44
- 230000008569 process Effects 0.000 title claims abstract description 19
- 229930195733 hydrocarbon Natural products 0.000 title claims description 31
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 29
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 21
- 125000001741 organic sulfur group Chemical group 0.000 title claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 134
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 117
- 239000011593 sulfur Substances 0.000 claims abstract description 117
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 113
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims abstract description 80
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims abstract description 40
- 235000019253 formic acid Nutrition 0.000 claims abstract description 40
- 230000001590 oxidative effect Effects 0.000 claims abstract description 24
- IYYZUPMFVPLQIF-UHFFFAOYSA-N dibenzothiophene sulfoxide Natural products C1=CC=C2C3=CC=CC=C3SC2=C1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002283 diesel fuel Substances 0.000 claims abstract description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 73
- 230000003647 oxidation Effects 0.000 claims description 70
- 239000000243 solution Substances 0.000 claims description 50
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 43
- 238000000605 extraction Methods 0.000 claims description 38
- 239000002253 acid Substances 0.000 claims description 37
- 238000000926 separation method Methods 0.000 claims description 33
- 150000003464 sulfur compounds Chemical class 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 22
- 239000012071 phase Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 19
- 239000003921 oil Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000004821 distillation Methods 0.000 claims description 17
- 239000007789 gas Substances 0.000 claims description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
- 150000002978 peroxides Chemical class 0.000 claims description 15
- 150000003457 sulfones Chemical class 0.000 claims description 14
- ZQRGREQWCRSUCI-UHFFFAOYSA-N [S].C=1C=CSC=1 Chemical compound [S].C=1C=CSC=1 ZQRGREQWCRSUCI-UHFFFAOYSA-N 0.000 claims description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 11
- 150000002898 organic sulfur compounds Chemical class 0.000 claims description 11
- -1 sulfur organic compounds Chemical class 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000013021 overheating Methods 0.000 claims description 10
- 238000001179 sorption measurement Methods 0.000 claims description 10
- 230000000694 effects Effects 0.000 claims description 9
- 239000000292 calcium oxide Substances 0.000 claims description 8
- 235000012255 calcium oxide Nutrition 0.000 claims description 8
- 230000008901 benefit Effects 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000003350 kerosene Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 5
- 239000010779 crude oil Substances 0.000 claims description 5
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- 238000003795 desorption Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 4
- 238000002474 experimental method Methods 0.000 claims description 4
- 230000003993 interaction Effects 0.000 claims description 4
- 238000011084 recovery Methods 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 238000002336 sorption--desorption measurement Methods 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000007420 reactivation Effects 0.000 claims description 3
- 238000007086 side reaction Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- 230000033228 biological regulation Effects 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 238000005191 phase separation Methods 0.000 claims description 2
- 239000002798 polar solvent Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 150000003577 thiophenes Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 claims 10
- 239000002994 raw material Substances 0.000 claims 10
- 238000012360 testing method Methods 0.000 claims 7
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 5
- 230000005484 gravity Effects 0.000 claims 5
- 239000003208 petroleum Substances 0.000 claims 5
- 239000000571 coke Substances 0.000 claims 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 3
- 238000004458 analytical method Methods 0.000 claims 3
- 229910052739 hydrogen Inorganic materials 0.000 claims 3
- 239000001257 hydrogen Substances 0.000 claims 3
- 229930192474 thiophene Natural products 0.000 claims 3
- 208000004998 Abdominal Pain Diseases 0.000 claims 2
- 208000002881 Colic Diseases 0.000 claims 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 2
- 235000011613 Pinus brutia Nutrition 0.000 claims 2
- 241000018646 Pinus brutia Species 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- 239000008186 active pharmaceutical agent Substances 0.000 claims 2
- 239000012670 alkaline solution Substances 0.000 claims 2
- 239000011260 aqueous acid Substances 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 2
- 238000009472 formulation Methods 0.000 claims 2
- 210000003128 head Anatomy 0.000 claims 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims 2
- 229910052740 iodine Inorganic materials 0.000 claims 2
- 238000004949 mass spectrometry Methods 0.000 claims 2
- 230000004048 modification Effects 0.000 claims 2
- 238000012986 modification Methods 0.000 claims 2
- 230000035515 penetration Effects 0.000 claims 2
- 238000000746 purification Methods 0.000 claims 2
- 238000004064 recycling Methods 0.000 claims 2
- 230000008929 regeneration Effects 0.000 claims 2
- 238000011069 regeneration method Methods 0.000 claims 2
- 239000002002 slurry Substances 0.000 claims 2
- 238000003756 stirring Methods 0.000 claims 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims 1
- 206010067484 Adverse reaction Diseases 0.000 claims 1
- 240000002234 Allium sativum Species 0.000 claims 1
- 241000272517 Anseriformes Species 0.000 claims 1
- 206010003497 Asphyxia Diseases 0.000 claims 1
- 241000070918 Cima Species 0.000 claims 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 235000010205 Cola acuminata Nutrition 0.000 claims 1
- 244000228088 Cola acuminata Species 0.000 claims 1
- 235000015438 Cola nitida Nutrition 0.000 claims 1
- 241001522296 Erithacus rubecula Species 0.000 claims 1
- 235000016623 Fragaria vesca Nutrition 0.000 claims 1
- 240000009088 Fragaria x ananassa Species 0.000 claims 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 claims 1
- 241000447437 Gerreidae Species 0.000 claims 1
- LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 claims 1
- 241001272567 Hominoidea Species 0.000 claims 1
- 101001126819 Homo sapiens PH-interacting protein Proteins 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 241001026509 Kata Species 0.000 claims 1
- 241000406668 Loxodonta cyclotis Species 0.000 claims 1
- 101000844073 Odontomachus monticola U-poneritoxin(01)-Om5a Proteins 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 102100030275 PH-interacting protein Human genes 0.000 claims 1
- 208000030555 Pygmy Diseases 0.000 claims 1
- 101100042848 Rattus norvegicus Smok gene Proteins 0.000 claims 1
- 240000006394 Sorghum bicolor Species 0.000 claims 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 claims 1
- 244000299461 Theobroma cacao Species 0.000 claims 1
- 235000009470 Theobroma cacao Nutrition 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- 101150054429 Tprn gene Proteins 0.000 claims 1
- 241000251221 Triakidae Species 0.000 claims 1
- 206010052428 Wound Diseases 0.000 claims 1
- 208000027418 Wounds and injury Diseases 0.000 claims 1
- 206010048232 Yawning Diseases 0.000 claims 1
- 241001080519 Zera Species 0.000 claims 1
- GQCYCMFGFVGYJT-UHFFFAOYSA-N [AlH3].[S] Chemical compound [AlH3].[S] GQCYCMFGFVGYJT-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 150000007513 acids Chemical class 0.000 claims 1
- 239000012190 activator Substances 0.000 claims 1
- 239000000853 adhesive Substances 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 claims 1
- 230000006838 adverse reaction Effects 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 230000004075 alteration Effects 0.000 claims 1
- 238000000137 annealing Methods 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 238000003776 cleavage reaction Methods 0.000 claims 1
- 210000001520 comb Anatomy 0.000 claims 1
- 239000000306 component Substances 0.000 claims 1
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 235000019784 crude fat Nutrition 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 238000005520 cutting process Methods 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 238000005202 decontamination Methods 0.000 claims 1
- 230000003588 decontaminative effect Effects 0.000 claims 1
- 238000006356 dehydrogenation reaction Methods 0.000 claims 1
- 230000029087 digestion Effects 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 230000009977 dual effect Effects 0.000 claims 1
- 206010015037 epilepsy Diseases 0.000 claims 1
- 235000019197 fats Nutrition 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 claims 1
- 238000011049 filling Methods 0.000 claims 1
- 239000012467 final product Substances 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 230000004907 flux Effects 0.000 claims 1
- 239000006260 foam Substances 0.000 claims 1
- 235000013305 food Nutrition 0.000 claims 1
- 210000001061 forehead Anatomy 0.000 claims 1
- 150000002240 furans Chemical class 0.000 claims 1
- 235000004611 garlic Nutrition 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000004128 high performance liquid chromatography Methods 0.000 claims 1
- 229940063183 hyophen Drugs 0.000 claims 1
- 239000012535 impurity Substances 0.000 claims 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 1
- 239000011630 iodine Substances 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 238000000622 liquid--liquid extraction Methods 0.000 claims 1
- 239000000401 methanolic extract Substances 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- 230000003472 neutralizing effect Effects 0.000 claims 1
- 239000003758 nuclear fuel Substances 0.000 claims 1
- 238000006213 oxygenation reaction Methods 0.000 claims 1
- 210000004197 pelvis Anatomy 0.000 claims 1
- 210000002640 perineum Anatomy 0.000 claims 1
- 230000035699 permeability Effects 0.000 claims 1
- 239000002574 poison Substances 0.000 claims 1
- 231100000614 poison Toxicity 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 229910052705 radium Inorganic materials 0.000 claims 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 claims 1
- 238000010992 reflux Methods 0.000 claims 1
- 230000001850 reproductive effect Effects 0.000 claims 1
- 238000012552 review Methods 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 230000007017 scission Effects 0.000 claims 1
- 230000001953 sensory effect Effects 0.000 claims 1
- 230000035943 smell Effects 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 238000000638 solvent extraction Methods 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 claims 1
- 229910052815 sulfur oxide Inorganic materials 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 101150104615 tadh gene Proteins 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 230000032258 transport Effects 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
- 238000009736 wetting Methods 0.000 claims 1
- 230000003009 desulfurizing effect Effects 0.000 abstract 1
- IYYZUPMFVPLQIF-ALWQSETLSA-N dibenzothiophene Chemical class C1=CC=CC=2[34S]C3=C(C=21)C=CC=C3 IYYZUPMFVPLQIF-ALWQSETLSA-N 0.000 abstract 1
- 239000003209 petroleum derivative Substances 0.000 abstract 1
- 239000003502 gasoline Substances 0.000 description 5
- 239000010705 motor oil Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 3
- FCEHBMOGCRZNNI-UHFFFAOYSA-N 1-benzothiophene Chemical compound C1=CC=C2SC=CC2=C1 FCEHBMOGCRZNNI-UHFFFAOYSA-N 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000013178 mathematical model Methods 0.000 description 2
- 102100039339 Atrial natriuretic peptide receptor 1 Human genes 0.000 description 1
- 241000252206 Cypriniformes Species 0.000 description 1
- 208000005156 Dehydration Diseases 0.000 description 1
- 101000961044 Homo sapiens Atrial natriuretic peptide receptor 1 Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- JSOQIZDOEIKRLY-UHFFFAOYSA-N n-propylnitrous amide Chemical compound CCCNN=O JSOQIZDOEIKRLY-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B25/00—Doors or closures for coke ovens
- C10B25/20—Lids or closures for charging holes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/654,016 US6402940B1 (en) | 2000-09-01 | 2000-09-01 | Process for removing low amounts of organic sulfur from hydrocarbon fuels |
| PCT/US2001/041554 WO2002018518A1 (en) | 2000-09-01 | 2001-08-03 | Process for removing low amounts of organic sulfur from hydrocarbon fuels |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG107646A true BG107646A (bg) | 2003-10-31 |
Family
ID=24623157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG107646A BG107646A (bg) | 2000-09-01 | 2003-03-19 | Метод за отделяне на малки количества органична сяра от въглеводородни горива |
Country Status (29)
| Country | Link |
|---|---|
| US (2) | US6402940B1 (cs) |
| EP (1) | EP1315785B1 (cs) |
| JP (1) | JP4216586B2 (cs) |
| KR (1) | KR100815598B1 (cs) |
| CN (1) | CN1257254C (cs) |
| AR (1) | AR030589A1 (cs) |
| AT (1) | ATE388215T1 (cs) |
| AU (2) | AU2001279318B2 (cs) |
| BG (1) | BG107646A (cs) |
| BR (1) | BR0113603A (cs) |
| CA (1) | CA2420699A1 (cs) |
| CZ (1) | CZ2003598A3 (cs) |
| DE (1) | DE60133110T2 (cs) |
| EA (1) | EA005298B1 (cs) |
| EC (1) | ECSP034497A (cs) |
| ES (1) | ES2303835T3 (cs) |
| HR (1) | HRP20030144A2 (cs) |
| HU (1) | HUP0300877A3 (cs) |
| IL (1) | IL154567A0 (cs) |
| MX (1) | MXPA03001738A (cs) |
| NO (1) | NO20030953L (cs) |
| NZ (1) | NZ524407A (cs) |
| PL (1) | PL194786B1 (cs) |
| PT (1) | PT1315785E (cs) |
| SK (1) | SK2512003A3 (cs) |
| TW (1) | TWI243202B (cs) |
| UA (1) | UA74002C2 (cs) |
| WO (1) | WO2002018518A1 (cs) |
| ZA (1) | ZA200301464B (cs) |
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