AU669163B2 - Aqueous cleaning composition containing protein binding dye - Google Patents
Aqueous cleaning composition containing protein binding dye Download PDFInfo
- Publication number
- AU669163B2 AU669163B2 AU37599/93A AU3759993A AU669163B2 AU 669163 B2 AU669163 B2 AU 669163B2 AU 37599/93 A AU37599/93 A AU 37599/93A AU 3759993 A AU3759993 A AU 3759993A AU 669163 B2 AU669163 B2 AU 669163B2
- Authority
- AU
- Australia
- Prior art keywords
- dye
- composition according
- surfactant
- composition
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000203 mixture Substances 0.000 title claims description 101
- 102000004169 proteins and genes Human genes 0.000 title claims description 50
- 108090000623 proteins and genes Proteins 0.000 title claims description 50
- 238000004140 cleaning Methods 0.000 title claims description 44
- 239000004094 surface-active agent Substances 0.000 claims description 50
- 239000002904 solvent Substances 0.000 claims description 47
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 claims description 43
- 239000002689 soil Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 23
- 239000002736 nonionic surfactant Substances 0.000 claims description 21
- 244000005700 microbiome Species 0.000 claims description 15
- -1 Rose Bengal Chemical compound 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 5
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 5
- NKLPQNGYXWVELD-UHFFFAOYSA-M coomassie brilliant blue Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=C1 NKLPQNGYXWVELD-UHFFFAOYSA-M 0.000 claims description 5
- 230000002779 inactivation Effects 0.000 claims description 4
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 3
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- CTXPTPBEMQHKNZ-UHFFFAOYSA-O [4-[(4-anilinophenyl)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]-2-methylphenyl]methylidene]-3-methylcyclohexa-2,5-dien-1-ylidene]-ethyl-[(3-sulfophenyl)methyl]azanium Chemical compound C=1C=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S(O)(=O)=O)C)C=2C=CC(NC=3C=CC=CC=3)=CC=2)C(C)=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 CTXPTPBEMQHKNZ-UHFFFAOYSA-O 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- RAMNYUMITLZMIC-UHFFFAOYSA-N sodium;3-[[4-[(4-diethylazaniumylidenecyclohexa-2,5-dien-1-ylidene)-[4-[ethyl-[(3-sulfophenyl)methyl]amino]-2-methylphenyl]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C(C)=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 RAMNYUMITLZMIC-UHFFFAOYSA-N 0.000 claims description 2
- FJBHGWADYLMEJG-UHFFFAOYSA-M sodium;3-[[4-[[4-(diethylamino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]methyl]-n-ethylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC=1C=C(C=CC=1)S([O-])(=O)=O)=C(C=C1)C=CC1=[N+](CC)CC1=CC=CC(S([O-])(=O)=O)=C1 FJBHGWADYLMEJG-UHFFFAOYSA-M 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- OALHHIHQOFIMEF-UHFFFAOYSA-N 3',6'-dihydroxy-2',4',5',7'-tetraiodo-3h-spiro[2-benzofuran-1,9'-xanthene]-3-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 OALHHIHQOFIMEF-UHFFFAOYSA-N 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 description 90
- IINNWAYUJNWZRM-UHFFFAOYSA-L erythrosin B Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 IINNWAYUJNWZRM-UHFFFAOYSA-L 0.000 description 34
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 238000009472 formulation Methods 0.000 description 25
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000000243 solution Substances 0.000 description 19
- 230000000694 effects Effects 0.000 description 18
- 238000012360 testing method Methods 0.000 description 17
- 108091003079 Bovine Serum Albumin Proteins 0.000 description 13
- 238000002474 experimental method Methods 0.000 description 13
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 239000000980 acid dye Substances 0.000 description 12
- 229940098773 bovine serum albumin Drugs 0.000 description 12
- 239000000919 ceramic Substances 0.000 description 11
- 239000000725 suspension Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 9
- 239000007844 bleaching agent Substances 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 8
- 230000003993 interaction Effects 0.000 description 8
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 7
- 238000005562 fading Methods 0.000 description 7
- 230000001965 increasing effect Effects 0.000 description 7
- 238000012800 visualization Methods 0.000 description 7
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 6
- 238000007619 statistical method Methods 0.000 description 6
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 230000031700 light absorption Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 231100000760 phototoxic Toxicity 0.000 description 4
- 238000000985 reflectance spectrum Methods 0.000 description 4
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000001332 colony forming effect Effects 0.000 description 3
- 229960001484 edetic acid Drugs 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000002070 germicidal effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- AZJPTIGZZTZIDR-UHFFFAOYSA-L rose bengal Chemical compound [K+].[K+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(I)C(=O)C(I)=C2OC2=C(I)C([O-])=C(I)C=C21 AZJPTIGZZTZIDR-UHFFFAOYSA-L 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000000540 analysis of variance Methods 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000004174 erythrosine Substances 0.000 description 2
- 238000007046 ethoxylation reaction Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 2
- 238000007539 photo-oxidation reaction Methods 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 229960003138 rose bengal sodium Drugs 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000013207 serial dilution Methods 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- QEJORCUFWWJJPP-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO.CCCCOCCO QEJORCUFWWJJPP-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UALWOGOPWHNMBZ-UHFFFAOYSA-N C(CCCCCCCC=C/CCCCCCCC)(=O)OCC(OC(CCCCCCCC=C/CCCCCCCC)=O)COC(CCCCCCCC=C/CCCCCCCC)=O.C(CCCCCCCCCCCCCCC)(=O)OCC(OC(CCCCCCCCCCCCCCC)=O)COC(CCCCCCCCCCCCCCC)=O Chemical compound C(CCCCCCCC=C/CCCCCCCC)(=O)OCC(OC(CCCCCCCC=C/CCCCCCCC)=O)COC(CCCCCCCC=C/CCCCCCCC)=O.C(CCCCCCCCCCCCCCC)(=O)OCC(OC(CCCCCCCCCCCCCCC)=O)COC(CCCCCCCCCCCCCCC)=O UALWOGOPWHNMBZ-UHFFFAOYSA-N 0.000 description 1
- 239000004150 EU approved colour Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 241000143957 Vanessa atalanta Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000030833 cell death Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- CAPAZTWTGPAFQE-UHFFFAOYSA-N ethane-1,2-diol Chemical compound OCCO.OCCO CAPAZTWTGPAFQE-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- UZABCLFSICXBCM-UHFFFAOYSA-N ethoxy hydrogen sulfate Chemical class CCOOS(O)(=O)=O UZABCLFSICXBCM-UHFFFAOYSA-N 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 238000013401 experimental design Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 108010037896 heparin-binding hemagglutinin Proteins 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- SYJRVVFAAIUVDH-UHFFFAOYSA-N ipa isopropanol Chemical compound CC(C)O.CC(C)O SYJRVVFAAIUVDH-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229940006093 opthalmologic coloring agent diagnostic Drugs 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000011546 protein dye Substances 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929206115A GB9206115D0 (en) | 1992-03-20 | 1992-03-20 | Soil visualisation |
| GB9206115 | 1992-03-20 | ||
| GB929215555A GB9215555D0 (en) | 1992-07-22 | 1992-07-22 | Improvements relating to cleaning compositions |
| GB9215555 | 1992-07-22 | ||
| GB9222813 | 1992-10-30 | ||
| GB929222813A GB9222813D0 (en) | 1992-10-30 | 1992-10-30 | Cleaning compositions |
| GB9304732 | 1993-03-09 | ||
| GB939304732A GB9304732D0 (en) | 1993-03-09 | 1993-03-09 | Improvements in or relating to germicidal compositions |
| PCT/GB1993/000551 WO1993019152A1 (en) | 1992-03-20 | 1993-03-17 | Improvements in or relating to cleaning compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU3759993A AU3759993A (en) | 1993-10-21 |
| AU669163B2 true AU669163B2 (en) | 1996-05-30 |
Family
ID=27450849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU37599/93A Ceased AU669163B2 (en) | 1992-03-20 | 1993-03-17 | Aqueous cleaning composition containing protein binding dye |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0631610B1 (en, 2012) |
| JP (1) | JPH07504699A (en, 2012) |
| CN (1) | CN1051798C (en, 2012) |
| AU (1) | AU669163B2 (en, 2012) |
| BR (1) | BR9306119A (en, 2012) |
| CA (1) | CA2131618A1 (en, 2012) |
| CZ (1) | CZ229394A3 (en, 2012) |
| DE (1) | DE69311706T2 (en, 2012) |
| ES (1) | ES2104134T3 (en, 2012) |
| HU (1) | HU212979B (en, 2012) |
| IN (1) | IN178308B (en, 2012) |
| MY (1) | MY109183A (en, 2012) |
| SK (1) | SK112494A3 (en, 2012) |
| WO (1) | WO1993019152A1 (en, 2012) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5424000A (en) * | 1993-10-05 | 1995-06-13 | West Agro, Inc. | Acid cleanings and staining compositions |
| DE19621966A1 (de) * | 1996-05-31 | 1997-12-04 | Basf Ag | Verwendung von natürlichen oder naturidentischen synthetischen Farbstoffen zur vorübergehenden Markierung oder Einfärbung von festen und flüssigen Materialien |
| US8974363B2 (en) | 1997-12-11 | 2015-03-10 | Provectus Pharmatech, Inc. | Topical medicaments and methods for photodynamic treatment of disease |
| US6677287B1 (en) | 1998-05-18 | 2004-01-13 | The Procter & Gamble Company | Implement containing cleaning composition and disappearing dye |
| BR9910538A (pt) * | 1998-05-18 | 2001-01-16 | Procter & Gamble | Implemento contendo composição de limpeza e corante de desaparecimento |
| US8557298B2 (en) | 1998-08-06 | 2013-10-15 | Provectus Pharmatech, Inc. | Medicaments for chemotherapeutic treatment of disease |
| DE60015832T2 (de) | 1999-03-24 | 2005-10-27 | JohnsonDiversey, Inc., Sturtevant | Verfahren zum Nachweis von Protein und Kit dafür |
| EP1039299B1 (en) * | 1999-03-24 | 2004-11-17 | JohnsonDiversey, Inc. | A method of detecting protein and a kit using the same |
| WO2001036663A2 (en) * | 1999-11-15 | 2001-05-25 | Chemclean Corporation | Bio-burden visualization system |
| US6905672B2 (en) * | 1999-12-08 | 2005-06-14 | The Procter & Gamble Company | Compositions and methods to inhibit tartar and microbes using denture adhesive compositions with colorants |
| IN230386B (en, 2012) * | 2003-06-18 | 2009-03-27 | Unilever Nv | |
| GB0314211D0 (en) * | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
| WO2007054238A1 (en) * | 2005-11-08 | 2007-05-18 | Unilever N.V. | Hygiene indicator device |
| GB0525504D0 (en) | 2005-12-14 | 2006-01-25 | Bristol Myers Squibb Co | Antimicrobial composition |
| US8673836B2 (en) * | 2007-03-20 | 2014-03-18 | The Procter & Gamble Company | Laundry detergent composition with a reactive dye |
| JP2009075084A (ja) * | 2007-08-30 | 2009-04-09 | Sakura Color Prod Corp | 洗浄確認用インジケータを用いた洗浄度の確認方法 |
| JP5174408B2 (ja) * | 2007-09-25 | 2013-04-03 | 花王株式会社 | ヌメリ抑制剤組成物 |
| JP5213159B2 (ja) * | 2007-09-25 | 2013-06-19 | 花王株式会社 | バイオフィルム生成抑制方法 |
| GB0823265D0 (en) | 2008-12-20 | 2009-01-28 | Convatec Technologies Inc | Antimicrobial Composition |
| GB201020236D0 (en) | 2010-11-30 | 2011-01-12 | Convatec Technologies Inc | A composition for detecting biofilms on viable tissues |
| MX2015007771A (es) | 2012-12-20 | 2015-09-04 | Convatec Technologies Inc | Procesamiento de fibras celulosicas quimicamente modificadas. |
| US9170205B2 (en) * | 2013-09-18 | 2015-10-27 | Metrex Research, LLC | Disinfection and cleaning confirmation system |
| EP3569258B1 (fr) * | 2018-05-14 | 2023-01-18 | Patrice Slupecki | Procede de validation du cycle de traitement d'un porte instrument dynamique |
| EP4303580A4 (en) * | 2021-03-05 | 2024-07-31 | Shachihata Inc. | KIT FOR MAKING AN ELECTRON DONOR VISIBLE AND METHOD FOR MAKING AN ELECTRON DONOR VISIBLE |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990014591A1 (en) * | 1989-05-17 | 1990-11-29 | Isoline A/S | Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method |
| US5071573A (en) * | 1990-07-23 | 1991-12-10 | The Procter & Gamble Company | Microemulsified silicones in liquid fabric care compositions containing dye |
| US5110868A (en) * | 1991-01-14 | 1992-05-05 | E. I. Du Pont De Nemours And Company | Biodegradable compositions for controlled release of chemical agents |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63159758A (ja) * | 1986-12-24 | 1988-07-02 | Osaka Eyazoole Kogyo Kk | 便座クリ−ナ− |
| US5039441A (en) * | 1988-02-10 | 1991-08-13 | Colgate-Palmolive Company | Safe acidic hard surface cleaner |
| US4858465A (en) * | 1988-06-21 | 1989-08-22 | Rockwell International Corporation | Water washable contaminant detection and labeling compositions and method for utilizing same |
-
1993
- 1993-03-17 CA CA002131618A patent/CA2131618A1/en not_active Abandoned
- 1993-03-17 ES ES93906690T patent/ES2104134T3/es not_active Expired - Lifetime
- 1993-03-17 EP EP93906690A patent/EP0631610B1/en not_active Expired - Lifetime
- 1993-03-17 AU AU37599/93A patent/AU669163B2/en not_active Ceased
- 1993-03-17 BR BR9306119A patent/BR9306119A/pt not_active IP Right Cessation
- 1993-03-17 WO PCT/GB1993/000551 patent/WO1993019152A1/en active IP Right Grant
- 1993-03-17 SK SK1124-94A patent/SK112494A3/sk unknown
- 1993-03-17 JP JP5516364A patent/JPH07504699A/ja active Pending
- 1993-03-17 DE DE69311706T patent/DE69311706T2/de not_active Expired - Fee Related
- 1993-03-17 CZ CZ942293A patent/CZ229394A3/cs unknown
- 1993-03-17 HU HU9402706A patent/HU212979B/hu not_active IP Right Cessation
- 1993-03-18 IN IN164CA1993D patent/IN178308B/en unknown
- 1993-03-19 MY MYPI93000501A patent/MY109183A/en unknown
- 1993-03-20 CN CN93104596.7A patent/CN1051798C/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1990014591A1 (en) * | 1989-05-17 | 1990-11-29 | Isoline A/S | Method for simultaneous control of cleaning and hygiene and agent for use when carrying out the method |
| US5071573A (en) * | 1990-07-23 | 1991-12-10 | The Procter & Gamble Company | Microemulsified silicones in liquid fabric care compositions containing dye |
| US5110868A (en) * | 1991-01-14 | 1992-05-05 | E. I. Du Pont De Nemours And Company | Biodegradable compositions for controlled release of chemical agents |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1077986A (zh) | 1993-11-03 |
| WO1993019152A1 (en) | 1993-09-30 |
| EP0631610A1 (en) | 1995-01-04 |
| HU9402706D0 (en) | 1994-12-28 |
| EP0631610B1 (en) | 1997-06-18 |
| JPH07504699A (ja) | 1995-05-25 |
| IN178308B (en, 2012) | 1997-03-22 |
| ES2104134T3 (es) | 1997-10-01 |
| HU212979B (en) | 1997-01-28 |
| CZ229394A3 (en) | 1995-04-12 |
| HUT71066A (en) | 1995-11-28 |
| CA2131618A1 (en) | 1993-09-30 |
| DE69311706D1 (de) | 1997-07-24 |
| SK112494A3 (en) | 1995-04-12 |
| BR9306119A (pt) | 1998-06-23 |
| AU3759993A (en) | 1993-10-21 |
| CN1051798C (zh) | 2000-04-26 |
| MY109183A (en) | 1996-12-31 |
| DE69311706T2 (de) | 1997-12-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU669163B2 (en) | Aqueous cleaning composition containing protein binding dye | |
| EP0652709B1 (en) | Improvements in or relating to germicidal compositions | |
| CA2704765C (en) | Aqueous acidic hard surface cleaning and disinfecting compositions | |
| US6267976B1 (en) | Skin cleanser with photosensitive dye | |
| ES2365489T3 (es) | Composiciones acuosas fuertemente ácidas para limpieza de superficies duras. | |
| MXPA01001509A (es) | Composiciones acidas para la limpieza y desinfeccion de superficies duras. | |
| CN106999618A (zh) | 用于颜料消毒的添加剂组合物及其方法 | |
| CN1102647C (zh) | 松油型洗涤组合物 | |
| US6680264B2 (en) | Glass cleaning wipe | |
| CA1209156A (en) | Method for sanitizing toilets | |
| GB2307915A (en) | Pine oil type cleaning compositions | |
| CN108410593A (zh) | 一种多效型洗衣液及其制备方法 | |
| JP2023008435A (ja) | 液体洗浄剤及び洗浄液 | |
| CN105586182B (zh) | 衣服领袖专用祛渍皂 | |
| CN119529946A (zh) | 一种耐晒的餐具洗涤剂组合物及其制备方法 | |
| JP3417632B2 (ja) | 液体洗浄剤組成物 | |
| JP2023050916A (ja) | 電子供与物可視化キット及び電子供与物の可視化方法 | |
| CZ52296A3 (en) | Method of distinguishing organic residues on hard surface areas | |
| RO111852B1 (ro) | Detergenți lichizi | |
| SK104196A3 (sk) | Ekologicky neškodné detergentné a dezodoračné prípravky na WC misy |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |