CN108410593A - 一种多效型洗衣液及其制备方法 - Google Patents
一种多效型洗衣液及其制备方法 Download PDFInfo
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- CN108410593A CN108410593A CN201810255199.0A CN201810255199A CN108410593A CN 108410593 A CN108410593 A CN 108410593A CN 201810255199 A CN201810255199 A CN 201810255199A CN 108410593 A CN108410593 A CN 108410593A
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- liquid detergent
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- type liquid
- cushion
- glycerine
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- 239000007788 liquid Substances 0.000 title claims abstract description 73
- 239000003599 detergent Substances 0.000 title claims abstract description 63
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004382 Amylase Substances 0.000 claims abstract description 23
- 102000013142 Amylases Human genes 0.000 claims abstract description 23
- 108010065511 Amylases Proteins 0.000 claims abstract description 23
- 235000019418 amylase Nutrition 0.000 claims abstract description 23
- 108091005804 Peptidases Proteins 0.000 claims abstract description 22
- 239000004365 Protease Substances 0.000 claims abstract description 22
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims abstract description 22
- 239000000440 bentonite Substances 0.000 claims abstract description 22
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 22
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 235000011187 glycerol Nutrition 0.000 claims abstract description 21
- GCKVRHFRDJAIGL-UHFFFAOYSA-M [NH4+].[Br-].C(CCCCCCCCCCC)[P+](CC)(C)C.[Br-] Chemical compound [NH4+].[Br-].C(CCCCCCCCCCC)[P+](CC)(C)C.[Br-] GCKVRHFRDJAIGL-UHFFFAOYSA-M 0.000 claims abstract description 18
- 239000003513 alkali Substances 0.000 claims abstract description 17
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004061 bleaching Methods 0.000 claims abstract description 5
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
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- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 14
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- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical group [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 6
- 239000000347 magnesium hydroxide Substances 0.000 claims description 6
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 6
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- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- -1 polyoxyethylene Polymers 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 7
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- 239000001509 sodium citrate Substances 0.000 description 6
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 6
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- 241000894006 Bacteria Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 101710093543 Probable non-specific lipid-transfer protein Proteins 0.000 description 2
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- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
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- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- AUBSNUSTVUZGCC-UHFFFAOYSA-N [NH4+].[Br-].C(C)[PH3+].[Br-] Chemical compound [NH4+].[Br-].C(C)[PH3+].[Br-] AUBSNUSTVUZGCC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
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- 238000003556 assay Methods 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
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- 230000002478 diastatic effect Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- FYAFBPSCUASJMG-UHFFFAOYSA-N ethyl(methyl)azanium;bromide Chemical compound [Br-].CC[NH2+]C FYAFBPSCUASJMG-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000004438 eyesight Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 210000002429 large intestine Anatomy 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
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- 235000013575 mashed potatoes Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
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- 230000001473 noxious effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
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- 231100000614 poison Toxicity 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- HIDKSOTTZRMUML-UHFFFAOYSA-M potassium;dodecanoate Chemical class [K+].CCCCCCCCCCCC([O-])=O HIDKSOTTZRMUML-UHFFFAOYSA-M 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C11D1/008—Polymeric surface-active agents
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- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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Abstract
本发明公开了一种多效型洗衣液及其制备方法，涉及日用化学品领域。本发明采用非离子表面活性剂、缓冲物、十二烷基二甲基乙基溴化铵、甘油、膨润土、硅藻土、月桂酸钾、碱性蛋白酶、淀粉酶等进行复配制备多效型洗衣液。该洗衣液表面活性剂含量少，可节约成本，制备步骤简单，浓度低可快速溶解，易漂洗，抗稀释能力强，具备抗菌，柔顺、漂白、去污力强等多重功效，能够深层洁净被洗物，配方中不添加任何香精、增白剂，香味自然，PH值在7‑9，对皮肤伤害小，废水排出对环境污染小。
Description
【技术领域】
本发明涉及日用化学品领域，特别涉及一种多效型洗衣液及其制备方法。
【背景技术】
改革开放近40年来,随着社会生产力的迅猛发展、人们生活水平的大幅提高和对生活质量重视度的增加”,再加上，制作衣服的材料由单一的纯棉和真丝发展到了以棉布、麻布、丝绸、呢绒、皮革、化纤、混纺等等,因此,衣物的洗涤用品已从传统的肥皂为市场主流发展到以洗衣粉，再到近年来突起的洗衣液口。市场上的各种洗衣液与洗衣粉相比，更易溶解、使用方便、生产设备简单、产品利润较高,对皮肤温和,并且排入自然界后，在环境中的降解程度比洗衣粉要快且彻底,所以洗衣液成为了新一代的洗涤剂,逐渐替代了洗衣粉。
随着科学的进步和生活水平的提高,市场上的洗衣液五花八门,品类繁多,容易让消费者在挑选时眼花缭,按照目前市场上的洗衣液产品还可分为常规型与功能型。常规型洗衣液的功能主要集中在去污上。而功能型的洗衣液是针对不同消费者的要求融入了一些附加功能,常见的有:抗菌洗衣液、柔顺洗衣液和护手洗衣液等等。
常规洗衣液已经处于结束阶段,技术以及配方虽然成熟,但常规洗衣液的去污力与功能型洗衣液相比,去污效果仍稍逊一筹。主要是由于酶与一些助洗剂在洗衣液中的使用受到限制,酶在水中不稳定,一些阴离子表面活性剂如硫酸盐可使蛋白酶和脂肪酶失活,使去污能力下降。
现如今,随着人们对生活品质要求的提高,仅提供具有去污效果的常规型洗衣液已经远远不能满足消费者的需求,而功能型洗衣液提供的多功能(例如用量少、便宜、易漂洗、去污能力强、不伤手、气味清香、环境污染小等等)、简易性,才能满足消费者的需求。
【发明内容】
针对现有技术存在的问题，本发明采用非离子表面活性剂、缓冲物、十二烷基二甲基乙基溴化铵、甘油、膨润土、硅藻土、月桂酸钾、碱性蛋白酶、淀粉酶等进行复配，提供一种低浓度可快速溶解，易漂洗，抗稀释能力强具备抗菌，柔顺、漂白、去污力强等多重功效，能够深层洁净被洗物的多效型洗衣液。
为达到上述目的，本发明所采用的技术方案是：
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂0.02-8.0％、缓冲物0.1-1.0％、十二烷基二甲基乙基溴化铵1.0-2.0％、甘油0.2-1.6％、膨润土0.5-2.0％、硅藻土1.0-2.2％、月桂酸钾1-2％、碱性蛋白酶0.2-0.5％、淀粉酶0.01-1.0％、碱性PH调节剂0.01-1.0％、余量为去离子水。
所述一种多效型洗衣液，由以下质量百分比的组分组成：非离子表面活性剂4％、缓冲物0.5％、十二烷基二甲基乙基溴化铵2％、甘油0.8％、膨润土0.5％、硅藻土1％、月桂酸钾1.2％、碱性蛋白酶0.24％、淀粉酶0.3％、碱性PH调节剂0.2％、去离子水89.26％。
所述非离子表面活性剂，由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以1～3：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以1～3：1的质量比组成，作用是提升洗衣液抗稀释性能。
所述甘油为含量30-50％的低浓度化妆品级甘油，一是可以促进表面活性剂增溶，二是作软化剂用，在洗涤过程中保护纤维，减少纤维磨损，使纤维更加柔顺。
所述膨润土为活性白土，粒度大小为200目，活性白土是用粘土(主要是膨润土)为原料，经无机酸化处理，再经水漂洗、干燥制成的吸附剂，外观为乳白色粉末，无臭，无味，无毒，吸附性能很强，能吸附有色物质、有机物质，所述硅藻土为氢氧化镁改性硅藻土，粒度大小为300目。
相应地，本发明还提供多效型洗衣液的制备方法，包括如下步骤：按质量百分比计数，将去离子水升温至40-60℃,搅拌条件下，按顺序依次加入非离子表面活性剂、缓冲物、十二烷基二甲基乙基溴化铵、月桂酸钾，全部溶解后，搅拌条件下,加入低浓度甘油、膨润土、硅藻土,搅拌30-60min，得到混合液，调节温度至30-40℃,搅拌条件下,将碱性PH调节剂加入所述混合液中搅拌均匀，加入碱性蛋白酶、淀粉酶搅拌均匀，即得洗衣液。
本发明添加了碱性蛋白酶、淀粉酶，生物酶的加入能去除一些表面活性剂无法去除的污渍,具有高效生物催化自动分解污垢等特点，如衣物上的血迹，奶渍，汗渍等。蛋白酶可去除衣物上附着紧密的蛋白类污垢,淀粉酶可去除衣物上粘到的淀粉类污垢,如巧克力渍,土豆泥渍等。
本发明具有以下有益效果：
1.本发明多效型洗衣液配方体系中表面活性剂为非离子表面活性剂，由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以1～3：1的质量比组成，配方中添加膨润土和氢氧化镁改性硅藻土，其中膨润土选粒度大小为200目的活性白土，吸附性能很强，能吸附有色物质、有机物质，氢氧化镁改性硅藻土可吸附活性红色物质，添加两者可代替一部分的表面活性剂，极大的减少了表面活性剂的添加量，从而减弱了表面活性剂对液体蛋白酶、淀粉酶活性的影响，确保蛋白酶、淀粉酶在液态环境无需稳定剂而保持超高活性，非离子表面活性剂、膨润土、氢氧化镁改性硅藻土、生物酶的复合，起到协同增效的作用，综合提升洗衣液的去污力，同时活性白土的添加，使得洗衣液还具备较好的漂白功能。配方中添加十二烷基二甲基乙基溴化铵可以抑制金黄色葡萄球菌和大肠埃希菌在衣物上增殖,保护衣物，减少细菌增殖可能对人体造成伤害，添加低浓度化妆级别的甘油，一是可以促进表面活性剂增溶，二是作软化剂用，在洗涤过程中保护纤维，减少纤维磨损，使纤维更加柔顺。
2.本发明多效型洗衣液表面活性剂含量少，节约成本，制备简单易操作，各项指标符合衣料洗涤剂《衣料用液体洗涤剂》Q/BT 1224-2012中的要求，低浓度可快速溶解，易漂洗，抗稀释能力强，具备抗菌，柔顺、漂白、去污力强等多重功效，能够深层洁净被洗物，该洗衣液配方中不添加任何香精、增白剂，香味自然，PH值在7-9，对皮肤伤害小，废水排出对环境污染小。
【具体实施方式】
下面结合实施例对本发明的技术方案做进一步的阐述：
实施例1
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂6％、缓冲物0.6％、十二烷基二甲基乙基溴化铵1.4％、30-50％低浓度化妆品级甘油1.0％、膨润土1.2％、硅藻土1.6％、月桂酸钾1.5％、碱性蛋白酶0.45％、淀粉酶0.6％、碱性PH调节剂0.5％、去离子水85.25％。
所述非离子表面活性剂由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以1：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以1：1的质量比组成。
多效型洗衣液的制备方法：包括如下步骤：按重量份数，每份1kg，称取85份去离子水升温至40-60℃,搅拌条件下，按顺序依次加入6份非离子表面活性剂、0.6份缓冲物、1.4份十二烷基二甲基乙基溴化铵、1.5份月桂酸钾，全部溶解后，搅拌条件下,加入1份30-50％低浓度化妆品级甘油、1.2份膨润土、1.6份硅藻土,搅拌30-60min，得到混合液，调节温度至30-40℃,搅拌条件下,将0.5份碱性PH调节剂加入所述混合液中搅拌均匀，加入0.35份碱性蛋白酶、0.6份淀粉酶搅拌均匀，即得洗衣液。
实施例2
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂4％、缓冲物0.5％、十二烷基二甲基乙基溴化铵2％、30-50％低浓度化妆品级甘油0.8％、膨润土0.5％、硅藻土1％、月桂酸钾1.2％、碱性蛋白酶0.24％、淀粉酶0.3％、碱性PH调节剂0.2％、去离子水89.26％。
所述非离子表面活性剂由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以2：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以2：1的质量比组成。
制备方法：与实施例1中的制备方法相同。
实施例3:
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂7％、缓冲物0.2％、十二烷基二甲基乙基溴化铵1.6％、30-50％低浓度化妆品级甘油1.5％、膨润土1.3％、硅藻土1.7％、月桂酸钾1.1％、碱性蛋白酶0.3％、淀粉酶0.4％、碱性PH调节剂0.2％、去离子水％84.70。
所述非离子表面活性剂由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以3：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以3：1的质量比组成。
制备方法：与实施例1中的制备方法相同。
实施例4:
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂5％、缓冲物0.25％、十二烷基二甲基乙基溴化铵1.8％、30-50％低浓度化妆品级甘油1.1％、膨润土0.6％、硅藻土1.4％、月桂酸钾1.35％、碱性蛋白酶0.4％、淀粉酶0.5％、碱性PH调节剂0.62％、去离子水86.98％。
所述非离子表面活性剂由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以1.5：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以1.5：1的质量比组成。
制备方法：与实施例1中的制备方法相同。
实施例5:
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂4.5％、缓冲物0.3％、十二烷基二甲基乙基溴化铵1.2％、30-50％低浓度化妆品级甘油1.2％、膨润土0.68％、硅藻土1.73％、月桂酸钾1.48％、碱性蛋白酶0.43％、淀粉酶0.82％、碱性PH调节剂0.45％、去离子水87.21％。
所述非离子表面活性剂由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以2.5：1的质量比组成。
所述缓冲物由柠檬酸和柠檬酸钠以2.5：1的质量比组成。
制备方法：与实施例1中的制备方法相同。
对比实施例1:
一种多效型洗衣液，由以下质量百分比的组分组成：
非离子表面活性剂7.2％、缓冲物0.6％、十二烷基二甲基乙基溴化铵1.4％、甘油1.0％、硅藻土1.6％、月桂酸钾1.5％、碱性蛋白酶0.35％、淀粉酶0.6％、碱性PH调节剂0.5％、去离子水85.25％。
本实施例与实施例1的区别在于：配方中去掉膨润土，非离子表面活性剂的质量百分比由6.0％变为7.2％。
制备方法：与实施例1中的制备方法相同。
对比实施例2
非离子表面活性剂7.6％、缓冲物0.6％、十二烷基二甲基乙基溴化铵1.4％、甘油1.0％、膨润土1.2％、月桂酸钾1.5％、碱性蛋白酶0.35％、淀粉酶0.6％、碱性PH调节剂0.5％、去离子水85.25％。
本实施例与实施例1的区别在于：配方中去掉硅藻土，非离子表面活性剂的质量百分比由6.0％变为7.6％。
制备方法：与实施例1中的制备方法相同。
对比实施例3
非离子表面活性剂7.0％、缓冲物0.6％、十二烷基二甲基乙基溴化铵1.4％、膨润土1.2％、硅藻土1.6％、月桂酸钾1.5％、碱性蛋白酶0.35％、淀粉酶0.6％、碱性PH调节剂0.5％、去离子水85.25％。
本实施例与实施例1的区别在于：配方中去掉碱性蛋白酶、淀粉酶，非离子表面活性剂的质量百分比由6.0％变为7.95％。
制备方法：与实施例1中的制备方法相同。
对比实施例4
非离子表面活性剂7.4％、缓冲物0.6％、膨润土1.2％、硅藻土1.6％、月桂酸钾1.5％、碱性蛋白酶0.35％、淀粉酶0.6％、碱性PH调节剂0.5％、去离子水85.25％。
本实施例与实施例1的区别在于：配方中去掉十二烷基二甲基乙基溴化铵，非离子表面活性剂的质量百分比由6.0％变为7.4％。
制备方法：与实施例1中的制备方法相同。
去污力效果测试实施例
按GB/T 13174-2008的方法，人工造的各块布，在固定时间固定强下，添加相同量的洗衣液进行去污测试，分别对实施例1-3及对比实施例1-3制备的洗衣液进行碳黑油、蛋白类、皮脂类、淀粉类等污渍的去污效果测试，并与标准洗衣液、市售洗衣液进行对比，试验结果见表1。从表1数据可知，实施例一、实施例二、实施例三表现出较强的去污力，尤其对碳黑类、蛋白、皮脂、淀粉类表现出非常优异的去污效果,且显著优于对比实施例一、对比实施例二和对比实施例三的去污效果,说明膨润土、氢氧化镁改性硅藻土、碱性蛋白酶和淀粉酶的复配起到了明显的协同增效作用。虽然本发明采用的是常规的非离子表面活性剂,但令人惊奇的是,对于本发明洗衣液的配方体系而言,膨润土、氢氧化镁改性硅藻土、碱性蛋白酶和淀粉酶都是必需的成分。
表1去污力效果测试结果
抗菌性能测试实施例
对实施1-3、对比实施例4获得的洗衣液进行抗菌性能测试，根据QB/T2738-2012《日化产品抗菌抑菌效果的评价方法》进行，测试结果如表2。从表2数据可知，实施例1-3获得的洗衣液对大肠埃希菌、金黄色葡萄球菌的平均杀菌率分别为99.86％，99.91％，对大肠埃希菌、金黄色葡萄球菌的平均抑菌率分别为88.16％，88.50％；对比实施例4获得的洗衣液对大肠埃希菌、金黄色葡萄球菌的杀菌率、抑菌率均明显下降了很多，说明了在本发明配方体系中十二烷基二甲基乙基溴化铵作为杀菌、抑菌效果明显，不可或缺。
表2抗菌效果测试结果
漂洗效果测试实施例
按GB/T15818-2006的方法,对实施例1-5获得的洗衣液进行漂洗后泡沫高度的测试，结果如表3，从表3中漂洗液泡沫高度的变化情况可知，本发明实施例1-5获得的洗衣液浓度低可快速溶解，易漂洗，基本上经过漂洗2次，被洗物可漂洗干净。
表3实施例1-3洗衣液漂洗效果测试
洗衣液清洗废水检测对比
选取标准洗衣液、市售洗衣液、按本发明实施例1-3制备的洗衣液,抽取一定数量的洗衣液样品,分别配制成浓度为1.0g/L的洗衣液水溶液，根据GB11914-89水质化学需氧量的测定方法，来测定以上洗衣液样品的COD含量，再以相同洗衣液的用量洗涤衣物，漂洗2次，对漂洗废水进行PH值、磷、氮含量检测，检测结果如表4。
表4
从表4中可以得知，与标准洗衣液和市售洗衣液进行比较，本发明实施例1-3所制备的洗衣液PH值接近中性，COD含量低，COD排放达到一级A标,且不含磷、氮，本发明洗衣液是天然植物皂基成分，没有有毒物质残留，水很干净，环境污染极小。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (7)
1.一种多效型洗衣液，其特征在于，由以下质量百分比的组分组成：
非离子表面活性剂0.02-4.0％、缓冲物0.1-1.0％、十二烷基二甲基乙基溴化铵1.0-2.0％、低浓度甘油0.2-1.6％、膨润土0.5-2.0％、硅藻土1.0-2.2％、月桂酸钾1-2％、碱性蛋白酶0.02-0.8％、淀粉酶0.01-1.0％、碱性PH调节剂0.01-1.0％、余量为去离子水。
2.根据权利要求1所述一种多效型洗衣液，其特征在于，由以下质量百分比的组分组成：非离子表面活性剂4％、缓冲物0.5％、十二烷基二甲基乙基溴化铵2％、甘油0.8％、膨润土0.5％、硅藻土1％、月桂酸钾1.2％、碱性蛋白酶0.24％、淀粉酶0.3％、PH调节剂0.2％、去离子水89.26％。
3.根据权利要求1所述一种多效型洗衣液，其特征在于，所述非离子表面活性剂，由脂肪醇聚氧乙烯(9)醚和脂肪醇聚氧乙烯(7)醚以(1～3)：1的质量比组成。
4.根据权利要求1所述一种多效型洗衣液，其特征在于，所述缓冲物由柠檬酸和柠檬酸钠以1～3：1的质量比组成。
5.根据权利要求1所述一种多效型洗衣液，其特征在于，所述甘油为含量30-50％的低浓度化妆品级甘油。
6.根据权利要求1所述一种多效型洗衣液，其特征在于，所述膨润土为活性白土或者天然漂白土，粒度大小为200目，所述硅藻土为氢氧化镁改性硅藻土，粒度大小为300目。
7.根据权利要求1-6任一权利要求所述一种多效型洗衣液的制备方法，其特征在于，包括如下步骤：
按质量百分比计数，将去离子水升温至40-60℃,搅拌条件下，按顺序依次加入非离子表面活性剂、缓冲物、十二烷基二甲基乙基溴化铵、月桂酸钾，全部溶解后，搅拌条件下,加入低浓度甘油、膨润土、硅藻土,搅拌30-60min，得到混合液，调节温度至30-40℃,搅拌条件下,将碱性PH调节剂加入所述混合液中搅拌均匀，加入碱性蛋白酶、淀粉酶搅拌均匀，即得洗衣液。
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| CN113604294A (zh) * | 2021-09-16 | 2021-11-05 | 廊坊佰美生物科技有限公司 | 商用洗衣液及其制备方法 |
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