AU625900B2 - Method and composition for surface treatment - Google Patents

Method and composition for surface treatment Download PDF

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Publication number
AU625900B2
AU625900B2 AU39511/89A AU3951189A AU625900B2 AU 625900 B2 AU625900 B2 AU 625900B2 AU 39511/89 A AU39511/89 A AU 39511/89A AU 3951189 A AU3951189 A AU 3951189A AU 625900 B2 AU625900 B2 AU 625900B2
Authority
AU
Australia
Prior art keywords
sol
composition
powder
adhesion promoter
zirconia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU39511/89A
Other languages
English (en)
Other versions
AU3951189A (en
Inventor
Rowena Roshanthi Landham
John Alfred Treverton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rio Tinto Alcan International Ltd
Original Assignee
Alcan International Ltd Canada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB888819259A external-priority patent/GB8819259D0/en
Priority claimed from GB898912424A external-priority patent/GB8912424D0/en
Application filed by Alcan International Ltd Canada filed Critical Alcan International Ltd Canada
Publication of AU3951189A publication Critical patent/AU3951189A/en
Application granted granted Critical
Publication of AU625900B2 publication Critical patent/AU625900B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/74—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process for obtaining burned-in conversion coatings
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
    • C23C18/1208—Oxides, e.g. ceramics
    • C23C18/1216—Metal oxides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/1229—Composition of the substrate
    • C23C18/1241—Metallic substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1254—Sol or sol-gel processing
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Chemically Coating (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • ing And Chemical Polishing (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Glanulating (AREA)
  • Cosmetics (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
AU39511/89A 1988-08-12 1989-08-11 Method and composition for surface treatment Ceased AU625900B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB888819259A GB8819259D0 (en) 1988-08-12 1988-08-12 Method & composition for metal treatment
GB8819259 1988-08-12
GB8912424 1989-05-31
GB898912424A GB8912424D0 (en) 1989-05-31 1989-05-31 Metal treatment method

Publications (2)

Publication Number Publication Date
AU3951189A AU3951189A (en) 1990-02-15
AU625900B2 true AU625900B2 (en) 1992-07-16

Family

ID=26294277

Family Applications (1)

Application Number Title Priority Date Filing Date
AU39511/89A Ceased AU625900B2 (en) 1988-08-12 1989-08-11 Method and composition for surface treatment

Country Status (15)

Country Link
EP (1) EP0358338B1 (enExample)
JP (1) JPH0285373A (enExample)
KR (1) KR900003403A (enExample)
CN (1) CN1040811A (enExample)
AT (1) ATE109217T1 (enExample)
AU (1) AU625900B2 (enExample)
BR (1) BR8904061A (enExample)
CA (1) CA1337145C (enExample)
DE (1) DE68917059T2 (enExample)
DK (1) DK394089A (enExample)
ES (1) ES2059772T3 (enExample)
IN (1) IN176027B (enExample)
MY (1) MY104467A (enExample)
NO (1) NO893250L (enExample)
PT (1) PT91432B (enExample)

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US5427632A (en) * 1993-07-30 1995-06-27 Henkel Corporation Composition and process for treating metals
US5449415A (en) * 1993-07-30 1995-09-12 Henkel Corporation Composition and process for treating metals
DE59508772D1 (de) * 1994-06-23 2000-11-09 Creavis Tech & Innovation Gmbh Herstellung keramischer schichten und deren verwendung
JPH08134694A (ja) * 1994-11-10 1996-05-28 Natl Inst For Res In Inorg Mater 超耐アルカリ性酸化アルミニウム複合膜とその製造方 法
GB9424711D0 (en) * 1994-12-07 1995-02-01 Alcan Int Ltd Composition for surface treatment
FR2738260B1 (fr) * 1995-08-30 1998-01-16 Aisin Seiki Partie en alliage de tial et procede de preparation de celle-ci
US5720902A (en) * 1995-09-21 1998-02-24 Betzdearborn Inc. Methods and compositions for inhibiting low carbon steel corrosion
WO1997015959A1 (fr) * 1995-10-24 1997-05-01 Isa Ag Arch Procede de fabrication d'une cellule electrochimique et cellule electrochimique obtenue selon ce procede
CN1203209C (zh) * 1997-09-17 2005-05-25 舍米塔尔公开有限公司 金属底材的防腐蚀方法和组合物
GB9721650D0 (en) * 1997-10-13 1997-12-10 Alcan Int Ltd Coated aluminium workpiece
US5964928A (en) * 1998-03-12 1999-10-12 Natural Coating Systems, Llc Protective coatings for metals and other surfaces
DE19943789A1 (de) * 1999-09-13 2001-03-15 Fraunhofer Ges Forschung Verfahren zur Abscheidung von Zirkonoxid-Schichten unter Verwendung von löslichen Pulvern
EP1151153B1 (en) * 1999-11-04 2010-06-16 Koninklijke Philips Electronics N.V. Protection of a surface by partially subjecting it to an electrochemical treatment
JP2001226782A (ja) * 1999-12-03 2001-08-21 Fuji Heavy Ind Ltd チタン−ニッケル合金材の表面処理方法
JP2001240977A (ja) 2000-02-29 2001-09-04 Nippon Paint Co Ltd 金属表面処理方法
JP4393660B2 (ja) * 2000-02-29 2010-01-06 日本ペイント株式会社 Ｐｃｍ用ノンクロメート金属表面処理剤、ｐｃｍ表面処理方法および処理されたｐｃｍ鋼板
CN1740402A (zh) * 2000-03-22 2006-03-01 以利沙控股有限公司 一种用于处理导电表面的增强性工艺方法以及由此形成的产品
US20030211330A1 (en) * 2002-05-09 2003-11-13 Anderson Robert A. Method of preparing a metal material for bonding
GB0225670D0 (en) 2002-11-05 2002-12-11 Rolls Royce Plc Method of forming a diffusion barrier on a titanium alloy substrate
ES2302873T3 (es) * 2003-01-17 2008-08-01 Nanmat Technology Co., Ltd. Metodo de pretratamiento sin cromato para aleaciones de metal.
DE10320765A1 (de) * 2003-05-09 2004-11-25 Degussa Ag Mittel zur Beschichtung von Metallen zum Schutz vor Korrosion
FR2857672B1 (fr) * 2003-07-15 2005-09-16 Dacral Utilisation de l'yttrium, du zirconium, du lanthane, de cerium, du praseodyme ou du neodyme comme element renforcateur des proprietes anticorrosion d'une composition de revetement anticorrosion.
JP4801879B2 (ja) * 2003-12-26 2011-10-26 学校法人日本大学 硬質膜およびその形成方法
US10041176B2 (en) 2005-04-07 2018-08-07 Momentive Performance Materials Inc. No-rinse pretreatment methods and compositions
CN100478404C (zh) * 2005-06-22 2009-04-15 河南大学 一种可在有机介质中分散的纳米二氧化锆微粒及其制备方法
DE102006010875A1 (de) * 2006-03-07 2007-09-13 Ks Aluminium-Technologie Ag Beschichtung eines thermisch und erosiv belasteten Funktionsbauteils
US8747952B2 (en) 2007-01-19 2014-06-10 Airbus Operations Gmbh Materials and processes for coating substrates having heterogeneous surface properties
DE102007003761B4 (de) 2007-01-19 2016-01-28 Airbus Operations Gmbh Beschichtete Substrate mit heterogenen Oberflächeneigenschaften
EP1978131B2 (de) * 2007-03-29 2019-03-06 ATOTECH Deutschland GmbH Mittel zur Herstellung von Korrosionsschutzschichten auf Metalloberflächen
DE102007047082A1 (de) * 2007-10-01 2009-04-02 Robert Bosch Gmbh Verfahren zur Herstellung einer metallischen Schicht
JP2009209407A (ja) * 2008-03-04 2009-09-17 Mazda Motor Corp 化成処理剤及び表面処理金属
DE102009046673A1 (de) 2009-11-13 2011-05-19 Evonik Degussa Gmbh Verwendung einer keramischen Membran auf Basis eines Polymerfasern aufweisenden Substrates als Feuchtespeicher
CN102608265B (zh) * 2012-02-29 2014-11-19 东莞市升微机电设备科技有限公司 释放舱与被测试物接触的表面的处理方法
EP2662420A1 (en) * 2012-05-07 2013-11-13 Neoker, S.L Silica-surface modified alpha-alumina whiskers and uses thereof
US20140322540A1 (en) * 2013-04-26 2014-10-30 The Boeing Company Surface treatment for structural bonding to aluminum
US10435806B2 (en) 2015-10-12 2019-10-08 Prc-Desoto International, Inc. Methods for electrolytically depositing pretreatment compositions
CN108585885B (zh) * 2018-05-12 2021-03-05 浙江大学 一种氧化锆尺寸呈正态分布的耐磨抗冲击防腐涂层、其制备方法和用途
US11173518B2 (en) 2018-08-20 2021-11-16 WilCraft Can, LLC Process for reusing printed cans
US11312107B2 (en) * 2018-09-27 2022-04-26 Apple Inc. Plugging anodic oxides for increased corrosion resistance
CN109487244A (zh) * 2018-11-23 2019-03-19 中国人民解放军国防科技大学 一种耐磨疏水ZrO2涂层的低温快速制备方法
CN112159974A (zh) * 2020-09-30 2021-01-01 国网黑龙江省电力有限公司电力科学研究院 增强金具耐磨性的氧化物涂料及其应用
CN112341888B (zh) * 2020-11-30 2021-10-15 江苏科技大学 一种金属锈层处理涂料组合物及其制备方法和应用
CN115613022B (zh) * 2022-09-28 2024-08-16 湖南金裕环保科技有限公司 铝及铝合金无铬本色钝化剂及其制备方法
JP2025060180A (ja) * 2023-09-29 2025-04-10 日本パーカライジング株式会社 金属表面処理剤、金属材料の製造方法および金属材料

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US4271210A (en) * 1979-10-25 1981-06-02 Westinghouse Electric Corp. Method of forming transmissive, porous metal oxide optical layer of a vitreous substrate
US4614673A (en) * 1985-06-21 1986-09-30 The Boeing Company Method for forming a ceramic coating

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CA1278985C (en) * 1985-04-30 1991-01-15 Allegheny Ludlum Corporation Grain-oriented silicon steel and stress coating therefor
JP2512402B2 (ja) * 1988-06-22 1996-07-03 日新製鋼株式会社 ジルコニア膜の製造方法
JP2519363B2 (ja) * 1991-11-21 1996-07-31 株式会社日立製作所 プリント基板における配線パタ―ンの欠陥検査方法

Patent Citations (3)

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GB940216A (en) * 1959-02-18 1963-10-30 Alpha Molykote Corp Lubricant and process for preparing bonded lubricant coating
US4271210A (en) * 1979-10-25 1981-06-02 Westinghouse Electric Corp. Method of forming transmissive, porous metal oxide optical layer of a vitreous substrate
US4614673A (en) * 1985-06-21 1986-09-30 The Boeing Company Method for forming a ceramic coating

Also Published As

Publication number Publication date
EP0358338A2 (en) 1990-03-14
EP0358338A3 (en) 1990-04-11
ES2059772T3 (es) 1994-11-16
DK394089D0 (da) 1989-08-11
CA1337145C (en) 1995-10-03
NO893250L (no) 1990-02-13
JPH0285373A (ja) 1990-03-26
CN1040811A (zh) 1990-03-28
MY104467A (en) 1994-04-30
PT91432B (pt) 1995-12-29
ATE109217T1 (de) 1994-08-15
DK394089A (da) 1990-02-13
AU3951189A (en) 1990-02-15
BR8904061A (pt) 1990-03-27
DE68917059T2 (de) 1994-11-17
PT91432A (pt) 1990-03-08
DE68917059D1 (de) 1994-09-01
KR900003403A (ko) 1990-03-26
EP0358338B1 (en) 1994-07-27
NO893250D0 (no) 1989-08-11
IN176027B (enExample) 1995-12-23

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