AU2010101182A4 - Polyester resin composition and a process for manufacturing the same - Google Patents
Polyester resin composition and a process for manufacturing the same Download PDFInfo
- Publication number
- AU2010101182A4 AU2010101182A4 AU2010101182A AU2010101182A AU2010101182A4 AU 2010101182 A4 AU2010101182 A4 AU 2010101182A4 AU 2010101182 A AU2010101182 A AU 2010101182A AU 2010101182 A AU2010101182 A AU 2010101182A AU 2010101182 A4 AU2010101182 A4 AU 2010101182A4
- Authority
- AU
- Australia
- Prior art keywords
- group
- polyester
- polyester resin
- acid
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
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- 238000000034 method Methods 0.000 title claims description 84
- 239000000203 mixture Substances 0.000 title claims description 58
- 229920001225 polyester resin Polymers 0.000 title claims description 42
- 239000004645 polyester resin Substances 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title description 15
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 68
- 239000004970 Chain extender Substances 0.000 claims description 63
- 229920000642 polymer Polymers 0.000 claims description 57
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 claims description 50
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 40
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 34
- 239000011541 reaction mixture Substances 0.000 claims description 34
- 238000002360 preparation method Methods 0.000 claims description 29
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 23
- 239000003054 catalyst Substances 0.000 claims description 23
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical group COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 21
- 150000002148 esters Chemical class 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 17
- 239000011347 resin Substances 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 238000006068 polycondensation reaction Methods 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 15
- 238000005886 esterification reaction Methods 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims description 12
- 150000002009 diols Chemical class 0.000 claims description 12
- 230000032050 esterification Effects 0.000 claims description 12
- -1 pentaerythitol Chemical compound 0.000 claims description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 11
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- 229920001730 Moisture cure polyurethane Polymers 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 125000003700 epoxy group Chemical group 0.000 claims description 7
- 239000004609 Impact Modifier Substances 0.000 claims description 6
- 239000001361 adipic acid Substances 0.000 claims description 6
- 235000011037 adipic acid Nutrition 0.000 claims description 6
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 67
- 229920000728 polyester Polymers 0.000 description 47
- 238000010101 extrusion blow moulding Methods 0.000 description 40
- 239000000523 sample Substances 0.000 description 34
- 239000000243 solution Substances 0.000 description 31
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 22
- 238000013329 compounding Methods 0.000 description 20
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 239000000047 product Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000011521 glass Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 238000001125 extrusion Methods 0.000 description 12
- 229920005692 JONCRYL® Polymers 0.000 description 11
- 239000000155 melt Substances 0.000 description 10
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 239000012086 standard solution Substances 0.000 description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000011049 filling Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000004593 Epoxy Substances 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 6
- 229940011182 cobalt acetate Drugs 0.000 description 6
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical compound [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 238000012512 characterization method Methods 0.000 description 4
- 239000007863 gel particle Substances 0.000 description 4
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 238000010348 incorporation Methods 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 4
- 229940071125 manganese acetate Drugs 0.000 description 4
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 239000004606 Fillers/Extenders Substances 0.000 description 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229920006127 amorphous resin Polymers 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000002706 hydrostatic effect Effects 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 239000004246 zinc acetate Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 150000001399 aluminium compounds Chemical class 0.000 description 2
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 2
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 2
- 150000001463 antimony compounds Chemical class 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical class [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000002291 germanium compounds Chemical class 0.000 description 2
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000004312 hexamethylene tetramine Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical class COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- VOGDKZZTBPDRBD-UHFFFAOYSA-N 2-[2-(4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole Chemical compound O1CCN=C1C1=CC=CC=C1C1=NCCO1 VOGDKZZTBPDRBD-UHFFFAOYSA-N 0.000 description 1
- FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
- ORWQBKPSGDRPPA-UHFFFAOYSA-N 3-[2-[ethyl(methyl)amino]ethyl]-1h-indol-4-ol Chemical compound C1=CC(O)=C2C(CCN(C)CC)=CNC2=C1 ORWQBKPSGDRPPA-UHFFFAOYSA-N 0.000 description 1
- DGUJJOYLOCXENZ-UHFFFAOYSA-N 4-[2-[4-(oxiran-2-ylmethoxy)phenyl]propan-2-yl]phenol Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 DGUJJOYLOCXENZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920008790 Amorphous Polyethylene terephthalate Polymers 0.000 description 1
- 101100205030 Caenorhabditis elegans hars-1 gene Proteins 0.000 description 1
- 229920008651 Crystalline Polyethylene terephthalate Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 229910005793 GeO 2 Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102100037681 Protein FEV Human genes 0.000 description 1
- 101710198166 Protein FEV Proteins 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
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- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- JVLRYPRBKSMEBF-UHFFFAOYSA-K diacetyloxystibanyl acetate Chemical compound [Sb+3].CC([O-])=O.CC([O-])=O.CC([O-])=O JVLRYPRBKSMEBF-UHFFFAOYSA-K 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 239000012153 distilled water Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 229940119177 germanium dioxide Drugs 0.000 description 1
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- ZGCHATBSUIJLRL-UHFFFAOYSA-N hydrazine sulfate Chemical compound NN.OS(O)(=O)=O ZGCHATBSUIJLRL-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
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- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
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- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical compound C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
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- 238000012667 polymer degradation Methods 0.000 description 1
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- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- 229910052710 silicon Inorganic materials 0.000 description 1
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- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229920006249 styrenic copolymer Polymers 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- ZPKUAUXTKVANIS-UHFFFAOYSA-N tetradec-1-enylbenzene Chemical compound CCCCCCCCCCCCC=CC1=CC=CC=C1 ZPKUAUXTKVANIS-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 125000002348 vinylic group Chemical group 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IN2020MU2010 | 2010-07-14 | ||
| IN2020/MUM/2010 | 2010-07-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2010101182A4 true AU2010101182A4 (en) | 2010-12-09 |
Family
ID=43304132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2010101182A Expired AU2010101182A4 (en) | 2010-07-14 | 2010-10-28 | Polyester resin composition and a process for manufacturing the same |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9221971B2 (enExample) |
| EP (1) | EP2593494B1 (enExample) |
| JP (1) | JP5931061B2 (enExample) |
| KR (1) | KR101799132B1 (enExample) |
| CN (1) | CN103154078B (enExample) |
| AU (1) | AU2010101182A4 (enExample) |
| ES (1) | ES2671600T3 (enExample) |
| WO (1) | WO2012007958A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012007958A1 (en) * | 2010-07-14 | 2012-01-19 | Pearl Engineering Polymers Ltd. | Polyester resin composition and process for manufacturing the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101995457B1 (ko) * | 2012-05-25 | 2019-07-02 | 에스케이케미칼 주식회사 | 폴리에스테르 수지의 제조 방법 |
| KR101969004B1 (ko) | 2012-06-05 | 2019-04-15 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조 방법 |
| KR20140076354A (ko) | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR101992392B1 (ko) | 2012-12-12 | 2019-09-30 | (주)새한폴리머 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| KR20140076355A (ko) | 2012-12-12 | 2014-06-20 | 삼성정밀화학 주식회사 | 생분해성 지방족/방향족 폴리에스테르 공중합체의 연속 제조방법 |
| WO2016168818A1 (en) * | 2015-04-17 | 2016-10-20 | Global Strategies, Inc. | High strength ribbon-woven disposable fabric articles |
| KR102004594B1 (ko) * | 2016-12-30 | 2019-08-02 | 롯데첨단소재(주) | 폴리카보네이트 공중합체 및 이의 제조 방법 |
| JP6741184B1 (ja) * | 2018-10-16 | 2020-08-19 | 東洋紡株式会社 | 熱収縮性フィルム用ポリエステル樹脂、熱収縮性フィルム、熱収縮性ラベル、及び包装体 |
| BR112021014943A2 (pt) * | 2019-02-27 | 2021-09-28 | Basf Se | Ésteres cerosos de etilenoglicol, dispersão de cera, uso dos ésteres, produto de limpeza cosmético para pele e cabelo, e, processo para a produção de um produto de limpeza cosmético |
| KR102167672B1 (ko) * | 2019-08-26 | 2020-10-19 | 주식회사 휴비스 | 형태안정성이 향상된 재생 폴리에스테르 이형단면사 및 이의 제조방법 |
| KR102226711B1 (ko) * | 2019-10-29 | 2021-03-11 | 에스케이씨 주식회사 | 폴리에스테르 용기의 재생 방법 및 이를 위한 폴리에스테르 필름 |
| JPWO2022131219A1 (enExample) * | 2020-12-15 | 2022-06-23 | ||
| EP4265665A4 (en) | 2020-12-15 | 2024-12-11 | TOYOBO MC Corporation | POLYESTER RESIN |
| CN112724615B (zh) * | 2020-12-16 | 2022-10-21 | 金发科技股份有限公司 | 一种pbt树脂组合物及其制备方法和应用 |
| CH718330A1 (de) * | 2021-02-08 | 2022-08-15 | Alpla Werke Alwin Lehner Gmbh & Co Kg | Verfahren zur Herstellung eines rPET-Kunststoffmaterials zur Verwendung in einem Dünnwand-Spritzgussverfahren und im Dünnwand-Spritzgussverfahren hergestellter Hohlkörper. |
| WO2022167679A1 (de) * | 2021-02-08 | 2022-08-11 | Alpla Werke Alwin Lehner Gmbh & Co. Kg | Verfahren zur herstellung eines rpet-kunststoffmaterials zur verwendung in einem dünnwand-spritzgussverfahren und im dünnwand-spritzgussverfahren hergestellter hohlkörper |
| KR102603611B1 (ko) * | 2021-06-24 | 2023-11-20 | 주식회사 삼양사 | 돌기 발생이 억제된 열가소성 폴리에스테르계 엘라스토머 수지 조성물의 제조방법 |
| CN113637148B (zh) * | 2021-07-28 | 2022-11-01 | 武汉科技大学 | 一种基于三乙二醇的可降解共聚酯、制备及应用 |
| KR20240070541A (ko) | 2021-09-27 | 2024-05-21 | 도요보 가부시키가이샤 | 폴리에스테르 수지 |
| KR102751922B1 (ko) * | 2022-04-20 | 2025-01-09 | 에스케이케미칼 주식회사 | 재생 비스(2-히드록시에틸)테레프탈레이트를 포함하는 폴리에스테르 수지 및 이를 이용한 필름 |
| CH719622A1 (de) | 2022-04-22 | 2023-10-31 | Alpla Werke Alwin Lehner Gmbh & Co Kg | Verfahren zur Herstellung eines rPET-Kunststoffmaterials zur Verwendung in einem Dünnwand Spritzgussverfahren und im Dünnwand-Spritzgussverfahren hergestellte Behälter, wie Becher, Schalen, Wannen oder Stegverpackungen. |
| KR20240024420A (ko) | 2022-08-16 | 2024-02-26 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 혼합물, 이의 제조방법 및 이로부터 제조된 폴리에스테르 필름 |
| KR20240151052A (ko) * | 2023-04-10 | 2024-10-17 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조방법 |
| CN117586487B (zh) * | 2024-01-19 | 2024-04-02 | 山东瑞丰高分子材料股份有限公司 | 高温耐候pctg材料及其制备方法 |
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| US4161579A (en) * | 1978-04-10 | 1979-07-17 | Celanese Corporation | Extrusion grade polyethylene terephthalate |
| US4219527A (en) | 1978-10-31 | 1980-08-26 | Celanese Corporation | Extrusion grade polyethylene terephthalate |
| US4554329A (en) * | 1985-01-30 | 1985-11-19 | Celanese Corporation | Modified PET polymers and copolymers suitable for extrusion blow molding |
| JP3210702B2 (ja) | 1991-10-23 | 2001-09-17 | ポリプラスチックス株式会社 | ブロー成形用ポリエステル樹脂組成物及びその成形品 |
| US5391694A (en) * | 1993-10-15 | 1995-02-21 | Shell Oil Company | Solid state polymerization of polyesters with low diffusion resistance prepolymer granules |
| US5442036A (en) | 1994-09-06 | 1995-08-15 | Eastman Chemical Company | Branched copolyesters especially suitable for extrusion blow molding |
| IT1275478B (it) * | 1995-07-05 | 1997-08-07 | M & G Ricerche Spa | Resine poliestere aventi migliorate proprieta' |
| JP3468628B2 (ja) * | 1995-11-16 | 2003-11-17 | 株式会社クラレ | 共重合ポリエステルおよびその成形品 |
| CA2189286C (en) | 1995-11-16 | 2000-05-30 | Shinji Tai | Copolyesters and molded articles comprising the same |
| JP3601560B2 (ja) * | 1996-02-26 | 2004-12-15 | 日立化成工業株式会社 | ポリエステル樹脂の製造法及び塗料の製造法 |
| TWI224115B (en) * | 1999-12-27 | 2004-11-21 | Ind Tech Res Inst | Compositions based on high molecular weight polyesters and method for making the same |
| US20030134915A1 (en) | 2001-12-17 | 2003-07-17 | Scantlebury Geoffrey Raymond | Production of transparent polyester using waste |
| ES2286405T3 (es) * | 2002-02-01 | 2007-12-01 | Basf Corporation | Extendedores de cadena oligomeros para el procesamiento, procesamiento y reciclado de polimeros de condensacion, sintesis, composiciones y aplicaciones. |
| US20040151854A1 (en) * | 2003-02-03 | 2004-08-05 | Pecorini Thomas Joseph | Extrusion blow molded articles |
| WO2004104067A1 (ja) * | 2003-05-21 | 2004-12-02 | Mitsubishi Chemical Corporation | 脂肪族ポリエステル及びその製造方法 |
| US7087706B2 (en) * | 2004-02-06 | 2006-08-08 | Invista North America, S.A.R.L | Polyester with high carboxyl end groups and methods for making |
| US7358322B2 (en) * | 2004-03-09 | 2008-04-15 | Eastman Chemical Company | High IV melt phase polyester polymer catalyzed with antimony containing compounds |
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| WO2007123582A2 (en) * | 2005-12-09 | 2007-11-01 | Polyone Corporation | Nanonylon composites prepared by chain extension reactive extrusion |
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| US8080191B2 (en) | 2006-10-20 | 2011-12-20 | Pepsico, Inc. | Extrudable polyethylene terephthalate blend |
| KR101024090B1 (ko) * | 2006-12-21 | 2011-03-22 | 코오롱인더스트리 주식회사 | 난연성 및 형태안정성이 우수한 폴리에스테르 원사의제조방법 및 그로부터 제조되는 폴리에스테르 원사 |
| WO2008105000A2 (en) * | 2007-03-01 | 2008-09-04 | Reliance Industries Limited | Controlled branched polyester and process for making the same |
| WO2009004745A1 (ja) | 2007-07-01 | 2009-01-08 | Ftex Incorporated | ポリエチレンテレフタレート系グラフト共重合樹脂およびその成形体の製造方法 |
| US20090035502A1 (en) * | 2007-07-31 | 2009-02-05 | Kulkarni Sanjay Tammaji | Polymeric composition suitable for manufacturing pasteurizable containers |
| ES2718245T3 (es) | 2008-04-18 | 2019-06-28 | Pepsico Inc | Composiciones de poliéster y procedimiento para preparar artículos por moldeo por extrusión y soplado |
| US20110187029A1 (en) * | 2008-09-29 | 2011-08-04 | Basf Se | Aliphatic-aromatic polyester |
| EP2350162B1 (de) | 2008-09-29 | 2017-11-15 | Basf Se | Aliphatische polyester |
| AU2010101182A4 (en) | 2010-07-14 | 2010-12-09 | Basf Se | Polyester resin composition and a process for manufacturing the same |
-
2010
- 2010-10-28 AU AU2010101182A patent/AU2010101182A4/en not_active Expired
-
2011
- 2011-06-24 CN CN201180034694.5A patent/CN103154078B/zh active Active
- 2011-06-24 US US13/810,042 patent/US9221971B2/en active Active
- 2011-06-24 EP EP11806395.7A patent/EP2593494B1/en active Active
- 2011-06-24 JP JP2013519218A patent/JP5931061B2/ja active Active
- 2011-06-24 KR KR1020137003683A patent/KR101799132B1/ko active Active
- 2011-06-24 WO PCT/IN2011/000425 patent/WO2012007958A1/en not_active Ceased
- 2011-06-24 ES ES11806395.7T patent/ES2671600T3/es active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012007958A1 (en) * | 2010-07-14 | 2012-01-19 | Pearl Engineering Polymers Ltd. | Polyester resin composition and process for manufacturing the same |
| CN103154078A (zh) * | 2010-07-14 | 2013-06-12 | 巴斯夫欧洲公司 | 聚酯树脂组合物及其制备方法 |
| US9221971B2 (en) | 2010-07-14 | 2015-12-29 | Kulkarni Sanjay Tammaji | Polyester resin composition and a process for manufacturing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013530300A (ja) | 2013-07-25 |
| EP2593494A4 (en) | 2016-12-21 |
| US20130115402A1 (en) | 2013-05-09 |
| US9221971B2 (en) | 2015-12-29 |
| ES2671600T3 (es) | 2018-06-07 |
| CN103154078A (zh) | 2013-06-12 |
| CN103154078B (zh) | 2018-06-19 |
| EP2593494A1 (en) | 2013-05-22 |
| JP5931061B2 (ja) | 2016-06-08 |
| WO2012007958A1 (en) | 2012-01-19 |
| EP2593494B1 (en) | 2018-03-14 |
| KR101799132B1 (ko) | 2017-11-17 |
| KR20130041205A (ko) | 2013-04-24 |
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