AU2002317607A1 - Method of increasing the lifetime of a hydro-oxidation catalyst - Google Patents
Method of increasing the lifetime of a hydro-oxidation catalystInfo
- Publication number
- AU2002317607A1 AU2002317607A1 AU2002317607A AU2002317607A AU2002317607A1 AU 2002317607 A1 AU2002317607 A1 AU 2002317607A1 AU 2002317607 A AU2002317607 A AU 2002317607A AU 2002317607 A AU2002317607 A AU 2002317607A AU 2002317607 A1 AU2002317607 A1 AU 2002317607A1
- Authority
- AU
- Australia
- Prior art keywords
- hydro
- support
- lifetime
- increasing
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- MMVKAPBGSIOVHR-UHFFFAOYSA-N 2-methyl-3-[methyl(trimethylsilyloxy)silyl]propanoic acid Chemical compound OC(=O)C(C)C[SiH](C)O[Si](C)(C)C MMVKAPBGSIOVHR-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30934501P | 2001-08-01 | 2001-08-01 | |
| US60/309,345 | 2001-08-01 | ||
| PCT/US2002/024339 WO2003011454A2 (en) | 2001-08-01 | 2002-07-31 | Method of increasing the lifetime of a hydro-oxidation catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2002317607A1 true AU2002317607A1 (en) | 2003-02-17 |
Family
ID=23197830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002317607A Abandoned AU2002317607A1 (en) | 2001-08-01 | 2002-07-31 | Method of increasing the lifetime of a hydro-oxidation catalyst |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7122491B2 (https=) |
| EP (1) | EP1453605B1 (https=) |
| JP (1) | JP4307253B2 (https=) |
| KR (1) | KR100901282B1 (https=) |
| CN (1) | CN1231296C (https=) |
| AT (1) | ATE320851T1 (https=) |
| AU (1) | AU2002317607A1 (https=) |
| BR (1) | BR0211796A (https=) |
| DE (1) | DE60210087T2 (https=) |
| ES (1) | ES2260459T3 (https=) |
| WO (1) | WO2003011454A2 (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6821923B1 (en) | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
| US7361619B2 (en) * | 2003-04-11 | 2008-04-22 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| US7419928B2 (en) * | 2003-04-11 | 2008-09-02 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| MY145792A (en) * | 2006-11-17 | 2012-04-30 | Dow Global Technologies Inc | Hydro-oxidation process using a catalyst prepared from a gold cluster complex |
| JP2010159245A (ja) * | 2008-09-19 | 2010-07-22 | Sumitomo Chemical Co Ltd | 酸化化合物の製造方法 |
| TWI377981B (en) * | 2009-01-15 | 2012-12-01 | Univ Nat Changhua Education | Metal oxide nanotube-supported gold catalyst and preparing method thereof |
| US20100311571A1 (en) * | 2009-01-16 | 2010-12-09 | Quantumsphere, Inc. | Methods of making catalytic materials by dispersion of nanoparticles onto support structures |
| US20100184588A1 (en) * | 2009-01-16 | 2010-07-22 | Quantumsphere, Inc. | Methods of making catalytic materials by dispersion of nanoparticles onto support structures |
| BR112012009244A2 (pt) * | 2009-10-29 | 2019-09-24 | Imp College Science Techonology And Medicine | processo para preparar um produto oxigenado a partir de um alcano processo para preparar metanol a partir de metano e processo para preparar peroxido de hidrogenio ou uma especie de hidroperoxido |
| KR101107504B1 (ko) * | 2011-08-29 | 2012-01-31 | 주식회사크러텍 | 플라스틱 스크랩에 혼합된 분진제거장치 |
| CN103801326B (zh) * | 2012-11-14 | 2016-03-02 | 国家纳米科学中心 | 一种负载型纳米金催化剂及其制备方法 |
| CN110475748B (zh) * | 2017-04-07 | 2022-12-30 | 住友化学株式会社 | 含钛的硅氧化物的制造方法、环氧化物的制造方法、和含钛的硅氧化物 |
| DE102017208639A1 (de) | 2017-05-22 | 2018-06-07 | Audi Ag | Verfahren zur Reaktivierung von Abgaskatalysatoren |
| US11589610B2 (en) | 2019-12-15 | 2023-02-28 | Shaheen Innovations Holding Limited | Nicotine delivery device having a mist generator device and a driver device |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3923843A (en) * | 1972-03-13 | 1975-12-02 | Shell Oil Co | Epoxidation process with improved heterogeneous catalyst |
| US5145403A (en) * | 1991-06-26 | 1992-09-08 | Meter Devices Company, Inc. | Safety cover for meter socket |
| DE4425672A1 (de) | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| JP2615432B2 (ja) | 1994-10-28 | 1997-05-28 | 工業技術院長 | 金−酸化チタン含有触媒による炭化水素の部分酸化方法 |
| JP3658790B2 (ja) | 1995-03-30 | 2005-06-08 | 住友化学株式会社 | 触媒及びオキシラン化合物の製造方法 |
| DE19600708A1 (de) | 1996-01-11 | 1997-07-17 | Basf Ag | Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| KR100255480B1 (ko) | 1996-03-21 | 2000-05-01 | 사또 다께오 | 탄화수소의 부분산화용촉매 및 탄화수소의 부분산화방법 |
| JP4026884B2 (ja) * | 1996-06-07 | 2007-12-26 | 旭化成株式会社 | メソポア分子ふるい、およびその製造方法 |
| DE19781813T1 (de) * | 1996-06-07 | 1999-05-27 | Asahi Chemical Ind | Mesoporen-Molekularsieb und Verfahren zu dessen Herstellung |
| DE19623609A1 (de) | 1996-06-13 | 1997-12-18 | Basf Ag | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
| RU2189378C2 (ru) | 1996-07-01 | 2002-09-20 | Дзе Дау Кемикал Компани | Способ получения олефиноксидов прямым окислением олефинов, каталитический состав для этого процесса и способ его регенерации |
| US6323351B1 (en) | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
| ES2280636T3 (es) | 1997-06-30 | 2007-09-16 | Dow Global Technologies Inc. | Composicion de catalizador y procedimiento para la oxidacion directa de propileno a oxido de propileno. |
| US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
| DE19804712A1 (de) * | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Standzeitverlängerung von mit Goldteilen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| US6252095B1 (en) | 1998-02-24 | 2001-06-26 | Director-General Of Agency Of Industrial Science And Technology | Catalyst for partially oxidizing unsaturated hydrocarbon |
| US5939569A (en) | 1998-03-10 | 1999-08-17 | Jones; C. Andrew | Epoxidation process |
| ES2203109T3 (es) | 1998-04-15 | 2004-04-01 | Dow Global Technologies Inc. | Procedimiento para la oxidacion directa de olefinas a oxidos de olefina. |
| DE19835481A1 (de) | 1998-08-07 | 2000-02-17 | Bayer Ag | Verfahren zur Oxidation von Kohlenwasserstoffen |
| JP2002532482A (ja) | 1998-12-16 | 2002-10-02 | ザ ダウ ケミカル カンパニー | オレフィンのオレフィンオキシドへの直接酸化法 |
| JP2000279809A (ja) | 1999-03-30 | 2000-10-10 | Nippon Shokubai Co Ltd | エポキシド製造用触媒及びエポキシドの製法 |
| RU2234369C2 (ru) | 1999-04-08 | 2004-08-20 | Дау Глобал Текнолоджиз Инк. | Способ гидроокисления олефинов до оксидов олефинов с использованием катализатора на основе окисленного золота |
| DE60021071T2 (de) | 1999-04-08 | 2006-05-18 | Dow Global Technologies, Inc., Midland | Verfahren zur herstellung eines gold und titanium beinhaltenden katalysators |
| DE19920753A1 (de) | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden |
| DE19918431A1 (de) * | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung eines Katalysators zur selektiven Oxidation von Kohlenwasserstoffen |
| JP4395580B2 (ja) | 1999-04-28 | 2010-01-13 | 独立行政法人産業技術総合研究所 | エポキシドの製造方法 |
| DE19925926A1 (de) | 1999-06-08 | 2000-12-14 | Bayer Ag | Katalysatoren auf Basis Titan-haltiger, organisch-anorganischer Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen |
| AU770334B2 (en) | 1999-12-09 | 2004-02-19 | Dow Global Technologies Inc. | Activation and regeneration of a hydro-oxidation catalyst |
| DE10060775A1 (de) * | 2000-12-07 | 2002-06-13 | Creavis Tech & Innovation Gmbh | Oligomere Silasesquioxane und Verfahren zur Herstellung von oligomeren Silasesquioxanen |
| US6478589B2 (en) * | 2001-01-31 | 2002-11-12 | Ekstrom Industries, Inc. | Electrical service apparatus safety shield with wire guides |
-
2002
- 2002-07-31 AU AU2002317607A patent/AU2002317607A1/en not_active Abandoned
- 2002-07-31 CN CNB028152050A patent/CN1231296C/zh not_active Expired - Fee Related
- 2002-07-31 EP EP02748279A patent/EP1453605B1/en not_active Expired - Lifetime
- 2002-07-31 US US10/484,328 patent/US7122491B2/en not_active Expired - Fee Related
- 2002-07-31 BR BR0211796-7A patent/BR0211796A/pt not_active IP Right Cessation
- 2002-07-31 WO PCT/US2002/024339 patent/WO2003011454A2/en not_active Ceased
- 2002-07-31 DE DE60210087T patent/DE60210087T2/de not_active Expired - Fee Related
- 2002-07-31 AT AT02748279T patent/ATE320851T1/de not_active IP Right Cessation
- 2002-07-31 JP JP2003516679A patent/JP4307253B2/ja not_active Expired - Fee Related
- 2002-07-31 ES ES02748279T patent/ES2260459T3/es not_active Expired - Lifetime
- 2002-07-31 KR KR1020047001499A patent/KR100901282B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP1453605B1 (en) | 2006-03-22 |
| DE60210087T2 (de) | 2007-03-08 |
| ES2260459T3 (es) | 2006-11-01 |
| WO2003011454A3 (en) | 2003-05-08 |
| JP2004536705A (ja) | 2004-12-09 |
| WO2003011454A2 (en) | 2003-02-13 |
| JP4307253B2 (ja) | 2009-08-05 |
| CN1538878A (zh) | 2004-10-20 |
| KR100901282B1 (ko) | 2009-06-09 |
| US7122491B2 (en) | 2006-10-17 |
| CN1231296C (zh) | 2005-12-14 |
| BR0211796A (pt) | 2004-08-03 |
| KR20040019093A (ko) | 2004-03-04 |
| DE60210087D1 (de) | 2006-05-11 |
| US20040171893A1 (en) | 2004-09-02 |
| EP1453605A2 (en) | 2004-09-08 |
| ATE320851T1 (de) | 2006-04-15 |
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