BR0016380A - Complexo metálico,processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica - Google Patents

Complexo metálico,processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica

Info

Publication number
BR0016380A
BR0016380A BR0016380-5A BR0016380A BR0016380A BR 0016380 A BR0016380 A BR 0016380A BR 0016380 A BR0016380 A BR 0016380A BR 0016380 A BR0016380 A BR 0016380A
Authority
BR
Brazil
Prior art keywords
olefins
metal complex
catalytic composition
hydrosilylation process
acetylenic derivatives
Prior art date
Application number
BR0016380-5A
Other languages
English (en)
Other versions
BR0016380B1 (pt
Inventor
Istvan Marko
Sebastien Sterin
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Publication of BR0016380A publication Critical patent/BR0016380A/pt
Publication of BR0016380B1 publication Critical patent/BR0016380B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878—Si-C bond
    • C07F7/0879—Hydrosilylation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Abstract

"COMPLEXO METáLICO, PROCESSO DE HIDROSSILILAçãO DE OLEFINAS OU DE DERIVADOS ACETILêNICOS E COMPOSIçãO CATALìTICA". A presente invenção se refere a complexos metálicos de fórmula (1) na qual M, X, Y~ 1~ Y~ 2~, R~ 1~,R~ 2~, R~ 5~ e R~ 6~ são tais como definidos na reivindicação 1. Esses complexos são particularmente apropriados para a catálise de reações de hidrossililação.
BRPI0016380-5A 1999-12-07 2000-12-01 complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica. BR0016380B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9915432A FR2801887B1 (fr) 1999-12-07 1999-12-07 Complexes metalliques appropries a la catalyse de reactions d'hydrosilylation, composition catalytique les contenant et leur utilisation
PCT/FR2000/003362 WO2001042258A1 (fr) 1999-12-07 2000-12-01 Catalyseurs pour reactions d'hydrosilylation

Publications (2)

Publication Number Publication Date
BR0016380A true BR0016380A (pt) 2002-09-03
BR0016380B1 BR0016380B1 (pt) 2011-02-22

Family

ID=9552985

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0016380-5A BR0016380B1 (pt) 1999-12-07 2000-12-01 complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica.

Country Status (15)

Country Link
US (1) US6803440B2 (pt)
EP (1) EP1235836B1 (pt)
JP (1) JP3854151B2 (pt)
KR (1) KR100595948B1 (pt)
CN (1) CN1237068C (pt)
AT (1) ATE272066T1 (pt)
AU (1) AU2182001A (pt)
BR (1) BR0016380B1 (pt)
CA (1) CA2393629C (pt)
DE (1) DE60012571T2 (pt)
ES (1) ES2220580T3 (pt)
FR (1) FR2801887B1 (pt)
MX (1) MXPA02005645A (pt)
PL (1) PL203798B1 (pt)
WO (1) WO2001042258A1 (pt)

Families Citing this family (43)

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Publication number Priority date Publication date Assignee Title
FR2813081B1 (fr) * 2000-08-17 2005-12-23 Rhodia Chimie Sa Procede de preparation d'huiles silicones par hydrosilylation de synthons contenant au moins un cycle hydrocarbone dans lequel est inclus un atome d'oxygene en presence d'un complexe metallique catalytique
FR2825709B1 (fr) * 2001-06-07 2005-07-01 Rhodia Chimie Sa Composition silicone reticulable en elastomere par hydrosilylation, en presence de catalyseurs metalliques a base de carbenes, et catalyseurs de ce type
DE10152989A1 (de) * 2001-10-26 2003-05-08 Bayer Ag Komplexe N-heterocyslischer Carbene und ihre Verwendung
KR100648880B1 (ko) * 2002-04-29 2006-11-24 로디아 쉬미 히드로실릴화용 조립체, 이의 제조 방법 및 이를 포함하는실리콘 조성물
AU2002367984A1 (en) * 2002-05-23 2003-12-12 Rhodia Chimie Silicone composition which can be crosslinked into an elastomer by hydrosilylation in the presence of carbene-based metal catalysts, and catalysts of this type
FR2853319B1 (fr) 2003-04-03 2005-05-06 Rhodia Chimie Sa Composition reticulable pour electrolyte de batterie
US20060270547A1 (en) * 2003-08-11 2006-11-30 Katrin Kohler N-heterocyclic carbenes that can be immobilized
FR2864543B1 (fr) 2003-12-30 2006-03-03 Rhodia Chimie Sa Procede de preparation de polyorganosiloxanes (pos) par polymerisation par ouverture de cycle(s) et/ou redistribution de pos, en presence de carbene(s) et compositions de pos mises en oeuvre dans ce procede
JP5188004B2 (ja) * 2004-02-17 2013-04-24 東レ・ダウコーニング株式会社 液状中鎖アルキル変性ポリジメチルシロキサン精製品の製造方法および化粧料
DE102005051587A1 (de) * 2005-10-27 2007-05-03 Consortium für elektrochemische Industrie GmbH Zwitterionische Strukturelemente aufweisende Partikel
DE102005051578A1 (de) * 2005-10-27 2007-05-03 Wacker Chemie Ag Verfahren zur Hydrosilylierung
FR2900153B1 (fr) * 2006-04-21 2008-07-18 Rhodia Recherches & Tech Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene
US20100016621A1 (en) * 2006-09-28 2010-01-21 Yugen Zhang Hydrosilylation
US8563459B2 (en) * 2009-05-01 2013-10-22 Gelest Technology, Inc. Fixed-bed hydrosilylation catalyst complexes and related methods
KR101166082B1 (ko) 2009-12-31 2012-07-23 한국과학기술연구원 포화 ｎ-헤테로사이클릭 카르벤-리간드 금속 착물 유도체, 이의 제조방법 및 이를 촉매로 이용한 수소화규소 반응으로 제조한 실란화합물의 제조방법
WO2013000788A1 (en) * 2011-06-29 2013-01-03 Dow Corning Corporation Hydrosilylation reaction curable compositions and methods for their preparation and use
EP2975045B1 (en) * 2013-03-14 2018-07-25 National Institute of Advanced Industrial Science and Technology Metal complex and supported metal complex having disiloxane as ligand, preparation method therefor, and supported metal catalyst prepared using same
KR101596090B1 (ko) * 2013-06-11 2016-02-19 주식회사 엘지화학 폴리이미드 수지 및 이의 제조방법
RU2635604C2 (ru) 2013-06-27 2017-11-14 Блюстар Силикон Франс Сас Вулканизуемые в горячем состоянии полиорганосилоксановые композиции, используемые для изготовления электрических проводов или кабелей
FR3008325B1 (fr) 2013-07-12 2019-10-04 Centre National De La Recherche Scientifique - Cnrs Nouveaux catalyseurs a ligand silene
FR3008324B1 (fr) * 2013-07-12 2019-10-04 Centre National De La Recherche Scientifique - Cnrs Nouveaux catalyseurs a ligand silylene
WO2016024611A1 (ja) * 2014-08-12 2016-02-18 国立大学法人九州大学 ヒドロシリル化反応触媒
KR102443609B1 (ko) 2014-08-12 2022-09-15 고쿠리쓰다이가쿠호진 규슈다이가쿠 하이드로실릴화 반응 촉매
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
FR3028258B1 (fr) 2014-11-07 2017-01-13 Bluestar Silicones France Nouveaux catalyseurs de reticulation de compositions silicones
FR3028512B1 (fr) 2014-11-14 2016-12-09 Bluestar Silicones France Procede d'hydrosilylation mettant en œuvre un catalyseur organique derive de germylene
WO2017010366A1 (ja) 2015-07-14 2017-01-19 国立大学法人九州大学 ヒドロシリル化反応触媒
JP6620823B2 (ja) 2016-01-22 2019-12-18 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
FR3051190A1 (fr) 2016-05-10 2017-11-17 Bluestar Silicones France Procede d'hydrosil mettant en oeuvre un catalyseur organique derive de germylene
FR3061183B1 (fr) 2016-12-23 2020-09-11 Bluestar Silicones France Compose du cobalt utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
WO2018159595A1 (ja) 2017-02-28 2018-09-07 国立大学法人九州大学 ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒
JP6944549B2 (ja) 2017-06-22 2021-10-06 エルケム・シリコーンズ・フランス・エスアエスＥＬＫＥＭ ＳＩＬＩＣＯＮＥＳ Ｆｒａｎｃｅ ＳＡＳ フリーラジカル光開始剤及びシリコーン組成物におけるその使用
FR3068699B1 (fr) 2017-07-05 2019-08-16 Elkem Silicones France Sas Compose du fer utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
CN110614122B (zh) * 2018-06-20 2023-03-24 万华化学集团股份有限公司 一种负载型硅氢加成催化剂的制备方法
FR3099484B1 (fr) 2019-07-29 2021-07-30 Michelin & Cie composition de caoutchouc silicone pour revêtement de membrane de cuisson.
FR3099485B1 (fr) 2019-07-29 2021-07-30 Michelin & Cie composition de caoutchouc silicone pour revêtement de membrane de cuisson.
FR3103821B1 (fr) 2019-11-29 2021-11-12 Michelin & Cie stratifié à base de compositions de caoutchouc silicone
FR3103820B1 (fr) 2019-11-29 2022-08-05 Michelin & Cie Membrane expansible pour moule de cuisson revêtue d’une composition de caoutchouc silicone
WO2022229519A1 (fr) 2021-04-29 2022-11-03 Elkem Silicones France Sas Procédé d'hydrosilylation catalysé par un complexe de gallium
FR3126417A1 (fr) 2021-08-31 2023-03-03 Elkem Silicones France Sas Procédé d’hydrosilylation catalysé par un complexe de fer
FR3126418B1 (fr) 2021-08-31 2023-08-04 Elkem Silicones France Sas Procédé d’hydrosilylation catalysé par un complexe de cobalt
FR3131918A1 (fr) 2022-01-18 2023-07-21 Elkem Silicones France Sas Procédé d’hydrosilylation photocatalysé par un complexe de manganèse

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US4288345A (en) * 1980-02-06 1981-09-08 General Electric Company Platinum complex

Also Published As

Publication number Publication date
CA2393629A1 (fr) 2001-06-14
PL203798B1 (pl) 2009-11-30
US20030083454A1 (en) 2003-05-01
KR20020059446A (ko) 2002-07-12
US6803440B2 (en) 2004-10-12
FR2801887A1 (fr) 2001-06-08
CA2393629C (fr) 2005-10-18
EP1235836A1 (fr) 2002-09-04
JP3854151B2 (ja) 2006-12-06
PL356486A1 (en) 2004-06-28
MXPA02005645A (es) 2003-02-10
DE60012571D1 (de) 2004-09-02
ES2220580T3 (es) 2004-12-16
WO2001042258A1 (fr) 2001-06-14
ATE272066T1 (de) 2004-08-15
BR0016380B1 (pt) 2011-02-22
AU2182001A (en) 2001-06-18
DE60012571T2 (de) 2005-01-05
CN1237068C (zh) 2006-01-18
JP2003516230A (ja) 2003-05-13
CN1414969A (zh) 2003-04-30
FR2801887B1 (fr) 2002-10-11
KR100595948B1 (ko) 2006-07-03
EP1235836B1 (fr) 2004-07-28

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B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 22/02/2011, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: BLUESTAR SILICONES FRANCE (FR)

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 22.02.2021