BR0016380A - Complexo metálico,processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica - Google Patents

Complexo metálico,processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica

Info

Publication number
BR0016380A
BR0016380A BR0016380-5A BR0016380A BR0016380A BR 0016380 A BR0016380 A BR 0016380A BR 0016380 A BR0016380 A BR 0016380A BR 0016380 A BR0016380 A BR 0016380A
Authority
BR
Brazil
Prior art keywords
olefins
metal complex
catalytic composition
hydrosilylation process
acetylenic derivatives
Prior art date
Application number
BR0016380-5A
Other languages
English (en)
Other versions
BR0016380B1 (pt
Inventor
Istvan Marko
Sebastien Sterin
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Publication of BR0016380A publication Critical patent/BR0016380A/pt
Publication of BR0016380B1 publication Critical patent/BR0016380B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C07F7/0872—Preparation and treatment thereof
    • C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
    • C07F7/0878—Si-C bond
    • C07F7/0879—Hydrosilylation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2291—Olefins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/828—Platinum

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"COMPLEXO METáLICO, PROCESSO DE HIDROSSILILAçãO DE OLEFINAS OU DE DERIVADOS ACETILêNICOS E COMPOSIçãO CATALìTICA". A presente invenção se refere a complexos metálicos de fórmula (1) na qual M, X, Y~ 1~ Y~ 2~, R~ 1~,R~ 2~, R~ 5~ e R~ 6~ são tais como definidos na reivindicação 1. Esses complexos são particularmente apropriados para a catálise de reações de hidrossililação.
BRPI0016380-5A 1999-12-07 2000-12-01 complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica. BR0016380B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9915432A FR2801887B1 (fr) 1999-12-07 1999-12-07 Complexes metalliques appropries a la catalyse de reactions d'hydrosilylation, composition catalytique les contenant et leur utilisation
PCT/FR2000/003362 WO2001042258A1 (fr) 1999-12-07 2000-12-01 Catalyseurs pour reactions d'hydrosilylation

Publications (2)

Publication Number Publication Date
BR0016380A true BR0016380A (pt) 2002-09-03
BR0016380B1 BR0016380B1 (pt) 2011-02-22

Family

ID=9552985

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0016380-5A BR0016380B1 (pt) 1999-12-07 2000-12-01 complexo metálico, processo de hidrossililação de olefinas ou de derivados acetilênicos e composição catalìtica.

Country Status (15)

Country Link
US (1) US6803440B2 (pt)
EP (1) EP1235836B1 (pt)
JP (1) JP3854151B2 (pt)
KR (1) KR100595948B1 (pt)
CN (1) CN1237068C (pt)
AT (1) ATE272066T1 (pt)
AU (1) AU2182001A (pt)
BR (1) BR0016380B1 (pt)
CA (1) CA2393629C (pt)
DE (1) DE60012571T2 (pt)
ES (1) ES2220580T3 (pt)
FR (1) FR2801887B1 (pt)
MX (1) MXPA02005645A (pt)
PL (1) PL203798B1 (pt)
WO (1) WO2001042258A1 (pt)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
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FR2813081B1 (fr) * 2000-08-17 2005-12-23 Rhodia Chimie Sa Procede de preparation d'huiles silicones par hydrosilylation de synthons contenant au moins un cycle hydrocarbone dans lequel est inclus un atome d'oxygene en presence d'un complexe metallique catalytique
FR2825709B1 (fr) * 2001-06-07 2005-07-01 Rhodia Chimie Sa Composition silicone reticulable en elastomere par hydrosilylation, en presence de catalyseurs metalliques a base de carbenes, et catalyseurs de ce type
DE10152989A1 (de) * 2001-10-26 2003-05-08 Bayer Ag Komplexe N-heterocyslischer Carbene und ihre Verwendung
AU2003246862A1 (en) * 2002-04-29 2003-11-17 Rhodia Chimie Assembly for hydrosylilation, method for preparing same and silicone compositions incorporating same
AU2002367984A1 (en) * 2002-05-23 2003-12-12 Rhodia Chimie Silicone composition which can be crosslinked into an elastomer by hydrosilylation in the presence of carbene-based metal catalysts, and catalysts of this type
FR2853319B1 (fr) 2003-04-03 2005-05-06 Rhodia Chimie Sa Composition reticulable pour electrolyte de batterie
CN1835958A (zh) * 2003-08-11 2006-09-20 默克专利有限公司 可被固定的n－杂环碳烯
FR2864543B1 (fr) 2003-12-30 2006-03-03 Rhodia Chimie Sa Procede de preparation de polyorganosiloxanes (pos) par polymerisation par ouverture de cycle(s) et/ou redistribution de pos, en presence de carbene(s) et compositions de pos mises en oeuvre dans ce procede
JP5188004B2 (ja) * 2004-02-17 2013-04-24 東レ・ダウコーニング株式会社 液状中鎖アルキル変性ポリジメチルシロキサン精製品の製造方法および化粧料
DE102005051578A1 (de) * 2005-10-27 2007-05-03 Wacker Chemie Ag Verfahren zur Hydrosilylierung
DE102005051587A1 (de) * 2005-10-27 2007-05-03 Consortium für elektrochemische Industrie GmbH Zwitterionische Strukturelemente aufweisende Partikel
FR2900153B1 (fr) * 2006-04-21 2008-07-18 Rhodia Recherches & Tech Procede de condensation de motifs silyles a l'aide d'un catalyseur de type carbene
EP2066601B1 (en) * 2006-09-28 2012-10-24 Agency for Science, Technology And Research Hydrosilylation
DE102010028454A1 (de) * 2009-05-01 2011-01-27 Gelest Technologies, Inc. Festbett-Hydrosilylierungs-Katalysator-Komplex und Verfahren hierzu
KR101166082B1 (ko) * 2009-12-31 2012-07-23 한국과학기술연구원 포화 ｎ-헤테로사이클릭 카르벤-리간드 금속 착물 유도체, 이의 제조방법 및 이를 촉매로 이용한 수소화규소 반응으로 제조한 실란화합물의 제조방법
JP2014520904A (ja) * 2011-06-29 2014-08-25 ダウ コーニング コーポレーション ヒドロシリル化反応硬化性組成物、並びに、その調製及び使用方法
CN105209474B (zh) * 2013-03-14 2017-07-14 国立研究开发法人产业技术综合研究所 具有二硅氧烷作为配体的金属络合物和负载型金属络合物、它们的制备方法和通过使用负载型金属络合物制备的负载型金属催化剂
KR101596090B1 (ko) * 2013-06-11 2016-02-19 주식회사 엘지화학 폴리이미드 수지 및 이의 제조방법
CN105408406B (zh) 2013-06-27 2017-09-26 蓝星有机硅法国两合公司 尤其可用于生产电线或电缆的可热硫化聚有机硅氧烷组合物
FR3008325B1 (fr) * 2013-07-12 2019-10-04 Centre National De La Recherche Scientifique - Cnrs Nouveaux catalyseurs a ligand silene
FR3008324B1 (fr) * 2013-07-12 2019-10-04 Centre National De La Recherche Scientifique - Cnrs Nouveaux catalyseurs a ligand silylene
JP6327426B2 (ja) 2014-08-12 2018-05-23 国立大学法人九州大学 ヒドロシリル化反応触媒
EP3181226A4 (en) * 2014-08-12 2018-04-18 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
FR3028258B1 (fr) 2014-11-07 2017-01-13 Bluestar Silicones France Nouveaux catalyseurs de reticulation de compositions silicones
FR3028512B1 (fr) 2014-11-14 2016-12-09 Bluestar Silicones France Procede d'hydrosilylation mettant en œuvre un catalyseur organique derive de germylene
WO2017010366A1 (ja) 2015-07-14 2017-01-19 国立大学法人九州大学 ヒドロシリル化反応触媒
EP3406616B1 (en) 2016-01-22 2022-06-29 Shin-Etsu Chemical Co., Ltd. Novel isocyanide compound and hydrosilylation reaction catalyst
FR3051190A1 (fr) * 2016-05-10 2017-11-17 Bluestar Silicones France Procede d'hydrosil mettant en oeuvre un catalyseur organique derive de germylene
FR3061183B1 (fr) 2016-12-23 2020-09-11 Bluestar Silicones France Compose du cobalt utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
EP3590596B1 (en) 2017-02-28 2023-07-12 Kyushu University, National University Corporation Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction
EP3642192A1 (fr) 2017-06-22 2020-04-29 Elkem Silicones France S.A.S. Photoamorceurs radicalaires et leurs utilisations dans les compositions silicones
FR3068699B1 (fr) 2017-07-05 2019-08-16 Elkem Silicones France Sas Compose du fer utile comme catalyseur d'hydrosilylation, de silylation deshydrogenante et de reticulation de compositions silicones
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒
CN110614122B (zh) * 2018-06-20 2023-03-24 万华化学集团股份有限公司 一种负载型硅氢加成催化剂的制备方法
FR3099484B1 (fr) 2019-07-29 2021-07-30 Michelin & Cie composition de caoutchouc silicone pour revêtement de membrane de cuisson.
FR3099485B1 (fr) 2019-07-29 2021-07-30 Michelin & Cie composition de caoutchouc silicone pour revêtement de membrane de cuisson.
FR3103821B1 (fr) 2019-11-29 2021-11-12 Michelin & Cie stratifié à base de compositions de caoutchouc silicone
FR3103820B1 (fr) 2019-11-29 2022-08-05 Michelin & Cie Membrane expansible pour moule de cuisson revêtue d’une composition de caoutchouc silicone
WO2022229519A1 (fr) 2021-04-29 2022-11-03 Elkem Silicones France Sas Procédé d'hydrosilylation catalysé par un complexe de gallium
FR3126418B1 (fr) 2021-08-31 2023-08-04 Elkem Silicones France Sas Procédé d’hydrosilylation catalysé par un complexe de cobalt
FR3126417B1 (fr) 2021-08-31 2024-06-21 Elkem Silicones France Sas Procédé d’hydrosilylation catalysé par un complexe de fer
FR3131918A1 (fr) 2022-01-18 2023-07-21 Elkem Silicones France Sas Procédé d’hydrosilylation photocatalysé par un complexe de manganèse

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US4288345A (en) * 1980-02-06 1981-09-08 General Electric Company Platinum complex

Also Published As

Publication number Publication date
KR20020059446A (ko) 2002-07-12
EP1235836B1 (fr) 2004-07-28
DE60012571D1 (de) 2004-09-02
KR100595948B1 (ko) 2006-07-03
US20030083454A1 (en) 2003-05-01
CN1414969A (zh) 2003-04-30
AU2182001A (en) 2001-06-18
DE60012571T2 (de) 2005-01-05
PL356486A1 (en) 2004-06-28
EP1235836A1 (fr) 2002-09-04
PL203798B1 (pl) 2009-11-30
JP3854151B2 (ja) 2006-12-06
CN1237068C (zh) 2006-01-18
CA2393629C (fr) 2005-10-18
ES2220580T3 (es) 2004-12-16
JP2003516230A (ja) 2003-05-13
US6803440B2 (en) 2004-10-12
CA2393629A1 (fr) 2001-06-14
MXPA02005645A (es) 2003-02-10
WO2001042258A1 (fr) 2001-06-14
FR2801887A1 (fr) 2001-06-08
ATE272066T1 (de) 2004-08-15
FR2801887B1 (fr) 2002-10-11
BR0016380B1 (pt) 2011-02-22

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B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 22/02/2011, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved

Owner name: BLUESTAR SILICONES FRANCE (FR)

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 22.02.2021