ATE320851T1 - Verfahren zur standzeitverlängerung eines hydro- oxidationskatalysators - Google Patents
Verfahren zur standzeitverlängerung eines hydro- oxidationskatalysatorsInfo
- Publication number
- ATE320851T1 ATE320851T1 AT02748279T AT02748279T ATE320851T1 AT E320851 T1 ATE320851 T1 AT E320851T1 AT 02748279 T AT02748279 T AT 02748279T AT 02748279 T AT02748279 T AT 02748279T AT E320851 T1 ATE320851 T1 AT E320851T1
- Authority
- AT
- Austria
- Prior art keywords
- hydro
- support
- catalyst
- oxidation catalyst
- extensing
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- MMVKAPBGSIOVHR-UHFFFAOYSA-N 2-methyl-3-[methyl(trimethylsilyloxy)silyl]propanoic acid Chemical compound OC(=O)C(C)C[SiH](C)O[Si](C)(C)C MMVKAPBGSIOVHR-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- GBPOWOIWSYUZMH-UHFFFAOYSA-N sodium;trihydroxy(methyl)silane Chemical compound [Na+].C[Si](O)(O)O GBPOWOIWSYUZMH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J33/00—Protection of catalysts, e.g. by coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0209—Esters of carboxylic or carbonic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30934501P | 2001-08-01 | 2001-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE320851T1 true ATE320851T1 (de) | 2006-04-15 |
Family
ID=23197830
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02748279T ATE320851T1 (de) | 2001-08-01 | 2002-07-31 | Verfahren zur standzeitverlängerung eines hydro- oxidationskatalysators |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7122491B2 (de) |
| EP (1) | EP1453605B1 (de) |
| JP (1) | JP4307253B2 (de) |
| KR (1) | KR100901282B1 (de) |
| CN (1) | CN1231296C (de) |
| AT (1) | ATE320851T1 (de) |
| AU (1) | AU2002317607A1 (de) |
| BR (1) | BR0211796A (de) |
| DE (1) | DE60210087T2 (de) |
| ES (1) | ES2260459T3 (de) |
| WO (1) | WO2003011454A2 (de) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6821923B1 (en) | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
| US7419928B2 (en) * | 2003-04-11 | 2008-09-02 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| US7361619B2 (en) * | 2003-04-11 | 2008-04-22 | Exxonmobil Research And Engineering Company | Fischer-Tropsch catalyst production |
| RU2445159C2 (ru) * | 2006-11-17 | 2012-03-20 | Дау Глобал Текнолоджиз Инк. | Способ гидроокисления с использованием катализатора, полученного из кластерного комплекса золота |
| JP2010159245A (ja) * | 2008-09-19 | 2010-07-22 | Sumitomo Chemical Co Ltd | 酸化化合物の製造方法 |
| TWI377981B (en) * | 2009-01-15 | 2012-12-01 | Univ Nat Changhua Education | Metal oxide nanotube-supported gold catalyst and preparing method thereof |
| US20100311571A1 (en) * | 2009-01-16 | 2010-12-09 | Quantumsphere, Inc. | Methods of making catalytic materials by dispersion of nanoparticles onto support structures |
| WO2010083342A1 (en) * | 2009-01-16 | 2010-07-22 | Quantumsphere, Inc. | Catalysts by dispersion of nanoparticles onto support structures |
| CN102741207B (zh) * | 2009-10-29 | 2015-12-02 | 帝国科技及医学学院 | C1-c3烷烃的选择性催化氧化 |
| KR101107504B1 (ko) * | 2011-08-29 | 2012-01-31 | 주식회사크러텍 | 플라스틱 스크랩에 혼합된 분진제거장치 |
| CN103801326B (zh) * | 2012-11-14 | 2016-03-02 | 国家纳米科学中心 | 一种负载型纳米金催化剂及其制备方法 |
| WO2018186491A1 (ja) * | 2017-04-07 | 2018-10-11 | 住友化学株式会社 | チタン含有珪素酸化物の製造方法、エポキシドの製造方法、及びチタン含有珪素酸化物 |
| DE102017208639A1 (de) | 2017-05-22 | 2018-06-07 | Audi Ag | Verfahren zur Reaktivierung von Abgaskatalysatoren |
| US11589610B2 (en) | 2019-12-15 | 2023-02-28 | Shaheen Innovations Holding Limited | Nicotine delivery device having a mist generator device and a driver device |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3923843A (en) | 1972-03-13 | 1975-12-02 | Shell Oil Co | Epoxidation process with improved heterogeneous catalyst |
| US5145403A (en) * | 1991-06-26 | 1992-09-08 | Meter Devices Company, Inc. | Safety cover for meter socket |
| DE4425672A1 (de) * | 1994-07-20 | 1996-01-25 | Basf Ag | Oxidationskatalysator, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| JP2615432B2 (ja) | 1994-10-28 | 1997-05-28 | 工業技術院長 | 金−酸化チタン含有触媒による炭化水素の部分酸化方法 |
| JP3658790B2 (ja) | 1995-03-30 | 2005-06-08 | 住友化学株式会社 | 触媒及びオキシラン化合物の製造方法 |
| DE19600708A1 (de) | 1996-01-11 | 1997-07-17 | Basf Ag | Oxidationskatalysator mit einem Gehalt an Lanthanoidmetallen, Verfahren zu seiner Herstellung und Oxidationsverfahren unter Verwendung des Oxidationskatalysators |
| EP0827779A4 (de) | 1996-03-21 | 1999-06-30 | Agency Ind Science Techn | Katalysatoren und methode zur teiloxidation von kohlenwasserstoffen |
| JP4026884B2 (ja) * | 1996-06-07 | 2007-12-26 | 旭化成株式会社 | メソポア分子ふるい、およびその製造方法 |
| WO1997046743A1 (en) * | 1996-06-07 | 1997-12-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Mesopore molecular sieve and process for the production thereof |
| DE19623609A1 (de) | 1996-06-13 | 1997-12-18 | Basf Ag | Oxidationskatalysator und Verfahren zur Herstellung von Epoxiden aus Olefinen, Wasserstoff und Sauerstoff unter Verwendung des Oxidationskatalysators |
| CN1152028C (zh) | 1996-07-01 | 2004-06-02 | 陶氏环球技术公司 | 烯烃直接氧化成烯烃氧化物的方法 |
| US6323351B1 (en) | 1997-06-30 | 2001-11-27 | The Dow Chemical Company | Process for the direct oxidation of olefins to olefin oxides |
| US6562986B2 (en) | 1997-06-30 | 2003-05-13 | Dow Global Technologies, Inc. | Process for the direct oxidation of olefins to olefin oxides |
| EP1024895B1 (de) | 1997-06-30 | 2005-11-30 | Dow Global Technologies Inc. | Verfahren zur herstellung von olefinoxiden durch direktoxidation von olefinen |
| DE19804712A1 (de) * | 1998-02-06 | 1999-08-12 | Bayer Ag | Verfahren zur Standzeitverlängerung von mit Goldteilen belegten Trägerkatalysatoren für die Oxidation ungesättigter Kohlenwasserstoffe |
| WO1999043431A1 (en) | 1998-02-24 | 1999-09-02 | Japan As Represented By Director-General Of Agency Of Industrial Science And Technology | Catalyst for partially oxidizing unsaturated hydrocarbon |
| US5939569A (en) | 1998-03-10 | 1999-08-17 | Jones; C. Andrew | Epoxidation process |
| ID26171A (id) | 1998-04-15 | 2000-11-30 | Dow Chemical Co | Proses untuk oksidasi langsung olefin-olefin ke oksida-oksida olefin |
| DE19835481A1 (de) | 1998-08-07 | 2000-02-17 | Bayer Ag | Verfahren zur Oxidation von Kohlenwasserstoffen |
| AU756230B2 (en) | 1998-12-16 | 2003-01-09 | Dow Global Technologies Inc. | Process for the direct oxidation of olefins to olefin oxides |
| JP2000279809A (ja) | 1999-03-30 | 2000-10-10 | Nippon Shokubai Co Ltd | エポキシド製造用触媒及びエポキシドの製法 |
| KR100715136B1 (ko) | 1999-04-08 | 2007-05-10 | 다우 글로벌 테크놀로지스 인크. | 금 및 티탄을 포함하는 촉매의 제조방법 |
| ID30342A (id) | 1999-04-08 | 2001-11-22 | Dow Chemical Co | Proses untuk hidro-oksidasi olefin oksida dengan menggunakan katalis emas teroksidasi |
| DE19918431A1 (de) * | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung eines Katalysators zur selektiven Oxidation von Kohlenwasserstoffen |
| DE19920753A1 (de) | 1999-04-23 | 2000-10-26 | Bayer Ag | Verfahren zur Herstellung von amorphen, edelmetallhaltigen Titan-Silizium-Mischoxiden |
| JP4395580B2 (ja) | 1999-04-28 | 2010-01-13 | 独立行政法人産業技術総合研究所 | エポキシドの製造方法 |
| DE19925926A1 (de) | 1999-06-08 | 2000-12-14 | Bayer Ag | Katalysatoren auf Basis Titan-haltiger, organisch-anorganischer Hybridmaterialien zur selektiven Oxidation von Kohlenwasserstoffen |
| KR20030003219A (ko) | 1999-12-09 | 2003-01-09 | 더 다우 케미칼 캄파니 | 하이드로-산화 촉매의 활성화 및 재생 |
| DE10060775A1 (de) * | 2000-12-07 | 2002-06-13 | Creavis Tech & Innovation Gmbh | Oligomere Silasesquioxane und Verfahren zur Herstellung von oligomeren Silasesquioxanen |
| US6478589B2 (en) * | 2001-01-31 | 2002-11-12 | Ekstrom Industries, Inc. | Electrical service apparatus safety shield with wire guides |
-
2002
- 2002-07-31 BR BR0211796-7A patent/BR0211796A/pt not_active IP Right Cessation
- 2002-07-31 AT AT02748279T patent/ATE320851T1/de not_active IP Right Cessation
- 2002-07-31 US US10/484,328 patent/US7122491B2/en not_active Expired - Fee Related
- 2002-07-31 AU AU2002317607A patent/AU2002317607A1/en not_active Abandoned
- 2002-07-31 WO PCT/US2002/024339 patent/WO2003011454A2/en not_active Ceased
- 2002-07-31 CN CNB028152050A patent/CN1231296C/zh not_active Expired - Fee Related
- 2002-07-31 EP EP02748279A patent/EP1453605B1/de not_active Expired - Lifetime
- 2002-07-31 JP JP2003516679A patent/JP4307253B2/ja not_active Expired - Fee Related
- 2002-07-31 KR KR1020047001499A patent/KR100901282B1/ko not_active Expired - Fee Related
- 2002-07-31 DE DE60210087T patent/DE60210087T2/de not_active Expired - Fee Related
- 2002-07-31 ES ES02748279T patent/ES2260459T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2260459T3 (es) | 2006-11-01 |
| US20040171893A1 (en) | 2004-09-02 |
| KR100901282B1 (ko) | 2009-06-09 |
| JP2004536705A (ja) | 2004-12-09 |
| BR0211796A (pt) | 2004-08-03 |
| WO2003011454A3 (en) | 2003-05-08 |
| DE60210087T2 (de) | 2007-03-08 |
| CN1231296C (zh) | 2005-12-14 |
| CN1538878A (zh) | 2004-10-20 |
| WO2003011454A2 (en) | 2003-02-13 |
| US7122491B2 (en) | 2006-10-17 |
| AU2002317607A1 (en) | 2003-02-17 |
| KR20040019093A (ko) | 2004-03-04 |
| JP4307253B2 (ja) | 2009-08-05 |
| DE60210087D1 (de) | 2006-05-11 |
| EP1453605A2 (de) | 2004-09-08 |
| EP1453605B1 (de) | 2006-03-22 |
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