ATE512165T1 - Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst - Google Patents

Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst

Info

Publication number
ATE512165T1
ATE512165T1 AT07840004T AT07840004T ATE512165T1 AT E512165 T1 ATE512165 T1 AT E512165T1 AT 07840004 T AT07840004 T AT 07840004T AT 07840004 T AT07840004 T AT 07840004T AT E512165 T1 ATE512165 T1 AT E512165T1
Authority
AT
Austria
Prior art keywords
salt
hydrocarbon surfactant
fluorinated monomers
aqueous polymerization
polymerizing agent
Prior art date
Application number
AT07840004T
Other languages
German (de)
English (en)
Inventor
Paul Douglas Brothers
Subash Vishnu Gangal
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Application granted granted Critical
Publication of ATE512165T1 publication Critical patent/ATE512165T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/26—Tetrafluoroethene
    • C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT07840004T 2006-11-09 2007-11-09 Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst ATE512165T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US85800806P 2006-11-09 2006-11-09
PCT/US2007/023642 WO2008060463A1 (en) 2006-11-09 2007-11-09 Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant

Publications (1)

Publication Number Publication Date
ATE512165T1 true ATE512165T1 (de) 2011-06-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
AT07840004T ATE512165T1 (de) 2006-11-09 2007-11-09 Wässrige polymerisation von fluorierten monomeren unter verwendung eines polymerisationsmittels, das fluorpolyethersäure oder -salz und kohlenwasserstofftensid umfasst

Country Status (6)

Country Link
US (1) US7897682B2 (enExample)
EP (1) EP2084195B1 (enExample)
JP (1) JP5439186B2 (enExample)
CN (1) CN101605826B (enExample)
AT (1) ATE512165T1 (enExample)
WO (1) WO2008060463A1 (enExample)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8080621B2 (en) * 2005-06-10 2011-12-20 Arkema Inc. Aqueous process for making fluoropolymers
JP5470044B2 (ja) * 2006-11-09 2014-04-16 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 高分子量フルオロポリエーテル酸または塩およびフルオロポリエーテル酸または塩界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
US20090281241A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Aqueous Polymerization of Fluorinated Monomer Using a Mixture of Fluoropolyether Acids or Salts
US20100113691A1 (en) * 2008-11-06 2010-05-06 E. I. Du Pont De Nemours And Company Fluoro olefin polymerization
US8436054B2 (en) * 2008-12-23 2013-05-07 E I Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer produced in situ
US8153738B2 (en) * 2008-12-23 2012-04-10 E I Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8436053B2 (en) * 2008-12-23 2013-05-07 E.I. Du Pont De Nemours And Company Fluorinated ionomer produced by aqueous polymerization using dispersed particulate of fluorinated ionomer
US8835547B2 (en) * 2008-12-23 2014-09-16 E I Du Pont De Nemours And Company Fluoropolymer particles having a nucleus of fluorinated ionomer
US8058376B2 (en) 2008-12-23 2011-11-15 E. I. Du Pont De Nemours And Company Fluoropolymer produced by aqueous polymerization using dispersed particulate of fluorinated lonomer produced in situ
RU2522749C2 (ru) * 2009-07-31 2014-07-20 Зм Инновейтив Пропертиз Компани Соединения фторполимера, содержащие многоатомные соединения, и способы из производства
US9920141B2 (en) * 2009-12-18 2018-03-20 Solvay Specialty Polymers Italy S.P.A. Process for manufacturing a dispersion of a vinylidene fluoride polymer
JP5684283B2 (ja) * 2009-12-18 2015-03-11 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フルオロポリマーの製造方法
JP6030562B2 (ja) 2010-11-09 2016-11-24 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 水性分散体フルオロモノマーの重合における炭化水素含有界面活性剤のテロゲン性挙動の低下
WO2012064846A1 (en) * 2010-11-09 2012-05-18 E. I. Du Pont De Nemours And Company Nucleation in aqueous polymerization of fluoromonomer
CN103201300B (zh) 2010-11-09 2016-11-09 纳幕尔杜邦公司 使用烃表面活性剂的含氟单体的含水聚合
JP5730093B2 (ja) * 2011-03-28 2015-06-03 株式会社クレハ フッ化ビニリデン系重合体の製造方法
CN102585070B (zh) * 2012-01-06 2015-12-09 石家庄市海森化工有限公司 三氟氯乙烯-乙烯共聚物的制备方法
CN102627719B (zh) * 2012-03-23 2014-05-07 上海三爱富新材料股份有限公司 一种高强度耐蠕变性的聚四氟乙烯制备方法
EP3074430B1 (en) 2013-11-26 2019-02-20 The Chemours Company FC, LLC Employing polyalkylene oxides for nucleation in aqueous polymerization of fluoromonomer
KR102021683B1 (ko) * 2015-03-13 2019-09-16 다이킨 고교 가부시키가이샤 도료 조성물 및 피복 물품
CN108017746B (zh) * 2016-10-28 2020-03-20 中昊晨光化工研究院有限公司 一种低压缩永久变形的过氧化物硫化氟橡胶及其制备方法
CN113717300B (zh) 2017-03-31 2023-11-17 大金工业株式会社 含氟聚合物的制造方法、聚合用表面活性剂和表面活性剂的使用
US11279814B2 (en) 2017-03-31 2022-03-22 Daikin Industries, Ltd. Production method for fluoropolymer, surfactant for polymerization, and use of surfactant
US11851519B2 (en) 2017-08-10 2023-12-26 Daikin Industries, Ltd. Method for producing purified polytetrafluoroethylene aqueous dispersion liquid, method for producing modified polytetrafluoroethylene powder, method for producing polytetrafluoroethylene molded body, and composition
US11401352B2 (en) * 2017-09-08 2022-08-02 Solvay Specialty Polymers Italy S.P.A. Method for making fluoropolymers
JP7088202B2 (ja) * 2017-09-28 2022-06-21 Ａｇｃ株式会社 変性ポリテトラフルオロエチレンの製造方法、変性ポリテトラフルオロエチレン粉末の製造方法、延伸多孔体の製造方法
US11634514B2 (en) 2018-02-08 2023-04-25 Daikin Industries. Ltd. Method for manufacturing fluoropolymer, surfactant for polymerization, use for surfactant, and composition
CN111836835B (zh) 2018-03-01 2023-07-14 大金工业株式会社 含氟聚合物的制造方法
WO2019172382A1 (ja) * 2018-03-07 2019-09-12 ダイキン工業株式会社 フルオロポリマーの製造方法
CN112154162B (zh) * 2018-05-18 2022-07-26 Ａｇｃ株式会社 含氟聚合物的制造方法及含氟离子交换聚合物的制造方法
WO2020071504A1 (ja) * 2018-10-03 2020-04-09 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法
CN113728015B (zh) 2019-04-26 2025-03-11 大金工业株式会社 氟聚合物水性分散液的制造方法和氟聚合物水性分散液
US20220259337A1 (en) 2019-04-26 2022-08-18 Daikin Industries, Ltd. Method for producing aqueous fluoropolymer dispersion, drainage treatment method, and aqueous fluoropolymer dispersion
CN118146601A (zh) * 2019-07-23 2024-06-07 大金工业株式会社 含氟聚合物的制造方法、聚四氟乙烯组合物和聚四氟乙烯粉末
MX2022004325A (es) * 2019-10-11 2022-09-19 Gujarat Fluorochemicals Ltd Proceso para preparar fluoropolímeros y fluoroelastómeros en presencia de un hidrocarburo de tipo sulfonato no fluorado que contiene tensioactivo.
WO2021100835A1 (ja) 2019-11-19 2021-05-27 ダイキン工業株式会社 フルオロポリマーの製造方法
JP7352110B2 (ja) 2019-11-19 2023-09-28 ダイキン工業株式会社 フルオロポリマーの製造方法、ポリテトラフルオロエチレンの製造方法、パーフルオロエラストマーの製造方法および組成物
JP6989792B2 (ja) 2019-12-25 2022-01-12 ダイキン工業株式会社 フルオロポリマーの製造方法
KR20230009876A (ko) * 2020-05-14 2023-01-17 구자라트 플루오로케미칼스 리미티드 플루오르화 및 비-플루오르화 계면활성제의 조합을 사용한 플루오로단량체 중합 방법
ES3039143T3 (en) 2020-10-01 2025-10-17 Chemours Co Fc Llc Low reactivity hydrocarbon dispersing agents in the aqueous polymerization of fluoropolymers
JP7606110B2 (ja) 2020-11-19 2024-12-25 ダイキン工業株式会社 ポリテトラフルオロエチレンの製造方法およびポリテトラフルオロエチレンを含有する組成物
JPWO2022244784A1 (enExample) 2021-05-19 2022-11-24
WO2023277140A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 高純度フルオロポリマー含有組成物の製造方法および高純度フルオロポリマー含有組成物
WO2023277139A1 (ja) 2021-06-30 2023-01-05 ダイキン工業株式会社 フルオロポリマー組成物の製造方法およびフルオロポリマー組成物
EP4497762A1 (en) 2022-03-23 2025-01-29 Daikin Industries, Ltd. Method for producing fluoropolymer, and composition
CN119072500A (zh) 2022-04-28 2024-12-03 大金工业株式会社 含有氟树脂的组合物的制造方法和含有氟树脂的组合物
WO2023210819A1 (ja) 2022-04-28 2023-11-02 ダイキン工業株式会社 フルオロポリマーの製造方法
JP7492186B1 (ja) 2023-01-18 2024-05-29 ダイキン工業株式会社 電気化学デバイス用合剤、電気化学デバイス用合剤シート、電極、及び、電気化学デバイス
WO2024154773A1 (ja) 2023-01-18 2024-07-25 ダイキン工業株式会社 テトラフルオロエチレン系ポリマー組成物、電気化学デバイス用バインダー、電極合剤、電極、及び、二次電池
WO2024248144A1 (ja) 2023-05-31 2024-12-05 ダイキン工業株式会社 フルオロポリマー水性分散液の製造方法およびフルオロポリマー水性分散液
CN116854841A (zh) * 2023-07-31 2023-10-10 河南省氟基新材料科技有限公司 一种锂电级聚偏二氟乙烯粘结剂的制备方法
TW202528491A (zh) 2023-12-06 2025-07-16 美商科慕Ｆｃ有限責任公司 部分氟化芳基醚界面活性劑組成物及使用方法

Family Cites Families (60)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2559752A (en) * 1951-03-06 1951-07-10 Du Pont Aqueous colloidal dispersions of polymers
US2713593A (en) * 1953-12-21 1955-07-19 Minnesota Mining & Mfg Fluorocarbon acids and derivatives
US3271341A (en) * 1961-08-07 1966-09-06 Du Pont Aqueous colloidal dispersions of polymer
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3291843A (en) * 1963-10-08 1966-12-13 Du Pont Fluorinated vinyl ethers and their preparation
US3391099A (en) * 1966-04-25 1968-07-02 Du Pont Polymerization process
GB1292268A (en) 1970-02-16 1972-10-11 Bitterfeld Chemie Process for the dimerisation of hexafluoropropene epoxide
US3839425A (en) * 1970-09-16 1974-10-01 Du Pont Perfluoroalkyletheramidoalkyl betaines and sulfobetaines
US4036802A (en) * 1975-09-24 1977-07-19 E. I. Du Pont De Nemours And Company Tetrafluoroethylene copolymer fine powder resin
US4342675A (en) * 1978-06-16 1982-08-03 E. I. Du Pont De Nemours And Company Process for preparing aqueous dispersion of polytetrafluoroethylene
US4358545A (en) * 1980-06-11 1982-11-09 The Dow Chemical Company Sulfonic acid electrolytic cell having flourinated polymer membrane with hydration product less than 22,000
US4463144A (en) * 1980-09-10 1984-07-31 Asahi Glass Company Ltd. Process for producing propylene-tetrafluoroethylene copolymer
US4381384A (en) * 1981-08-17 1983-04-26 E. I. Du Pont De Nemours And Company Continuous polymerization process
US4380618A (en) * 1981-08-21 1983-04-19 E. I. Du Pont De Nemours And Company Batch polymerization process
US4552631A (en) * 1983-03-10 1985-11-12 E. I. Du Pont De Nemours And Company Reinforced membrane, electrochemical cell and electrolysis process
DE3486428T2 (de) 1983-12-26 1996-10-10 Daikin Ind Ltd Halogen enthaltendes Polyether
US4621116A (en) * 1984-12-07 1986-11-04 E. I. Du Pont De Nemours And Company Process for copolymerization of tetrafluoroethylene in the presence of a dispersing agent comprising a perfluoroalkoxybenzene sulfonic acid or salt
US4743658A (en) * 1985-10-21 1988-05-10 E. I. Du Pont De Nemours And Company Stable tetrafluoroethylene copolymers
IT1189092B (it) * 1986-04-29 1988-01-28 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri fluorurati
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
JP3275402B2 (ja) * 1992-12-02 2002-04-15 ダイキン工業株式会社 水性分散組成物およびその製法、ならびに撥水撥油剤および離型剤
US5285002A (en) * 1993-03-23 1994-02-08 Minnesota Mining And Manufacturing Company Fluorine-containing polymers and preparation and use thereof
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
JP3172983B2 (ja) * 1993-09-20 2001-06-04 ダイキン工業株式会社 ビニリデンフルオライド系重合体の水性分散液およびその製法
IT1270703B (it) * 1994-11-17 1997-05-07 Ausimont Spa Microemulsioni di fluoropoliossialchileni in miscela con idrocarburi, e loro uso in processi di (co)polimerizzazione di monomeri fluorurati
US5637748A (en) * 1995-03-01 1997-06-10 E. I. Du Pont De Nemours And Company Process for synthesizing fluorinated nitrile compounds
US5688884A (en) * 1995-08-31 1997-11-18 E. I. Du Pont De Nemours And Company Polymerization process
US5789508A (en) * 1995-08-31 1998-08-04 E. I. Du Pont De Nemours And Company Polymerization process
IT1295535B1 (it) * 1996-07-01 1999-05-12 Ausimont Spa Processo di polimerizzazione di vinilidenfluoruro (vdf)
US5763552A (en) * 1996-07-26 1998-06-09 E. I. Du Pont De Nemours And Company Hydrogen-containing flourosurfacant and its use in polymerization
US5866711A (en) * 1996-09-13 1999-02-02 E. I. Du Pont De Nemours And Company Fluorocyanate and fluorocarbamate monomers and polymers thereof
US5969067A (en) * 1996-09-13 1999-10-19 E.I. Dupont De Nemours And Company Phosphorus-containing fluoromonomers and polymers thereof
US6277485B1 (en) 1998-01-27 2001-08-21 3M Innovative Properties Company Antisoiling coatings for antireflective surfaces and methods of preparation
WO1999062999A1 (en) * 1998-05-29 1999-12-09 Daikin Industries, Ltd. Spherulite-micronizing agent for crystalline fluororesin and crystalline fluororesin composition containing the micronizing agent
US6395848B1 (en) * 1999-05-20 2002-05-28 E. I. Du Pont De Nemours And Company Polymerization of fluoromonomers
US6429258B1 (en) * 1999-05-20 2002-08-06 E. I. Du Pont De Nemours & Company Polymerization of fluoromonomers
US6482979B1 (en) 1999-12-22 2002-11-19 Dyneon Llc Perfluorinated acid fluorides and preparation thereof
US6613860B1 (en) 2000-10-12 2003-09-02 3M Innovative Properties Company Compositions comprising fluorinated polyether silanes for rendering substrates oil and water repellent
DE10106145A1 (de) * 2001-02-10 2002-08-22 Clariant Gmbh Verwendung von neuen Alkyl- und Arylalkoxylaten als Emulgatoren in der Emulsionspolymerisation
US7125941B2 (en) * 2001-03-26 2006-10-24 3M Innovative Properties Company Aqueous emulsion polymerization process for producing fluoropolymers
JP3900883B2 (ja) 2001-10-05 2007-04-04 ダイキン工業株式会社 含フッ素重合体ラテックスの製造方法
ITMI20020260A1 (it) 2002-02-12 2003-08-12 Ausimont Spa Dispersioni acquose di fluoropolimeri
US6841616B2 (en) * 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
US6869997B2 (en) * 2003-05-06 2005-03-22 Arkema, Inc. Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant
JP2004359870A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
JP2004358397A (ja) 2003-06-05 2004-12-24 Daikin Ind Ltd 界面活性剤、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
WO2005003075A1 (ja) 2003-07-02 2005-01-13 Daikin Industries, Ltd. フルオロアルキルカルボン酸誘導体、含フッ素重合体の製造方法及び含フッ素重合体水性分散液
US20050090613A1 (en) * 2003-10-22 2005-04-28 Daikin Industries, Ltd. Process for preparing fluorine-containing polymer latex
US7141537B2 (en) * 2003-10-30 2006-11-28 3M Innovative Properties Company Mixture of fluorinated polyethers and use thereof as surfactant
EP1533325B1 (en) * 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
ITMI20050007A1 (it) * 2005-01-05 2006-07-06 Solvay Solexis Spa Uso di dispersioni acquose di polimeri a base di vdf nella preparazione di vernici per rivestimenti di substrati architettonici
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0514387D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
US20070015937A1 (en) 2005-07-15 2007-01-18 3M Innovative Properties Company Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas
WO2007046345A1 (ja) 2005-10-17 2007-04-26 Asahi Glass Company, Limited ポリテトラフルオロエチレン水性乳化液、それから得られるポリテトラフルオロエチレンファインパウダーおよび多孔体
JP5141256B2 (ja) 2005-10-20 2013-02-13 旭硝子株式会社 ポリテトラフルオロエチレン水性分散液およびその製品
EP1939223B1 (en) 2005-10-20 2011-07-13 Asahi Glass Company, Limited Method for producing melt-moldable fluororesin
JP5343355B2 (ja) 2005-10-26 2013-11-13 旭硝子株式会社 含フッ素乳化剤の残留量が少ないフッ素樹脂およびその製造方法
JP5470044B2 (ja) * 2006-11-09 2014-04-16 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 高分子量フルオロポリエーテル酸または塩およびフルオロポリエーテル酸または塩界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合

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Publication number Publication date
JP2010509444A (ja) 2010-03-25
CN101605826A (zh) 2009-12-16
CN101605826B (zh) 2013-03-13
WO2008060463A1 (en) 2008-05-22
EP2084195B1 (en) 2011-06-08
EP2084195A1 (en) 2009-08-05
JP5439186B2 (ja) 2014-03-12
US20080114121A1 (en) 2008-05-15
US7897682B2 (en) 2011-03-01

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